CONFI

DENTI
AL*
(SULI
T*)
SET196
2/1

Cl
ass/Ti
ngkat
an :
……………… Name/Nama:………………………………………
I
dent
ityc
ardnumber:……………… Cent
renumber/i
ndexnumber:
…………….
.
..
.
..
.
..
.
..
.
.
(
Nomborkadpengenalan) (Nomborpus
at/angkagi
li
ran)

96
2/1 STPM 201
9

J
ABATANPELAJ
ARANNEGERIKELANTAN

MODULG-
CAKNA

CHEMI
STRY1201
9
SET1
Oneandah
alfh
our
s(Sat
ujams
eteng
ah)
SI
JILTI
NGGIPERSEKOLAHANMALAYSI
A Forex aminer‟
s
us
e
(
MALAYSI AHI
GHERSCHOOLCERTI
FICATE) (
Unt ukkegunaan
pemer i
ksa)
Instructionst ocandidates : Secti
onA
DONOTOPENTHI SQUESTI ONPAPERUNTI LYOUARE
TOLDTODOSO. Sect
ionB
Ther ear efifteenques t
ionsi nSec ti
onA. Foreachques t
ion,f ourc hoices Bah
( agianB)
ofans wersar egiven.Ch oos eonec orrectanswerandi ndicat eitont he 1
6
Mul tiple-ch
oi ceAns werSh eetpr ovi
ded.Readt hei nstructionsont he
Mul tiple-ch
oi ceAnswerSh eetverycarefull
y.Answeral lques tions
. Mar ks
willnotbededuc tedf orwr ongans wers. 1
7
Ans weral lques tionsi nSec ti
onB.Wr i
tey ourans wersi nt hes pac es Sect
ionC
prov i
ded.Ans weranyt woques ti
onsinSec ti
onC.Al les s entialwor king Bah
( agianC)
shoul dbes hown. Fornumer icalanswers,uni
ts h
ouldbequot edwh er ever
appr opr i
ate.
Begi neac hans weronaf r eshs heetofpaperandar rangey ourans wer sin
numer i
calor der.

Ans
wer
smaybewr
itt
eni
nei
therEngl
ishorBah
asaMal
ays
ia.
Tot
al
(
Juml
ah)

Ar
ahankepadac
alon
J
ANGANBUKAKERTASSOLANI
NISEHI
NGGAANDADI
BENARKANBERBUATDEMI
KIAN
Ada l ima bel as soalan dalam Bah agian A.Bagis etiap soalan,empatpi lihan jawapan
diberikan.Pili
hs atujawapany angbet uldant andakanj awapani tupadaBor angJ awapan
AnekaPi lihanyangdibekalkan.Bacaar ahanpadaBor angJawapanAnekaPi li
hani tudengan
telit
i.Jawabs emuas oalan.
Mar kaht idakakandi tol
akbagijawapany angsalah.
Jawabs emuas oalandalamBah agianB. Tulisj
awapanandadir uangyangdi
sediakan.
Jawabmana- manaduas oalandalam Bah agi
anC.Semuaj alankerjayangs esuaih endaklah
ditunjukkan.Bagij awapanber angka,uni thendaklahdinyatakandimana- manay angs esuai
.
Mul akans eti
apj awapanpadah elaianker tasjawapany angbah ar
udans usunj awapananda
mengi kutt ert
ib
berangka.

J
awapanbol
ehdi
tul
isdal
ambah
asaI
ngger
isat
auBah
asaMal
ays
ia.

1
CONFI
DENTI
AL*
(SULI
T*)
SET196
2/1

Sec
tionA[15mar
ks]
1 Twoat
omi
cpar
tic
lesPandQh
avethefol
lowi
ngcompos
iti
ons
:

P:
12pr
otons
,12neut
rons
,10el
ect
rons
Q:
12pr
otons,
12neut
rons,
12el
ect
rons

Wh
ichoft
hef
oll
owi
ngi
str
ue?

