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For offline, simply dovnload our Educore App once & dovnload the e- books inside the app. Educore App is available for Windows Desktop, 10S & Android Eaycore works best in Desktop, Laptop, 7" & 10° tables ‘Typeset by Disha DTP Team Contact us at support@educoreonline.com for any further Note: This app is not accessible on Mobiles. DISHA PUBLICATION ALL RIGHTS RESERVED © Reserved ‘No part of this publication may be reproduced in any form without prior permission of the publisher. The authorand the ‘Publisher do not take any legal responsibilty for any errors or misrepresentations that might have crept in. We have tried and made our best efforts to provide accurate up-to-date information in this book. For further information about the books from DISHA, Log on to www.dishapublication.com or email to info@dishapublication.com GP_3021Senay sonr Ll. 12. 13. 14. 15. 16. 17. 18. 19. 20. a. 22. JEE Advanced 2017 Solved Paper Brean CHAPTERS BASED ON CLASS 11" SYLLABUS ‘Some Basic Concepts of Chemistry Structure of Atom Classification of Elements and Periodicity in Properties ‘Chemical Bonding and Molecular Structure States of Matter Thermodynamics Equilibrium The s-Block Elements Organic Chemistry — Some Basic Principles & Techniques Hydrocarbons CHAPTERS BASED ON CLASS 12 SYLLABUS The Solid State & Surface Chemistry Solutions Electrochemistry Chemical Kinetics & Nuclear Chemistry General Principles and Processes of Isolation of Elements The p-Block Elements The d- and f-Block Elements & Co-ordination Compounds Haloalkanes and Haloarenes Alcohols, Phenols and Ethers Aldehydes, Ketones and Carboxylic Acids ‘Compounds Containing Nitrogen Carbohydrates, Amino Acids, Polymers & Miscellaneous Match the Following Analytical Chemistry 1-6 7-14 15-18 19-24 25-32 33-40 41-50 51-54 55-68 69-76 77-82 83 - 88 89 - 98 99 - 108 109 - 112 113 - 126 127 - 140 141-144 145 - 152 153 - 168 169 - 180 181 - 188 189 - 192aa BEX) 268 1, Some Basic Concepts of Chemistry 1-16 2. Structure of Atom 17-25 3. Classification of Elements and Periodicity in Properties 26-29 4, Chemical Bonding and Molecular Structure 30-43 5. States of Matter 44-54 6. Thermodynamics 55-64 7. Equilibrium 65-84 8. The s-Block Elements 85 - 88 9. Organic Chemistry — Some Basic Principles & Techniques 89 - 104 10. Hydrocarbons 105 - 117 11, The Solid State & Surface Chemistry 118 - 123, 12. Solutions 124-133, 13. Electrochemistry 134-148, 14. Chemical Kinetics & Nuclear Chemistry 149 - 161 15. General Principles and Processes of Isolation of Elements 162 - 164 16. The p-Block Elements 165 - 180 17. The d- and f-Block Elements & Co-ordination Compounds 181 - 197 18, _Haloalkanes and Haloarenes 198 - 203, 19. Alcohols, Phenols and Ethers 204 - 215 20. Aldehydes, Ketones and Carboxylic Acids 216 - 239 21, Compounds Containing Nitrogen 240 - 253 22. Carbohydrates, Amino Acids, Polymers & Miscellaneous Match the Following 254 - 260 23. Analytical Chemistry 261 - 268 + The chapters have been divided as per the Class 11° & 12 syllabus followed by the NCERT books. Some of the chapters which are spit in the class 11" & 12 syllabus in NCERT have been combined. There might be certain topis/ chapters which are not covered in NCERT but are a part of JEE Advanced/ITJEE syllabus. >_3021ee ar | PAPER-1 Soe ‘This section contains 7 questions. Each question has 4 options (A), (B), (©)and (D). ONE or MORE THAN ONE ofthese four ‘options is (ate) correct. 1. An ideal gas is expanded from (p,. V).;) to (P3. V>.T3) under different conditions, The correct tatement() among the following istare) (A). The work done on the gas is maximum when itis compressed irreversibly from (p. V3) t0 (Pi. V,) against constant pressure p, (B) If the expansion is carried out freely, it is simultaneously both isothermal as well as adiabatic (© The work done by the gas isles when its expanded reversibly fom V; to V; under adiabatic conditions as compared to that when expanded reversibly from YV, 10 V, under isothermal eonditions (D)_Thechange in internal energy of the gas is(i) zero, ifit is expanded reversibly with T = T, and (ii positive, ifitisexpanded reversibly under adiabatic conditions with Ty + Ty 2. Fora solution formed by mixing liquids L and M, the vapour pressure of L. plotted against the mole fraction of M in solution is shown inthe following figure, Here x, and Xyq represent mole fractions of Land M, respectively, in the solution. The correct statement(s) applicable to this system is(are) A Y ww 0 (A). ThepointZ represents vapour pressure of pure liquid ‘Mand Raoult’ law is obeyed from x,=0 t0x,=1 (B) The point represents vapour pressure of pure liquid Land Raoult's law is obeyed when x, -> 1 (©The point represents vapour pressure of pure liquid Mand Raoul’s law is obeyed when x, -> 0 (D) Attractive intermolecular interactions between L-L in pure liquid Land M-M in pure liquid M are stronger than those between L-M when mixed in solution, 3. The correct statement(s) about the oxoacids, HCIO, and HCIO,istare) (A). The central atom in both HCIO, and HICIO is sp? hybridized 8) HCIO, is more acidic than HCIO because of the resonance stabilization ofits anion © CIO, is ormed in the reation between Cl, and 1,0 (D) The conjugate base of HCIO, is weaker base than 1,0 Thecolow ofthe Xp molecules of group 17 element changes gradually from yeliow to violet dow the group. This isdue to (A). Thephysicl state ofX, atroom temperature changes from gas to solid down the group (®) Decrease in ionization energy down the group (©, Decrease in x* ~0* gap down the group {B)_Dezrease in HOMO-LUMO gap down the group Addition of excess aqueous ammonia to pink coloured aqueous solution of MCI; 6H,0(X) and NH,Cl gives an octahedral complex Y in the presence of at. In aqueous solution, complex Y behavesas 1:3 electrolyte. The reaction of X with excess HICI at room temperature results in the formation ofa blue coloured complex Z. The calculated spin only magnetic moment of X and. is 3.87 B.M., whereas itis zer0 for complex Y. Among the following options, which statement()isfare)corret? (A)_ Addition of silver nitrate to ¥ gives only two equivalents ofsilve chloride (8) Thebybridization ofthe central metal ion in Y is sp? ©. Zisatetrahedral complex (D) When XandZare in equilibrium at 0°C, the colour of the solution is pink ‘The IUPAC name(s) ofthe following compound is(are) (A)_{-chloro-4-methylbenzene ®) 4-chlorotoluene (© 4-methyichlorobenzene ©) L-methyi-4-chlorobenzene ‘The correct statement() forthe following addition reactions istare) Ee aprcnc a {Mand N vo oH HG Cth c ayycwc w s+ OntOand Pare identical molecules (B) (Mand O)and (N and P) are two pairs of diastereomers (©) (Mand O)and (N and P) are two pairs ofenantiomers Bromination proceeds through trans-addition in both, the reactions SEs Tt 'S questions. The answer to each question isa SINGLE DIGIT INTEGER ranging ftom 0109, both inclusive, 8. A crystalline solid of a pure substance has a face-centred ‘cubic structure with a cell edge of 400 pm. Ifthe density of ‘the substance in the crystal is 8 gcm3, then the number of atoms present in 256 g ofthe crystal is N * 10°. The value of Nis 9, The conductance of 0.0015 M aqueous solution ofa weak monobasic acid was determined by using a conductivity cell consisting of platinized Pt electrodes. The distance between the electrodes is 120 cm with an area of cross section ‘of I em?, The conductance ofthis solution was found to be 5 x 10°98, The pHof the solution is 4. The value of limiting molar conductivity (AS) ofthis weak monobasic acid in 10. 2, JEE Advanced 2017 Solved Paper ‘aqueous solution is Z 10? em"! mol"! . The value of Z is ‘The sum ofthe number of lone pais of electrons on each central atom inthe following species is [TeBrg}*, [BrF,]*, SNF, and [XeF]- (Atomic numbers: N= 7, F=9, Xe=54) “Among Hp, Hey*, Lip, Bey, By, C;,Np,Oz and F, the number of diamagnetic species is (Atomicnumbers: H= 1, He: N=7,0=8, Among the following, the numberof aromatic compound(s) ‘OAAOO OOCO LD Eocene This section contains 6 questions of MATCHING TYPE, contains two tables each having 3 columnsand 4 rows, Based on each table, there are three questions, Each question has four options (A), (B), (C) and (D) ONLY ONE ofthese four option is correct (Qs. 13-15) : By appropriately matching the information given inthe three columns ofthe following table. ‘The wave function, pm is a mathematical function whose value depends upon spherical polar coordinates (r, 0, 4) of the electron and characterized by the quantum numbersn, land m,. Here's distance from nucleus, 0 iscolatitude and 6 is azimuth. Inthe ‘mathematical functions given inthe table, Zisatomic number and ays Bohr radius ColsmaT Column? Caen 2 {2 2 tse © vam (Ze ° o> © 2sorbiat (®)Oneria nade (© Prbailiy density at mules «1 3 So (a 2} lis) oc! Gi vam <(Z]P re) coso—()Prabatitiy desis maximamat nus % iv) 34,2 orbital (iv) xy-plane isa nodal plane (8) _ Energyneeded to excite electron from n=2 n state ton =4 state is > times the energy needed to excite electron from n=6state state 10 GP_3021CHEMISTRY 13, For the given orbital in Column 1, the only CORRECT ‘combination for any hydrogen-like species is (A) GS) 8 Mine © Mme ©) Undine) 14, For hydrogen atom, the only CORRECT combination is A) OO) 8 WMO@ © Moe) © MWR 15, For He* ion, the only INCORRECT combination is A) OO® ®B) iQ © Mee © HHO) 3 (Qs. 16-18) : By appropriately matching the information given in the three columns of the following table Columns 1, 2 and 3 contain starting materials, reaction conditions, and type of reactions, respectively. ‘Column 1 Column 2 Columns T Toluene @_NaOHBr, (PY Condensation (W) Acetophenone (i) Bry/hv ”—(Q) Carboxylation (Ql) Benzaldchyde i). (CHyCO),O/ (R)_Substitution ‘CH,COOK Phenol (iv) NaOWCO, _(S)_Haloform 16. For the synthesis of benzoie acid, the only CORRECT combination is ) Mae ® aye) © MME ©) a@)R) 17, The only CORRECT combination that gives two different carboxylic acidsis, (a) ae ® wMpeing © ani ©) MOS) 18, The only CORRECT combination in which the reaction proceeds through radical mechanism is (A) ae) ® MO © MéGiiy(R) ) (GIR) PAPER - 2 Faces ‘This section contains 7 questions. Each question has 4 options (A),(B),(©)and (D), ONLY ONE of these four options iscortect, 1. Purewater freezes at273 K and | bar. The addition of 345 ‘of ethanol to 500 gof water changes the freezing point of the solution. Us the freezing point depression constant of waters? K kg mol"! The figures shown below represent plots of vapour pressure (V.P.) versus temperature (T) [molecular weight of ethanol is 46 g mol"!