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Published in Fizika Goreniya i Vzryva, Vol. 52, No. 1, pp. 52–59, January–February, 2016.
Original article submitted January 21, 2015; revision submitted March 18, 2015.
Abstract: The problem of the combustion of a methane–air mixture in a slot burner with adiabatic
outer walls is solved. The problem is investigated numerically in a one-dimensional formulation
and dimensional variables. The range of existence of stable high-temperature combustion of the
methane–air mixture is determined as a function of gas flow rate and methane content in the mix-
ture. The mechanism of failure of stable combustion is determined. The effect of heat transfer of
the gas insert with an inner insert on combustion stability is shown.
Keywords: slot burner, methane–air mixture, inner insert, thermal expansion, stable combus-
tion.
DOI: 10.1134/S0010508216010068
tion of the mixture; the temperature in the transverse The boundary conditions are
direction of the inner insert is considered to be uniform; ∂T (2L, t)
the burner pressure is constant. T (0, t) = Tv , = 0,
∂x
In view of the assumptions made, the mathematical
∂a(2L, t)
formulation of the problem has the following form. The a(0, t) = av , = 0,
energy equation for the reaction mixture is given by ∂x
(7)
∂T1 (0, t) ∂T1 (L, t)
∂T ∂T ∂ ∂T α = = 0,
cρ + cρu = λ + (T1,S − T ) ∂x ∂x
∂t ∂x ∂x ∂x h pμ
ρ(0, t) = , u(0, t) = uv .
E RT (0, t)
+ ρQak0 exp − , 0 x 2L, (1)
RT The following notation is used: t is time, x is the
coordinate in the longitudinal direction, T is the tem-
T1 (x, t), x < L, perature, a is the mass concentration of methane in the
T1,S (x, t) =
T1 (2L − x, t), x L; mixture, ρ is the density, p is the pressure, c is the spe-
cific heat, u is the flow velocity of the mixture, D is the
the energy equation for the insert is diffusion coefficient, λ is the thermal conductivity, α is
∂T1 ∂ 2 T1 α the heat transfer coefficient, R is the universal gas con-
c 1 ρ1 = λ1 − (T1 − T (x, t))
∂t ∂x2 h1 stant, k0 is the pre-exponential factor in the Arrhenius
α law, E is the activation energy, Q is the heat of reac-
− (T1 − T (2L − x, t)), 0 x L; (2) tion, h is the height of the section of the slot burner,
h1
μ is the molar weight of the gas, ξ is the boundary of
the mass balance equation of the combustible compo- the preheated region of the insert, L is the length of the
nent in the mixture is insert, and Tw and T1w are the maximum temperatures
∂a ∂a ∂ ∂a of the initial heating of the mixture and the inner in-
ρ + ρu = Dρ
∂t ∂x ∂x ∂x sert, respectively. The subscripts 1 and v denote the
parameters of the inner insert and the parameters at
E
− ρak0 exp − , 0 x 2L; (3) the burner inlet.
RT The initial conditions for the combustion problem
the ideal gas equation is can generally introduce non-uniqueness into the solu-
ρ tion. For example, in studies [4, 18] for a chemical re-
p = RT = const; (4) actor with an inert inset, it has been shown that the
μ
combustion mode being established depends on the ini-
the continuity equation is
tial conditions and non-uniqueness regions for this mode
∂ρ ∂(ρu) have been determined in the case where the character-
+ = 0. (5)
∂t ∂x istics of the state being established depend on the ini-
The initial conditions are tial temperature of the gas. It has been demonstrated
⎧ [13, 15] that stable combustion of a gas mixture in a
⎪
⎪ Tv , x ξ,
⎪
⎪ U-shaped channel can be achieved in the case of com-
⎪
⎨ x−ξ
Tv + Tw , ξ < x L, bustion initiation by a preheated inner wall. In the
T (x, 0) =
⎪ L −ξ present study, the effect of the initial conditions on the
⎪
⎪
⎪
⎩ Tv + Tw 2L − x , L < x 2L,
⎪ combustion mode being established is not considered as
L the main objective was to investigate the conditions of
⎧ (6) the maintenance of combustion. The initial conditions
⎪ av , x ξ,
⎪
⎪ given by Eqs. (6) imply that prior to the process, the
⎨ L−x burner is filled with heated gas, whose density is deter-
a(x, 0) = av , ξ < x L,
⎪
⎪ L−ξ mined from the gas temperature.
⎪
⎩ The mass concentration of methane in the mixture
0, L < x 2L,
a is related to its volume contents avol as
x−ξ avol μCH4
T1 (x, 0) = T1v + T1w , 0 x L, a= ,
L−ξ (100 − avol )μair + avol μCH4
pμ where μCH4 is the molar weight methane and μair is
ρ(x, 0) = , U (x, 0) = Uv .
RT (x, 0) the molar weight of air. The diffusion coefficient and
thermal conductivity depend on temperature as follows:
48 Krainov and Moiseeva
s s
T T (n + 1)th time layer (Tin+1 ) is calculated by Eq. (1),
λ = λst , Dρ = Dst ρst [14].