A PandQareis
omers.
B Pisani
onandQisanatom.
C PandQarebothi
ons.
D PandQareis
otopes
.

2 Thewavel
eng
thoft h
efi
rstl
inei
nth
eLy
mans
eri
esi
s
7 -
1
[RH=1.
097x1
0m ]

A 1.
22x10-7m
B 3.
42x10-8m
C 8.
1 0-6m
6x1
D 5.
1 0-7m
8x1

3 Wh
ichoft
hef
oll
owi
ngpar
tic
lesh
asonl
ypai
redel
ect
rons
?

A O-
B F
C Fe2+
D Zn

4 Whi
ch of th
efoll
owing statements ex
plai
ns wh
y al
umi
nium c
onduc
ts
el
ectr
ici
tywh
enapotent
ialdif
ferenc
eisappli
edt
oit?

A Al
umi
niumi
onsmov
etot
hepos
iti
vet
ermi
nal
B Th
ecrys
tallat
tic
ebr eaksdown.
C Th
eatomsofalumi ni
umbec omeions
.
D Th
ebondingel
ectronsinthecry
stall
att
icemov
e.

5 Whic
hoft
hef
oll
owi
ngs
ubs
tanc
esh
ast
hes
trong
esti
nter
mol
ecul
arf
orc
eini
tsl
iqui
d
st
ate?

A NH3
B CH4
C C2H5OH
D CO2

6 Wh
ichoft
hef
oll
owi
ngpai
rsofs
ubs
tanc
esh
ast
hes
ames
hape?

A CO2andSi
O2

2
CONFI
DENTI
AL*
(SULI
T*)
SET196
2/1

B BeH2andH2S
C BCl3andPCl
3
-
D CH4andAlCl
4

7 Calc
ulat
ethev
olume(incm3)occupi
edby0.
30gofag
as(
Mr=30)at308kPa
31Pam3mol-
1 -
and300K?[
R=8. K1]

A 48
B 69
C 81
D 120

8 A closedc ont
ainerc ontai
ns30% nitr
ogenand70% ox y
genbyv olumeatr oom
c
onditi
ons.250c m3 c
ar bondiox
ide( whic
hismeasuredatr oom condi
tions
)ar e
i
ntr
oducedintothecontainer.
Whichofthefol
lowi
ngs
tatement
siscorrect
?

A Thepartialpressureofnit r
og endecrease.
B Partoftheox yg
enr eactswi t
ht hecarbondioxi
de.
C Thepart
ialpressur
eofnitrogenandox y
g endec
reaseswh
ilet
hepar
tial
pr
essureofcarbondioxi
dei ncrease.
D Thepart
ialpressur
eofox y
g enr emai
nsthesame.

9 Th
ereac
tionbet
weenXO2andO3i
sgi
venbel
ow.

2XO2+O3→ X2O5 +O2

Whic
hoft hefoll
owi
ngismos tprobablyth
emec h
anis
mfort
her
eac
tioni
fth
e
reac
tioni
sfi
rstor
derwi
thr
espectt
obot hXO2andO3?

s
low

2XO2+O3 → X2O6 +O
f
ast
A
X2O6+O→ X2O5 +O2

s
lo
XO2+O3 →
w X3+O2
B f
ast
XO3+XO3→ X2O5 + 2O2

s
low
XO2+O3 → XO3+O2
C f
ast
XO3+XO2→ X2O5

s
low
XO2+O3 → XO3+O2
D f
ast
XO5+XO2→ X2O5 + O2

3
CONFI
DENTI
AL*
(SULI
T*)
SET196
2/1

1
0 Wh
ichoft
hef
oll
owi
ngi
scor
rec
treg
ardi
ngt
heh
alf
-l
if
eofaf
irs
tor
derr
eac
tion?