} Among the following, the option representing change in the freezing point is t I 3 = a | Water + Ethanol 270273 TK — ® VPiber —+ 273 KS © VPibar —» © VP lar —* 2. For the followingccell, 214s) [ZnSO,(aq) || CuSO4(aq) | Cuts) when the concentration of Zn? is 10 times the concentration of Cu, the expression for AG (in J mot) is [Fis Faraday constant; R is gas constant; Tis temperature; E*(eall)=1,1V) (LIF (© 2303RT+1.1F (B) 2303RT-22F D) -22F‘The standard state Gibbs free energies of formation of (graphite) and C(diamond) at T = 298 K are -A,G°[C(graphite)]= OKI mot 8,6" [C{diamond)] =2.9 mot? ‘The standard state means thatthe pressure should be I ar, ‘and substance should be pure at a given temperature. The conversion of graphite [C(graphite)] to diamond {C(diamond)] reduces its volume by 2» 10-6 m! mol! If graphite) is converted to C(diamond) iothermally at 1'=298 K, the pressure at which C( graphite iin equlibrium swith C(diamand),is [Useful information: 15= 1 kgm?s-®; 1 Pa= 1 kgm! s%, ar = 105 Pal (A) 14501 bar (B) 58001 bar (© 1450bar (©) 29001 bar Which ofthe following combination will produce H, gas? (A) Fe Metal and cone. HNO; (®) Cumetal and cone. HNO, (©) Znmetal and NOH(aq) (©) Aumetal and NaCN(aq) in the presence of at ‘The order ofthe oxidation state of the phosphorus atom in HPO,, ,POy, HsPO, and 11,P,0, is (A) HyPO;> HPO, > HjPO,> H,P,0, (B) HPO, >H1,PO, > 1,P0,>11,P;0, (©) H;PO,>H,P20, > H;PO;> H,PO, (©) HPO, >11,PO,>11,P,0,>11,P0, ‘The major product of the following reaction is on CQ) a ‘)NaNOp Lore “hao NH, ou ‘cl ONa » (4) Cl oul © oe, \=8 N=N OH S o CO JEE Advanced 2017 Solved Paper ‘The order of basicity among the following compounds is MN Ni OL nyc? Su, NON HNN A 1 m mm Vv (A) erervemt @ w>n>m>1 © Werte ©) betvenen ESsonen ‘This section contains 7 questions. Each question has 4 options. (A),(B), (C)and (D). ONE or MORE THAN ONE of these four ‘options is (are) correct. 8 ‘The correct statement(s) about surface properties is(are) (A) Adsorption is accompanied by decrease in enthalpy and decrease in entropy ofthe system (B) The critical temperatures of ethane and nitrogen are 563 K and 126 K, respectively. The adsorption of ‘thane will be more than that of nitrogen on same amount of activated charcoal ata given temperature (© Clouds an emulsion type of colloid in which liquid is dispersed phase and gas is dispersion medium (©) Brownian motion of colloidal particles docs not depend on the size ofthe particles but depends on viscosity of the solution 9, Forareaction taking place in a container in equilibrium with its surroundings, the effect of temperature on its equilibrium ‘constant K in terms of change in entropy is described by (A) With increase in temperature, the value of K for ‘exothermic reaction decreases because the entropy change of the system is positive (B) With increase in temperature, the value of K for ‘endothermic reaction increases because unfavourable ‘change in entropy of the surroundings decreases (© With increase in temperature, the value of K for ‘endothermic reaction increases because the entropy ‘change of the system is negative (©) With increase in temperature, the value of K for exothermic reaction decreases because favourable ‘change in entropy of the surroundings decreases 10, Inabimolecular reaction, the steric factor P was experimentally determined to be 4.5. The correct option(s) among the following is(are) (A). Theactivation energy of the reaction is unaffected by the value of the steric factor (B) Experimentally determined value of frequency factor is higher than that predicted by Arthenius equation (© Since P=4.5, the reaction will not proveed unless an effective catalyst is used (D) The value of frequency factor predicted by Arrhenius ‘equation is higher than that determined experimentally 1. For the following compounds, the correct statement(s) with respect to nucleophilic substitution reaction is(are) Co Cr o ay GP_3021CHEMISTRY 2 2B. 4. H, cH, oa I H,C—C— Br Br cH, ay vy (A) Landi fdlowS,1 mechanism (B) Landi follow$,2 mechanism (©) Compound IV undergoes inversion of configuration (0) Theorder of reactivity fo 1, I and 1V is: 1V>1> I Among the following, the correct statement(s)is(are) (A)_Al(CH,)s has the three-centre two-electron bonds in itsdimerie structure (@) BH; has the three-centre two-electron bonds in its dimeri structure (© AICI, has the three-centre two-electron bonds in its dimeric structure (©) TheLewis acidity of BC, i greater than that of AICI, ‘Tae option(s) with only amphoteric oxides isfare) (A) C1,0,,BeO, Sn0, S10, ®)_x,0,,C10, $n0, POO (© NO,B,0,,P60,n0, (©) 210, A1,0,,Pb0, PLO, ‘Compounds P and R upon ozonolysis produce Q and S, respectively. The molecular formula of Qand $ is CsH,0.Q undergoes Cannizzaro reaction but not halofoem reaction, ‘whereas $ undergoes haloform reaction but not Cannizzaro reaction @ P a wyZaiH20” (cyHx0) noyone, i) R @ RANeaBO? ceo, ‘The option(s) with suitable combination of P and R, respectively, is(are) (a) HC: © SEs This section contains 2 paragraphs, each describing theory, experiments, data ce. four questions related to the two paragraphs with two questions on each paragraph, Each question has only ‘one correct answer among the four given options (A), (B), (C) and (0). PARAGRAPH UponheatingKCIO, inthe presence ofeatalytic amount ofMnO,, agas Wis formed ExtessamountofW reacts with white phosphors to give X. The reaction ofX with pure HNO, gives Y and 18. Wand X ar, respectively (A) O,and P,0, © Oj and POjo 16. Yand Zar, respestively (A) N,OsandH1,PO, —@)_NOsand IPO, (© NjOyandHPo,’ — (D)_NjO, and H, PS, PARAGRAPH? ‘Thereaction ofcompound Pwith CH, MgB (excess) n(CyH),0 followed byaddition of H,OgivesQ Thecompound Qontreatment with H,SO, at 0°Cgives R. The reaction of with CHjCOCLin the (B) O, and P,O, o Otand PLOsy presenge anhydrous in CHC followedbytreatment with 1,0 produces compound $ [Et in compound P is ethyl group} Hoy oS Et —>Q—> R—+S 17, “The produ is aoe “w H,coc WoC HSC. cH, © | HOS coct, The reactions, Qto R and R to, are (A) Dehydration and Friedel-Crafts acylation (B) Aromatic sulfonation and Friedel-Crafts acylation Friedel-Crafts alkylation, dehydration and Friedel Crafts acylation (D)_Friedel-Crattsalkylation and Friede!—Craftsacylation2 JEE Advanced 2017 Solved Paper SOLUTIONS Paper - 1 ABO 3 (A) During adiabatic expansion, the final temperature is less than the initial temperature. ‘Therefore the final volume in adiabatic expansion will also be less than ‘the final volume in isothermal expansion, This can be graphically shown as fe VAT) reversible otbermal ‘everble aiatic ‘The magnitude of work done by the gas is equal tothe aa under thecurve. As een ffom the figure the area under curve in reversible isothermal is more, Hence, the magnitude of work done is lesser in adiabatic reversible expansion as compared to the corresponding, work in isothermal expansion. 4 (8) _Infecexpansion, P= 0. W fcarried out isothermally (AU=0)=>q=0(Adiabatic) ; From! law If carried out adiabatically (q = 0) => AU (Isothermal) ; From I law: oF vy Y rN v During irreversible compression, maximum work is ddone on the gas (corresponding to shaded area) When T,=T, => AU=nC,AT=0 In reversible adiabatic expansion, T, HCI+ HOC HCI0,+ 1,0 > C10; +10" ‘Acid Basel Basel acid | Since 1,0 is accepting 11° from HICIO, so H,0 is stronger base compared to CIO; (GD) ‘The colour of X, molecules of halogens is due to absorption of light inthe visible region. The energy acquired inthis manner excites the valence electron fiom the highest occupied molecular orbital (HOMO) tothe lowest unoccupied molecular orbital (LUMO), ice, transition from x" to" molecular orbital X, :018, 0418, 028, 0°28, 02p2, 1p? © 2p,2, © 60) [cott.o),]cl, Serra [CON] Ch, % 0 Pink Solution 1:3 destoite HCI (excess) (d°sp' hybridisation of central roo epee ‘metal atom as NH, isa strong - field ligand) @ 3AgCI G09 of AgCI) isa weak field ligand) one) ra X and Z in equilibrium at 0°C = then equilibrium is shifted towards X, making colour of solution pink. GP_3021(CHEMISTRY 6 (A.B) TUPAC name a cH, 1 1 2 2 a) |-chloro-4-methylbenzence @) ‘4-chilorotoluene 3 3 4 cH; al 7. (BD) (B) _Bromination proceeds through trans-addition in both the reactions. Mand Nare identical, hence, M and O and N and P are two set of diastereomers, @) Br cn, i iH H a a cu; H = 1 cn, : cH, dL — ck, ony, i i Br trane-2-Butene veer Bromonien ion NY H CH, cHy Br Br cHy H cH, on Mand Wares (rawr Dione) Br ony i ; cH, el ” ; =o a cu, | BeBe H; H on, on — « F u vs CH; “Near eed-Buene ce-samnom in NS H cH, cH, Br pr—-un Br ~ Ht pr e cn, cu, @) and are enantiomers ‘ne2, }Divemebuare10, @ 6 6 (6) H, Hef Density(@)= f= msi = TN, (d= density) For FCC, Z Givena=4» 10-%em bom (11079) xoxo (tao) xox —— 8610 6410 + M= No. of atoms = —— “x Ny, 19 oF atoms lar mass 256 x10 610% 8x6x16 ~ ValueofN=2 =2«108 The formula for conductances G = x <# sx107 u “io K=6% 10Sscm™ «x1000_ 6x10 x1000 M0005 vs pina Ur] =104=ca=000150 104 D001 An. 1o* Ag 00015 Mn 1075 em? mote! ieen6 Species Numberoflone pars ‘on central atom @ [Tebr,P 1 Gi) (Br, 2 ii) SNES 0 (iv) [XeF 3 ‘Tetal number oflone pairs= 1+2+0+3=6 (it, Cl,, Bey, Cy, Nas F3) is? ~ (Diamagnetic) Glsotls! (Paramagnetic) ols! ot1s?,o2s? _(Diamagnetic) Gls! o*1s%,02s%,6¢2s? (Diamagnetic) ols, 0°18, 028%, 028%, 2p = x2p) (Paramagnetc) ols? o* 1s, 023%, 0°28, n2p% = 203 (Diamagnetic) 2 6 B. © 14.) JEE Advanced 2017 Solved Paper 02s, 6*2s*, x2p, = x2p},02p2 (Diamagnetic) als?,o* ols, 0", 0287, 61282, x2p2 ,72p% = n2pi,n*2p2 = x*2ph (Paramagneti) ols?, o* Is?, 0282, 6*2s?, 62p2 ,x2p% = nap}. n*2p8 = 0293 (Diamagnetic) OAD Ton-aromatie Anti-aromatic Nomaromatie Antaromatic AOg Aromatic Aromatic Aromatic ‘Aromatic Aromatic 1s wave function for He' is given by (2) Vad) 2 «(gold ice, itis independent of cos 0 ‘The probability of findingan electron at zero distance from the nucleus is zero. The probability increases ‘gradually asthe distance increases, goes tomaximum and then begins to decrease. Fora given orbital with principal quantum number, n ‘and azimuthal quantum numbr,é ‘Number of radial nodes = (n- ¢—1) Vem GP_3021CHEMISTRY 9 BO 16. (a) m © 18. 