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10,000), the
Dittus ~ Boelter equation may be used asa fitst approximation:
. ws 3 (T, >1, 4 = dm
Freundlich Isotherm:
q=Kp'n = Ken
P= partial pressure of solute
C= concentration of solute
Value of n varies b/w 1 to 5
BET Equation (Braunauer-Emmet-Teller Equation)
x
1° mG— pit © = Dal
X= p/P,
vapor pressure of the adsorbate at the given temperature
= a temp dependent constant for a particular gas-solid system.
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Chemical Engineering
CHEMICAL ENGINEERING “100 Formula Sheet”
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ant Desi
reece
#67) Cost index: A cost index is merely an index value for a given point in time showing the cost at that
time relative to a certain base time.
index value at present time
Present cost = original cost X (ey value at time original cost was obtalned)
The Chemical Engineering Plant Cost Index and Nelson Refinery Construction index are
the two most useful for estimating plant costs. The Engineering News Record Construction
Cost Index mainly measures the cost of civil structures such as dams, and buildings. The
Marshall and Swift Equipment Cost Index gives the index for the cost of equipment by
industry and the cost of buildings by type and geographical region.
it ij tt
rae GOED CERT Lr
‘capacity of equipment b’
#69: |Fixed capital cost Estimation (Lang Factor Method) - The fixed copital cost of the project is given as a
{function of the total purchase equipment cost by the equation.
Ci =fiCe
C= fixed capital cost,
C.=the total delivered cost of all the major equipment items: storage tanks, reaction vessels, columns, etc.,
fiz the “Lang factor”, which depends on the type of process.
Lang propdsed three separate factors based on the type of process plant.
{3.10 for predominantly solids processing plant
{fir 4.74 for predominantly fluids processing plant
= 3.63 for a mixed fluids-solids processing plant
#70. Straight line method- The annual depreciation cost d is given as
vv,
7m
Where, V= original value of the property at the start of the service life
salvage value of property at the end of the service life
n= service life, years
a
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Chemical Engineering
CHEMICAL ENGINEERING “100 Formula Sheet”
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The asset value V. (or Book Value) of the equipment at any time during the service life is given as:
Va=V-ad
Where a= number of years in actual use.
The asset value V, is given by the relation
2
Vaz V(1-f)
Where f represents the fixed percentage factor, related to V and V, as:
afm
fe 1-(v./v)""
The fraction f must be equal to or less than 2/n, where n is the depreciable life in years. When f=2/n, this
method is known as double declining-balance (200 percent) depreciation.
(lt should be noted that the double declining-balance method is often applied to cases where the salvage value is
considered to be zero.)
=pti
De = Depreciation for year p = a W-V,)
7
oR
2m—p+1
De = Depreciation for year p too W-V,)
For example n=3 years, then depreciation for the first year (p=1)
3-141
ar2ray YY) =
De = Depreciation for year (p = 1) = W-Vv,)
i
eae)
7a Faetor OF Safety (FOS) = Ultimate stress / working stress
= maximum load / actual load = Fmax/ F
Depreciation =
If FoS = 1 then the component is on the point of failure
If FoS <1 then the component is in a failed state
If FoS > 1 then the component is safe.
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Chemical Engineering
CHEMICAL ENGINEERING “100 Formula Sheet”
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(ETSTHS BFESERE WOH TOEBRESSREVATIG »of 0 future amount Softer miterest periods can be determined
from
1
Psa
Where = compound interest rate.
#76. Capitalized cost K is related to replacement cost (Cx) and original cost of equipment (Cy) as
© One of the most important formulas.
Effective annual interest rate = iggy = (1+ a =
Where r= nominal interest rate
m= interest period per year
pd
(Circumferential stress cylindrical vessel) = oy = 75
(Longitudinal stress for cylindrical vessel) = 0, = >=
pa
4g
Stress for Spherical vessel
Where, t= thickness of shell
fiameter of cylinder or sphere
> design pressure
int efficiency
Weare
Prine eae
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Chemical Engineering
CHEMICAL ENGINEERING “100 Formula Sheet”
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[e
umentation and Proc
Transfer function of first order system:
Y(s) _ _Kp
X(s) Seta
Step Function:
X(t) = Au(t)
Dynamic response:
YO=0 r<0
¥@) = A(t")
Impulse Function: X=0;1<0
uA.
X(t) = Ad(t) Epis?
aa X=0;1>b
Dynamic response: a lim X@) = A(t)
= b>0
wo=e" L{A8()} =A
X(s) = bis?
Dynamic response:
Y() = br br(1— e/*)
Slope = 5
b(t — 2) + bae"!* :
0 t
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Chemical Engineering
SY
CHEMICAL ENGINEERING “100 Formula Sheet”
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Sinusoidal Function:
X=0;1<0
=o 0 X=Asin of t>0
= t<
; =4 X@=
X=Asinot 120 x0 +
1
1
1
0 t
Dynamic response: Wena nen
YO = Sy > as 8 Ft + sin@t
Toe +1 ta +l tra +1
or
A F
+ —————sin(wt + 6)
Vo? +1
Where
@ <0 phase lag
=)
g = tan (—@r) @>0 phase lead
Called phase, When
For two systems in series, f the output from system 1 is not affected by the output from system 2, the
systems are said to be non-interacting.
a
1" _* A ae x
G G Hf Gy
xO)
wo “HIG
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GATETest House
CHEMICAL ENGINEERING “100 Formula Sheet”
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The standards form of second order system is given by differential equation:
2.
oor +e oT ey = xO)
Transfer function is given by:
¥(s) 1
X(s)_7?s? + 207s +1
Step response of a second-order system
Case ¢ Nature of roots Description of response
I I Real Overdamped or nonoscillatory
Response time
Timit
1.0
y(n)
Response
Rise time A
fae
woe @q = natural frequency = —
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Radian frequency @ =
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we
CHEMICAL ENGINEERING “100 Formula Sheet”
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System Response
‘Sample Second-Order System Response ‘Sample Second-C
Ise Input
vo UnitStep Input toaUnit
SSS o7 r r ,
Underdamped f
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