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Section 2 + 7 / Microscopic World and Redox Reactions/ Dr. Kelvin Lau–Ph.D. (Pure Chemistry - HKU)/ All Right Reserved 1
All rights reserved by Beacon College Ltd except that all public exam questions, if any, are licensed by copyright owner HKEAA.
Chemistry/ IG LIVE 19-20/ L1 Dr. Kelvin Lau (抄襲翻印,必定追究)
Section 2 + 7 Microscopic World and Redox Reactions
第二章: 微觀世界
物質的分類:
Section 2 + 7 / Microscopic World and Redox Reactions/ Dr. Kelvin Lau–Ph.D. (Pure Chemistry - HKU)/ All Right Reserved 2
All rights reserved by Beacon College Ltd except that all public exam questions, if any, are licensed by copyright owner HKEAA.
Chemistry/ IG LIVE 19-20/ L1 Dr. Kelvin Lau (抄襲翻印,必定追究)
Section 2 + 7 Microscopic World and Redox Reactions
Compounds (化合物):
A substance formed by two or more kinds of elements chemically joined together.
由兩種或以上元素化合而成的物質。
Molecule (分子):
Section 2 + 7 / Microscopic World and Redox Reactions/ Dr. Kelvin Lau–Ph.D. (Pure Chemistry - HKU)/ All Right Reserved 3
All rights reserved by Beacon College Ltd except that all public exam questions, if any, are licensed by copyright owner HKEAA.
Chemistry/ IG LIVE 19-20/ L1 Dr. Kelvin Lau (抄襲翻印,必定追究)
Section 2 + 7 Microscopic World and Redox Reactions
1. Barium oxide (氧化鋇) - BaO
Classification(分類):
Electron diagram(電子結構圖):
Electrical Conductivity(導電性):
Section 2 + 7 / Microscopic World and Redox Reactions/ Dr. Kelvin Lau–Ph.D. (Pure Chemistry - HKU)/ All Right Reserved 4
All rights reserved by Beacon College Ltd except that all public exam questions, if any, are licensed by copyright owner HKEAA.
Chemistry/ IG LIVE 19-20/ L1 Dr. Kelvin Lau (抄襲翻印,必定追究)
Section 2 + 7 Microscopic World and Redox Reactions
2. Hydrogen selenide(硒化氫) – H2Se
Classification(分類):
Electron diagram(電子結構圖):
Electrical Conductivity(導電性):
Section 2 + 7 / Microscopic World and Redox Reactions/ Dr. Kelvin Lau–Ph.D. (Pure Chemistry - HKU)/ All Right Reserved 5
All rights reserved by Beacon College Ltd except that all public exam questions, if any, are licensed by copyright owner HKEAA.
Chemistry/ IG LIVE 19-20/ L1 Dr. Kelvin Lau (抄襲翻印,必定追究)
Section 2 + 7 Microscopic World and Redox Reactions
3. Strontium (鍶) - Sr
Classification(分類):
Electron diagram(電子結構圖):
Electrical Conductivity(導電性):
Section 2 + 7 / Microscopic World and Redox Reactions/ Dr. Kelvin Lau–Ph.D. (Pure Chemistry - HKU)/ All Right Reserved 6
All rights reserved by Beacon College Ltd except that all public exam questions, if any, are licensed by copyright owner HKEAA.
Chemistry/ IG LIVE 19-20/ L1 Dr. Kelvin Lau (抄襲翻印,必定追究)
Section 2 + 7 Microscopic World and Redox Reactions
4. Quartz (石英) – SiO2
Classification(分類):
Electron diagram(電子結構圖):
Electrical Conductivity(導電性):
Section 2 + 7 / Microscopic World and Redox Reactions/ Dr. Kelvin Lau–Ph.D. (Pure Chemistry - HKU)/ All Right Reserved 7
All rights reserved by Beacon College Ltd except that all public exam questions, if any, are licensed by copyright owner HKEAA.