0) Lo 2 @) Referans 13. Energy needed toexcite from n=2ton=4 8 nh AE, 61362? « se0V on dividing, Alkylbenzenes when treated with Br, at high temperature, in the presence of sunlight and absence of halogen carrier undergo halogenation in the side chain, Thus fs A Bry Le. - Tea Toe Beruylcionide Benwy cinive Ope Oe von Hom Oo ‘COOH Perkin condensation of benzaldehyde with (CH,CO),0/CH,COOK yields cis and trans form of cinnamic acid, (OCHsCOONs GHGCHO + (CHZCO),0 OTN Cr cH = cHCOOH Berzaldehyde Acetic anhydride (DH? inamic acid ‘dsand vane Paper - 2 {As Tincrease, VP. increases at Km 4.51000 46 %500 T-20K 273~ Zn(s)+ Cups > Znf’ + Culs) Yaa) Given (2n2"]= 10{Cu"} AG=-2F (1.1) +2303 RT logi910=2.303 RT-2.2F10 3 (A) Ate aG=0 @-)= = 14510 5 = 145 «10°Pa 1. asx «10°+ 1Pa 14500 105+ 1= 14501» 105Pa= 14501 Bar 4. (© Fe+conc. HNO, > Fe,0, Cu cone. HNO} -»CuNO, +NO, + H,0 4Au + 8NaCN +0, + 21,0 ->4NafAu(CN))+4NSOH Zn+ NaOH» NaZn0,+ Hy (©) Correct order HPO, > H,P,0g > HyPO3 > HPO, by ebay Gy © Step: ONINOR HOLE, aH Mu, Naw & Step2: vas) Diazocoupling ire He 2O fy #4 ua vn sia, Sint avy The conjugate acid is stabilized by resonance with two different “NH group. Hence electron density increases on N of = NH ve We Cy on Sw cs Sin, o JEE Advanced 2017 Solved Paper The conjugate acid is stabilized by resonance with ‘one -NH, group. Hence as compared to IV lesser increase of electron density on N of = NH NANT Hog 0) Lone pair is not involvd in aromaticity. Hence more available ) ay Lone pair is involved in aromatic sextet, Hence not available Hence the corteet order of basic strength is Iv> I> > (A,B) (A) As adsorption is spontaneous, AG for the process is ve. Adsorption is accompained by decrease in randomness, Therefore AS and TAS for the process is also negative. As AS for the process is —ve and the ‘process is spontaneous, AH for the process has to be “ve ie, enthalpy of the system decreases. Under a given set of conditions of temperature and pressure the easily liquefiable gases e.g. C,H, NH, ‘and HCI are adsorbed more than the gases like N, H, and CO. The ease with which a gas-can be liquefied is determined by its critical temperature. Critical temperature is the minimum temperature above ‘which a gas can be liquified. This implies that gases ‘with high critical temperature values can be easily liquified as compared to gases with low critical temperature value. (A,B,D) (A,B) The Arrhenius equation is k= AetaRt ‘where A= Pre-exponential factor Aiisnot directly related with temperature and activation energy. NH Where A= Zk P (Frequency factor)” (tei factor) Hence we can say the Ei independent of strc factor p- Kaul K theoretical $0, Axoat ” Aired GP_3021CHEMISTRY un 1. ABO, c I 0 (Cmte ef Broan rates é Land I follow S,2 als, as both ae 1° halide (© Compound (IV) undergoes inversion of configuration due to presence of chiral carbon atom. 12. (A,B,D) (A) Structure of AL(CH,), 3C-2e" Bond B) Structure of BH, 1 GX B LS 3c-26° iC (© SteuctureofAL,Cl, ON el ae Na “er (©) BCI, is stronger lewis acid as the bond formed with the base will involve 2p orbital overlap which isstronger than 3p orbital overlap in the case of AICI, 13, (A.D) NO=>Neutral BO, = Acidic CO= Basie Allothe oxides are amphoteric 14. (A,B) an) Y Woveitsls a l © ay A BOERS > Q(CiHLO) i, CH nen () « a \(+ve cannizaro reaction) ° 1 c ° 00,0140, Neu i WzZnto > 3 +H-CH ne (© (+e haloform reaction)R 18, n. JEE Advanced 2017 Solved Paper ant a +cH, le Mis (-ve cannizaro reaction) @) @ 2 9 »N \ i Oo cH oven, CY it, +H, -E-cH, ta Nau, cH, (Gve haloform reaction) ) © © & 6B) KCIO,; 3 KCI+ 0 ° om P+ 0; P00 (bie) (exces) Ox) P,O,,+HNO,—> Nz05+HPOS w wo & 8 © 9 OMe CCH), 6 j “OF cI OL) P) ” [x0 HoH 0" O-H CCH), CH): cCHy, ~cH,-¢-cH, OU OL [0 (Getyaraon) @ cH, ® ci, -C-c1/alcl, ‘Geylation) cH, CCH) CH Coch, o GP_3021(CHEMISTRY ‘Which of the following compounds will form significant amount of meta product during mono-nitration reaction ? ‘OH OCcOCH, a a The increasing order ofthe reactivity ofthe following halides for the Sy! reaction is CHLCHCH CH, CHCHCH,CL a a 0 PrH,CO-C,H,-CH,CL a @ ay Na,Zn0, (B) 2n0+C0,-+ZnC0, (1) base and acid 2) base and base @) avid and acid @) avid and base Both lithium and magnesium display several similar properties due to the diagonal relationship; however, the ‘one which is incorrect is (1). Both form basic carbonates, (2) Both form soluble bicarbonates (@)_ Both form nitrides Nitrates ofboth Liand Mg yield NO, and O; on heating 3-Methyl-pent-2-ene on reaction with HBr in presence of peroxide forms an addition product, The number of possible stereoisomers for the product is () S% @) Zer0 @) Two Four ‘A metal erystallises in a face centred cubic structure. Ifthe ‘edge length ofits unit cell is’, the closest approach between two atoms in metallic erystal will be () @ Wa @) Va @ ¥ ‘Two reactions R, and R, have identical pre-exponential factors. Activation energy of R, exceeds that of Ry by 10k mot". Ifk; and k, are rate constants for reactions Ry and respectively at 300K, then In(ky/k,) is equal to (R=8314J mol !K"}) m8 @r @ 6 wam2 4 16. 17. The correct sequence of reagents for the following ‘conversion will be HQ CH, : “0 CHO cH,” (1). TAg¢NHL),]” OFF, HY/CH,OH, CH; MgBr @)_CHjMgBr, H*/CH,OH, [Ag(NH,),]* OF" G)_CHjMgBr, [Ag(NH),)° OFF, H'/CH,OH (4) [Ag(NHL),]* OF, CH,MgBr, H'/CH,OH ‘The Tyndall effect is observed only when following, ‘conditions are satisfied (@) The diameter ofthe dispersed particles is much smaller than the wavelength ofthe light used (b) ‘The diameter of the dispersed particle is not much smaller than the wavelength ofthe light used. (©). The reftactive indices of the dispersed phase and dispersion medium are almost similar in magnitude (@) The refractive indices of the dispersed phase and dispersion medium differ greatly in magnitude. (1) (@and(@) @) (banda) G) (@and(o) (4) (byand(e) ‘Which ofthe following compounds will behave asa reducing, sugar in an aqueous KOH solution? HOH 9. CHOW 1 i HYScoc, HOILC So. cHhoHt HOH. o. CHLOH ‘ Pi Hy none Q.CH,OCH, ) Kou on ou Given Cigraphie) * O18) > COLE) + AJP =-393.5 ki mot! 1 Hy (g)+ 50,8) > H,00); a 19. 20, 24. 2. 24 JEE MAIN 2017 Solved Paper CO4(g)+ 2H,O() + CHY(g)+ 20,62). AHP =+8903kJmot"! ‘Based on the above thermochemical equations the value of| A HP at 298 K forthe reaction C eahite)* 2H(8) —> CH,(g) will be () +748kImort ——Q) +1440 mot! @) =748kImor 4) = 144.0kF molt ‘Which of the following reactions isan example of a redox reaction? ())_ Xe, +0,F, > XeF, +0, Q)Xck, + PFs > [XeF]* PF @)_ XcFg+H,0-> XcOF,+2HF () Xek,+2H,0—> Xe0,F,+4HF ‘The products obtained when chlorine gas reacts with cold and dilute aqueous NaOHare (@) ClO-andclos ——@)_Clogand clog @) Cr-andcio- @ Crand clos “The major product obtained inthe following reaction is Be CH, _‘BuoK, cng 0) yCGHGCHKOBUICHACHs Q) CH CH= CHC,H, 8) CC HCHOBICH,CoH, 4) COCHGCHLO'BUICHCHH, Sodium salt of an organi acid" produces effervescence with cone, H,SO,,'X'reats wit the acidified aqueous CaCl, solution to give whit prespitate which declourises acidic solution of KMnO, (1) CglgCOONa @) HCOONa @) CHjCOONa @) NaxC0, Which of the following species is not paramagnetic ? @ NO @ @) 0, ® B ‘The freezing point of benzene decreases by 0.45°C when 0.2g of acetic acid is added 1020 g of benzene. ITacetic acid associates to form a dimer in benzene, percentage association of acetic acid in benzene willbe (K for benzene= 5.12 kg mol!) () 646% @ 804% 0) 16% ) 146% Which of the following molecules is least resonance stabilized? 0 O oll J GP_3021(CHEMISTRY ZF @ I ® SN 0’ 25. On treatment of 100 mL of 0.1 Msolution of CoC. 6H,0 with excess AgNOs; 1.2 = 102? ions are precipitated. The complexis: (@) [Co(H,O),C1,]C12H,0 2) [ColH,0);C1,]3H,0 B) [ColtH,OVJIC1; (4) [Co(H,0),C1}C1,H,0 26, The major product obtained in the folowing reaction is 7 DIBAL-H. ‘coor on on 0 THO @ qo ‘coon ‘cHo 8 rer ® Qe ‘coon clo 2. 28, 29, 30, mins ‘A water sample has ppm level concentration of following 0,803-= 100, NOs =50 the anion/anions that make/makes the water sample Unsuitable for drinking isare () only NOS both $0}- and NOs B) only @) only SOF 1 gram ofa carbonate (MjCO;) on teatment with excess HCI produces 0.01186 mole af CO,, The molar mass of M,CO, in gmol”" is () 1186 @ a3 @) 1186 @ 1186 Given . 36V.E8 5, = -O74V, eer eter Ee =1.33V,E° =LSIV. eyo 10 soz Among the followin, the strongest reducing agents Oa @Q) Mn+ @ co @ ‘The group having isoelectronic species is () OFF Nat, Mg @) O-.F.Na,Mg* (@) 0%. F,Na, Mg (8) OF LNat, Mg?aad JEE MAIN 2017 Solved Paper SOLUTIONS (@)_ Nitration takes place in presence of concentrated HINO, + concentrated H,S0, In strongly acidie nitration medium, the amine is converted into annum ion NH"), substitution is thus controlled not by ~ NH group but by ~ NIT;* ‘group which, because of its positive charge, directs the entering group to the meta-position instead of ortho, and para ° NH, Nitj gp: mairecting = Ni yp. 0, pirecting 3) From 1" lawofthermodynamies AU=q+w For adiabatic process qz0 AuU=w @) Since Sy1 reactions involve the formation of carbocation as intermediate in the rate determining, step, more isthe stability f carbocation higher will be the reactivity ofalkyl halides towards Sy! route ‘Since stability of carbocation follows order cH,-cr- Ct; on 190, Sie? 2n00; ° tee ied lt 10, (1) Mgcan form basic carbonate like 4 Henson, 3MgCOs. Mg(OH),. 