Thermodynamic Properties of Oxygen from the Triple Point to 300 K with Pressures to 80 MPa Richard B, Stewart and Richard T Jacobsen Center for Applied Thrmodsnamic State, Coleg of Engineering, Unversity of Idaho, Moscom ID 83843 W. Wagner Instn fr Thermo- und Fuidynamit, Rubr-Universtt Bochum, Bochum, Germany Received July 10, 1980; revised manuscript recived May 2, 1991 A joint project by the authors has resulted in two new thermodynamic property formulations for oxygen. The fundamental equation explicit in Helmholtz energy by Schmidt and Wagner has been used for the calculation of the property tables pre- sented here, and for comparisons or ealculat ‘The formulation by Stewart and Jacobsen ied properties tothe experimental data, is used in this paper in comparisons of properties calculated by the two formulations. These comparisons provide the basis for independent assestment of the accuracy of the available data and calculated properties. The procedures used in determining the formulations by Wagner and Schmidt, and by Stewart and Jacobsen were published earlier. ‘The fundamental equation is valid for thermodynamic properties of oxygen from the freezing line to 300 K at pressures to 80 MPa, A separate vapor pressure equa- tion and equations for the saturated liquid ideal gas heat capacity are included. Fun thalpy, entropy, isochoric heat capacity (C.), and saturated vapor densities and the ms for calculating internal energy, en- |, isobaric heat capacity (Cy) and velocity of sound are also included. Tables of thermodynamic properties of oxygen are given within the range of validity of the fundamental equation. ‘The fundamental equation reported here ‘an uncertainty of 0.10 percent, heat capaci sound values within 1.0 percent. These un ‘may be used to calculate densities with ities within 2.0 percent, and velocity of wertainty values are valid for the range ‘outside of the critical region. Comparisons of calculated properties to experimental ‘ata are included to verify the accuracy of ‘Key word: dons; enthalpy entropy; equation of sate; heat capa dynamic properties; velocity of sound. Contes 4. Inroaucuion. ... oy 11. Prior Correlations of Thermodynamic Properties of Oxygen. + 920 41.2. The Fundamental Equation =. 020 2. Experimental Data for the Single Phase Region....-.-- sees 2 21. Peo-T Data oa 22! Heat Capacity Data, 921 23. Velocity of Sound Data - ou 24, Virial Coefficients . 92 25. The Critical Point.ss..sccsscssesseses 923 26. The Triple Point...... Feces 924 3. Liquid-vapor Coexistence Properties 1.0... 924 3.1. The Vapor Pressure Fqation 4 (©1991 by the US. Secretary of Commerce on behalf ofthe United States Tis copyright is assigned to the Amerian Isitueof Physics tnd the American Chemical Society: Reprins sealable fom ACS; sce Reprints List back of te (0047-2689/91/040917-105/811.00 917 the formulation, ‘aygem: propery table; thermo- nts, 3.2, Une t:quation tor the Saturated Vapor Density. 33. The Equation for the je Saturated iuia 4, Ideal Gas Properties... ‘The Fundamental Equation For Oxygen « Comparison of the Fundamental Eastin to ata 6.1. Comparisons ofthe Fundamental Equation to Pp-T Data ......+..- (62, Comparisons of the Fundamental Equation to Heat Capacity Data ..... (63. Comparisons of the Fundamental Equation to Velocity of Sound Data. 64. Comparisons of the Fundamental Equa- tion with the Ancillary Equations for Va- por Pressure, Saturated Liquid Density and Saturated Vapor Density 7. Recommended Range of the Formulation and Estimated Accuracy of Calculated Properties, 8. References verse. 928 932 oa 4. Phvs. Chem. Ret. Data, Vol. 20. No. 5. 