4 rx seat ins + 62. oa PUENTE ‘. aaeenemer ner sestcone02112010 FORMTP 2010148 [00 ee Mavmnezo10 CARIBBEAN EXAMINATIONS COUNCIL ADVANCED PROFICIENCY EXAMINATION CHEMISTRY -UNIT Paper 0. minutes | READ THE FOLLOWING INSTRUCTIONS CAREFULLY. 1. Thistewteonsistsof45items, Youwillhave 9 minutes toanswer ther, 2 Inadtionwohistestbookl, you should have ananswer shectandaData Booklet. 3. Bachitem nthistesthas four suggested answers letered(A).(B), (C).(D). Read each item you Sraboretmer ae accor bor 4. Onjuraswerier ind enuntershichcoreponkyourhomand sade espchavng todas ri ieterjosbocchoxe Last wae Septent Samim : ‘Whichof te following the HIGHEST energy ranstioninanorganiccompound? 5 (A) ator SampleAnswer i ® tee : © See ®0e0 : @ fer ‘The bestansvertothis item i “to 6", so answer space (C) has ben shaded 5. Myouwanttochange youranswer, besuetoeraseitcomplecly before you inyournew choice. 6 Whenyouaretoldtobegin tm te page and work as quickly and ascareflly ax youesn. Ifyou cannotansweranitem, mii andgoontothe nextene. ¥oumay urn tothe omted tema. ‘Your scot wilbe the otal number of comect answer. 7. Youmaydoanyroughwerkinthisbookle. 8 Figwesarenotnecessaiy drawn scale ; 9. Theuseofsiten non programmablecacultrs allowed DO NOT TURN THIS PAGE UNTIL YOU ARE TOLD TO DO 80. Copyright © 2002 Cuitbean Examinations Canel, Alnighs reserved, c21120101CAFE2010 YUNNAN farseatien 42 1. AratioactveetementMofmass number A, §, and atomic numer Z, undergoes decay, followed by @ decay. Te final element, wilbe cy ® © o 2. What isthe average ative atomic mas of ‘omit, gvea he fllowing topic masses and relative abundance? 1 "Br 505% "Br-495% 7899 ® 90 © ne ©) wor 3. Anion7Zconsins23 protons. Whatisthe electronic configuration of"! (a) tad saraet ® ase © [ansess © tanseas 4. A bonds rom the overtapping of w ® © o vo sorbitls one Sand one poeta 9. two prbialsend-on ‘wo porbias sideways e2ii010cAPE2010 ‘Which ofthe following actos increases the festinistioneneky ofan stm? (A) Greater nuclear charge @) Lageratomie radius (©) Larger numberof valence electrons o Increased serecning by innet lcrons ‘Thebonds in $0; ion are BEST described w @ © © covalent and polar icaicand polar polar, covalent andsingle lig covalent nd double ‘The bond angles in the PH, molecule are the smeasthatofNCI,, Is shape would BEST be dosebed as (A) Sipyamit ©) pyrmeat (©) teeahedat (D) geal ‘Which ofthe followings tre abou S dof hydrogen and Sd of onygen at O°C and O1KPs? They A) comtain the same number of molerlee (@) posses ihe same amountof kinetic cory (© reactcompletly witheach other ©) reacto produce Sd’ of water Which ofthe following solids has a giant molecular aie? (A) Copper @) Cabondiorite (©) Magnesiumoxide (D) —Sibeondionie GOON TOTHENEXTPAGE3. 10, Thesimplest formula for acompoundinat 13. ‘onttins 50% S and 30% Oby mass s so ® so, © so © so, [A piece of copper metal spaced in iver nitrate solution, a shown inthe diagram below ecusent sy Ast0, 00) 11, Whichofte following would MOST tikely beobsered? 1 (A) Copper meta dissolves and the Selusin remain coos. (®) Copper metal is deposited andthe ‘eluontumstue (© Silvermeal terms snd te soltion remainscoloutess. (©) Silvermetal forms andibesolion 5 ‘ume ble 12. A gas ina syringe ocupies a volume of 50 cm? and has a pressure of 0.49346 !umospheres. What is the pressure ofthe _sif te plunger ofthe syringes posedin reducing the volume ofthe gato 20 em? (Ctmogphere» 101325 Pa w 20kPa @) _125kPa (©) 200004 (©) 1250004 eaii2910CAPE2O10 ‘Which ofthe ftlowing ene is MOST likely ‘obehave like anidal pas? (A) Ammon ®) Helm © Methane ©) Oyen tem 14 eerste fllowing information, “The enthapy of solution of sium cherie 298 K can be calculated from the data Bhentelow. NaCls) 9 NW +CHE; AH=0787 I met! Na’) + water + Navas AH =-406 1 mot" hcg) + water Crag: ai =-377 kr mol Which isthe coret valu forthe enthalpy soon? () ~1370k mot! ® ~4ksmor" © ¥4ksmor ©) 570K mot! What is the standard heat of reaction (GH) a 101-328 kPa of pressure and 298 Tote equation giventeiow? 