31,01 aes regs While Li can form only carbonate (LiCO;) not basic uo foun carbonate. wicnon IL. (4) Iftwo chirality centres are created as a result of an (comsibcation) addition reaction four stereoisomers can be obtained ° as products cuy cH, ra = nZ Negi,” s ‘cis-3, methyl pent-2-ene 07 Soc, een [evs toi —CH-CH-CH,—CH, cH 2, Brome, meth pentane Eaters) cH, CH ht Br Be Hl HE-G- Cth on h cH, HC 1 on @ 16. (1) CH, CH, “ ee HOCH, 9 c1,0H noct, cr 0 —Agxou Wt Scatwcon Br H 4 Br OW ou OF Hemiketal H CH, HAC: H [pi ornine Gis Gls HOW OH cron aun a) evesiver | rats OF 12, (4) ForaFCC unitcell test _ ou va (a Reducing sugar) a-hydroxy ketone " f Raa closest distance (2) = 28. 8 QoSm6 n. 19, 20. 2. 2. 8) Given COja)+ 21,00 > CH) +20,(8), 4? =8903.(0) Cape) + 2 @)-> COB); ar L Hy(e)+ 70,8) > 1,010), AJP =-285 8k mot! i) A,H? = D(A Hous ~ (ArH? peatats 393.5kImot (i) 890.3 =[1(ay HP)cu, +2*0)]-L1(-393.5)+2(-285.9)] (6; Hau, = 8903-965. =74.8KI/mol (1) Inthe reaction sn Ker, +O,F, > Ker, +0, ia (8). Cly+ NaOH» NaCl+ NaCIO+H,0 [oold and dilute] (2) Elimination reaction is highly favoured if (@) Bulkier base is used (©) Higher temperature is used Hence in given reaction biomolecular elimination reaction provides majr product. cn is ‘ Calls cf SS 001+ Br (8) NagC,0, +150, > Na,S0, +COT +CO,1+1,0 (exe) NNagC0, +CaCly->CaC,Ogb + 2NaC1 . (oti) SCaC;0,1-42KMn0, +8150, tout K,$0, +5CaS0, +2MnS0, + 10CO, +8H,0 (cts) 2 1 NO->one unpaired electrons presentin * molecular oxbithence paramagnetic 2. 2 25. 26. @ 4 “ @ JEE MAIN 2017 Solved Paper €0-» of, 01.003. Ry 222 ‘no unpaired electron hence diamagnetic. ‘vo unaired electron hence paramagnet. 'B, contains two unpaired electrons hence paramagnetic Inbenzene 2CH,COOH = (CH,COOH), Ia aw - 1000 AT,= Kym @ 1-$=0527 a=0945 °% degree of association = 94.6% ° js nonaromatic and hence least reasonance stabilized whereas other three are aromatic. Molarity x Volume( ml) ‘Moles of complex = 1000 000. 1000 01 mole ‘Moles of ions precipitated with excess of 12x10 02x10 AgNO, 0.01 xn=002 -2 ttmeans 2CI- fons present in ionization sphere + complex is{Co(H,0),C1}CI, HO 2 moles DIBAL-Hisan clectrophilic reducing agent. Itreduoes both ester and carboxylic group into an aldehyde at GP_3021(CHEMISTRY mie low temperature, BW Foggy? ESV a p EB =136V onicr a Pogoitices =133V co,H CHO . am 27. (3) Above 2 ppm concentration of F- in drinking water etree cause brown mottling of teth Since Cr is having least reducing potential, so Cr is. 28 (2). Given chemical oq? the best reducing agent. M,CO,+2HC > 2MCI+H,0+CO, 30. (I)_Isoelectronie species have same no. of electrons. lem 001186 mot ions 2 Nag? fiom the balanced chemical eq $20 2 nM,CO;=n00, Noofe= 10 10 0 1 therefore OF, Nat, Mg*? are isoeletronie 1 = 001186 M,CO, 1 = M,CO, oori86 => M=843 gmimolCHAPTER Some Basic Concepts of Chemistry | cee JEE dvanced/ IIT- a 5’ Rms 1. Themodem atomic mass unit is based on (1980) 2. The total number of electrons present in 18 ml of water is (1980) 3. 3g ofasalt of molecular weight 30 is dissolved in 250 g of water. The molality of the solution is. (1983 - 1 Mark) The weight of 1 « 10%? molecules of CuSO, SH,Ois (2991-1 Mark) $8. The compound YBa,Cu,O,, which shows super- conductivity, has copper in oxidation state assume thatthe rare carth clement ytrium isin its usual +3 oxidation sate (1994-1 Mark) C Trae eontauecos 1. 27g of Al will react completely with how many grams of oxygen? (1978) @ 88 ) 16g © Re @ 242 2. A-compound was found to contain nitrogen and oxygen in the ratio 28 gm and 80 gm respectively. The formula of compound is (1978) @ NO () N,0, © N,, @ NO, 3. The largestnumber of molecules isin (1979) (@) 36gofwater (b) 28 gofcarbon monoxide (©) 46 g ofethyl alcohol (@) 54 gofnitrogen pentoxide 4. The total number of electrons in one molecule of carbon dioxide is (1979) @ 2 ) 4 ©) 6 @ 8 A gaseous mixture contains oxygen and nitrogen in the ratio of | 4 by weight. Therefore the ratio of their number of molecules is (1979) @ ba © 18 © 7:32 @ 3:16 2. 1B. MW 2.16 g ofsilver carbonate on being strongly heated yields a residue weighing (1979) (@) 216g (b) 2488 (© 232g (@) 2648 Mis molecular weight of KMn0,, The equivalent weight of KMnO, when itis converted into K,MnO, is (1980) @ M () M3 (© Mis @ M7 1£0,50 mole of BaCl, is mixed with 0.20 mol of Na,PO,, the ‘maximum number of moles of Ba,(PO,), that canbe formed is (1981-1 Mark) (@ 070 (®) 050 (©) 020 (@ 010 One mole fN;H, loses ten mols of electrons to form anew compound Y. Assuming that al the nitrogen appears inthe new compound, what isthe oxidation sat of nitrogen in ¥? (There is no change inthe oxidation stat of hydrogen). (1981-1 Mark) @ 4 © 3 @ 8 (@ + The oxidation numberof carbon in CHO is © (1982-1 Mark) @ -2 () +2 @ 0 (@) +4 Armolal solution isone that contains one mole ofa solute in (1986-1 Mark) @ ® 1000 g ofthe solvent one litre ofthe solvent (©) one litre ofthe solution () 224liteesofthe solution The brown ring complex compound is formulated as {[Fett1,0),(NO))SO,, The oxidation state of iron is @ 1 () 2 (1987-1 Marky @3 @o The equivalent weight of MnSO, is half ofits molecular ‘weight when itis converted to (1988-1 Mark) @ Mn,0, (&) MnO, ( Mnoy (@ Moo} In which mode of expression, the concentration ofa solution remains independent oftemperature? (1988 Mark) (@) Molarity (6) Normality (©) Formalty (d) Molality GP_302115, 16. v. 20. a. 2. 2B. m4, opie. wise Sotved Papers - CHEMISTRY ‘The oxidation number of phosphorus in Ba(H,PO,)> is: (1990-1 Mark) @ 8 ) 2 on @ = The oxidation states ofthe most electronegative element in the products ofthe reaction, BaO, with dil. H,SO, is (1991-1 Marky (b) -Land—2 (@ —2and-1 (1992 - 1 Marky (a) Oand-1 (©) -2and0 Forte redx easton MaO} + CO} +H» Mn8*+ C0, +140 the core coecents ofthe reactants forthe balanced reaction are (1992-1 Mark) Mn0z Cx a @ 2 5 6 ® 6 5 2 @ 5s 6 2 ® 2 6 s The normality of 0.3 M phosphorous acid (H,PO; is, (1999-2 Marks) @ a () 09 © 03 @ 06 The oxidation number of sulphur in Sy, SF, HS respectively, are (1999-2 Marks) @ 0,+1and-2 () #2,41and-2 (©) 0,+1and+2 (@ -2+1and-2 Amongst the following identify the species with an atom in +6 oxidation state (20008) ©) Mn0x (6) CHONE (© Ni @ C0,Cl, ‘The reaction, 3C1O-(aq) —» C10 ; (aq) + 2C1aq), isan exampleof 20015) (@)_ oxidation reaction (©) reduction reaction (©) disproportionation reaction (@)_ decomposition reaction ‘An aqueous solution of 6.3 g oxalic acid dihydrate is made up to 250 mi. The volume of 0.1 N NaOH required to completely neutralize 10 mil ofthis olution is (20018) @ Om () 20m (© 10m (4m In the standardization of Na,S,0, using K,Cr,0, by ‘odometry, the equivalent weight OfK,Cr,0,i8 (20018) (@) (molecular weighty2 (©) (molecular weighty’6 (©) (molecular weighty3 (6) same.as molecular weight Howmany moles of electron weigh one kilogram? (2002S) L 108 x10 (2) 6.02310 © 6023 sos © 5508"! recor 2S. Which has maximum number of atoms? (20038) (@) 24gofC(12) (b) SogofFe(56) (©) 27gofAl(27) (d) 108g of Ag (108) Mixture X= 0.02 mol of [Co(NH,),S0, Brand 0.02 molof [Co(NH,),Br]SO, was prepared in tre ofsolution. 20035) | ite ofmixture-X++ excess AgNO, —_ ¥. {ite of mixture X+ excess BaCl, —_, Z ‘No. ofmoles of Y and Zare (@) 001,001 (b) 0.02,001 (©) 001,002 (d)_0.02,002 27. The pair ofthe compounds in which both the metals are in the highest possible oxidation state is (20048) ©) [Fe(CN)g]*[CO(CN) 6} (db) CrO,C1,,Mn0g (©) Tis,MnO, (d) [Co(CN),}".MnO, 28, Consider a titration of potassium dichromate solution with acidified Mohr's salt solution using diphenylamine as indicator. The number of moles of Mohs salt required per mole of dichromate is, (2007) @ 3 ) 4 5 @ 6 E Bie 1. What weight of AgCI willbe precipitated when a solution containing 4.77 g of NaCl is added ta solution of 5.77 got AgNO,? (1978) 2 One gram ofan alloy of aluminium and magnesium when tweated with excess of dil, HCL forms magnesium chloride, aluminium chloride and hydrogen. The evelved hydrogen, collected over mercury at 0°C has a volume of 120 litres at 0.92 atm. pressure. Calculate the composition ofthe alloy. (H=1,Me=24,a1=27) (1978) 3. Igniting MnO, converts it quantitatively to Mn,0, A sample of pyrolusite is ofthe following composition | MnO, 80%, SiO, and other inert constituents 15%, rest being water, The ‘sample is ignited in air to constant weight. What is the percentage of Mn in the ignited sample? (1978) [0=16,Mn=349] 4.4215 g ofa metalic carbonate was heated ina hard glass tube and the CO, evolved was found to measure 1336 ml at 27°C and 700 mm pressure. What is the equivalent weight of the metal? (1979) @) 55 gofamintureof FeSO, 7H,0 and Fe,(S0,),. 9,0 requires 4 ml of0.1 NKMn0, solution for complete exidation. Calculate the number of gram mole of hydrated ferric sulphate inthe mixtureSome Basic Concepts of Chemistry § ——________ 4 10. (b) The vapour density (hydrogen = 1) of a mixture consisting of NO, and N,O, is 383 at 26 7°C. Calculate ‘the number ofmoles of NO, in 100g ofthe mixture 979) 5 mil ofa gas containing only carbon and hydrogen were ‘mixed with an excess of oxygen (30 ml) and the mixture exploded by means ofan electri spark. After the explosion, the volume of the mixed gases remaining was 25 ml, On adding concentrated solution of potassium hydroxide, the volume further diminished to 15 mi ofthe residual gas being pure oxygen. All volumes have been reduced to N.T.P Calculate the molecular formula ofthe hydrocarbon gas. zz) In the analysis of 0.500 g sample of feldspar, a mixture of chlorides of sodium and potassium is obtained which ‘weighs 0.1 180g. Subsequent treatment of mixed chlorides with silver nitrate gives 0.245 1g ofsilver chloride. What is the percentage of sodium oxide and potassium oxide in feldspar. (1979) ‘A compound contains 28 percent of nitrogen and 72 percent cof metal by weight. 