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Chemistry/ IG LIVE 19-20/ L1 Dr.

Kelvin Lau (抄襲翻印,必定追究)


Section 2 + 7 Microscopic World and Redox Reactions

Section 2: Microscopic World


Classification of Substances:

Section 2 + 7 / Microscopic World and Redox Reactions/ Dr. Kelvin Lau–Ph.D. (Pure Chemistry - HKU)/ All Right Reserved 1
All rights reserved by Beacon College Ltd except that all public exam questions, if any, are licensed by copyright owner HKEAA.
Chemistry/ IG LIVE 19-20/ L1 Dr. Kelvin Lau (抄襲翻印,必定追究)
Section 2 + 7 Microscopic World and Redox Reactions

第二章: 微觀世界
物質的分類:

Section 2 + 7 / Microscopic World and Redox Reactions/ Dr. Kelvin Lau–Ph.D. (Pure Chemistry - HKU)/ All Right Reserved 2
All rights reserved by Beacon College Ltd except that all public exam questions, if any, are licensed by copyright owner HKEAA.
Chemistry/ IG LIVE 19-20/ L1 Dr. Kelvin Lau (抄襲翻印,必定追究)
Section 2 + 7 Microscopic World and Redox Reactions
Compounds (化合物):
A substance formed by two or more kinds of elements chemically joined together.
由兩種或以上元素化合而成的物質。

Ionic Compound (離子化合物):

Covalent Compound (共價化合物):

Molecule (分子):

Section 2 + 7 / Microscopic World and Redox Reactions/ Dr. Kelvin Lau–Ph.D. (Pure Chemistry - HKU)/ All Right Reserved 3
All rights reserved by Beacon College Ltd except that all public exam questions, if any, are licensed by copyright owner HKEAA.
Chemistry/ IG LIVE 19-20/ L1 Dr. Kelvin Lau (抄襲翻印,必定追究)
Section 2 + 7 Microscopic World and Redox Reactions
1. Barium oxide (氧化鋇) - BaO

Classification(分類):

Description of bonding and structure(鍵合與結構的描述):

Electron diagram(電子結構圖):

Melting point/ boiling point (熔點/沸點):

Electrical Conductivity(導電性):

Section 2 + 7 / Microscopic World and Redox Reactions/ Dr. Kelvin Lau–Ph.D. (Pure Chemistry - HKU)/ All Right Reserved 4
All rights reserved by Beacon College Ltd except that all public exam questions, if any, are licensed by copyright owner HKEAA.
Chemistry/ IG LIVE 19-20/ L1 Dr. Kelvin Lau (抄襲翻印,必定追究)
Section 2 + 7 Microscopic World and Redox Reactions
2. Hydrogen selenide(硒化氫) – H2Se

Classification(分類):

Description of bonding and structure(鍵合與結構的描述):

Electron diagram(電子結構圖):

Melting point/ boiling point (熔點/沸點):

Electrical Conductivity(導電性):

Section 2 + 7 / Microscopic World and Redox Reactions/ Dr. Kelvin Lau–Ph.D. (Pure Chemistry - HKU)/ All Right Reserved 5
All rights reserved by Beacon College Ltd except that all public exam questions, if any, are licensed by copyright owner HKEAA.
Chemistry/ IG LIVE 19-20/ L1 Dr. Kelvin Lau (抄襲翻印,必定追究)
Section 2 + 7 Microscopic World and Redox Reactions
3. Strontium (鍶) - Sr

Classification(分類):

Description of bonding and structure(鍵合與結構的描述):

Electron diagram(電子結構圖):

Melting point/ boiling point (熔點/沸點):

Electrical Conductivity(導電性):

Section 2 + 7 / Microscopic World and Redox Reactions/ Dr. Kelvin Lau–Ph.D. (Pure Chemistry - HKU)/ All Right Reserved 6
All rights reserved by Beacon College Ltd except that all public exam questions, if any, are licensed by copyright owner HKEAA.
Chemistry/ IG LIVE 19-20/ L1 Dr. Kelvin Lau (抄襲翻印,必定追究)
Section 2 + 7 Microscopic World and Redox Reactions
4. Quartz (石英) – SiO2

Classification(分類):

Description of bonding and structure(鍵合與結構的描述):

Electron diagram(電子結構圖):

Melting point/ boiling point (熔點/沸點):

Electrical Conductivity(導電性):

