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METODE MODIFIKACIJE RADNIH POVRŠINA MAŠINA 07 - Chapter2 PDF
METODE MODIFIKACIJE RADNIH POVRŠINA MAŠINA 07 - Chapter2 PDF
CHAPTER 2
2.1 INTRODUCTION
Fig.2.2. PVD process using Plasma Fig.2.3. PVD process using arc
evaporation sputtering
In a true electroless plating process, reduction of metal ions occurs only on the
surface of a catalytic substrate in contact with the plating solution. Once the
catalytic substrate is covered by the deposited metal, the plating continues
because the deposited metal is also catalytic.
Composite
Ion Implantation
In the Ion plating (IP) process, the target material is initially melted
while the substrate is bombarded with ions before deposition to raise it to the
required temperature. The coating flux ion is attracted to the substrate by biasing
the substrate with a negative voltage. Thus sufficient ion energy is available for
good inter mixing of coating and substrate at the interfaceIon implantation is the
introduction of ionized dopant atoms into a substrate with enough energy to
penetrate beyond the surface. The most common application is substrate doping.
The use of 3 to 500 keV energy for boron, phosphorus or arsenic dopant ions is
sufficient to implant the ions from 100 to 10,000A below the silicon surface. The
depth of implantation, which is proportional to the ion energy, can be selected to
meet a particular application.
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Anodizing
The electric current passing through an electrolyte converts the metal surface to a
durable aluminium oxide. The difference between plating and anodizing is that
the oxide coating is integral with the metal substrate as opposed to being a
metallic coating deposition. The oxidized surface is hard and abrasion resistant,
and it provides some degree of corrosion resistance.
Boronising
layer of a metal boride. The reaction takes place between boron and component,
therefore it can be generally limited to steels, titanium-based alloys and cobalt-
based hard metals. In steels, boronising is carried out in the austenite regime
(between 810–1020 °C) for several hours, resulting in the formation of layers
commonly between 60 and 165 m thick. The surface reaction layer thus formed
consists of two separate phases, namely a layer of Fe2B adjacent to the substrate
and an outer layer of FeB. The proportions of the two phases are dependent upon
the composition of the boronising environment and the alloy content of the steel
(higher alloy content favours FeB formation). Care is taken to reduce the
proportion of FeB in the boride layer since this always exists in tension; as such,
high-alloy and stainless steels are unsuitable for boronising. The hardness of the
boronised layer is dependent upon the exact composition of the steel but is
commonly in the range 16000–19000 MPa (as measured on the Vickers scale).
This is significantly higher than many commonly occurring abrasives and, as
such, boronising has been employed in situations requiring abrasive wear
resistance.
Nitriding
more voluminous than the original steel, and therefore they create compressive
residual surface stresses. Therefore, nitrided steels usually exhibit improved
fatigue and corrosion fatigue resistance. Similar beneficial effects can be
achieved by shot peening.
material into the melt pool so that the new material alloys into the melt layer.
Laser cladding is one of several surface alloying techniques performed by lasers.
The overall goal is to selectively coat a defined area. In laser cladding, a thin
layer of metal (or powder metal) is bonded with a base metal by a combination of
heat and pressure. Specifically, ceramic or metal powder is fed into a carbon
dioxide laser beam above a surface, melts in the beam, and transfers heat to the
surface. The beam welds the material directly into the surface region, providing a
strong metallurgical bond. Powder feeding is performed by using a carrier gas in
a manner similar to that used for thermal spray systems. Large areas are covered
by moving the substrate under the beam and overlapping disposition tracks.
Shafts and other circular objects are coated by rotating the beam. Depending on
the powder and substrate metallurgy, the microstructure of the surface layer can
be controlled, using the interaction time and laser parameters. Laser surface
treatment can be controlled to achieve alloying, cladding, grain refining or
transformation hardening a metal surface without actually affecting the metal
itself. A material of poor oxidation can be modified with a surface alloy which
can show improved resistance. Laser grain refining eliminates or minimizes
surface defects such as inclusions, pores and improves grain structure.
Carburizing
can penetrate into holes and tight gaps), making it very flexible in terms of
component treatment.
Cyaniding
Carbo-nitriding
Applications
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Parts that are subject to high pressures and sharp impacts are
commonly case hardened, e.g. firing pins and rifle bolt faces, or engine
camshafts.
Cladding
Laser Cladding
are obtained as follows: Short Peening, Water-Jet Peening and Laser Peening.
In short peening the surface of the work piece is hit repeatedly with
large number of cast-steel, glass or ceramic shot (size of 0.125mm to 5mm
diameter), making overlapping indentation on the surface; this action causes
plastic deformation of the surfaces. Thus improving the fatigue life of the
component. Extensively used on shafts, gears, springs, oil-well drilling
equipment, and jet engine parts.
Explosive Hardening
Mechanical Plating
Fine particles of metal are compacted over the work piece surfaces by
impacting them with spherical glass, ceramic, or porcelain beads. The beads are
propelled by rotary means. This process typically is used for hardened-steel parts
for automobiles.
Case Hardening
Hard Facing
Surface Texturing
Diffusion Coating
Electroplating
Electroforming
Conversion Coating
These coatings are used for purposes such as pre-painting, decorative finishes,
and protection against corrosion.
Hot Dipping
In this process, the work piece, usually steel or iron, is dipped into a
bath of molten metal, such as zinc, tin, aluminum and terne (lead alloyed with
10% to 20% tin). Hot dipped coatings on discrete or sheet metal provide
galvanized pipe, plumbing supplies, and many other products with long time
resistance to corrosion. Various pre-coated steel sheets are used extensively in
automobile bodies.
Porcelain Enameling
Organic Coatings
Deicing fluids and battery acids that are also impacted by particles such as dust,
gravel, stones and deicing salts.
Painting
Diamond Coating