3 atoms of metal combine with 2 atoms OfN. Find the atomic weight ofmetal (198) ()_Asample of MnO, 44,0 is strongly heated in ai. The residue is MnO, (i) The residue is dissolved in 100 ml of 0.1 N FeSO, containing dilute H,S0, (ii) ‘The solution reacts completely with 50 ml of KMnO, solution (iv) 25mlofthe KMnO, solution used in stp (ii) requires 30m of. N FeSO, solution for complete reaction Find the amount of MnSO, 4H,0 present inthe sample. (1980) (@) One litte ofa sample of hard water contains 1 mg of CaCI, and 1 mg of MgC. Find te total hardness in terms of parts of CaCO, per 10® parts of water by weight. (6) Asample ofhard water contains 20 mg ofCa"* ions per litre. How many milli-equivalent of Na,CO, would be required to soften I litre ofthe sample? (©) 1.gmof Mg is burnt in a closed vessel which contains 0SgmofO, © Which reactant islet in excess? (Gi) Find the weight of the excess reactants? Gi), Howmay milliliters of0.5'N H,SO, will dissolve the residue in the vessel (1980) A hydrocarbon contains 10.5g of carbon per gram of hydrogen. | litre ofthe vapour of the hydrocarbon at 127°C and | atmosphere pressure weighs 2.8g, Find the molecular formula 19s) 2. 13. 1 18. 16. W. Find (i) The total number of neutrons and (id) The total mass ofneutron in 7 mg of ¥C. (Assume that mass of neutron = mass of hydrogen stom) A mixture contains NaCl and unknown chloride MCI. () 1 g ofthis is dissolved in water. Excess of acidified ‘AgNO, solution is added to it 2.567 g of white ppt. is formed (1 goferiginal mixture isheated to 300°C. Some vapours ‘come out which are absorbed in acidified AgNO, solution, 1.341 gof white precipitate was obtained. Find the molecular weightof unknown chloride. (1980) ‘A 1,00 am sample of H,O, solution containing X'per cent H,0, by weight requires ml of a KMnO, solution for complete oxidation under acidic conditions. Calculate the normality ofthe KMnO, solution. (1981 - 3 Marks) Balance the following equations. (1980) (@ QKO+HT+ NOs > Cu" +NO+H,O (1981-1 Marky (i) K,[FACN),J+H,80,+H,0 > K,80, + FeSO, +(NH,),80,+CO (1981-1 Mark) (ii) C,H,OH+ 1,4 OH > CHL, + HCO 5 +1 +H,0 (1981-1 Mark) Hycroxylamine reduces iron (Il) according to the equation: 2NHLOH +4 Fe > N,O(g) T+ H,0 +4 Fe® +41 Iron (II) thus produced is estimated by titration with standard permanganate solution. The reaction is MnO; +S Fe2*+ 8H" ‘A.10 ml sample ofhydroxylamine solution was diluted to 1 litre. 50 ml. of this ciluted solution was boiled with an excess ofiron (ID solution. The resulting solution required 12m of 0.02 M KMnO, solution for complete oxidation of iron (UD). Calculate the weight of hydroxylamine in one litre ofthe original solution. (H= 1, N= 14, = 16, K=39, Mn=S5, 6) (1982-4 Marks) The density of a 3 M sodium thiosulphate solution (Na,S,0,) is 1.25 g per ml. Calculate (i) the percentage by weight of sodium thiosulphate, (i) the mole faction of sodium thiosulphate and (i) the molaities ofa’ and S,0,2- ions (1983 -§ Marks) 408 gofamixture of BaO and an unknown carbonate MCO, ‘was heated strongly. The residue weighed 3.64 g. This was dissolved in 100 ml of !N HCL The excess acid required 16 ml of 25 N NaOH solution for complete neutralization [dentify the metal M. (1983-4 Marks) (At wt H=1, C= 12,0=16,C1=355,Ba= 138) Mn2* +5 Fe! +4H,0opie. wise Sotved Papers - CHEMISTRY 19, 20. a 2. 2B. 24, 25, Complete and balance the following reactions: (Zn NOs 9204 NH} (1983-1 Mark) (i) Cr,03" +C4Hj0-> CHO, +C* (1985-1 Mark) (ii) HNO, +HCI>NO+Cl, (1983-1 Mark) (iv) Ce + 8,03" SOP +Ce* () Ctl Cr+ C10- (4983 - 1 Mark) (1983 - 1 Marky (vi) Mn+ PbO,>MnOg +H,O (1986-1 Mark) (vi) S+ OH S?-+ 8,03 (1986-1 Mark) (il) CIOs +1-+H,S0,-> C+ HSO% (1986-1 Mark) () AgtAsH> HAsO, +H (1986-1 Mark) 2.68» 10° molesofa solution containing an ion 4" requite 1.61 « 10° moles of MnO for the oxidation of 4"* to 'AO} in acid medium, What isthe value of n? (1984-2 Marks) Five of 8Nniticaci, 48 ml of SN hydrochloric acid and a certain volume of 17M sulphuric acid are mixed together and made upto 2itee. Thirty ml ofthis acid mixture exactly neutralise 42,9 ml of sodium carbonate solution containing ene gram ofNa,CO,,10H,0 in 100m of water. Calculate the amount in gram ofthe sulphate ions in solution (1985 - 4 Marks) Arrange the following in inereasing oxidation number of iodine, (1986-1 Mark) 1,,HI,HIO,,ICl (What isthe weight ofsodium bromate and molarity of solution necessary to prepare 85.5 ml of0 672 N solution ‘when the halfcell reaction is BiO3 +611" + 66> Br-+3H,0 i) What would be the weight as well as molarity ifthe half-cell reaction is: 2BrO; + 12H*+ 10e-—> Br, +6H,0 (1987-5 Marks) A sugar syrup of weight 214.2 g contains 34.2 g of sugar (C jlagO,).Caleulate: (i) moll concentration and i) moe fraction of sugar in the syrup. (1988-2 Marks) A sample of hydrazine sulphate (N;H,SO,) was dissolved in 100 mi of water, 10 ml of this solution was reacted with excess of ferric chloride solution and warmed to complete the reaction, Ferrous ion formed was estimated and it required 20 ml, of M/SO potassium permanganate solution, Estimate the amount ofhydrazine sulphate in one litre ofthe solution (1988-3 Marks) 6. n. 28, 29, 3. 32. Reaction SF +N,H, Ny + 4F +H MnOj + SFe?* + 811" > Mn?" + SFe?* + 41,0. ‘An equal volume ofa reducing agent is titrated separately with IM KMn0, in acid neutral and alkaline media. The volumes ofKMrO, required are20 min acid, 334ml. neutral and 100 ml inalkaline media. Find outthe oxidation state of| manganese in each reduction product. Give the balanced equations forall the thre half reactions. Find out the volume of IM K,Cr,0, consumed; if the same volume of the reducing agent ititrated in acid medium. (1989 -$ Marks) Armixture of H,C,0, (oxalic acid) and NaHC,O, weighing 2.02 was dissolved in water and solution made upto one litre. Ten miliites ofthe solution required 3.0m, of 0.1N sodium hydroxide solution for complete neutralization, In another experiment, 10.0 ml, ofthe same solution, in hot dilute sulphuric acid medium. requite 4.0 mi. of 0.1 N Potassium permanganate solution for complete reaction Calculate the amount of H,C,O, and NaHCO, in the mixture (190° 5 Marks) solid mixture (50 consisting oflead nitrate and sodium nitrate was heated below600°C until the weight of thersidue ‘was constant. Ifthe loss in weight is 280 percent, find the amount oflead nitrate and sodium nitrate inthe mixture. (1990-4 Marks) Calculate the molality of 1 litre solution of 93% H,SO, (weight/volume). The density ofthe solution is 1.84 g/ml. (1990-1 Marks) {A solution of 0.2 of a compound containing Cu2* and 207 ons on titan with 02 MKMn0,in presence of 80, consumes 226 ml of the oxidant ‘The resultant scluionsneutlized with NajCO. aed ith sete dcidandteaed with exces Kt Th liberated iodine rqutes TI 3mlof0.05 MNa,S,0, sluten fr eomplteredtion Find out the molar ratioof Cu?* to C02" in the compound Write down the balanced redox reactions involved in the above titrations, (1991 - 5 Marks) A.1.0 gsample of Fe,O, solid of 55.2% purity is dissolved in acid and reduced by heating the solution with zine dust. ‘The resultant solution is cooled and made upto 100.0 ml. An aliquot of25.0 ml of this solution requires 17.0 ml of 0.0167 ‘Molution of an oxidant for titration. Calculate the number of electrons taken up by the oxidant in the reaction of the above titration. (1991-4 Marks) 42.0 g sample of a mixture containing sodium carbonate, sodium bicarbonate and sodium sulphate is gently heated till the evolution of CO, ceases. The volume of CO, at 750 ‘mm Hg pressure and at 298 K is measured to be 123.9 ml. A 1 Sg ofthe same sample requires 150 ml, of (M/10) HCL for complete neutralisation. Calculate the % composition of the ‘components of the mixture. (1992 - § Marks)Some Basic Concepts of Chemistry § ——________ 4 33. One gram of commercial ANO, is dissolved in 50 ml, of water Its treated with 50 ml, of a KI solution, The silver ‘odide thus precipitated is filtered off Excess of KI in the filterateis titrated with (M/10) KIO, solution in presence of 6MHCItil all Fons are converted into ICI. Itrequires SO ml cof(M/10) KIO, solution, 20 ml. ofthe same stock solution of| KI requires 30 ml. of (M/10)KIO, under similar conditions Calculate the percentage of AgNO, inthe sample (Reaction : KIO, +2KI-+6HC1—> 3ICI+ 3KC1+ 34,0) (1992-4 Marks) 34, Upon mixing 45.0 ml. of0.25 M lead nitrate solution with 25.0 ml of, 10 M chromic sulphate solution, precipitation of| lead sulphate takes place. Howmany moles oflead sulphate are formed” Also, calculate the molar concentrations of the species left behind inthe final solution, Assume that lead sulphate is completely insoluble (1993 - 3 Marks) 35, The composition ofa sample of Wustit is F530} 00 ‘What percentage of te iron is present in the form of Fe ay? (1994 - 2 Marks) 36. 