Q. Dear Dr. Galv: How is acid rain
measured and what do we know about the
corrosion protection of galvanizing in
“acid rain conditions”?
A. Our highly industrialized society and fast-
paced lifestyle have resulted in greater
uantities of hydrogen atoms being
istributed ‘by wind currents or absorption
and later release by rain clouds. Chemical
pollutants combine with atmospheric
moisture to create acid rain. Due to heavy
industrialization, major cities often have the
highest levels of acid rain. Carbon monoxides,
from the exhausts of automobiles and
chemicals from industry are the main
contributors of the raw materials that create
acid:rain, but other sources include fertilizers
and pesticides. The map below, compiled by
the National Center for Atmospheric Studies,
indicates acid rains falling on the United
States vary in pH content.
The lower a-pH (which means “part of
hydrogen”) number, the more acidic the
solutions being described. A pH number
identifies degree, not amount, of a solution's
acidity or alkalinity.
THE pH of LIQUIDS
The neutral point on the pH scales is 7.0.
‘Think of the above picture as a weighing scale
which tips to the left (where numbers are
ASK DR. GALV
lower) for acid content and to the right (higher
numbers) for alkaline content. Rain water can
vary from a pH of 3.0 to a pH of 8.5,
depending on meteorological conditions and
the geographical location where it falls.
The question of how the galvanized coating
protects in acid rain conditions has no definite
answers. However, if the question is asked by
a prospective customer, helping them to
tnklerstand the problem fay be beneficial
Studies conclude that factors such as ait.
direction, velocity, surface wetness and
duration of its wetness, combined with
average temperature, can be used to estimate
where the effects of acid rain is likely to be
more severe. These factors also provide clues
to dealing with the problem, z
Q. Dear Dr. Galv: How can I make sure
certain areas are not coated with-zinc when
I galvanize a steel fabrication such as
threaded bolts, surfaces which must be
welded after fabrication or drilled holes?
A. Gauze tape can be used to protect
cylindrical components, including threaded
bolts and pins, but is not suitable for flat
surfaces. The tape should be cloth based and
must be tightly wrapped around the relevant
area. Plastic insulation tape is not suitable
‘The temperature in the galvanizing bath will
cause the gauze to burn but the carbon residue
remaining will be sufficient to keep the zinc
from metallurgically combining with the steel.
After galvanizing, remove the carbon residue
with a wire brush.
Flat areas can be protected through the use of
high temperature paints, such as those used to
protect automobile exhaust systems. It is also
possible to use special pastes, which are
particularly effective at protecting bore holes
or internal threads. ‘These paints and paste
products are sold by automotive suppliers
‘The paste is intended for sealing small holes in
the exhaust systems of cars. When moistened
with a little water, these pastes can also be
pressed into holes and openings to prevent
ingress of zinc. However, it is extremely
important to take care not to trap air inside
and obviously, it will be necessary to remove
the residue after galvanizing.
Augssr /Sepkembyr IG Vol al