Section 2 + 7 / Microscopic World and Redox Reactions/ Dr. Kelvin Lau–Ph.D. (Pure Chemistry - HKU)/ All Right Reserved 7
All rights reserved by Beacon College Ltd except that all public exam questions, if any, are licensed by copyright owner HKEAA.
Chemistry/ IG LIVE 19-20/ L1 Dr. Kelvin Lau (抄襲翻印,必定追究)
Section 2 + 7 Microscopic World and Redox Reactions
5. Ammonium iodide (碘化銨) – NH4I

Classification(分類):

Description of bonding and structure(鍵合與結構的描述):

Electron diagram(電子結構圖):

Melting point/ boiling point (熔點/沸點):

Electrical Conductivity(導電性):

Section 2 + 7 / Microscopic World and Redox Reactions/ Dr. Kelvin Lau–Ph.D. (Pure Chemistry - HKU)/ All Right Reserved 8
All rights reserved by Beacon College Ltd except that all public exam questions, if any, are licensed by copyright owner HKEAA.
Chemistry/ IG LIVE 19-20/ L1 Dr. Kelvin Lau (抄襲翻印,必定追究)
Section 2 + 7 Microscopic World and Redox Reactions
Other examples(其他例子):

Diamond (鑽石)

Titanium(鈦) - Ti

Arsine (胂) – AsH3

Potassium hydroxide(氫氧化鉀) – KOH

Silicon carbide (碳化硅) - SiC

Section 2 + 7 / Microscopic World and Redox Reactions/ Dr. Kelvin Lau–Ph.D. (Pure Chemistry - HKU)/ All Right Reserved 9
All rights reserved by Beacon College Ltd except that all public exam questions, if any, are licensed by copyright owner HKEAA.
Chemistry/ IG LIVE 19-20/ L1 Dr. Kelvin Lau (抄襲翻印,必定追究)
Section 2 + 7 Microscopic World and Redox Reactions

Section 7: Redox Reactions (氧化還原反應)

Section 2 + 7 / Microscopic World and Redox Reactions/ Dr. Kelvin Lau–Ph.D. (Pure Chemistry - HKU)/ All Right Reserved 10
All rights reserved by Beacon College Ltd except that all public exam questions, if any, are licensed by copyright owner HKEAA.
Chemistry/ IG LIVE 19-20/ L1 Dr. Kelvin Lau (抄襲翻印,必定追究)
Section 2 + 7 Microscopic World and Redox Reactions
Reduction of O.A. Oxidation of R.A.
(氧化劑的還原作用) (還原劑的氧化作用)
X- ➔ X2 (Cl-, Br-, I-)

SO32- ➔ SO42-
MnO4- ➔ Mn2+
Fe2+ ➔ Fe3+

M ➔ Mn+ (M = K-Ag)

X- ➔ X2 (Br-, I-)

SO32- ➔ SO42-
Cr2O72- ➔ Cr3+
Fe2+ ➔ Fe3+

M ➔ Mn+ (M = K-Ag)

SO32- ➔ SO42-

Cl2 ➔ Cl- Br2 ➔ Br- Fe2+ ➔ Fe3+

M ➔ Mn+ (M = K-Ag)

Fe3+ ➔ Fe2+ I- ➔ I2

Mm+ ➔ M
M ➔ Mn+
(Displacement reaction between metal
(Given that M is more reactive than M)
and metals and metal cations)
(M 較 M 活潑)
(金屬與金屬離子之間的置換反應)

X2 ➔ X -
Y- ➔ Y2
(Displacement reaction between halogen
(Given that X2 is more reactive than Y2)
and halide ions)
(X2 較 Y2 活潑)
(鹵素與鹵素離子之間的置換反應)

Section 2 + 7 / Microscopic World and Redox Reactions/ Dr. Kelvin Lau–Ph.D. (Pure Chemistry - HKU)/ All Right Reserved 11
All rights reserved by Beacon College Ltd except that all public exam questions, if any, are licensed by copyright owner HKEAA.
Chemistry/ IG LIVE 19-20/ L1 Dr. Kelvin Lau (抄襲翻印,必定追究)
Section 2 + 7 Microscopic World and Redox Reactions
Example 1:
Acidified potassium permanganate solution + sodium bromide solution
(酸化高錳酸鉀溶液 + 溴化鈉溶液)

Section 2 + 7 / Microscopic World and Redox Reactions/ Dr. Kelvin Lau–Ph.D. (Pure Chemistry - HKU)/ All Right Reserved 12
All rights reserved by Beacon College Ltd except that all public exam questions, if any, are licensed by copyright owner HKEAA.
Chemistry/ IG LIVE 19-20/ L1 Dr. Kelvin Lau (抄襲翻印,必定追究)
Section 2 + 7 Microscopic World and Redox Reactions
Method 1: By using ionic half equation
An acidic aqueous solutions contains H+(aq), and H2O (l), they are used for
balancing ionic half equations.