8.0575 « 10 kg of Glauber’s salt is dissolved in water to ‘obtain | dm? of solution ofdensity 1077.2 kg m>. Calculate the molarity, molality and mole faction of Na,SO, in the solution (1994-3 Marks) 37. A300gsample containing Fe,0,,Fe,0, andan inertimpure substance, is treated with excess of KI solution in presence ofdiluteH,SO, The entre iron is converted into Fe along with the liberation ofiodne. The resulting solutions diluted 0 100ml A20:mlof the diluted solution requires 11,0 ml of 0.5 MINa,S,0, solution to reduce the iodine present. ASO ri ofthe diluted solution, ater complete extraction ofthe ‘odie requites 12,80 ml of0.25 MKMnO, solution in dilute H,S0, medium for the oxidation of Fe. Calculate the percentages of Fe,O, and Fe,0, inthe original sample. (1996-5 Marks) 38, An aqueous solution containing 0.10 gKIO, formula weight = 214.0) was treated with an excess of KI solution, The solution was acidified with HCI, The liberated I, consumed 45.0 mL of thiosulphate solution to decolourise the blue starch-iodine complex. Calculate the molarity ofthe sodium thiosulphate solution, (1998-5 Marks) 39, Howmany millilitres of0.5 MH,SO, are needed to dissolve 0.5 gofcopper(tt) carbonate? (1999-3 Marks) 40, A plant virus is found to consist of uniform eylindrcal particle of 150 Ain diameter and $000 A long. The specie volume of the virus is 0.75 em'/g, Ifthe virus is considered to bea single particle, find its molar mass (1999-3 Marks) 411. Hydrogen peroxide solution (20 ml) reacts quantitatively witha solution of KMnO, (20 mi) acidified wit dilute H,S0, Thesame volume ofthe KMn0, solution is just decolourised by 10 ml of MnSO, in neutral medium simultaneously forming a dark brown precipitate of hydrated MnO,, The brown precipitate is dissolved in 10 ml of 0.2 M sodium oxalate under boiling condition in the presence of dilute H,S0,. Write the balanced equations involved in the reactions and calculate the molarity of H,0,, (2001 - 5 Marks) 42, Calculate the molarity of watrifits density is 1000 kg/m* (2003-2 Marks) 5 ESS 1. Read the following statement and explanation and answer as per the options given below STATEMENTS): Inthe titration ofNa,CO, with HClusing methyl orange indicator, the volume required at the equivalence point is twice that ofthe acid required using pphenolphthalein indicator. EXPLANATION€E) : Two moles of HCl are required for the complete neutralization of one mole of Na,CO, (1991 - 2 Marks) (@) Both and E aretrue, and E isthe correct explanation ofS. (6) BothS and Earetruc, but Eis not the correct explanation ofS. (©) Sistruebut E is false. (@ Sisfalse but Eis true. 1 Eee 1. A student performs a titration with different burettes and finds titre values of 25.2 mL, 25.25 mL and 25.0 mL. The ‘numberof significant figures in the average titre value is 2010) 2 Silver atomic weight = 108 g mo") hasa density of 10.5 8 em’. The number of silver atoms on a surface of area 10")? 1m? can be expressed in scientific notation as y « 10%. The value of x is 2010) 3. Thedifference in the oxidation numbers ofthe two types of sulphur atoms in Na,S,04 is (2011) 4. Ifthe value of Avogadro number is 6.023 « 1023 mol-! and the value of Boltzmann constant is 1.380 * 10°23 )K-!, then the number of significant digit in the calculated value of the universal. gas constant is (JEE Adv. 2019)oy 1 opie. wise Sotved Papers - CHEMISTRY I Secton-s Ina.compound C, Hand N atomsare present in 9: 1: 3.5 by ‘weight, Molecular weight of compound is 108, Molecular formula of compound is [2002] (CN, (0) GHN (©) CAN, @CyH,NS. With increase of temperature, which ofthese changes? 12002) (@)_ molality (b) weight fraction of solute (©) molarity (@) mote fraction, Number of atoms in 558.5 gram Fe (at. wt. of Fe= 55.85 smol")is (@) twice that in 60 g carbon (b) 6023 x 10% (©) halfthat in 8 g He (@) 5585 x 6.023 x 108 ‘What volume of hydrogen gas, at273 Kand | atm. pressure will be consumed in obtaining 21.6 g of elemental boron (atomic mass= 10.8) from the reduction of boron trichloride by hydrogen ? 12003] @ 612L () 48L © BAL @) 896L 25m| ofa solution of barium hydroxide on titration with 20.1 ‘molar solution of hydrochloric acid gave a litre value of 35ml. The molarity of barium hydroxide solution was 12003) @ 014 — (6) 028 ©) 035) 007 6.02 = 10% molecules of urea are present in 100 ml of ts solution. The concentration of urea solution is [2002] (2004) (@) 002M (b) 0.01M (c) 001M (4) 01M (Avogadro constant, Nx =6.02 «1023 mot) Toneutralise completely 20 ml.of 0.1 M aqueous solution ‘of phosphorous acid (H,PO;), the value of 0.1 M aqueous KOH solution required is {2004} (@) 40m (b) 20mL (e) 10mL—(@) mL. The ammonia evolved from the treatment of 030 g of an ‘organic compound for the estimation of nitrogen was passed in 100 mL of 0.1 M sulphuric acid. The excess of acid required 20 mL of 0.5 M sodium hydroxide solution for complete neutralization. The organic compound is (2004) (@) urea (b) benzamide (©) acetamide (@) thiourea ‘Two solutions ofa substance (non electrolyte) are mixed in the following manner. 480 mil of I.5M first solution + $20 ml of 1.2.M second solution, What is the molarity ofthe final mixture? 2005) (@) 270M () 134M (©) 150M (@) 120M Ifwe consider that 1/6, in place of 1/12, mass of carbon atom is taken to be the relative atomic mass uni, the mass of one ‘mole ofthe substance will 12005] UL. Rn 2B. 4 18, 16. W. (a) bea function of the molecular mass of the substance (6) remain unchanged (©) increase two fold (d) decrease twice How many mole of magnesium phosphate, Mg,(PO,): will contain 0,25 mole of oxygen atoms? [2006] (@) 125«107 (b) 25% 107 (©) 002 (@ 3.125% 102 Density of a 2.05M solution of acetic acid in water is 1L02,gmL. The molality ofthe solution is 12006) (@) 228molke! (b) 0.44 mol ke! (©) 1.14molkgt (a) 328mol kg ‘The density ing mL~!) ofa 3.60 M sulphuric acid solution that is 29% 1,S0, (molar mass= 98 2 mol-") by mass wil be @ 145 (164 2007] () 188 @) 12 Inthe reaction, (2007) 2Al(S) + 6HCI(aq) > 2A1°*(aq) + 6CI”(aq)+3113() (@) 112 LHy(g) at STP is produced for every mole Haq) ‘consumed (6) 6 LHCI(aq) is consumed for every 3 1 H,(g) produced (©) 336LH,(g)is produced regardless of temperature and pressure for every mote A/ that reacts (@_ 67.2 Hyg) at STP is produced for every mole Al that reacts Consider the following reaction AMO," + COG +211" xMn?* +2yCO> + FH20 The value’s ofx, y and zin the reaction are, respectively [JE M2013] (@ 5,2and16 (b) 2,Sands (©) 2,Sand16 (@ 5,2and8 ‘A gaseous hydrocarbon gives upon combustion 0.72 g of water and 3.08 g of CO. The empirical formula of the hydrocarbon is [JE M2013] © CH, 0) GH, ©) CoH @) Cylly Experimentally it was found that a metal oxide has formula My 9g0. Metal M, present as M°* and M®* in its oxide Fraction ofthe metal which exists as M?* would be [JE M2013] (@) 508% (@) 701% —(b) 408% (©) 605%CHAPTER Structure of Atom I Section-a TITAS 3 5 Rts 1. Themass of hydrogen atom is. fine Marky 2. Isotopes ofan element differ in the number of | in their nuclei (1982-1 Mark) 3. When therearetwoelectrons in the same orbital, they have spins. (4982-1 Mark) 4. Elements ofthe same mass number but of different atomic numbers are known as (1983 - 1 Mark) ‘The uncertainty principle and the concept of wave nature of matter were proposed by and respectively. (Heisenberg, Schrodinger, Maxwell, de Broglic) (1988 - 1 Mark) 6. The light radiations with discrete quantities of energy are called (4993 - 1 Mark) 7. Wave functions of electrons in atoms and molecules are called (1993 - 1 Mark) 8 The 2p,, 2py and 2p. orbitals of atom have identical shapes but differ in their (1993-1 Mark) ‘The outermost electronic configuration of Cris (1994-1 Mark) 8 Rio 1. The outer electronic configuration of the ground state chromium atom is 344s, (4982-1 Mark) 2. Gamma raysare electromagnetic radiations of wavelengths of 10-em to 10-5 em, (1983 - 1 Mark) 3. Theenergy ofthe electron in the 3c-orbital is ess than that inthe ds-orbital inthe hydrogen atom. (1983-1 Mark) 4. Theelectron density in the X¥plane in 34,2 _ 42 otbital is 2200. (1986 - 1 Mark) 5. Inagivenlectric particlesare deflected more than ca-particles in spite of «-particles having larger charge (1993-1 Mark) c ERCreryeiconuss ‘The number of neutrons in dipositive zine ion with mass ‘number 70 is (979) @ 4 &) 36 © 8 @ 0 Rutherford’s experiment on scattering of a-particles showed forthe firsttime that the atom has (1981-1 Mark) (a) electrons (b) protons (c) nucleus Any p-orbital can accommodate upto (@)_ four electrons (b) sixelectrons (©) twoelectrons with parallel spins (@) two electrons with opposite spins The principal quantum number of an atom is related tothe (1983 - 1 Mark) (4) neutrons (1983 - 1 Mark) (@) size ofthe orbital (6). spinangular momentum (©) ambital angular momentum (@) orientation ofthe orbital in space Rutherford’ scattering experiment is related to the size of the (1983 - 1 Mark) (@)_ nucleus (6) atom (©) electron (@) neutron The increasing order (Jowest first) forthe values of e/m (charge/mass) for electron (e), proton (p), neutron (n) and alpha particle (a)is (1984-1 Mark) (a) e,p.na (b) m,p.ea (©) np.ae (d) n,a,pe Correct set of four quantum numbers for the valence (outermost) electron of rubidium (Z= 37) is (1984-1 Mark) @ 5,0,0,4% 0) 5.1.0,4% (©) 5,1,1,4+% (d) 6,0,0,+% Which electronic level would allow the hydrogen atom to absorb a photon but not to emit a photon? (1984-1 Mark) (@) 3 © 2 (&) 2p @ Is GP_302110, 1B. 4 16. n. ——___ Tropiie-wise Sotved Papers - CHEMISTRY ‘Bohr mode! ean explain (@) the spectrum of hydrogen atom only (b) spectrum of an atom or ion containing one electron only (ce) the spectrum of hydrogen molecule (d)_ the solar spectrum The radius ofan atomic nucleus is ofthe order of (1985-1 Mark) (a) 10cm (b) 10cm () 10cm (@) 10%cm Electromagnetic radiation wth maximum wavelength is (1985 - 1 Mark) (@) ultraviolet (©) radiowave (©) X-ray (@)_ infrared Rutherford’ alpha particle seatering experiment eventually Jed tothe conclusion that (1986-1 Mark) (a) mass and energy are related (b) electrons occupy space around the nucleus: (©) neutrons are buried deep in the nucleus (d)_ the point of impact with matter can be precisely determined Which one of the following sets of quantum numbers represents an impossible arrangement? (1986 - 1 Mark) loom Mm, ®3 2 2 ¥ (b) 4 oO 0 % @ 3 2 3 % @ 5 3 0 ” The ratio ofthe energy ofa photon of 2000A wavelength radiation tthat of 40004 radiation is: (7986-1 Mark) fa) % (b) 4 © % @ 2 The iad of nucle that is isotonic is (1985 - 1 Mark) (1988 - 1 Mark) Ue! Ng i @ CGN, GP (EC. GN, SF © CGN.GF @ Be. GN, SF ‘The wavelength of'a spectral line for an electronic transition is inversely related to (1988 - 1 Mark) (@)_thenumber of lectrons undergoing the transition (b) the nuclear charge of the atom (© the difference in the energy of the energy levels involved inthe transition (@ the elosty ofthe letron undergoing the transition ‘The rita diagram in which the Aulbou principles vilated is (1988-1 Mark) a » @ [N NYT (b) [Ft ttt © [N TTT 18, 19. 20, a 2. 