3-6 ON FIG. 341.1 COMEN: Purpose This roir of charts interconvers ASTM 86 and stmospherie TDP distillation Limitations . s discussed in whe Introduction, occasions! severe errors may arise fiom the we of this figure Reliability : fe snd Serpeneet een the esimated and actual experimental temperatures st 10, 30, $0. ani ahd SOFeamt points are within 40°F. This i uue sarting Wah ealey ASE oes ala and converting tothe other. 58 from the following sources were used to evaluate the accuracy of the chan 26,35. 21,23, Special Comments ASTM D 86 distillation data ean be td direcily to TBP distilation data, However; the TBP to ASTM conversion involves a tisbamberror proce For ASTM D $6 temperatures above 475 F, ose ths lllowing correction for crackin Jog D = — 1.587 4. 0.00:737 GALI) orrection to be added 10 7, in degrees fahsenheit stillation temperature, in depress fahrenheit, Literature Sources AGB fom Eeminer and Pollock, Chem. Ene, Progr. 44 905 (1838). Favation GALLI) was given by S. Ts «Pass private communication (1963). Example - rine acre yar gnats, THE dislivion curve of a petroleum, fection having the following ASTM D 86 distilation teinperaiurest \ Puillation, percent by volume...... 10 30 5099 90 Temperature, deg FP... 400-420 ase 460 as on Oar ROSES D 6 dsilation tempernires above 18 F for erecing cing aap Geog TD, For the $85 F point 2t 90 percent isa, log Dax es 69373) (YEO 70 or D = SE. The comected Doptromt niperaiee tsi FE eres Poe Nat pana the Simospherie TBP SO-prcenttempuriere, Facey te lotr ohare oy teens gag een Cm neralte Of 458 F, AF 42 F. Thereore he TOP ore tempera tures 438 F 4p 2F = 440 F. From the upper chart fd the temperatuce diferences for each seinem of the TBP curves » Gull Research and Development Company, Pitseursmy : ASTM Teraporature ‘Sexment of Curve Difference (Percent by Volunie) (Degrees Fahreoheit) 201930 . 20 301030 501079 . > 01050 * S0-pereent temperature Lo-percent temperatere 434405513 P- sr anes valving th prediction of atmospheric AST3 curves from atmoiphare rae: Setenmincd ee eseeaOzOUHY, eNCEDL Thal the “ASTM SO-pereent lenpeieee eae determined by a tiaband-error procedure,BALA © AST, TEMPERATURE pIFSERENCE (eve 6 NIvidO Ox aves 708 vasy OX aav)aT 2 § 8.9 & 2 6 2g F 507, TEYAPERATURE,F asta, g 8 3 g a: 4 Gpnay ig. SYNWUAWRL d2° e dal _ 35SIMULATION SCIENCES INC R PROJECT EOD-9984 PRO/IT PROBLEM COMBINADA 2 STREAM TBP/ASTM CURVES - DEG C STREAM ID 2 ‘NAME NAFTAEST PHASE DRY LIQUID TBP AT 760 MM HG 1 LV PERCENT 27.511 5 33.812 20 43.330 30 79.800 50 108.982 70 335.576 30 165.323, 95 177.357 98 196.904 TBP AT 10 MM HG 1 LV PERCENT -57.062 5 52.293 10 45.071, 30 -17.179 50 5.393 70 26.166 90 49.632 95 59.196 98 74.815, D86 AT 760 MM HG 2 LV PERCENT 50.960 5 56.048 20 63.734 30 87.563, 50 208.750 70 131.425 20 156.432 95 170.638 98 193.721 D86 AT 760 MM HG WITH CRACKING 1 LV PERCENT 50.960 5 56.048, 20 63.734 30 87.563, 50 108.790 70 