1991918 Appendix A. Funetions. for iets to 100 (= 0408 gram’) c ° Workman” 131 29,33 1 27 G « “Data selected for determining the fundamental equation. q 100, erate | ih ¢ : 1G dain at gf C8 Apes 1 Hl . ‘4 Boidokov and, Gurino™® 6 * Michels et Hoa 3 Street ond’ Sagan : S Von iterbeek nd. Verbeke®, tere Nan Ierbeek Gnd Verbeke . | ‘ 3 yebere one oa rit 1 bisiit \ \ 1 \ ° 5 1 5 ww DENSITY (mol/dm') Fo. 2. pT Data 9 ccrdinats). Equation (4), with the second and third virial coef 25. The Critical Point cients represented by Eqs. (5,6), is valid for densities up to one-half the critical density. This permits the calcula- ‘The values of the critical paint P-p-T' selected for tion of saturated vapor density values for temperatures this formulation are those published by Weber’. The ‘up to 150K. Comparisons between experimental thermo- critical point parameters are, P. = 5.043 MPa, pe = 0.0 oe 0.0 5 Be sssuil ‘ Bote ee oe wr u 3 < 2°? or eaae 3 Soo ream] 0.0 | “0.2 “0.2 - 5 were ite od oo 5 —e-ege| 2 00 0.0 : npg eat cast aug, 2 aa th ul aS mK Oy ask F EE a ee a tn 0.2 “0.2 a2 2K 52 ie 0.0 0.0 Lagi) 02 1. n 23 tt Be Ae t00.0 8. too 00.0 PRESSURE (MPa) © Weber* 2 Pentermann and Wagner"? @ Weber" x Van tterbeek ond Verbeke” FRc, 6. Comparison of calculated vals of density from the fundamental equation to experimental dat for Tigi states below the eicl temperature. The data sein ting Bg 15 are Q Weber, Weber", ‘Table 5. Only nine of the P-p-T data points listed in ‘Table 5 were used in determining Eq. (15). The other data points had been rejected because of inconsistencies With other data or because the dataset had large system- atic erors. ‘Figure 6 compares density values calculated with the fundamental equation with P-p-T data of liquid oxygen at temperatures below the critical temperature, There are systematic differences between the data of Pentermann and Wagner and the data of Weber. These differences are approximately 0.11 percent for temperatures from 68K to 120K. 0.08 percent from 122 K to 135 K. and vary from 0.01 to 008 percent from 138 K to 150 K. No reason has been identified for these systematic differences, However, emphasis has been given to the data of Weber! in determining the fundamental equation, Data in the lig- uid region with density deviations greater than 0.2 per- cent are identiied in Table >. Figure 7 compares density values calculated using the fundamental equation with P-p-T data of oxygen vapor at tomperaturee below the critical temperature. All of ‘Weber's vapor data for temperatures from 85 K to 158 K are from Series 4 of his experiments. The experimental methods in this series differed from the other series in 4. Phys. Chom. Ret. Dats, Vol 20, No.5, 1991930 STEWART. JACOBSEN AND WAGNER: oa 2 sso v0 of appt reg] 0.2 22 i - oe 7 tol 10 102K cea 83 0.0 0 2 nner] Z 22 2 - 1 g Bt i ioe k Zoo 00 geet ee Soe 2 os —skwse oa ae k TO 107 k zoe Syhocs| 9 _T02P* arte} Hs. . a 0.2 : . i eats rm 108K Bo. 0.0} ———suragi2is0} 0.0 2.2 vation 0.2 0.2 7 a 5 2 and Ge ine 9 : ‘ gos 0.0} +s} 0.0 epi ba Suk "Lan ie 2a aaenrae a o Hoos oof Een 2 ee ee bw mei, os ie To 138 « tat ao SSS oe 0.0 ge ~~ “2 pee eee ‘ aw? mek O5 ue 0.0 peat 9.9 LF —____ prpeittintee | 0.2 7m eve Ll a G2 igaiciTonzuicie eres Bex 0.0 wR angaste| 0.0 Poe ao aod Poe inerenntae Gsiqeeem 130799 1020969100 Ol pd? Temmr nOmeeniorormeticats PRESSURE (MPa) © Weber* a Pentermann ong Wagner’? © Weber" 4 Baldckov end Gurino™™ liguid states below the eri fundamental equation with P-p-T data for oxygen at tem- peratures above the critical tomperature. Table S summa