ESTIMATION OF CONVECTIVE MASS TRANSFER IN SOLAR
DISTILLATION SYSTEMS,
SANJAY KUMAR and G. N. TIWARI"
Centre of Energy Studies, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110016, India
(Received 28 August 1995; revised version accepted 4 July 1936)
(Communicated by Peter Cooper)
‘Absfract—In this article # Ubermal model has been developed to determine the convective mass transfer
for different Grashof Number range in solar distillation process, The model is based on simple regression
analysis. Based on the experimental data obtained from the rigorous outdoor experimentation on
ppassive and active distilation systems for summer climatic conditions, the values of C and 1 have
bbeen calculated. The modified values of C and n for Nu=C(GrPri’, ate proposed as C=0.0322,
na04ll4 for 1.794x10° 3.2 x 10°, However, this relation
has the following limitations. (i) It is only valid
for a mean operating temperature range of
120°F (50°C) and equivalent temperature
difference of 30°F (approx. ~1°C) (Baum
and Bairamov, 1964; Cooper, 1970, 1973;
Rheinlander, 1982). (ii) It is independent of
cavity volume, ie, the average distance between
the condensing and evaporating surfaces. (iii)
It holds good for heat flow upwards in horizon-
tally enclosed air space Jakob, 1949; Cooper,
1970).
Clark also developed a model for a higher-
‘operating temperature range (255°C) in simu-
lated conditions for small inclination of the
condensing surface (Clark, 1990). He found
that values of coefficients for convective mass
transfer reduce to half that of Dunkle. This is
based on the fact that the rate of evaporation
is equal to the rate of condensation in an ideal
condition. This condition is achieved by using
a fan across the condensing cover which is not
a practicable solution for solar distillation
systems, operating in the field conditions. Later,
‘Tiwari and Lawrence (1991) attempted to incor-
porate the effect of inclination of the condensing
surface taking the same values of C and n as
proposed by Dunkle, Further, Adhikari er al
(1990, 1991, 1995) tried to modify the values,
of these coefficients in simulated conditions.
Here, the authors have presented the modified
values of C and » obtained from the outdoor
experimental data. This model has been devel-
oped by using simple regression analysis. These
values of Cand m have again been used to find
the theoretical distillate output. It is observed
that there is a reasonable agreement within an
accuracy of 12% between experimental observa-
tions and theoretical results calculated by modi-
fied values of C and » for summer climatic
conditions.
2, THERMAL MODEL
Heat transfer occurs across the humid ait
inside the enclosure of the distillation unit by
free convection which is caused by the action
of buoyancy force caused by density variation
in the humid air. Density variation is caused by
a temperature gradient in the finid. Hence, the
rate of heat transfer from the water surface to
the glass cover (qa.) by convection can be
estimated by
Gow = hed Tw = Ts) ay
459490
where Ay is found from the relation
Nun“ Gr Pye 2)
ke
where
HagX
Grn SBA 8)
e
wG
Pr he @
and
arar.-ny+| a
268.9x10°—P,
6)
(Malik er ai, 1982).
Ti is seen from eqn (2) that the value of hoy
depends upon the values of two constants,
namely Cand n. Iris observed from the different
values of C and » for a particular range of
Grashof Number given by various authors that
the percentage deviation between the theoretical
and experimental distillate output remains
within a reasonable percentage of accuracy for
indoor simulated conditions only, whereas for
‘outdoor conditions the deviation increases sig-
nificantly, Hence, there is a need to modify the
values of C and » in eqn (2). The modification
for values of C and n has been carried out by
regression analysis using experimental distillate
output (44), basin water temperature (T,,) and
glass temperature (T,).
Evaporative heat transfer rate (g.) is given
by
uw =0.016273(Py— Py) fey (6)
(Malik et af., 1982). Using eqn (2), eqn (6) can
be rewritten as
ou =0.016273(Py— Py): (keldy)- C(Ray*
a)
where Ra=Gr-Pr. Also,
Gon * 3600
a
eqn (8) can be rewritten using eqn (7)
My, =0.01627H( Py — Pg) (kg/d): (3600/L)
“C(Ray
Therefore
My: (8)
o
M/R=C(Rayt (10)
S. Kumar and G. N. Tiwari
where
R= 0.16273(Py,— Py) (kei) (3600/2)
ay
For field conditions, the values of Ty and 7,
vary significantly because of variations in
climatic conditions and correspondingly At,
and Ra also vary.
3, EXPERIMENTAL SET UP,
OBSERVATIONS AND UNCERTAINTY
3.1. Experimental set up and observations
A cross-sectional view of a single slope pas-
sive solar still made of fibre-reinforced plastic
(FRP) is shown in Fig. 1(a). The bottom sur-
face of the still was painted black by mixing a
special black dye with resin for better absorptiv-
ity. A window glass of 3mm thickness was
placed at an inclination (f) of 15° over the
FRP still Figure 1(b) shows the schematic dia-
gram of an active solar still coupled with a flat
plate collector (FPC). The area of the still and
FPC was taken as I and 2 m? respectively. The
collector was kept inclined at an angle of 45”
to the horizontal. The hot water from the
collector was pumped into the still basin to
raise the evaporative surface temperature. The
pump was kept in the “off” position during
non-sunshine hours to avoid heat losses caused
by reverse flow,
‘To perform the experiment with a minimum
storage effect, the basin of the solar still was
filled with 2em of water. The average spacing
(dj) between the water surface and the glass
cover was kept as 0.155 m. The outputs from
the passive and active stills were measured every
hour during daylight for 30 days in the months
of May and June, 1995. The outputs during
non-sunshine hours were collected daily in the
morning before the commencement of the
‘experiment. It was observed that only 510%
yields were obtained during non-sunshine hours
for both the passive and the active distillation
systems. This justifies the minimum heat storage
capacity in the basin water. The experiment was
conducted at IIT Delhi. In the active solar
distillation system, the water flow over the glass.