A Th
eh al
f-
lif
eisdependentonthepress
ure
B Th
eh al
f-
lif
edependentontheconcent
rati
onofthereact
ant
C Th
eh al
f-
lif
edecreaseswit
hdecreasi
ngtemperatur
e
D Th
eamountofs ubst
anceleftaf
teratimeint
ervaloff
ourhal
f-
li
fei
s6.
25%oft
he
or
igi
nalvalue

1
1 Wh
ichoft
hef
oll
owi
ngs
tat
ement
saboutc
atal
ysti
ninc
orr
ect
?

A Ac
atal
ystwi
llnotalt
erthecompos i
ti
onofanequi li
bri
ummi xt
ure.
B Ac
atal
ystmayformtemporarychemicalbondswiththereac
tants.
C Ac
atal
ystwi
llchang
et h
eratec ons
tantofar eac
tion.
D Ac
atal
ystwi
llchang
et h
epos i
ti
onofequi l
ibri
umofar evers
ibl
er eac
tion.

1
2 Th
ereac
tionf
ort
hepr
epar
ati
onofs
ulph
urt
riox
idei
ssh
ownbel
ow.

2SO2(
g)+O2(
g)↔ 2SO3(
g) ∆H=-
197kJ

Sul
phurdi
oxi
deandoxy
genar
epass
edoveraheatedvanadi
um (V)ox
idec
atal
yst
.
Whi
chofth
efoll
owi
ngmayi
ncr
eas
ethef
ormat
ionofsul
phurtr
iox
ide?

A Reductioninpr
essure
B Decreas ei
ntemperatur
e
C Additi
onofapr omotert
oth
ecatal
yst
D Inc
reasesinthevolumeoft
hecont
ainer

1
3 Whatisth
epHoft h
esolut
ionobt
ainedwhen300cm3of0.
2moldm-3s
ulph
uri
cac
idi
s
3 -
3
addedto200c
m of0.4moldm aqueouspot
assi
umh y
drox
ide?

A 1.
10
B 6.
88
C 9.
51
D 12.
60

1
4 Sil
versulphate,Ag2SO4ands tr
ont
ium sulph
ate,SrSO4areaddedt owat er
.Wh i
chof
thefol
lowingstatementsar
et rueregar
dingthesaturat
eds ol
uti
onobtained?
0-5mol3
dm-9andSr 0-7mol2
[Sol
ubili
typroduct,Ksp:Ag2SO4=1.
5x1 SO4=2.8x1 dm-6at
298K]

A SrSO4i
smor esolubl
ethanAg2S O4
B Thesulphat
eionsinthesaturateds olut
ioncomef r
omSr SO4
C Theconcentr
ationofth
es ul
ph ateionf r
omAg 2SO4canbeignored.
D Addit
ionofal i
ttl
esil
vernit
rat ewilldecreas
et hesol
ubili
tyofAg2SO4.

4
CONFI
DENTI
AL*
(SULI
T*)
SET196
2/1

1
5 Asolut
ionwhichc
ont
ainsM andN i
sanideals
olut
ion.Th
eph
asedi
agr
am oft
he
mi
xtureofM andNattemper
atur
eTisasf
oll
ows.

Wh
ichoft
hef
oll
owi
ngs
tat
ement
sist
rueoft
hes
olut
ionwh
ichc
ont
ainsM andN?

A Mix
t eyboi
ur l
sattemper atur
eT.
B Mix
t exi
ur saliqui
dat1 .
00atm.
C Mix
t ezex
ur is
tsasv apourat1.0at
m.
D Att
emper
atureT,thevapourcomposi
ti
onofmi
xt eyc
ur ont
ainsmor
eM.

5
CONFI
DENTI
AL*
(SULI
T*)
SET196
2/1

Sec
t i
onB (1
5mar ks
)
Answeral
lques
tions

1
6(a)Th
edi
agr
ambel
ows
howsf
ourt
rans
iti
onsofel
ect
roni
nth
ehy
drog
enat
om.