Chemistry/ IG LIVE 19-20/ L1 Dr. Kelvin Lau (抄襲翻印,必定追究)
Section 2 + 7 Microscopic World and Redox Reactions
5. Ammonium iodide (碘化銨) – NH4I
Classification(分類):
Electron diagram(電子結構圖):
Electrical Conductivity(導電性):
Section 2 + 7 / Microscopic World and Redox Reactions/ Dr. Kelvin Lau–Ph.D. (Pure Chemistry - HKU)/ All Right Reserved 8
All rights reserved by Beacon College Ltd except that all public exam questions, if any, are licensed by copyright owner HKEAA.
Chemistry/ IG LIVE 19-20/ L1 Dr. Kelvin Lau (抄襲翻印,必定追究)
Section 2 + 7 Microscopic World and Redox Reactions
Other examples(其他例子):
Diamond (鑽石)
Titanium(鈦) - Ti
Section 2 + 7 / Microscopic World and Redox Reactions/ Dr. Kelvin Lau–Ph.D. (Pure Chemistry - HKU)/ All Right Reserved 9
All rights reserved by Beacon College Ltd except that all public exam questions, if any, are licensed by copyright owner HKEAA.
Chemistry/ IG LIVE 19-20/ L1 Dr. Kelvin Lau (抄襲翻印,必定追究)
Section 2 + 7 Microscopic World and Redox Reactions
Section 2 + 7 / Microscopic World and Redox Reactions/ Dr. Kelvin Lau–Ph.D. (Pure Chemistry - HKU)/ All Right Reserved 10
All rights reserved by Beacon College Ltd except that all public exam questions, if any, are licensed by copyright owner HKEAA.
Chemistry/ IG LIVE 19-20/ L1 Dr. Kelvin Lau (抄襲翻印,必定追究)
Section 2 + 7 Microscopic World and Redox Reactions
Reduction of O.A. Oxidation of R.A.
(氧化劑的還原作用) (還原劑的氧化作用)
X- ➔ X2 (Cl-, Br-, I-)
SO32- ➔ SO42-
MnO4- ➔ Mn2+
Fe2+ ➔ Fe3+
M ➔ Mn+ (M = K-Ag)
X- ➔ X2 (Br-, I-)
SO32- ➔ SO42-
Cr2O72- ➔ Cr3+
Fe2+ ➔ Fe3+
M ➔ Mn+ (M = K-Ag)
SO32- ➔ SO42-
M ➔ Mn+ (M = K-Ag)
Fe3+ ➔ Fe2+ I- ➔ I2
Mm+ ➔ M
M ➔ Mn+
(Displacement reaction between metal
(Given that M is more reactive than M)
and metals and metal cations)
(M 較 M 活潑)
(金屬與金屬離子之間的置換反應)
X2 ➔ X -
Y- ➔ Y2
(Displacement reaction between halogen
(Given that X2 is more reactive than Y2)
and halide ions)
(X2 較 Y2 活潑)
(鹵素與鹵素離子之間的置換反應)
Section 2 + 7 / Microscopic World and Redox Reactions/ Dr. Kelvin Lau–Ph.D. (Pure Chemistry - HKU)/ All Right Reserved 11
All rights reserved by Beacon College Ltd except that all public exam questions, if any, are licensed by copyright owner HKEAA.
Chemistry/ IG LIVE 19-20/ L1 Dr. Kelvin Lau (抄襲翻印,必定追究)
Section 2 + 7 Microscopic World and Redox Reactions
Example 1:
Acidified potassium permanganate solution + sodium bromide solution
(酸化高錳酸鉀溶液 + 溴化鈉溶液)
Section 2 + 7 / Microscopic World and Redox Reactions/ Dr. Kelvin Lau–Ph.D. (Pure Chemistry - HKU)/ All Right Reserved 12
All rights reserved by Beacon College Ltd except that all public exam questions, if any, are licensed by copyright owner HKEAA.
Chemistry/ IG LIVE 19-20/ L1 Dr. Kelvin Lau (抄襲翻印,必定追究)
Section 2 + 7 Microscopic World and Redox Reactions
Method 1: By using ionic half equation
An acidic aqueous solutions contains H+(aq), and H2O (l), they are used for
balancing ionic half equations.
