MAIN EDITION British Chemical Standards issued by Bureau of Analysed Samples, Ltd, Directors (1979-8 P.D.RIDSDALE, B.Se., M.LM. (Managing) B. BAGSHAWE, A.Met., IM. R.P.MEERES, B.A, Oxon.) W.F, WiLson Certificate af Analyses B.CS:/SS! No. 403/1 LOW ALLOY STEEL Prepared under rigorous laboratory conditions and, AFTER STANDARDIZATION BY ANALYSTS IN GREAT BRITAIN, issued by the Bureau of Analysed Samples Ltd, ANALYSES (mean values) Analyst | c¢ | si | Mn | BP | s | cr | Mm | N | wu | v ‘No. & | % | ® | ® | ® | & | % | % | | % 8 33 | 0.028 | 0.035 | 0.33 | 0.076 032 | 0.071 0.083 | 14 18s | 0.628 | 0.633 1.87 | 0.028 | 0.034 3 0.083 | 1.86 | 0.029 | 035 0.083 | 1-83 | 0.028 | 0.033 | = | w|i 3 wx | me | me | oe | 0.32 | 01073 | O43 | Gis | Oz 0.086 | 183 | 0.028 | 0.033 | 0.33 | 0.073 | 0.13 | 0.19 | 0. 0.089 | 1:82 | 0.027 | 0.037 035 | 0674 | dis | dis 0.084 | 1.84 | 0.028 | 0.034 | 0.33 | 0.073 | 0.12 | 018 Average The above figures are those which each analyst has decided upon after careful verification British Chemical Standard — chips for chemical analysis. Spectroscopic Standard — disc sample for spectroscopic analysis, (Pro.CO-OPERATING ANALYSTS AND FIRMS INDEPENDENT ANALYST 1. PICKERING, J.L.,CChem, M.R.S.C, Ridsdale and Co, Ltd., Middlesbrough ANALYSTS representing MAKERS and USERS 2. BETTELLEY, J.,B.82, C.Chem., MR.S.C, G.KN. Group Technological Centre, Wolverhampton. 3, BORROWDALE, J.,B.Se., B.S.C. Scunthorpe Division, Scunthorpe. 4, CHAMBERLAIN, B.J.,M.Se., B.S.C, Bilston and Wolverhampton Works, Bilston. 5, CHAMBERS, H. F., Ford Motor Co, Ltd., Research and Engineering Centre, Basildon, 6. FAVAGER, B. J., GK.N. South Wales Ltd., Cardiff. 7, HENRYS, F.,A.Met, MM, Brymbo Steel Works Ltd., Brymbo, 8, KIDMAN, L.,A.Met, M.lM., B.S.C. Rotherham Works, Rotherham. 9. LAYCOCK, C.,A.Met, CEng, MLM., Round Oak Steelworks, Brierley Hill 10, LITTLE, J., Ravenscraig Works, Motherwell 11, PEMBERTON, R.,A.Met., Brown-Firth Research Laboratories, Sheffield.BCS/SS. No. 403/1 LOW ALLOY STEEL NOTES ON METHODS USED CARBON Analysts Nos. 1, 3, 4 and 10 determined carbon by non aqueous titration according to the British Standard Carbon Method 4°. Nos, 6 and 9 used high frequency combustion with infrared measurement and No. 7 the gravimetric British Standard Carbon Method 1*. Analyst No. 4 also used high frequency combustion with infrared measurement and found 0.87%. SILICON All analysts, determined silicon by double dehydration with perchloric acid according to the British Stendard Silicon Method 1°, MANGANESE, Analysts Nos. 1, 3, 4, 6 and 10 determined manganese photometrically after oxidation with perlodate and followed the procedure of the British Standard Manganese Method 2*, Analyst No, 7 oxidised the manganese with persulphate/silver nitrate and completed by titration with arsenite, No.9 used atomic absorption spectrometry. ‘Analyst No. 10 also determined, manganese titrimetrically with ammonium ferrous sulphate according to the British Standard Manganese Method 1* and found 1.82%, PHOSPHORUS Al analysts except No. 6 determined phosphorus photometrically as phosphovanadomolybdate according to the British Standard Phosphorus Method 2*. Analyst No, 6 used a titrimetric method after precipitation as Phosphomolybdate SULPHUR Analysts Nos. I and 3 determined sulphur gravimetrically according to the British Standard Sulphur Method 1%, Nos. 4, 6, 7, 9 and 10 used combustion methods. No. 4 absorbed the evolved guses in water and titrated with iodate} No, 16 absorbed in hydrogen peroxide and tisated with borate; Nos. 6,7 and 9 used high frequency combustion) infiared absorption. Analyst No. 4 also used high frequency combustion/inérared absorption and found 0.034%. CHROMIUM Analysts Nos, 1, 5, 8 and 11 determined chromiym by titration after oxidation with persulphate/silver nitrate according to the British Standard Chromium Method 1*, Nos. 2 and 9 used atomic absorption spectrometry. Analyst No.8 also used the photometric British Standard Chromium Method 2* and found 0.31%. MOLYBDENUM Analysts Nos. 1, 8 and 11 determined molybdenum photometrically as the oxythiocyanate according to the British Standard Molybdenum Method 1°. Nos.2 and 9 used atomic absorption spectrometry. NICKEL ‘Analysis Nos. 1, 2 and 9 determined nickel by atomic absorption spectrometry. No. 5 precipitated the nickel with dimethylglyoxime and completed cyanometrically according to the British Standard Nickel Method 1*. Nos, 8 and 1] used the dimethylglyoxime photometric British Standard Nickel Method 3*. Analyst No. 2 also used the British Standard Nickel Method 3* and found 0.12%, No. 5 also used atomic absorption spectrometry and found 0.13%. COPPER Analyst No. 1 determined copper photometrially with biseyslohexanone oxalyitydrazone according to the Analoid Method No. 65, Nos. 2 and 9 used atomic absorption spectromety. Analyst No, 3 used ie ish Standard Copper Method 2° in which the copper is separated a suiphile and cvaluated by dodimetic titration, Nos, ® and 11 determined copper pliotometrically with 22 diquinoly! according to the Brilsh Standard Copper Method 3°. ‘Analyst No, 5 also used atomic absorption spectrometry and found 0.18%, VANADIUM Analysts Nos. 1 and 8 determined vanadium photometrically as phosphovanadotungstate according to the ‘Analoid Method No. $9. Nos. 2 and 11 used the titrimetric British Standard Vanadium Method 1°, Analysts Nos. 5 and 9 used atomic absorption spectrometry Analyst No, 2 also used atomic absorption spectrometry and found 0.259%. No, 8 also used the British Standard Vanadium Method 1* and found 0.26%, “Methods for Sampling and Analysis of Iron, Steel and Other Ferrous Metals, BS. Handbook No. 19, first published 1970 by the British Standards Institution, 2 Park Street, London, WA 2BS, NEWHAM HALL, For BUREAU OF ANALYSED SAMPLES LTD. MIDDLESBROUGH, P.D. RIDSDALE, ENGLAND. ‘Managing Director. Preliminary Edition, November, 1978 Main Eaicion December, 1980