2B. m4, 28, o WITT The outermost electronic configuration of the most cleetronegative element is (1988 - 1 Mark) ()_ ns? np? (b)_ ns? npt (©) ns? np* ()_ ns? mph The correct ground state electronic configuration of chromium atom is: (1989 - 1 Mark) (@) [Ar]3a4s! (b) [Ar3dast © [Ande (©) [Anda 4st ‘The correct set of quantum numbers for the unpaired clectron of chlorine atom is (1989-1 Mark) n 1 m @ 2 1 0 o 2 1 1 © 3 1 1 @ 3 0 0 Which of the following does not characterise X-rays? (1992-1 Mark) (a) The radiation can ionise gases (b) ecauses ZnS to fluorescence (©). Defected by electric and magnetic fields (@) Have wavelengths shorter than ultraviolet rays Which ofthe following relates to photons both as wave motion and asa stream ofparicles? (1992-1 Mark) (@) Inference (0) B=me? (©) Difaction (@) Ein A 3p orbital has (19955) (@)_ two non spherical nodes (b) two spherical nodes (©) one spherical & one non spherical node (@) one spherical and two non spherical nodes Theorbital angular momentum ofan electron in 2s orbitals: (1996 - 1 Mark) Lh a b) Ze @ +p () Zero h h © a) 2. oF @ a5 Forad-clectron, the orbital angular momentum is (1997-1 Mark) (@) Vo(h/2n) (©) V2(h/2) (©) (hi2m) (@ 20h/2m) ‘The electrons, identified by quantum numbers m and J, ()n=4,1= 1 (i) (il)n=3,1=2, and (v)n=3, T= | can be placed in order of increasing energy, from the lowest to highest, as (1999 -2 Marks) @) (—. This momentum for an s-cleetron will be given by {2003} h (a) zero (>) on h @ th © ae © +335 5 Which one of the following groupings represents a collection of isoelectronic species %(At. nos. : Cs : $5, Br:35) (2003) (a) N¥,F,Na* (b) Be, Al*,Cl- (© C#*,C',Br (@) Na", Ca, Mg In Bohr series oflines of hydrogen spectrum, the third line from the red end corresponds to which one ofthe following iner-orbit jumps ofthe cletron for Bohr orbits in an atom of hydrogen {2003}, @ $52 © 451 © 245 @ 352 The de Broglie wavelength ofatennis ball ofmass 60g moving with a velocity of 10 metres per second is approximately (2003) (@) 10>! metres (b) 10° metres (©) 10° metres (@) 10° metres Planck's constant, h=6.63 » 1043s, Which of the following sets of quantum numbers is correct foran electron in 4f orbital ? [2004]Structure of Atom 10, UL 4 18, 16. Consider the ground state of Cr atom (X=24), The number ofelectrons with the azimuthal quantum numbers, ¢= Land 2are, respectively [2004] (@ 16and4 (b) 12ands (©) Wanda (@ IGands ‘The wavelength ofthe radiation emitted, when ina hydrogen atom electron falls from infinity to stationary state 1, would be (Rydberg constant = 1,097%107 m!) 12004] (@ 406nm (b) 192m, © nm @ 9bd0%nm Which one of the following sets of ions represents the collection of isoelectronic species? [2004], (@)_K*.Cr, Mg, Sc (b)Nat,Ca*, So, (©) K*Ca,Se%,Cr —(€)_ Nat, Mg, AI, (Atomic nos. :F =9, C= 17, Na= 11, Mg= 12, AL= 13, K=19,Ca=20,Se=21) In a multi-electron atom, which of the following orbitals ‘described by the three quantum members will have the same ‘energy inthe absence of magnetic and electric fields? 12005), m=0 © n-2/=1m=1 © 0-3, @ Danae ©) (Chand) © @and©) (@ (And ®) OF the following sets which one does NOT contain isoelectronic species? 12008) @B) n=2,1=0, ©) n=3,/=2,m=1 m=0 (@ BO}”,CO},NO} (b) S03", CO}, NOZ © ONN,CH —— @ PO}, $0", C10; According to Bohr’s theory, the angular momentum of an electron in SY orbit is [2006] (@) 10h/x (b) 2Sh/x (©) Shin @ 10h/x Uncertainty in the position of an electron (mass = 9.1 107 kg) moving with a velocity 300 ms, accurate upto 0.001% willbe 20061, (@ 192%102m (©) 192*102m (b) 3.84% 102m (@ 576% 107m (h=6.63 « 10Js) Which one of the following sets of ions represents colletion of isoelectronic species? [2006] @ NOR FS (b) Li*,Na' Me, Cat (©) K*,Cr,Ca®*, Se (@)_ Ba®*, Sr*,K*, Ca? Wm. 18, 19. a 2. 2B. mM Which ofthe following sets of quantum numbers represents the highest energy of an atom? 12007) @ n=4,1=0,m=0,s=+172 Which one of the following constitutes a group of the isoelectronic species? {2008} (@) CH,07,C0,NO_— (0) NO*,C},CN-.N 2 (©) CN",N2,0} CF @)_Nz,03,NO*,CO The ionization enthalpy of hydrogen atom is 1.312 * 1083 ‘mol! The energy required to excite the electron inthe atom is (2008), (@ 851% 105Jmot (b) 656% 105J mot (©) 756% 1083mor! (a) 9.84 108 mot! Calculate the wavelength (in nanometer) associated with a proton moving at 1.0 * 10° ms~! (Mass of proton = 1.67 « 10-27 kgand h=6.63 * 10-5) (@) 040m () 25nm 12009], (© 140nm (@ 032mm In an atom, an electron is moving with a speed of 600 mis with an accuracy of 0.005%. Certainity with which the Position ofthe electron can be located is (h=6 6» 10k m?s-!, mass ofelectron, e Vkg): [2009], (@ 5.10107 m () 192% 109m (©) 384* 103m (@ 152 10-4m The energy required to break one mole of Cl Cl bonds in Cl, is242 kJ mol"! The longest wavelength oflight capable ofbreaking a single Cl ~Cl bond is fromn= ton. (c=3% 108 ms!andN,=602 «103 mol), (2010) (@) 594nm (b) 640nm (©) 700nm @) 494mm Tonisation energy of He’ is 196 » 10-¥ Jaton The energy ‘ofthe first stationary state (n=!) of L?*is [2010] (@) 4811016 Fatom! —(b) 4.41 10-7 Sater! (© 22 «10'S Satom-! 882% 10-17 Fatom-! ‘A gas absorbs a photon of 355 nm and emits at two ‘wavelengths. Ione ofthe emissions iat 680 nm, the other isat 011) (@ 103Snm © 761m (b) 325mm (@ 518mmory 25, Ihe electrons identified by quantum numbers m and ¢ ) n=, B) n=4, © n=3, (D n=3, can be placed in order of increasing energy as @ OCI>Br. (1993 - 1 Mark) 3. Thebasic nature of the hydroxides of group 13 (Gr. IB) decreases progressively down the group. (1993 - 1 Mark) [ell MCQs with One Correct Answer 1, Thecorrect order of second ionisation potential of carbon, nitrogen, oxygen and fluorine is (1981-1 Mark) @ C>N>0>F () O>N>F>C (© O>F>N>C @ F>0>N>c ‘The element with the highest first ionization potential is, (1982-1 Mark) (6) carbon (@) oxygen (@)_ boron (©) nitrogen 3. The first ionisation potential in electron volts of nitrogen and oxygen atoms are respectively given by (1987-1 Mark) @ 146,136 () 136,146 © 136,136 (@ 146,146 4. Atomic radii of fluorine and neon in Angstorm units are respectively given by (1987-1 Mark) (@ 072,160 (b) 160,160 © onon (@)_ None of these values ‘5. The electronegativity of the following elements increases inthe order (1987-1 Mark) (@) C.NSiP () NSLP (©) SiRCN (@ BSN 6. The first ionisation potential of Na, Mg, Al and Siare inthe order (1988 - 1 Mark) (@) NaAlMg>Al> (©) NaMg>Al50,>P,0 (6) CO,>N,0,>S0, (©) Na0>MgO>AL0, (@) K,0>Ca0>MgO 15, Amongst H,O, HS, H,Seand HyTe,theone withthe highest boiling point is (20008) (@) 1,0 because of hydrogen bonding (b)_ HyTe because of higher molecular weight (6) H,S because of hydrogen bonding (@ H,Sebecause of lower molecular weight 16, Identify the correct order of acide strengths of CO,, CuO, 20, 1,0 202s) @) CaOp 5 Oe 1. Arrange the following in (Decreasing ionic size : Ma2*, O%,Na', F (1985-1 Mark) (ii) Increasing acidic property : ZnO, Na,O,,P,0,,MgO (1985-1 Mark) (it) Increasing fist ionization potential : Mg, Al Si, Na (1985-1 Mark) (iv) Increasing size: CI-,S*,Ca*, Ar (1986-1 Mark) (©) Increasing order ofonie size: N'-, Na*, FO, Mg (1991-1 Mark) (Increasing order of basic character : MgO, SrO, KO, Ni0,Cs,0 (1991-1 Mark) (ott) Arrange the following ionsin order of their increasing radii: Lit, Mg, K*,AD* 2. The first ionization energy of carbon atom is greater than that of boron atom whereas, the reverse struc forthe second ionization energy (1989 -2 Marks) BH RCs 1, Read the following statement and explanation and answer as per the options given below ASSERTION : The first ionization energy of Be is greater than that of B. (20008) REASON : 2p orbital is lover in energy than 2s (@)_Ifboth assertion and reason are CORRECT, and reason isthe CORRECT explanation ofthe assertion (b) Ifboth assertion and reason are CORRECT, but reason isNOT the CORRECT explanation ofthe assertion (6). Ifassertion is CORRECT, but reason is INCORRECT. (@)_Ifassertion is INCORRECT, but reason is CORRECT, 1 ERR 1. Among the following, the number of elements showing only ‘one non-zero oxidation state is O,CLEN,P.Sn, TI, Na, TL (1999-3 Marks) (2010)Classification of Elements and Periodicity in Properties ________________@ 4 [| Section-6 STS eIWATT3 1. According tothe Periodie Law of elements, the variation in properties ofelements is related to their 12003) (@)_ nuclear masses (0) atomic numbers (©) nuclear neutron-proton number ratios (@) atomic masses 2. Which one ofthe following isan amphoteric oxide? @ Nao (0)S0, 12003] © BO, @z00 3. Which one ofthe fllowing ions has the highest value of ionic radius? 2004) @ & @ Be © ui @ & 4. Among Al,0,,Si0,,P,0, and SO, the correct order of acid strength is 12004] (a) Al,0, Mg? > Nat > F>0% (0) Na >Mg* > At > 0% > F (©) Na* > Fo > Mg** >? > al () 0% > F > Nat > Mg** > A Which one of the following orders presents the correct sequence ofthe increasing basic ature ofthe given oxides? 011) @)_AlO) (©) _N: pyramidal, sp?, B: planar, sp? (@)_N: pyramidal, sp°, B tetrahedral, sp? Identify the least stable ion amongst the following (2002S) @) Lr (b) Be) B @c Which of the following molecular species has unpaired -electron(s) ? (2002S) @N OF © OF (@) OF Which ofthe following ae isoelectronic and isostructural? NO;-,CO,*,C10;-,$0, (20038) (0) 80,.NOy (@) NO;.CO2” (©) C0;,coe (@) CO}-S0, According tomolecular orbital theory which ofthe following statement about the magnetic character and bond order is correct regarding 03 2004s) (@) Paramagneticand Bond order <0, (6) Paramagnetic and Bond order > 05 (©) Diamagneticand Bond order O, Which species has the maximum number of lone pair of electrons on the central atom? (20055) (a) [COP (b) XeF, (c) SF, @ Or Among the following, the paramagnetic compound is 2007) (a) Na,0, © NO ©) 0 @ Ko, S51. The species having bond order different from that in CO is 2007) @ NO WN ON WN ‘Assuring that Hund’s rule is violated, the bond order and magnetic nature ofthe diatomic moleculeB, is (2010) (@) Land diamagnetic (b) O.and dimagnetic (©) Land paramagnetic (4) Oand paramagnetic 53. The species having pyramidal shape is. e201) @ SO; () BF, © Siof (A) OSF, Geometrical shapes ofthe complexes formed bythe reaction of Ni* with CI-,CN“and H,O, respectively, are (2011) (@)_ octahedral, tetrahedral and square planar (6) ‘tetrahedral, square planar and octahedral (©) square planar, tetrahedral and octahedral (@ octahedral, square planar and octahedral Assuming 2-2p mixing is NOT operative, the paramagnetic