方法 1:利用離子半反應式
酸性水溶液含有大量的 H+(aq)和 H2O(l)➔ 用作平衡離子半反應式。
1. 平衡涉及氧化數改變的原子數目
2. 利用 H2O 平衡 O 原子數目
3. 利用 H+平衡 H 原子數目
4. 利用 e-平衡電荷
Section 2 + 7 / Microscopic World and Redox Reactions/ Dr. Kelvin Lau–Ph.D. (Pure Chemistry - HKU)/ All Right Reserved 13
All rights reserved by Beacon College Ltd except that all public exam questions, if any, are licensed by copyright owner HKEAA.
Chemistry/ IG LIVE 19-20/ L1 Dr. Kelvin Lau (抄襲翻印,必定追究)
Section 2 + 7 Microscopic World and Redox Reactions
Method 2: By using oxidation number
方法 2:利用氧化數
6. 平衡涉及氧化數改變的原子數目
7. 數氧化數改變值
8. 把化學計量系數倍大,以平衡氧化數的改變。
9. 利用 H2O 平衡 O 原子數目
10.利用 H+平衡 H 原子數目
Section 2 + 7 / Microscopic World and Redox Reactions/ Dr. Kelvin Lau–Ph.D. (Pure Chemistry - HKU)/ All Right Reserved 14
All rights reserved by Beacon College Ltd except that all public exam questions, if any, are licensed by copyright owner HKEAA.
Chemistry/ IG LIVE 19-20/ L1 Dr. Kelvin Lau (抄襲翻印,必定追究)
Section 2 + 7 Microscopic World and Redox Reactions
Example 2:
Sodium iodide solution + chlorine water
(碘化鈉溶液 + 氯水)
Section 2 + 7 / Microscopic World and Redox Reactions/ Dr. Kelvin Lau–Ph.D. (Pure Chemistry - HKU)/ All Right Reserved 15
All rights reserved by Beacon College Ltd except that all public exam questions, if any, are licensed by copyright owner HKEAA.
Chemistry/ IG LIVE 19-20/ L1 Dr. Kelvin Lau (抄襲翻印,必定追究)
Section 2 + 7 Microscopic World and Redox Reactions
Example 3:
Zinc + acidified potassium dichromate solution
(鋅 + 酸化重鉻酸鉀溶液)
Section 2 + 7 / Microscopic World and Redox Reactions/ Dr. Kelvin Lau–Ph.D. (Pure Chemistry - HKU)/ All Right Reserved 16
All rights reserved by Beacon College Ltd except that all public exam questions, if any, are licensed by copyright owner HKEAA.
Chemistry/ IG LIVE 19-20/ L1 Dr. Kelvin Lau (抄襲翻印,必定追究)
Section 2 + 7 Microscopic World and Redox Reactions
Example 4:
Copper and acidified hydrogen peroxide solution
(銅和酸化過氧化氫溶液)
Section 2 + 7 / Microscopic World and Redox Reactions/ Dr. Kelvin Lau–Ph.D. (Pure Chemistry - HKU)/ All Right Reserved 17
All rights reserved by Beacon College Ltd except that all public exam questions, if any, are licensed by copyright owner HKEAA.
Chemistry/ IG LIVE 19-20/ L1 Dr. Kelvin Lau (抄襲翻印,必定追究)
Section 2 + 7 Microscopic World and Redox Reactions
Example 5:
Sodium thiosulphate solution + hydrochloric acid
(硫代硫酸鈉溶液 + 氫氯酸)
Hint: A yellow solid was formed. A colorless gas with choking smell evolved.
(提示: 有黃色固體生成。有無色的窒息性氣體釋出。)
Section 2 + 7 / Microscopic World and Redox Reactions/ Dr. Kelvin Lau–Ph.D. (Pure Chemistry - HKU)/ All Right Reserved 18
All rights reserved by Beacon College Ltd except that all public exam questions, if any, are licensed by copyright owner HKEAA.