331.425 20 186.432 95 170.638 98 193.711 VERSION 5.61 ourrur ‘TURBOSINA WET LIQUID 109.835 148.602 160.334 182.123 196.235 209.824 225.659 233.552 239.624 6.057 36.412 45.680 62.994 74.279 85.199 97.991 104.394 109.495 139.518 167.869 176.449 187.329 194.339 203.160 214.863 223.988 231.238 139.528 167.869 176.449 187.329 194.339 203.160 214.863 223.988 231.238 4 KEROSINA WET LIQUID 166.355 209.433 219.216 236.013 247.070 258.434 274.907 286.377 299.110, 50.451 84.884 92.778 106.394 115.402 124.697 138.239 147.716 158.282 200.297 226.277 232.177 239.490 244.050 249.990 262.498 273.953 286.669 200.297 226.277 232.277 239.490 244.050 247.388 289.217 269.907 281.582 PAGE P-607 386/EM DRRMFM SEP-96 5 DIESEL WET LIQUID 203.537 243.312 256.670 283.114 304.362 326.918 356.147 368.985 387.462 0.142 112.336 123.253 145.016 162.653 281.525 206.212 217.137 232.952 240.274 260.531 267.335 284.895 299.974 315.807 340.978 352.769 367.302, 240.274 257.367 263.749 279.966 293.542 307.371 328.273, 336.765 348.435SIMULATION SCIENCES INC. R PRO/II VERSION 5.61 oureur STREAM TBP/ASTM CURVES - DEG C PROJECT OD-9984 PROBLEM COMBINADA 2 STREAM ID 2 NAME NAFTAEST PHASE, DRY LIQUID ASTM D160 AT 760 MM HG 2 LV PERCENT 46.302 5 49.254 10 53.720 30 84.682 50 108.981 70 135.576 90 165.323 95 277.387 98 196.904 ASTM D1160 AT 10 MM HG 1 LV PERCENT 42.812 5 40.564 20 -37.161, 30 13.419 50 5.393 70 26.166 90 49.632 95 59.196 98 74.815 ASIN D2887 AT 760 MM HG 2 WT PERCENT 16.754 5 23.047 20 37.795 30 76.891 50 108.981 70 137.116 90 166.514 95 185.954 98 208.460 TBP AT 760 MM HG 1 WT PERCENT 27.583 5 35.162 10 46.104 30 82.834 50 11.685 70 137.498 90 166.461 9s 178.379 98 198.109 TURBOSINA WET LIQUID 238.063, 160.465 167.270 185.014 196.235 209.824 225.659 233.552 239.024 28.119 45.704 51.177 65.301, 74.279 85.199 97.991, 204.394 109.495 97.606 127.924 144.995 275.311 196.235 213.636 231.695 243.681 256.894 211.263 149.351, 160.84 182.691 196.716 210.203 226.042 233.753 239.853 KEROS: INA WET LIQUID 293 219. 224. 238. 247, 258 274 286. 299. 2. 82. 87. 108 ais. 124. aaa 147 158. 13 187 202. 228 247, 262. 280. 2399 318 167. 210. 219 236. 247. 258. 275. 286 299. 992 asi, a7 362 070 434 907 377 110 402 725 366 305 402 697 239 ns 282 356 250 284 945 070 381 999 398 31s 497 319 662 299 306 766 oes 675 318 PAGE P-608 386/EM DRRME SEP-96 DIESEL WET LIQUID 233.900 257.233 265.100 287.018 304.362 326.918 356.147 368.985 387.461 104.677 323.713 130.168 148.247 162.653, 282.525 208.212 217.137 232.952 195.277 225.687 244.381 277.739 304.362 329.369 358.370 379.304 402.149 205.020 243.946 257.230 283.887 305.265 327.761 357.028 369.482 308.248SIMULATION SCIENCES INC. R PAGE P-609 PROJECT EOD-9984 PRO/II VERSION 5.61 386/EM PROBLEM COMBINADA 2 ourpur DRRMEM STREAM TBP/ASTM CURVES - DEG C SEP-96 STREAM ID 6 7 5 8 NAME GASES Lec RESATM —_GASESDESP PHASE MIXED WET LIQUID WET LIQUID WET VAPOR TBP AT 760 MM HG 2 LV PERCENT 