(i
)Sket
cht
helinespectr
umf or
medasaresul
tofth
esef
ourt
rans
iti
ons
.Iny
our
di
agr
am,
dr
awanar
rowtosh
owthedirec
tionofdecr
eas
ingwav
elengt
h. [2
marks
]

(i
i)Bas
edonth
ediag
ramabove,expl
ainwhyth
eemi
ssi
ons
pec
trumofh
ydr
ogen
atom
consi
stsofdisc
ret
eli
nesi
nst
eadofaconti
nuousspec
trum. [2
marks]

……………………………………………………………………………………………………………

…………………………………………………………………………………………………….
.
..
.
..
.
..
.
.

(b) (
i)Ex
plai
nth
eter
mcoor
dinat
ebond. [
1
mark]

……………………………………………………………………………………………………………

6
CONFI
DENTI
AL*
(SULI
T*)
SET196
2/1

……………………………………………………………………………………………………………

(
ii)Whenalumi
niumchl
ori
de,AlCl3,
iscool
edfromthev
apours t
ate,moleculeswith
t
wic
et h
ev alueoftherel
ativ
emolecularmas sofAlCl
3isf
ormed.Drawadi agram tos h
ow
t
hechemicalbondi
nginth
esemolecul
es.Labelthet
ypesofc
hemicalbondsinyourdiagram.
[2mar ks]

1
7 Sul phuri
caci
d,H2SO4,
ismanufact
uredbytheCont
actprocess.Oneoft
hei
mpor
tant
r
eac
tioninth
ispr
oces
si sasfoll
ows:
-
1
2SO2(g)+O2(
g)↔ 2SO3(
g):∆H=-
197kJmol

At1000K,equil
ibri
um wasach
ievedwhenth
epartialpres
suresofSO2 ,O2 andSO3
g
asesi
nthemi
xtur
ear e0.
456at
m,0.
180atmand0.
364at
mr espect
ivel
y.

(
a)Defi
nethet
ermpar
tialpr
ess
ure.
[1mark]

……………………………………………………………………………………………………………

……………………………………………………………………………………………………………

(
b)Wri
teanexpr
ess
ionf
ort
heequi
li
bri
umc
ons
tant
,Kp,
fort
her
eac
tioni
nter
mofpar
tial
pr
essur
es.

1mar
[ k]

.
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.
..
.

……………………………………………………………………………………………………………

(
c)Cal
culat
eth
eval
ueofKpat1
000K. [
2
marks
]

(
d)Ex
plai
nth
eef
fec
tont
hepos
iti
onofequi
li
bri
umi
f

(
I) Th
et ot
alpr
ess
ureoft
hes
yst
em i
sreduc
edt
o0.
850at
m, [
2
marks]

……………………………………………………………………………………………………………

……………………………………………………………………………………………………………

……………………………………………………………………………………………………….
.
..
.
..
.

(ii
) Hel
iumg
asi
saddedt
oth
emi
xtur
ebutt
het
otalpr
ess
urei
smai
ntai
ned
ati
tsori
ginalval
ue. [
2
marks
]

7
CONFI
DENTI
AL*
(SULI
T*)
SET196
2/1

……………………………………………………………………………………………………………

……………………………………………………………………………………………………………

……………………………………………………………………………………………………………

Sec
tionC[30mar
ks]

Ans
weranyt
woques
tionsi
nth
iss
ect
ion.

Youmayans
weral
lth
equest
ionsbut,onl
yth
efir
sttwoans
wer
swi
llbemar
ked.
Wr i
te
t
heanswersi
ntheans
wer
ssheetpr
ovided.Begi
neachans
weronanewpageoft
heanswer
s
heet
.

18(a) Ni
trog
enandph os
phorusar
ei nthesamegr
oupinthePer
iodi
cTabl
e.Nit
rog
encan
f
ormtheNCl 3 mol
ecul
eonly
,butph osph
oruscanfor
m bot
hthePCl3aswellasthePCl
5
mol
ecule.