1. Balance the number of atoms with the change in oxidation number


2. Use H2O to balance the number of O atoms
3. Use H+ to balance the number of H atoms.
4. Use e- to balance the charges

方法 1:利用離子半反應式
酸性水溶液含有大量的 H+(aq)和 H2O(l)➔ 用作平衡離子半反應式。

1. 平衡涉及氧化數改變的原子數目
2. 利用 H2O 平衡 O 原子數目
3. 利用 H+平衡 H 原子數目
4. 利用 e-平衡電荷

Section 2 + 7 / Microscopic World and Redox Reactions/ Dr. Kelvin Lau–Ph.D. (Pure Chemistry - HKU)/ All Right Reserved 13
All rights reserved by Beacon College Ltd except that all public exam questions, if any, are licensed by copyright owner HKEAA.
Chemistry/ IG LIVE 19-20/ L1 Dr. Kelvin Lau (抄襲翻印,必定追究)
Section 2 + 7 Microscopic World and Redox Reactions
Method 2: By using oxidation number

1. Balance the number of atoms with the change in oxidation number


2. Count the changes in O.N.
3. Multiply the stoichiometric coefficients to balance the changes in O.N.
4. Use H2O to balance the number of O atoms
5. Use H+ to balance the number of H atoms.

方法 2:利用氧化數

6. 平衡涉及氧化數改變的原子數目
7. 數氧化數改變值
8. 把化學計量系數倍大,以平衡氧化數的改變。
9. 利用 H2O 平衡 O 原子數目
10.利用 H+平衡 H 原子數目

Section 2 + 7 / Microscopic World and Redox Reactions/ Dr. Kelvin Lau–Ph.D. (Pure Chemistry - HKU)/ All Right Reserved 14
All rights reserved by Beacon College Ltd except that all public exam questions, if any, are licensed by copyright owner HKEAA.
Chemistry/ IG LIVE 19-20/ L1 Dr. Kelvin Lau (抄襲翻印,必定追究)
Section 2 + 7 Microscopic World and Redox Reactions
Example 2:
Sodium iodide solution + chlorine water
(碘化鈉溶液 + 氯水)

Section 2 + 7 / Microscopic World and Redox Reactions/ Dr. Kelvin Lau–Ph.D. (Pure Chemistry - HKU)/ All Right Reserved 15
All rights reserved by Beacon College Ltd except that all public exam questions, if any, are licensed by copyright owner HKEAA.
Chemistry/ IG LIVE 19-20/ L1 Dr. Kelvin Lau (抄襲翻印,必定追究)
Section 2 + 7 Microscopic World and Redox Reactions
Example 3:
Zinc + acidified potassium dichromate solution
(鋅 + 酸化重鉻酸鉀溶液)

Section 2 + 7 / Microscopic World and Redox Reactions/ Dr. Kelvin Lau–Ph.D. (Pure Chemistry - HKU)/ All Right Reserved 16
All rights reserved by Beacon College Ltd except that all public exam questions, if any, are licensed by copyright owner HKEAA.
Chemistry/ IG LIVE 19-20/ L1 Dr. Kelvin Lau (抄襲翻印,必定追究)
Section 2 + 7 Microscopic World and Redox Reactions
Example 4:
Copper and acidified hydrogen peroxide solution
(銅和酸化過氧化氫溶液)

Hint: A blue solution is formed.


(提示: 有藍色溶液生成。)

Section 2 + 7 / Microscopic World and Redox Reactions/ Dr. Kelvin Lau–Ph.D. (Pure Chemistry - HKU)/ All Right Reserved 17
All rights reserved by Beacon College Ltd except that all public exam questions, if any, are licensed by copyright owner HKEAA.
Chemistry/ IG LIVE 19-20/ L1 Dr. Kelvin Lau (抄襲翻印,必定追究)
Section 2 + 7 Microscopic World and Redox Reactions
Example 5:
Sodium thiosulphate solution + hydrochloric acid
(硫代硫酸鈉溶液 + 氫氯酸)

Hint: A yellow solid was formed. A colorless gas with choking smell evolved.
(提示: 有黃色固體生成。有無色的窒息性氣體釋出。)

Section 2 + 7 / Microscopic World and Redox Reactions/ Dr. Kelvin Lau–Ph.D. (Pure Chemistry - HKU)/ All Right Reserved 18
All rights reserved by Beacon College Ltd except that all public exam questions, if any, are licensed by copyright owner HKEAA.

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