Tizes the P-p-T data in this fluid region with density deviations exceeding 0.2 percent. ‘The P-p-T data by Ewers" for temperatures from 305, to 400 K were also used in determining Eq, (15). These data were determined by an extrapolation of experimen- tal data fo the unit compressibility (P/pRT = 1). Densi- ties calculated with the fundamental equation differ from the unit compressibility data with a range of deviations from 0.018 to ~0.059 percent. ‘The critical point for oxygen is at a temperature of 3d values of dest fom the fundamental equation to experimental data for temperature, The data used in iting Eq 15 are O Weber, © Weber, 154.581 K and a density of 13.63 mol/dm’. The critical re- gion is generally described as bounded by temperatures within +5 percent of the critical temperature and =25 percent of the critical density. For oxygen, the critical re- sion is the region between temperatures of 146.85 K and 162.31 K and densities of 10.22 mol/ém and 17.04 ‘mol/dm’. Figure 9 compares pressures calculated from the fundamental equation with P-p-T data of oxygen at ‘temperatures from 154 K to 160 K, which includes the P- e-T data in the critical region and adjacent to the critical region. Pressure deviations are less than 0.2 percent for all of the P-p-T- data in thie temperature interval for Phys. Chem. Ref. Data, Vol 20, No 5, 19910A 141 k 70 142 144K TO 145 K [| Sri] Lead cit sau 1S K T0147 K | § 0.0 a 7 0.0 fxwunx 22 5: 7 eae ‘ 1 de tsanad a ios TO 110K ie 10149 & Q 02-—. “ 4 e wee Boo og Saad aad 2a see al Bu use 3S oe Tost « a eo te Z Bc ofan tts mo eed o ene GO np gL css ssa sss 9.2 : ae 1s toe ae 182 K 70 163 « 0.0 peewee — $< Leen ee x | 2,2 Catal cad og 2 as cast a asl ae “4K TOS K G's 184K 70 185.5 0.0 Pend ieSeoe® | 9.9 Lannie iP x GR dor diy 1.00 10,00 “Gor 0-10 1.00 10.00 PRESSURE (MPa) 0 © Weber® 2 @ Pentermann and Wagner’? x Virial dota (see text) + Suyame and Oishi 8 Furukawa and MeCoskey"* Fa 7. Comparison of aculated values of density from the fundamental equation to experimental data for this formulation cannot be used for C, values very close to the critical point, and no comparisons are given to these data ‘The data from Workman” are from a flow calorimeter for temperatures from 26 to 50°C and pressures from 10 {0 130 kgjem® (0,98 to 12.7 MPa). Only graphical results were published and no comparisons were made to values determined by the fundamental equation. In this low dencity, high temperature ragion tha calenlated values titel temperature, The data used to fit Ea (15) were O Weber and © Pen- are considered to be more accurate than the measured data, ‘Other experimenters have reported C, and G, values from calorimetric measurements, values derived from ve- locity of sound measurements for vapor states at pres- sures up (0 0.101325 MPa, anid values for the liquid atthe vapor pressure with temperatures up to 90 K. These data are summarized and compared to calculated values in the parlor work hy Stewart? 4. Phys. Chem. Ref, Data, Vol 20, No.5, 1991‘STEWART, JACOBSEN AND WAGNER ae EK TOIT 97 120 = oe 8 0.0 | Mapas erase —| oe EJ +e ot 02 oe sek yy 183 K To 198 k 0.06802 —aareatat| 0.0 [earosricr smite —| Z gph 1 che 1 | yori iii 6 ot ISKTOIOK 5's 200k Let % = 0.0 6 0.0 3 . 5 2 i pa ees PoP sree agers 1 all ata IEKTOISK Hoos 2 0.0 | gg op —Saasryfagetor—| 0.0 z= oa fee aye eee ea Bo wok G2 [0.0 f tppgParenctamietiete— 0.0 o2bm ee J og gh & Oe sk 4 20 E10 233 K G 5 : BD 0.0] Masons" 0.0 Pach roe tee 8, | Gio p2berr iii | 4 ,2rriiii a3 wok 4 240 k 0.0 Pie 3.0 poor ii) gr hPiiin ae mse yo atk 0.0 fg teertinsmetee—| 0.0 | atime masa, ag a tte os 10 15 20 25 30.35 0 § 10 15 20 25 30 35 DENSITY (Mol/dm?