species among the following is (DEE Ads, 2014) @ By OB ©) @N The geometries of the ammonia complexes of Ni? Pe and Zn** respectively are (IEE Ads 2010) (@) octahedral, square planar and tetrahedral (6). square planar, octahedral and tetrahedral (©) tetrahedral, square planar and octahedral (4) ctahodral, tetrahedral and square planar D BRC 4 58 1. CO,isisostuctural with (1986-1 Mark) @ HCl, () SAC, © C. (@ No, ‘2. The linear structure is assumed by (1991 - 1 Mark) @ SC, (b) NCO (CS, @)_ NOP 3. Which of he following have identical bond order? (1992-1 Mark) @ & 60; | wWCN 4. ‘Themolecules that will have dipole moment are (1992-1 Mark) (@) 2,2-dimethylpropane (b) txans-2-pentene (©) cis-3-hexene (@) 2233Hetramethytbutane 8. Thecompound(s) with TWO lone pairs of electrons on the central atom itare) (EE Ads. 2016) @ BF, (6) CIF, © Xr, @) SF, 6. According to Molecular Orbital Theory, (JEE Ad 2016) (@) CE isexpected tobe diamagnetic (©) OF? isexpected tohavea longer bond length than O, (©) Nj and Nj have the same bond order (8) He has the same energy as two isolated He atoms 5 Bie 1. Water isliquid while 1, isa gas at room temperature, (1978) 2. Write the Lewis dot structural formula for each of the following. Give, also, the formula of neutral molecule, which has the same geometry and the same arrangement of the bonding electrons as in each ofthe following. An example isgiven below in the case of H,O* Ho H H:0:H, HEN:H, Lewis dot Neutral structure molecule SVEN (ivy NCS (1983-1<4=4 Marks) 3. Howmany sigma bonds and how many pi-bonds re present ina benzene molecule? (1985-1 Mark) 4. Write the Lewis dot structure ofthe following 0,,C0Cl, (1986-1 Mark) 5. Arrange the following ()Nj,0,,F,,Cl, in inereasing order of bond dissociation energy. (1988-1 Mark) (i Increasing strength of hydrogen bonding (X-H-X) (1991-1 Mark) 0,S,R.CLN (ii)_Inthe decreasing order ofthe © - bond length present inthem (2004-4 Marks) 0, KO, and 0, [ASF] 6. Thedipole moment of KCI is 3 336 » 102% Coulomb meters ‘hich indicates that it is a highly polar molecule. The interatomic distance between K"* and Clin tis molecule is 2.6 «10"?m,Caleulate the dipole moment of KCI molecule if there were opposite charges of one fundamental unit located ateach nucleus. Calculate the percentage ionic character of ka. (1993-2 Marks) 7. Using the VSEPR theory, identify the type of hybridization and draw the structure of OF, What ae the oxidation states of Oand F? (1994-3 Marks) 8. A.compound of vanadium has a magnetic moment of 1.73 BM, Work out the electronic configuration of the vanadium {on inthe compound (1997-2 Marks) 9. Interpret the non-linear shape of H,S molecule and non- planar shape of PCI, using valence shell electron pair repulsion (VSEPR) theory. (Atomic numbers: H=1,P=15, S=16,CI=17) (1998- 4 Marks) 10, Write the MO. electron distribution of O,. Specify its bond order and magnetic property (2000-3 Marks) 11. Using VSEPR theory draw the shape of PCL, and BrF, (2003-2 Marks) 12, Drawthe structure of XeF, and OSF, according to VSEPR theory, clearly indicating the state of hybridisation ofthe central atom and lone pair of electrons (ifany) on the central atom. (2004-2 Marks) Bal Match the Following ‘Match the orbital overlap figures shown in List-I with the description given in Listll and select the correct answer using the code given below the lists. (JEE Adv. 2014) Topic-wise Solved Papers - CHEMISTRY Litt p—dzamtibonding d—dobonding Ce a p—dxbonding eo o8 s 4 d-deantibonding Code, Po oQ@ RS (a) 2 13 4 m4 3 1 2 @2 3 1 4 @ 4 13002 BH RSs 1. Read the following Assertion and Reason and answer as per the options given below (1998 - 2 Marks) 3@ Avert The cetonic arte 0,” \y ° neon: PA, sci it loved et srando Sat Scand (a) Ifboth assertion and reason are correct, and reason is emer (b)_ Ifboth assertion and reason are correct, but reason is Sere eames (9 Waneunis ctetin ators (d)_Ifassertion is incorrect but reason is correct. 2. Cale bite aston wd feos tera per the options given below: (1998 - 2 Marks) Rata fing ebay scombereomrere fucon avons eee ipl wai (a) Ifboth assertion and reason are correct, and reason is. tana opbeaiatac aaraon (b) Ifboth assertion and reason are correct, but reason is. eee (c) Ifassertion is correct but reason is incorrect. (@)_ Ifassertion is incorrect but reason is correct. 1 Eee 1. Based on VSEPR theory the number of 90 degree F-Br-F angles in Br is (2010) 2 Thetotal number oflone-pairs of electrons in melamine is (JEE Adv. 2013)Chemical Bonding and Molecular Structure. —____________» Ais of species having the formula XZ, is given below. XeF 4, SFy, SiFy, BFy-, Br, [Cu(NH,),?*, [FeCl [CoC and [PCL Defining shape on the bass ofthe location of X and Z atoms, the total numberof species having a square planar shape is (SEE Adv. 2014) 4 ea ‘Among the triatomic moleculeslions, BeCl;, N3 , N,O, NO$,0s,SCly, Cp, 15 and XeF, the total number of linear molecule(sVion(s) where the hybridization of the central atom does not have contribution from the d-orbitals) is [Atomic number: = 16, CI=17,1=53 and Xe= 54] (JEE Ad. 2015) Section-B JIT OW 73 Inwhich ofthe following species the interatomic bond angle is 109°28"? [2002] @ NH, Bry" (b) (NH)', BE, (©) NH,,BF, (@) (NHL). BFy ‘Which ofthe following are arranged in an inereasing order oftheir bond strengths? 12002) @) Of <0,<0,"<0;7" (6) 0,-<0, <0, <0," (©) Oy <032-<0, <0," (A) 0,'<0,<0, <0; Hybridisation of the underline atom changes in: (@) AIH changes to AI (6) HO changes to H,0" (©) Nils changes to NH (@ inall cases ‘An ether is more volatile than an alcohol having the same molecular formula. This isdueto 12003) {@) alcohols having resonance structures (6) inter-molecular hydrogen bonding in ethers (©) inter-motecular hydrogen bonding in alcohols (@) dipolar character of ethers Which one ofthe following pairs of molecules will have permanent dipole moments for both members? [2003] (@)_ NO, andCO, (b) NO, andO, (©) SiF,andCO, (@) SiF,andNO, Which one of the following compounds has the smallest bond angle in its molecule ? 12003) (@) OH, —(b) SH, (©) NH, (@) SO, ‘The pair of species having identical shapes for molecules of both species is 12003) (@) XeF,,CO, (b) BF, PCI, (©) PRUE, (@) CF,SF, The correct order of bond angles (smallest first in H,S, NH, BF, and Sill is [2004] (@) HSNO* @ 0,50, Which ofthe following hydrogen bonds is the strongest? 12007) (@) O-H---F (b) O-H---H (©) F-H---F (@ O-H---0, Which one of the following pairs of species have the same bond order? 12008), (@ CN-andNO* () CNrand cn (© 03 andcn- (@) NO* and CNY The bond dissociation energy of B-F in BF, i646 kI mot whereas that of CF in CF, is $15 kJ mol! The correct reason for higher B-F bond dissociation energy as compared tothatofC- Fis {2008} (@)_ stronger « bond between Band F in BF as compared tothat between Cand F in CF, (©) significant pr—pr interaction between Band Fin Bs ‘whereas there is no possibility of such interaction between C and Fin CF. (©) lower degree ofp interaction between Band Fin BB, than that between Cand F in CF, (@) smaller sizeof B-atom as compared tothat of C-atom Using MO theory, predict which of the following species has the shortest bond length? 12008) @ 0} 0; © oF @ OF Among the following the maximum covalent characteris shown by the compound 011) @ FeCl (b) SnCl (©) AIC — @) MgCl The hybridization of orbitals of N atom in NO; ,NO3* and NH, are respectively pou (@)_sp, sp*, sp? (b) sp*, sp, sp? (© 5, sp, sp (2) sp, sp*, sp The structure of IF, is rou) (@)_ square pyramidal (b) trigonal bipyramidal (©) octahedral (@) pentagonal bipyramidal Ortho-Nitrophenol is less soluble in water than p- and m- Nitrophenols because (2012) (@)_o-Nitrophenol is mote volatile steam than those of m- ‘and peisomers (6) o-Nitrophenol shows intramolecular H-bonding (©). o-Nitrophenol shows intermolecular H-bonding (@)_ Melting point of o-Nitrophenol is lower than those of ‘m-and p-isomers, 28, In which of the following pairs the two species are not isostructural ? [2012] (@) CO} and NOS (b)_ PCI; and Sic, (©) PFsand BrP; (@ AIR} and SF, 29, Which one ofthe following molecules is expected to exhibit diamagnetic behaviour ? [JEEM2013} @ & ) Ny © 0} (@) Sy 30, Which of he following isthe wrong statement ? [JEEM2013] (a) ONC] and ONO are not isoelectronic. (b) Oymolecule is bent (c) Ozone is violet-black in solid state (d) Ozone is diamagnetic gas. 31. _Inwhich ofthe following pais ofmolecules/ons, both the species are not likely to exist? (IEE M2013] (=) H3,He} () 1 ,He} (© HRHey (Hye? 32. Stability of the species Lip, Lij and Lif increases in the order of: (JEEM2013] @ Lip 2 1273 © 5 © 53°20 The temperature at which a real gas obeys the ideal gas laws over a wide range of pressure is (1981-1 Mark) (@) Critical temperature (6). Boyle temperature (©) Inversiontemperature (d) Reduced temperature The ratio of root mean square velocity to average velocity ofa gas moleculeat a particular temperature is (1981-1 Mark) (@) 1086:1 (6) 1:1086 (©) 2:1086 (@) 1086-2 elim atom is two times beaver than a hydrogen molecule. ‘A1298 K, the average kinetic energy ofa helium atom is (1982-1 Mark) (@)_twotimes that ofa hydrogen molecule. (b) same as that ofa hydrogen molecule (©) four times that ofa hydrogen molecule. (@)_halfthat ofa hydrogen motecule Equal weights of methane and hydrogen are mixed in an empty container at 25°C. The fraction ofthe total pressure exerted by hydrogen is (1984-1 Mark) 1 8 @ 5 5 1 16 5 Oi Rate of diffusion ofa gas is (@) directly proportional to its density. (6). directly proportional to its molecular weight (©) directly proportional tothe square root of its molecular weight (@ inversely proportional to the square root of its molecular weight The average velocity ofan ideal gas molecule at 27°C is 0.3 imise. The average velocity at 927°C wil be: (1986-1 Mark) (@) 06misee (6) 03misee (©) 0.9misee (@ 30misee Tn an der Waals equation of state for a non-ideal gas, the term that accounts for intermolecular forces is (1988-1 Mark) (1985 - 1 Marky @ (vb) () Rr oy © (r+3) @ «ry GP_3021