(
i)Wri
tetheel
ect
roni
cconf
igur
ati
onoft
heni
trog
enandph
osph
orusat
oms
. [
2
marks
]

(
ii) Dr
awt
heLewi
sdi
agr
amf
orNCl
3andPCl
5andpr
edi
ctt
hei
rsh
apes
. [
4
mar
ks]

(
iii
) Bas
edonyouranswer
sto(a)and(b),expl
ainwh
yphosph
oruscanformthePCl
5
mol
ecul
e butnit
rog
enc anformthe PCl
5 molecul
e butnit
rogencannotfor
m t
he NCl
5
mol
ecul
e.
[4marks]

(
b) Us
ingt
heh
ybr
idi
zat
iont
heor
y,ex
plai
nth
efor
mat
ionoft
heCH3Cl
. 5mar
[ ks]

1
9( a) 2-
chl
oro-
2-methl
ypr
opanereactswit
haqueouss
odi
umh
ydr
oxi
det
opr
oduc
e2-
met
hyl
-
2-2pr
opanolacc
ordingtot
hefol
lowingequati
ons
;

(
CH3)
3CCI+NaOH→ (
CH3)
3C(OH)+NaCI

Inanexperiment,anexc
es sof2-
chloro-2-
methly
propaneismixedwi
th1
00cm3of0.
10moldm-
3
s
odium h
ydroxi
de.Thec oncent
rationoft hesodium hy
drox
ideremai
ningi
smeas ur
edat
regul
arint
ervals
.Thefoll
owingresultsareobtai
ned.

Ti
me/min [
NaOH]
/moldm-3
0 0.
100
20 0.
090
40 0.
080

8
CONFI
DENTI
AL*
(SULI
T*)
SET196
2/1

60 0.
070
80 0.
060

(i
)Pl
otas
uitabl
egr
apht
odet er
minet
heor
derofr
eac
tionwit
hres
pec
ttos odium
h
ydr
oxide and det
ermine t
he r
ate constant.
4mar
[ ks]

(
ii)
Expl
ainwh
yanex
ces
sof2-
chl
oro-
2-met
hly
propanei
sus
ed. [
2
mar
ks]

(i
ii
)Th
er eact
ionisknowntobef
irs
tor
derwi
thr
espec
tto2-
chl
oro-
2-met
hly
propane.
Sug
g es
tamec hani
smf ort
hereact
ion [3
marks]

(
b) (
i) Wh
ati
sac
atal
yst
? 2mar
[ ks]

(
ii) Wi
tht
heai
dofs
uit
abl
edi
agr
ams
,ex
plai
nhowac
atal
ystwor
ks. [
4
mar
ks]

20 (
a)Bact
eri
alferment
ationofl
actos
einmil
kproduc
esy og
hur
twh
ichc
ont
ainsl
act
icac
id,
amonopr
oti
cacid.
As ampleofayogh
urtdr
inkhasapH3.5
2.

(
i)Def
inepH. 1mar
[ k]

(
ii)Cal
cul
atet
hec
onc
ent
rat
ionofh
ydr
ogeni
onsi
nth
esampl
eoft
hey
ogh
urt
dr
ink.
[1mark]

(ii
i)25.00cm3oft heyoghur
tdri
nkrequires27.85cm3of0.
100moldm-3potas
sium
h
ydr
ox ide.Phenolpht
h al
einisusedasanindicatorforthi
stit
rati
on.Cal
cul
atet h
e
c
oncent r
ation,inmoldm-3oflac
ticaci
dinthey oghurtdri
nk.
2mar
[ ks]

(
iv)Ex
plai
nwh
yth
eval
uesobt
ainedi
n(i
i)and(
ii
i)ar
edi
ffer
ent
. [
2
mar
ks]

(v
)Cal
cul
atet
heac
iddi
ssoc
iat
ionc
ons
tant
,Kaoft
hel
act
icac
id. [
4
mar
ks]

(
b)Pr edi
ctwhatwillbeobs er
vedwh
enas
olut
ionofpot
ass
ium i
odi
dei
sshakenwit
h
s
oli
dsil
verc h
lor
ide.
[KspofAgCl=1.
2x1 0-10] 5mar
[ ks]