*) © @ Weber® 9 6 Weber"? 9.2 Pentermann and Wagner” + Street ond Sagan™, Fic. 8, Comparison of calculated values of density fom the fundamental equation to experimental data for uid stats above the ciel temperature. The data used in fing Eq, 18 were Q Weber, © 6.3. Comparieone of the Fundamental Equation to Velocity of Sound Data In comparisons of velocity of sound data to values cal- culated with preliminary equations of state, the velocity ‘of sound data in the single phase, values for the saturated liquid reported by Straty and Younglove, and the single plese vapor dats by Van Tueibeck aud” Van Pacusel™ ‘were found to be concordant with the selected P-p-T and Cy data: These data are compared to values calculated with the fundamental equation in Rige 19 and 13 The J. Phys. Chem. Ret. Data, Vo. 20, No. 5, 1991 ‘c=ptrimental mearurementsinchaded preerure,tenapers- ture and velocity of sound. In these comparisons to single phase data, the input parameters were pressure and tem- perature, with the density determined from the funda- ‘ental equation for the calculation of velocity of sound. In Fig. 12, the data of Straty and Younglove® for tem- peratures from 70 K to 140 K are for the liquid phase. "Tie maninnusn deviation of dhe liguld data fs 203 peseent at 100 K and a pressure of 33 MPa. This isthe only data point exceeding the deviation scale of2 percent. The data SIS K include leven vanes at the mpper honndary af‘THERMODYNAMIC PROPERTIES OF OXYGEN 935, oo 250 « 0.0 [Bat ay2 Seay | 02 ae 270k 0.0 fag ype eo Z oebrui i Soe 22 K T0273 K Ee 3 Boje Oa 230K ay , > 00 ee mee eg rrr 3 wok Bee ; 1 0.0 | a" e995 $$ 0.2 1 Ee 5 WR 7a K a 2 2°hs————_ eee ne a2 300K 0,0 PRR egy *2 ager aogbea i sea wi 0.0 Mg Oye eee ere ‘oS 10 1S 20 25 30 35 3 DENSITY (Mol/dm*) © @ Weber" 0 0 Weber” 2 Pentermann nd Wagner"? = Michels et ol” Rc. 8. Comparison of eaeuated values of density from for Bid stat ‘he erital temperature, ‘The data used in fitting Eq 15 were © Weber’ © Weber, and © Pentermann and Wagner = Continved the critical region. The maximum deviation is ~ 1.4 per- cent at a pressure of 6.9 MPa. For the vapor data for tem- peratures from 190 K to 300 K, the maximum deviation is =0.79 percent at 190 K and a pressure of 34.3 MPa The deviations of the data of Van Iterbeek and Van Paemet" from calculated values are illustrated in Fig. 13. ‘This data set isin the vapor region at low temperatures, where the only reliable P-p-T values were those deter- ‘mined from a virial equation of state. The excellent rep- resentation of these velocity of sound data by the fundamental equation supports these calculated P-p-T values. ‘The deviations ofthe saturated liquid velocity of sound. data from calculated values are illustrated in Fig. 14, The data of Van Dael etal. are seen to be concordant with the data of Straty and Younglove®. The data points ex- ceeding +1 percent are identified in ‘Table 5. 154K TO 154.5 K 0.2 8 ee Ql 0 hep he 30,5 154.581 K ee eke PERCENT PRESSURE DEVIATION 2 2S oP ec 35 10 1s 200 S DENSITY (Mol /dm>) © Weber ' 8 @ Pentermann and Wagner 4 Fo, 9, Comparison of excuated values of presure ‘rom the fundamental equation to experimental ‘data used in fting Eq. (15) ae, © Weber” and (9 Pemtermann and Wagner” Comparison of the Fundamental Equation with the Ancillary Equations for Vapor Pressure, Saturated Liquid Density and Saturated Vapor Density ‘The quality of the fundamental equation is further it~ lustrated by the comparison of vapor pressure, saturated liquid density and saturated vapor