161.490 -131.714 307.316 -162.490 5 -158.549 -54.069 373.357 -161.490 10 130.303 -22.316 404.082 -161.490 30 -37.353 -6.820 484.833 -114.797 50 -6.946 -1.302 558.554 -11.719 70 2eaaa 21.621, 640.623 29.689 90 20.674 25.804 894.828 61.429 85 25.865 31.021, 894.828 80.479 98 32.598 36.423 894.828 120.010 TBP AT 10 MM HG 1 LV PERCENT -195.423 174.206 165.116 -195.423 5 -193.337-127.870 220.870 -195.423 10 -173.195 ~94.403 247.270 -195.423 30 -105.548 -62.857 318.098 -162.056 50 ~82.952 -78.732 384.648 85.514 70 -76.925 69.039 460.952 -55.414 90 62.223, 58.351. 713.354 ~31.273 95, -58.532. 54.414 713.354 716.657 98 3.212 -50.325 713.354 23.984 ASTM D6 AT 760 MM HG 1 LV PERCENT -152.559 120.469 351.820 -152.559 5 148.619 ~35.653 387.330 -143.613 20 -110.769 -0.969 403.850 -143.613 30 28.168 2.183 477.721 -105.934 50 -5.413 0.165 547.055 710.132 70 0.729 10.988 618.412 28.606 30 15.967 20.960 859.061 55.607 95 25.282 30.536 840.447 78.107 oa 38.679 40.486 840.447 124.799 ASTM DBG AT 760 MM HG WITH CRACKING 2 LV PERCENT -152.559 -120.469 336.804 152.559 5 -148.619 -35.653 362.477 -143.613 20 -110.769 0.969 373.201 ~143.613 30 -28.168 2.183 412.067 -105.934 50 -5.413 0.165 437.967 10.232 70 0.729 10.988 456.908 28.606 90 15.967 20.960 508.351 55.607 95 25.282 30.536 504.625 78.107 98 38.679 40.486 504.625 124.799SIMULATION SCIENCES INC PROJECT EOD- 9984 PRO/Iz PROBLEM COMBINADA 2 R VERSION 5.61 ourpur STREAM TBP/ASTM CURVES - DEG C 6 NAME casks PEASE MIXED ASTM D1160 AT 760 MM HG 1 LV PERCENT -137.732 5 -136.237 20 -122.841 30 -32.267 50 -6.946 70 ea 90 20.674 95 25.565 28 32.599 ASTM D1160 AT 10 mM HG 2 LV PERCENT 7178.52 5 177.442 20 167.124 30 101.785 50 -82.952 70 -76.925 80 ~62.223 95 58.532 98 53.212 ASTM D2887 AT 760 NM HG 2. WT PERCENT -235.700 5 133.437 20 -101.874 30 -39.822 50 -6.946 70 5.025 90 26.289 95 33.213 98 47.217 TBP AT 760 MM HG 1 WP PERCENT -161.490 5 -140.776 10 -97.521, 30 711.028 50 4.797 70 4.841 90 22.047 985 26.349 98 33.760 7 LPG WET LIQUID 123.095 -48.439 -17.888 -5.558 -2.302 11-621 25.804 31.011, 36.423, -168.025 -113.728 -91.110 81.915 -78.732 -63.039 58.351, -54.414 -50.335 -120.340 -73.216 -38.962 -13.340 72.302 18.485 32.068 39.520 52.772, -211.120 -37.168 711.977 -6.295 -0.846 12.478 26.336 31.703 36.508 e RESATM WET LIQUID 313.821 378.944 409.248 487.513, 558.554 640.623, 894.828 294.828 894.828 170.549 225.648 252.738 320.485 384.648 460.952 713.354 713.354 713.354 370.609 412.819 445.295 503.182 558.554 621.568 778.906 775.906 775.906 310.837 377.308, 409.709 492.980 569.269 656.127 894.828 894.828 894.828, PAGE P-610 386/EM DRRMPM SEP-96 ° GASESDESP WET VAPOR -182.905 -152..905 -152.905 -212.375 -11.719 29.689 61.429 80.479 120.010 -189.327 189.327 189.327 -160.312 86.514 -55.414 31.273 716.657 13.984 123.338 123.338 -123.338 -79.169 721.719 26.904 57.813 90.725 124.313 -161.490 -161.490 -157.915 -49.346 14.994 39.023 72.243 90.579 128.898