cover was kept uniform and constant with the
help of a regulator and a constant-head tank
provided at the height of about 1 m from the
level of the still, The water and glass temper-
atures were measured with calibrated cop-
per-constantan thermocouples and a digitalEstimation of convective mass transfer in solar distillation systems “1
@)
TOP VIEW. GLASS COVER —_ RUBBER GASKET.
DISTILLATE,
DRAIN NIPPLE SECTION Y-Y SECTION X-X
(ey
FLOAT VALVE,
overr.ow
SOLAR RADIATION = @
[14 powers @=
MAIN TANK.
rrowine water" = INLET
vi
GLASS COVER pis tiLLaTE OUTPUT AUXILIARY TANK.
(OVER FLOW OUTLET > (CHANNEL
{-FRP SOLAR STILL.
SOLAR
RADIATION SS BASIN LINER
Fnvxrriate
COLLECTOR INSULATED PIPE
Fig. 1. (2) Cross-sectional view of a single slope passive solar still. (b) Single slope active soler still coupled with FPC.462
8, Kumar and G. N. Tiwari
‘Table 1. Experimental observations of a typical day for a single slope passive solar still
Seri Time Water Glass Ambient Distillate
(hy) temp. CC) temp. CC) temp. CC) output (ml)
1 1000 458 408 8 130)
2 100 508 4S » 22
a 1200 556 an 2 360
4 1300 46 473 25 320
3 1490 523 455 2 Bs
6 $300 eB at ais 200
7 1600 4 366 a 100
‘Table 2. Experimental observations of a typical day for a single slope active solar still
Seria no. Gus Ambient Distt
(hy temp. (CC) temp. °C) output (ml).
' 100 a8 375 8 a0
2 Wo 38 423 4 330
3 108 462 45 310
4 300 $97 463 4% 970
8 1400586 aa ps oo
é 1300568 435 4“ 710
7 1600581 389 a 650
meter. Experimental observations for a typical % error=
hot day for both cases, ic. passive and active
stills, are shown in Tables I and 2, respectively.
3.2. Experimental uncertainty
The experimental method used is an indirect
approach for estimating the convective heat
transfer coefficient based on the mass of distil-
late collected from the still. This indireet method
will certainly have a considerable degree of
experimental uncertainty in the estimation of
convective heat transfer coefficients. An esti-
mate of internal and external uncertainty
(Nakra and Choudhary, 1985) has been carried
‘out separately for passive and active solar stills.
For this, data of a particular measurement for
a umber of days have been taken and an
estimate of individual uncertainties of the
sample values has becn calculated by taking the
square root of the sum of each sample standard
deviation divided by the square root of the
‘umber of samples. Estimate of internal uncer-
tainty (Up:
lott ort
NE
(Nakra and Choudhary, 1985). The total uncer-
tainty (internal and external) for passive and
active stills has been calculated as 25 and 19%,
respectively.
‘Also, the results will be influenced by a ther-
mal storage effect. The percentage error caused
by thermal storage can be calculated as follows:
us. 2)
distillate output during non-sunshine hours
distillate output during daylight hours
x 100
‘The errors for passive and active stills have
been estimated as 8 and 5%, respectively.
4. RESULTS AND DISCUSSION
Software has been developed to calculate the
values of C and n based on the experimental
data, namely basin water temperature, glass
temperature and distillate output, It is observed
that when the solar intensity is quite low,
7-9a.m., the output is reduced and there are
ficulties in accurately measuring outputs of
the order of 10-15 ml. This low distillate output
also causes inconsistency in the computation of
Cand n. Therefore, certain observations in the
morning and in the evening when distillate
‘output was found to be extremely low have not
been taken into account. It is interesting to note
that we get very consistent values of C= 0.0322
and n=0.411 for each set of six or more num-
bers of observations for the Grashof range of
1.794 x 10° to 5.724 x 10” in the case of a pa:
solar still and C=0.0538 and n=0.383 for a
Grashof range of 5.498 x 10 to 9.128 x L0° in
the case of an active solar still, Tables 3 and 4
show the computed values of convective heat
transfer coefficients (gy), evaporative heat
transfer coefficients (h,..), evaporative transferEstimation of convective mass transfer in solar distillation systems
463
‘Table 3. Computed values of hey. Hewy dee and present deviation between experimental and theoretical distillate output for
‘iodified values of C and m for 2 passive solar still
Peroent
deviation
Serial Experimental Theoretical etween
wo. ‘istlate dstilate ey sh Que exp. and theoretical
output (ml) ‘output (ml) (Wink) (Win?K) (Wim?) output
i 150 7 236 169 45 =r}
2 232 24 248 27 15436 t
3 360 336 296 ost 35325 12
4 30 a2 28 381 2os07 53
3 285, 382 26 ne 1664 5
é 20 ie 259 217 tas
7 100 ” 235 iat 50.28
Modified values of C=0,0322; n=0.4114, Grashot Range: 1.794% 10" 10%