density values. Vapor pressures from Fa, (7) ate compared in Fig. 15 with pres J. Phys. Chem. Ret. Data, Vol 20, No.5, 1991yap STEWART, JACOBSEN AND WAGNER, ‘Tasus 5. Comparizon of ealulted properties om the fundam the percent deviation in Figs 67-810 and 14 uation to experimental das, Summary of deviations exceeding the scale of No. Temperature Pressre Density ‘Range of Figures data ‘ange range eviatons Reference point © rs) (won?) (percent) 6 3 6 om - 113, 393-398 02 = ~032 6 8 8 34-105 380 — 384 021 = 031 & > m aes 160 ya 32 6 6 0 26— 85 369 390 Van tuerbeck” 6 1 1. 4s 313 Bridakov"™ 6 9a) 1s2-sea 449 ~ 504 160 - 199 Pentermann® (ca) 18458 Sot - 317 Mao tat Penermann”™ 1 3 8s 04 - 006 0.06 ~ 0.09 Webert 1 3 0 05 - 007 0.06 = 0.09 Webeet 7 3 rS fans — 04 006 = 018 Webet 7 4 100 fons = 021 (006 = 027 Weber? 1 1 10s 034 043 Weber? 1 4 12446 30-34 41-46 Weber 1 3 148150 33-35 41746 052 = 058 Webert 7 2 S254 35243 41293 =039 = 059, Weber? 7 5 19-51 2a 4a 24-70 036 - 022 Pentermann’ 7 5 152-153 45-48 ai-8s 070-03 Pentermann"® eal 1551585 45-50 1-1 =04 7 30 15458 49250 892 088 = 50) Pentemann 8 6g 136 s2-s3 97-136 Weber 8 sa 186, 52_ 54 100 = 148, Pentermann? 8 1a 18 51 BS Weber 8 30) 138 57-38 1-148 Pentermann”® see 10) 1 6 86 Weber fae so) © sae a1 36 entermann!? 8 1 10 AT ‘m4 Street 8 4 190 3-0 246 - 293 Suret™ 8 7 20 3-68 163 — 241 Street 0 1 1s 52 Goodin” 0 1 132 61 Goodin” mM A 135-156 Bi Goodin” 1“ 2 58,60 22,13 Stray? uw 4@ 1st-t64 2-18 Van Dact* “ 0 Si63 13257 outer Mu Baa 10-154 202-17 Gouter#® "None ofthe datapoints ted above for Fig. 6 was used in fitng Ey (18) Only one for Fig. 7 4 K) was used in iting Eq, (15). Eight of ‘he datapoints lsted for Fig. 6 were used in iting Eq (15, (ae cach at 186, 158 and 160K for Weber and five at 160K fom Pestermann®). "The numberof data points nthe ercl region i gen in parentheses, sures calculated using the fundamental equation at states defined by the Maxwell criteria, ie., equal pressures and Gibbs function for saturated liquid and vapor states at the same saturation temperature. This comparison shows no differences in vapor pressure values calculated using Eq. (7) from the values determined with the fundamental ‘equation to the number of significant figures given in the vapor pressures listed in Table 10, except for values ‘above 136 K. The difforenecs in the calculated vapor pressures above 136 K are: from 136 K to 140 K, +0.0001, MPa; from 147 K to 153 K, —0.0001 to —0.0002 MPa. Vapor pressure values calculated either with Eq. (7) or 4. Phys. Chem, Ref. Data, Vol. 20, No.5, 1991 from the fundamental equation are within the uncer- tainty of the selected vapor pressure data used in deter- mining Eg. (1). ‘The solid line in Fig. 16 illustrates the deviations be- tween values from the ancillary equation for saturated liquid density, Eq. (10), and values from the fundamental equation. Data forthe saturated liquid are also compared to values calculated with the fundamental equation using the Maxwell criteria in Fig, 16, Saturated vapor densities caleulated with the fundamental equation using the “Maxwell criteria are compared to values from Eq, (8) for saturated vapor density, in Fig. 17.