2a(3) + Cu (a9) + 20 a9) + Cu() A ats = 464.4 0 mol for Cu AN ageie =-152.4KI mot for2a* Hin = Ofer both 29 and Cu 217 mor @) 88 0kImor © +88.0%bmor" ©) 217 dat GOON TOTHENEXT PAGE16. 1. 1. —_-————$—— 4 ‘The rat law fora given reactions Rate [AF [B). What are the wits fork? (wot dvs! © mol dns et dn? 5! >? an 5+ ‘Hem festothe ble which shows the rate els forthe rection A+B [ Experiment | TAT 118 — rear oreecion) [farce nt [ont ar 10 | ou0 00052 7 [2 a0 as an | ee What isthe overall order ofthe reaction? 20 ®) Pint © second ©) thie ‘Nem 18 efers tothe following infrmstion, ‘The fotmam dtriblen of moecdarenepesattwokemperatuesT, and, showntelow x x my say = Number of weler hibersenes ert ton rumberof molecules ang the azvton caer 8 atte her temperate. > w x ® ¥ © xe o xy GOON TOTHE NEXT PAGE e2112010CAPE201019. Which ofthe following statements does NOT vefer to a system in dynamic caulbeu? (A) Teeresctin severe (8) Theamountsof athe speciesinthe syste remain constant. (© Theeoncentratons of al actants and products re equal (D) Theeate ofthe forvard reaction is ‘equal 1 the rate ofthe ack ard 20, Far he rsction Qt) qulibviumat 444°C, at atm pressure, he value of K,, #50. Se) reaching What i the vale of Kyat «pressure of 2 km athe sme temperature? w 3 ® 90 ©) © 21. nthe Hater cs. Nw 3H 22H, H=-50 samo, «the MAXIMUM yield of ammonia cbusined (A) hightemperature ang low pressure (8) hightemperature and bigh pressure (©) lowtemperatureandhign pressure {D) low temperstue and low presare 22, Which of the following acids is the WEAKEST? aaa | K, Golda) « 49510" ® 17410 © 63x10 © 13x10 e2112010CAFE2010 2. In pure ethanol (C.H,OH), the folowing culiium canexis with arimoniumions. NH; + GHLOH = NH, + CH0H, Which of the following combinations describes the fonctionof NH, and H,0H cording 0 Bete: Lawry theory? cHon wid bse conjugate se Hy (Acid Base (©) Conjugateacia (D) eid Hem 24 refers to the igure below which shows te pH change as propanoic acd is ‘ited ith dium droid Val oto Tnroae nae (e?) ‘Which indicator is MOST suitable for this Indieator pH range (A) Tiymorbve ta-28 (8) Metiyloange 29-46 (©) Metyteed 42-63 (D) Prenciptiaiin «83-100 GOON TO THENEXT PAGE25, A buffer is made by dissolving 28.8 of sodium benzoate, H,COONs, nda of (0.4 mol dim? benzoic sci, CH,COOH, Keeamenso ™ 648 10%mol da. The pi of hele w 23 @ 39 oO 2 © 50 26. Thesolubiy produc K, 2298 K forties Group metal suiphates given below. Kalam) caso, 24x 107 S180, 32x10° Baso, Tex 10" Which metal sulphate woul precipitate out ‘of solutionifequal volumes of 10° mold? ‘solution containing the sulphate on andthe Group ntl seine? w ® © o only and only Wand I onty Mand it 27, Barium carbonate is mre soluble in water ‘han in aqueous sodium carbonate because w ® ° © librium sls ar insole ‘barium ons cane dilace sodium sodium carbonate sonic butbarian ‘exbonae sot common in eet present inthe BaCO/Na,CO, mixtre 02112010CAPE2010 6 2. tem 28 refers othe electrochemical cell ow ots) 12 9) 1 Ae" (ag AB) From which acl doeletons origins? Aeten/AH9 2009/2009) (©) AeteavAgt 1 Zs) 200) (©) 2049 200) 148") IA) em29rferso the ftlowing diagram. 