Tv Tv the gas density ρn+1
i by Eq. (4), and the temperature of
n+1
The subscript “st” denotes the parameters at the inner insert T1,i by Eq. (2). The velocity of the
T = 300 K. gas phase ui is determined from the difference analog
The heat transfer coefficient in Eqs. (1) and (2) is of Eq. (5) at known density on the nth and (n + 1)-
given by the expression α = λNu/h, where the Nusselt th time layers. The concentration of the combustible
number Nu for the flow of the mixture in the narrow component on the (n + 1)th time layer (an+1 i ) is calcu-
gap formed by two parallel plates is defined, according lated by Eq. (3). The calculations are performed until
to [19], as a steady-state distribution of the state variables in the
⎧ 0.33
⎪ hRePr hRePr slot burner is established.
⎪
⎪ 0.979 , > 1000,
⎪
⎪ The algorithm described above was used to develop
⎪
⎪ x x
⎪
⎪ a computer program study the results of calculations
⎪
⎪ hRePr/x − 100
⎪
⎨ 3.78 + (Nu∗ − 3.78)
⎪ , for convergence with decreasing step in space. From
900 convergence of the results, a step in space was selected
Nu = (8)
⎪
⎪ hRePr that provides convergence of the results with an error
⎪
⎪ 100 1000,
⎪
⎪ x of no more than 0.3%. In the calculations, we checked
⎪
⎪
⎪
⎪ the satisfaction of the laws of conservation of mass and
⎪
⎪
⎪
⎩ 3.78, hRePr energy, which was 99.5%.
< 100.
x The establishment of the solution of the combus-
Here Re = ρuh/η is the Reynolds criterion, Pr = tion problem for the methane–air mixture in the slot
cη/λ is the Prandtl number, η is the dynamic viscos- burner was controlled by checking the satisfaction of
ity of air, and Nu∗ is the Nusselt number corresponding the conservation relations. The balance of the en-
to hRePr/x = 1000. Local values of the Nusselt num- ergy released and absorbed by the inert insert ΔQ =
ber (8) take into account the effect of the establishment
2L
of the flow of the mixture in the inlet portion of the α(T − T1 )dx ≈ [Δhαi (Ti − T1,i )] was calculated.
0 i
burner on the heat-transfer coefficient between the gas In steady-state combustion of the mixture in the
and the wall [19]. slot burner, ΔQ = 0, i.e., the heat absorbed by the
Problem (1)–(7) was solved numerically using a inert inner insert in the gas combustion zone is equal to
four-point implicit difference scheme [20]. Equation the heat transferred to the gas in the zone of its heating.
(5) was approximated by an implicit difference scheme The mass balance at the inlet and outlet of the burner,
with upwind differences. The difference grid was spec- ΔM = ρv uv h − ρ(2L, t)u(2L, t)h was controlled. In
ified so as to describe in detail the heating zone and steady-state combustion in the slot burner, ΔM = 0.
the narrow zone of chemical reactions and provide a The balanced relations were satisfied with accuracy
value of the order of unity for the Courant number
λst Δt
ΔM
· 100% ≈ 0.01%,
r= 2
≈ 1 . These requirements were satis- ρv u v h
cρst Δh
fied by steps in time and space (Δt = 10−5 s and
Δh = 10−5 m). According to [1], the thickness of ΔQ
· 100% ≈ 0.25%.
the heating zone ahead of the flame front is defined (Qav + cTv )ρv uv h
λst 1
by the expression l = , where un is the flame
cρst un
propagation rate. According to [2], for a 6% methane– RESULTS AND DISCUSSION
air mixture, un = 0.065 m/s and the corresponding
width of the heating zone ahead of the flame front for The calculations were performed for the following
λst thermal and kinetic parameters: Q = 55.7 MJ/kg, E =
≈ 2 · 10−5 m/s is l = 3 · 10−4 m. For the chosen 239 kJ/mol, c = 1065 J/(kg · K), λst = 0.025 W/(m · K),
cρst
step in space, the heating zone ahead of the reaction ρst = 1.179 kg/m3 , Dst = 1.992 · 10−5 m2 /s, R =
front contains 30 points of the difference scheme. 8.31 J/(mol · K), p = 0.10132 MPa, s = 2/3, η =
System (1)–(7) is solved using the following algo- 2 · 10−5 Pa · s, μ = 28 · 10−3 kg/mol, ξ = 10−2 m, Tv =
rithm for calculating the unknowns on the (n+1)th time 300 K, T1v = 1000 K, Tw = 1700 K, and Tw1 = 1400 K.
layer. The coefficients of heat transfer, diffusion, and In the slot burner, the slot size was h = 6 · 10−3 m,
heat conduction αi , Di , and λi are calculated from the the thickness of the insert h1 = 2 · 10−3 m, and the
known velocity, density, and temperature of the mix- total length of the channel 2L = 0.1 m. The ther-
ture on the nth time layer. The gas temperature on the mal and physical properties of the material of the
Combustion of Lean Methane–Air Mixtures in a Slot Burner with Adiabatic Outer Walls 49
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