‘THERMODYNAMIC PROPERTIES OF OXYGEN “Tamu 6. The estimated experimental uncertainty and the maximum de ‘ations oealclaea valves ftom the enone heat apacly ‘data of Goodwin and Weber” Estimated Max. dev. ‘Temp. erm Cr maa (percent) (percent) ‘« 32 20-32, 2 1s on hoi mao i Ba o- 22133 185 m2 os - 09 037 216 Ba 07 = o8 036 Ww a8 07-08 068 10 26 o7-0s 077 ass 26 07-08 07% 130 me 07-19 078 4 306 07 -095 9 BS 07 a3 116 MB a7 aia 17 360 07 Is 8 ma 6-07-14 9s xa o7-08 “un 5 389 a7 x9 16 406 5 - 07 2 58 Weber, awn duced fom By “Temperature at the maximum deviation, 7. Recommended Range of the Formulation and Estimated Accuracy of Calculated Properties ‘The formulation presented inthis paper is valid for the calulation of dhe thermodynamle properties of oxygen {rom the freezing line to 300 K at pressures up to 80 MPa. This range is consistent with the ranges of available data and extrapolation heyond estimated limits i not recom mended. It is recommended that coexistence properties be cal- culated by application of the Maxwell criteria, because the fundamental equation given here conforms to these requirements. The separate functions representing the vapor pressure saturated liquid density and saturated va- so density given inthis wrk ae useful eatinating eyue tions for iterative calculations 937 ‘The accuracy of calculated values of density, isochoric heat capacity and velocity of sound has been estimated from the accuracy with which the experimental data for ‘these properties are represented by calculated values, as iMuctrated in Figg. 4 to 17. The accuracy of caloulated ‘properties may also be inferred from the comparisons be- ‘ween properties calculated from the formulations by ‘Schmidt and Wagner‘ and by Stewart and Jacobsen’, as summarized in Tables 7 and 8 in Appendix B. All calcu- lated properties from both formulations may have sub- stantially larger errors in the near critical region (between 1022 and 17.04 moViin' at emperatures fi 146.85 to 162.31 K) than in other regions of the thermo- ‘dynamic surface. Both measurement and correlation are tuhjert to larger errore inthe evtical region than in othe regions of the thermodynamic surface. However, the au- ‘thors consider property values from the formulation by Schmidt and Wagner' to be more accurate for the critical region than those from the formulation by Stewart and Jacobsen’ The estimated accuracy of density values calculated with the formulation presented here is 20.1 percent (sce Figs. 5 to 9). Although calculated density values in the critical region are much larger (see Table 5), Fig. 10 ind cates that calculated pressures in the critical resion have an estimated accuracy of 0.1 percent. ‘The estimated accuracy of calculated isochoric heat ca- pacity values (see Fig. 10) is +2 percent. Tables 7 and 8 Indicate that errors in calculated isobaric Neat capacity values are generally of the same order of magnitude as the errors in isochoric heat capacity. Figure 11 indicates that the calculated values of the saturated heat capacity for the liquid are within 1 percent of the values derived by Goodwin and Weber* from their experimental data for isochoric heat capacity for the two phase resion. Calculated values of velocity of sound are estimated to bbe accurate to within + 1.0 percent, except near the ert- ical point (see Figs. 12 and 13), The accuracy of the cal ‘culated values of the velocity of sound for the saturated liquid is also within = 1.0 percent (see Fig. 14), except at temperatures below 60 K and near the critical tempera- ‘The comparisons summarized in Tables 7 and 8 indi- cate the differences in calculated properties from two equivalent formulations that were fited tothe same data sets. These comparisons indicate that differences in en- tropy are about the same magnitude as those in density, and that differences in internal energy and enthalpy are generally abuut five nes dhe magnitude of he alrer- ences in density 4. Phys. Chom, Ret. Data, Vol 20, No.5, 1901,938 ‘STEWART, JACOBSEN AND WAGNER 2 2 2 2 o a ‘09° S000 2 noPoi? © glotiisiit isp goo ago 00) oo zo yaa ao 180200 2 2. 