10 mat dng 504 00 eta Za 504) Which of the following does NOT cccurin ‘hecellshownsbove? (A) Electrons flow through the wire ‘fom the zine othe magnesium electrode. (B) Magnesium ons migrate ino the sat wide. (© Noccurreat lows when the sal ‘eidge sremeved. (©) The reaction atthe magnesium ‘lcs Mg(S) > Mg (ag) +26 GOON TOTHENEXT PAGESe Item 0 refers tothe diagram ofthe hydrogen electrode below. pare —> etm sa eee Platine plato 10 mot dn a 30, What needs tobe changed ove this hydrogen clctode an E*=0.00V 2 (A) Theconcentaton of I ions @) The meal used forthe elecrede (C) The temperature ofthe gs () Thepressre ofthe gas 31, Which ofthe folowing gps BEST ilusrtes the varationin meng pois of he elements Nato AY? 1 ating | ow PS) » | | | lee heme hg . . os) WES 32, Theclement, in EC hasan oxidation tate of won @ 8 © 4 o 3 GOONTOTHENEXT PAGE (2112010CAPE2N1033. Which ofthe fotiowing sets of ropeies iste forthe oxide of sulphur? Property of Oxide 1 1 a v sate at 25°C sod [soa Liga | Gas Bondingandsructurinoxde | tonictatice | Giant covalest | Covalent | Covalent molecular | molecular pHofaqueoussoluion 10 7 ° 3 “ ® © o u a wv ‘34, Calcium carbonate decomposes ata lower 36. temperature than barium exbonate beste “ ® © o caleium oxide is less stable than tai oxide the calcium ion is arger than the ‘aria ion the latice energy of cleum oxide ‘lage than tht of aru oxide ‘hestandard enthalpy of formation of alum oxides ess negative than that of ariamoxise ”. 38. Group elements ofthe periodic tabletave “ ® © o high meting pcs tow densities ‘hgh meting posts and ighelecrical ‘ondivie low densities but high electrical ‘onductvites ‘ow meng points an po etl (€21120101CAPE2010 ‘The high meling pont of praphite can be iba the (A) declined eectrons | (B) hoxagonlarungementethecbon | cms | (© strong covalent bonds within the yes (©) van der Waals forces betwoea the ayers ‘Silicon dioxide as asructresimilart that ‘of diamond. What are te advantages de ‘ive from using silicon dioxide ceramics ‘whea compared with see? 1 0 . w ® © © Silicon doce sesso defor ‘under compresin. e Silicon dioxide as higher meking pom, Silene ismareresisanto ox 1 and only {and tony Mandl enty Litanditt GOON TOTHENEXTPAGE38. Based on its position in Group VI ofthe iol, asin, atroom temperature en pressue,is MOST kel 2 (a) sai 8) it (©) bowngas ©) coloilessgas 39. Which of te following is NOT formed when chlorine reacts With hot aqueous w Ho ® NC © Nacio ©) mio, 40. The species containing ions or molecules Uke acenal atom by corn bonds iekrownas tend (®)—comples (© east () covedinatin suber a fers toh infomation blow. Ttement | Melting Point | Densiey tement [CO | wer 1 1538 786 0 0 20 a ma us l 41, Thetrnskion lementsare MOST likely (a) Kenly (&)Landitonty (©) Lanettenty () Mandittonty o2112010CAPE2010 2, cut supe gives (2) ndexpblue solution withexcess NE2q) (©) yellow-green solution with excess ‘concealed HCI Which ofthe following can be deduced from these cbservatios? formed 1. Thecomples ion [Cu(NH) me. WL (CuCNHL),P has a higher stability constant ban [CulHLO)P" IL, {CACLP has a tower stability constant than (CHO) (A) Lanattonly (@) —andiitoaly (©) Manditoaly (0) tana The onic aon forthe formation of hrm yroxid om chvomiun( slp rae NG) 6 (Costa) + OFF G9)» COR (®) B)_CPagh+ 30H (ag) + CHORD, (9) (©) Pag) + OFF (ag) + CON (09) (D) CP) + 50H CHORD, (9) GOON TOTHENEXT PAGE0. ‘m4 refers tothe folowing information, Wit precipiate Whit precipitate soluble in excess Insoluble in excess 44, Which of te following eagets does NOT aii the senifeaion of X=? (A) Aqueous KE () Dikeericr (©) Dilute HNO, (D) Dike HO, lem 45 refers tothe following information, ‘Aqueous BaCl, fllowed by excess ise HCI ded to EACH of four unknown, solutions, if and. The following observations rented, Awhile precipitates fanned which dsolvesin he acid iterate a.gs which ‘ecolourises MnO, 7H) H,_Noprecipateis formed TIL A dense whit precipiateis formed which is insoluble in exces acid 1V. white precipates formed that dissolves inthe cit liberate spas, which fossa white precipitate with COM) a). 45. Which ote following options corel dette the ons which may be present in EACH sober? 1 1 a wv sox c Hoo cop. ® 50, No, soe coz © sox o s coz 7 © soy No, co IF YOUFINISHBEFORE TIMEIS CALLED, CHECK YOUR WORK ON THISTEST. e2t120101¢aPE2010