Foy 4 HOME wore D Hone work Tr zy . met /2keT -f cf lde 0 4 | Cice 0 4n [Ss , c? 12 gT _ 0 ~ : a 4 Zet J we c( ye, du (= ) le de Vt “ ZaksT 2H HGT hewarite th pad om = % me nc*/2tgT y, fe) - fn fo? ( é © Pakgl % ‘ ey een ure du Vn) an c & 2 . Bu -4 Using Toth of unbegnds , {ute "du = 4 0 262 4 VERT. VJing? TH c= 7 a) nm 2 Tam mm m QO. Trt hamat compa» =>AU20 AH -O M3. 601 »Ve= 20L by = 5 alam Pe Foy (Vy YD atm) x E40) CL) = 200 & abn . eo = A) A) AU-C > g+w-5y qr ows - 20260 (J)aaa Fags 2 GQ). ants ly) 4 6N0OG) > FN, lg) + 6 H,0 Cg ) =) im = ted AHa® 25A,IN(N,) +6Ag HE Cujo) - Cag HY Co) 4 ay Helv) = 6 244 e) = 6.90.4 - 4x © 46.3) E ~APOP AT. Alty’= AW! 4 acev) = AUY + An eT) = AU? + ET A, ee Ae Ae ai pore 10. O} = 8.342 (Tel, ke 298 Le) xt - MAO 4F4 T= ABs x 0 CF) @ Gre G) * lg) > CuaGey Bends Lrolin No. Bemd enthalpy (AT [met ) ea 4 444 ¢=¢ 4 on Wa 4 436 Bondo fen rosa No Boma enthalpy LAT lmet) CoH 6 FR 444 aC 4 Scie DAW! - (44 4494 64194 456) - (bx 444 +343) 3 420 mel AT | ame ° | Ls og wing enitolpy of fenmation = Ay Hy CoP} Og (CH | ’ aes, The approximate value of An,’ wing Berl Pee coninict valne , ecu ent haloy 1) to» thom 4omd ent holpy vole ant avinage valuppoy $ Qi as yf, = Palm jf = dolm Ts 450 k Wis a EOS et oi ee Vy pe Wa iso g AUC e sel Ata mol CASO) én & : = 2.4010 MF 40 O v4 Paes PRE he Leip Buty: N_PNa .U.346, 9-43 at am) «C022 » 102? mod} Ve aor CO CUZ are k) (350k) = Zan On ctee 2, d- 3.758 gee ee Ga = 5 ¥x Fn ven di ) Mes Fis Polo) 17s co (gee 3)Page 320 One mole of an deal gas undergoes an isothermal expansion t 30 K fom 1.00 stm oa inal pressure while performing 200 J of expansion work. Caleutatethe-finat pressure of the pas ifthe es enteral pressureisOadeim ASSume pevecble ste neT th. Me = ane On 1 top we 8.3\47 x300 x Ly mol- 0.0806: 2. (4/? ) Dou ean eles werk oo. turevtsclle was weserbed by the question in book 3.23. It takes 330 joules of energy to raise the temperature of 24.6 g of benzene from 21.0° C to 28.7° C at constant pressure. What is the molar heat capacity of benzene at constant pressure? From the relationship 4=CpAT =nC pat Gp of benzene can be determined: te x01 wal” (qBiEn) ea7°C-210°0 36 J mol™! °C!Pase 5 346 Thestandard enthalpies of combustion of fumaric acid and maleic acid (to form carbon dioxide ‘and water) are ~1336.0 kJ mol~! and ~1359.2 kJ mol respectively. Calculate the enthalpy of the following isomerization process: HC (COOH H (COOH mL ee /\ iH HOOC H | maleic acid fumaric acid ‘The chemical equations and the standard enthalpies of combustion of | mole of fumarie acid and | mole of maleic acid are given below: fumatic + 302+ 4CO, +2H,0 4,4 = ~1336.0 KI mol! maleic #30; + 4CO; +2H,0 A, H® = ~1359.2 kJ mol! ‘The isomerization reaction (maleic acid —> fumaric acid) can be obtained as a combination of these two reactions: 4CO; +2H,0 > fumaric +30) A, H® = 1336.0 kd mol”! maleic +30) -» 4CO, +240 A,H® = ~1359.2 kJ mol”! ‘Therefore, the enthalpy of the isomerization process is ApH = 1336.0.KJ mol™! — 1359.2 ky mol”! = —23.2 kd mot! 3.87 Alcoholic fermentation is the process in which carbohydrates are broken down into ethanol ‘and carbon dioxide, The reaction is very complex and involves a number of enzyme-catalyzed steps. The overall change is Colli,04(9)-» 2C,HOH(D + 260368) Calculate the standard enthalpy change for this reaction, assuming thatthe carbohydrate is a-D- glucose, A,H® = 24H? [CHsOH(D] + 24/7? [CO,(@)] ~ AH” [CoH,206(8)] =2(-277.0 mot) +2 (3935 kd mol) — (—1274.5 kd mot") 66.5 kd mot