2 a fe 0} —*seaaeas 2 So %o poo gloiriiiis Sse a ee hee “Tee eo a 2 s 2 2 ZB thas a5 a oe Ce abe & to mo pa) “too aa ao 60180 Zoo Ss density = 20.2 deneity = G2 2 a o o & oo 5b 1 1 1 4 1 1 1 1 5 4 2 Zoo wza oie eo 200 “foo azo 140 “igo eo 200 Qo 2 a ° Q ar glo) Gh ee] foo iz 140 veo Teo 200 “Yoo tio 120 Tao 14050 2 ss 2 # o 204 0 22 eo ghee gfe tea foo iz ta Teo Tea 200 | “Yoo tio 720 1014080 TEMPERATURE (K} FRc, 10, Comparison of experimental data of the isochori heat eapacity from Goodwin and Weber" with vals from the fundamental equation. The density given for each graph i in mola.‘THERMODYNAMIC PROPERTIES OF OXYGEN 939 ty = 33.8 density = 39.7 2 = 2 = ° oe ° 3 2 ris. 1s ater wii go 100 «110 120 $0 60 70 80 30 100 density = 34.8 density = 40.6 2 ~ 2 = ° ° > 2 i 6 abe 30 100 «110 (120 50 60 70 80 90 tan density = 36.0 2 Oe ee 2 ee ao 90 100 110 120 density = 38.1 PERCENT DEVIATION IN TEMPERATURE (K} Fic. 10, Comparison of experimental dat of the isochoric heat capacity from Goodwin and Weber with waluet from the fundamental equation. The density given for each graph it in molidm? — Continued,910 DEVIATION IN Co (®) ‘STEWART, JACOBSEN AND WAGNER, 0.25 + ae 0.00 Q 7 fe -0.25 ao. ae ‘ 7 Ee eg 0.50 was oy 50 -U.1> ett . =1.00 | By ++ cxpsientel Saiee d 2 3 500 3 3000 2383 1.25 ria L 4 ta L 1 1 55 65 «75 «85 «(95 105-115 125 «135 «14d «1D TEMPERATURE (K) ‘0,11, Comparison of calculated values ofthe saturated ligudheat capacity (C,) from the fundamental equation to experimental valves {hom Goodwin snd Weber,THERMODYNAMIC PHOPEHIIES UF OXYGEN. vat a — 2 250 « ° 2 ° poo o slits t 2b. . a 5 280k ofa a sooo d ee eee qherisit : 124k 5 300 of woo of e2c2000 0 aglerirtit eee ee 5 130K 0S 10 18 20 25 30 35 : ° PERCENT DEVIA“ION IN VELOCITY OF SOUND 2 5 130K ° om900.0 0 2. eee po : 220k c oo ae eee 08 10 a5 20 2s 30 3S PRESSURE (MPa) Fic, 12. Comparison of experimental data forthe velociy of sound from Stray and Younglove® with calculated values fom the fundamental equation. 4. Phys. Chem, Ret, Data, Vol. 20, No.5, 1901ry STEWART, JACOBSEN AND WAGNER LOCITY OF SOUND PERCENT DEVIATION IN V: Fic. 13. ‘J. Phys, Chem, Ret. Data, Vol. 20, No. 5, 1991 : eer ; A al uw ; pate : : “ i ate 0 oe a f A 0 — i i i a = ry 1 - ; i 7 or 7 ool 1 ak 4 i : ae ° o 8 00 A i alegre tie ote PRESSURE (MPo) ‘Comparison of experimental data forthe veloe- iy of sound from Van 1 beck and. Van Pemet” wit clelated values from the fun Aamental equation‘THERMODYNAMIC PROPERTIES OF OXYGEN vas & Zo v3 2 : : z a ; S805 + « g 0 2% Pe 5 as os peth® 8? 00 opeuest a a8 cones oP 800, edece, BeOS TE Se weet By . ’ eee 55] Coaman. 65) 95)en105u2115] | 12598155. (145) 155) TEMPERATURE. (Kk) FRc. M4, Comparison of calculated values ofthe velocity of sound from the fundamental equation for the saturated liquid to experimental vals. 0.010 9.005 + 0.000 -0.005 PERCENT DEMATION IN VAPOR PRESSURE wooo | 55 6575S 95105125135 «TAS SS TEMPERATURE (kK) Fic. 15, Comparisons of valves of the vapor presure from Eq, (7) wth values calculated from the fundamental equation sng the Maxwell rtri z § ono Se 22 Stele water, 6 5 0.05 § Pentermonn ond. Wagner : Bo . + pay OM dota of,Weber” A = 3 0.00 o 7 Ge aes 6 0.05 a4, tte pra (10) 4 Bs tes . af 3 ot 3 Z-0.10 fete . | Be 4 * ' ® Boss 1 fos eee, Goss 6575-8585 105115 125135145155 TEMPERATURE. (Kk) Fic. 16 Comparzons of experimental data and valves from Eq, (10) with valves of the saturated liquid density frm the fundamental equation sing the Manvel extera. J. Phys. Chem, Ret. Data, Vol 20, No.5, 1991‘STEWART, JACOBSEN AND WAGNER: os 0.10 0.05 g PERCENT DEVATION IN ATURATED VAPOR DENSITY sa 0.10, ss S75 ass | Tos 15 125438 145155 TEMPERATURE. (K) Fc 17, Comparisons of values ofthe saturated vapor density from Eq, (8) with values cal lated from the fundamental equation using the Maxwell eter, 8. References RT Jacobi, R.B Stewart and M, Jang J. Phys Chem. Re atm 45,75 (C0) 2M Jahangir, RT Bcoben and RB tena J. Phys Chem. Re ‘ata, 15,59 (1986) RB Steart and RT Jacobse, J Phys, Chem. Ref Dat, 1, 735 mn 4 Sch and W. Wages, lid Phae Eglibris 1,15 1985). SD. Stewart RT Jacobse and W, Wagner, Repot No.8, The Geni for Apiied Themoddnamic Sadie, Unhersiy of lab, Snow Hate (7) ‘i apr and KM. de Reuck, Ong, Ineatonl Thermod ‘aie Tables othe Fi tte; baad on ony and equations by AW. Wagner, Sebi. Evers RB, Stent and RT Jacobsen {Bethe International Union o Pare nd Applied Chem Rael Sienfe Fubletons, Oxord (198), “Rb Stovart,Themodynamie Properties of Oxygen PhD. sera tin, Unertiy of lows ows hy (96) OUR Woven? 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Poh and, Schomdckr, Themo- oo 9 c ‘O1 ‘08 2 3 a * (09 () oy eo) % a5) G a 28 “ 0 0 a (os) &% (2 ey ey eo) wl ‘10 0 ® 8 16 3 @ (a % re) @ a "The values of internal energy and enthalpy ae anal i RB region: 4. Phys. Chom. Ref. Data, Vol 20, No.5, 1991,948, Appendix C. Thermodynamic Property Tables tor Oxygen ‘The thermodynamic properties of the ideal gas given in ‘Table 9 were derived from Faq. (11), Thermodynamic properties for Tables 10 and 11 were calculated using the fundamental equation [Eqs. (2, 14, 15)] with the coeffi- STEWART, JACOBSEN AND WAGNER cients and exponents given in Table 4 and the property functions given in Appendix A. The evexistenve states ‘were defined from the fundamental equation for calculat- ing the liquid and vapor densities using the Maxwell erite- ria, ie, equal pressures, temperatnres ancl Gibbs energy for the liquid and vapor phases. ‘Tams 9. Ideal gas popertes af ype T = ” G G Tae a a G K— WmckK Simo Simo K Smo K MootK nolo nob 3% Waa 19 =a su 08227364 —~=SCLOTSC« ES o MGSL 187208528199 310 20618 00S BAST 6 woe 130130819 So 2071293281 21180 29494 s 1557915926 82 ‘OMSL 99163213098 o 1a m2 2809 380 2007710128380 8688 n test 700952. 310-2142 106082 SM 8K 6 wig 20751 mms wo 202 «od et7 99 » 16570 08 = 0 30 7130014069278 30018 as 16ss 24652 msm 2aats ao 71376 mrs m2 s0407 0 ras (26s = amos 40 02173316 = RIMS 95 iz 774 = amos soo 22058 nm 303 100 mig 3929 sso. 57 2287 31.602 1s rms) 30850799 DOI a 2534 237932083 uo wss7 31981 m7 aus 60 mag} 957 eae 2856, us 1726 3396 78D mw D136 ISL AST 32.85 0 17850 348520798 D9 7502365 208407506838 Bs m9 3008 UB mo BSB S187 Sa BTS 10 10S 3763 Dw $50 2787 260139578) OSS as ssiss 3921908 suo 2398227 ho 0 1299 ens 079822 850 24169 296196 «6317 GE us wor 421300 io 26347 513742656877 150 was 43585 2088 1050-24518 3513706788 35:02 15 ias9s 45081 ns too 24682 348973605 353009 10, 1688 46107 02a 1150 24839 3606772747 aS S00 16s W771 4983 0 as 10 24990 3727365 38.6D 10 test 4840820800 Dols 1250 35136 Sussa OTS ws 149 50854 OM OIG 10025277 aams.7 27689 36.03 189 wost 5220 087 1350-84 ASRS 27893653 18s suo S376) see. 100 28545456468 79m 36.296 19) iiss 5532007, 145025673 ass BID 36.43 195 tet 56683 05092914 1300 25797 4990128282666 200 1337 Sela tnsi2 28127 135025017 S1I2L7 aah (36.66 210 ria 61085720800 29:135 10 25033 59595 S68 20 ws nd DM 1650 61a Sums) R607 20 174s 66887 as 18) 10025057 Secse3 RSS 37.069 240 19869 © 66803 ast 29178 17506365 Sasio8 = 28a 37191 230 138 7222 0S. 10026470 603733283 20 2O1M3 78644 0913.08 15025572 IHS DONS 0 mis S68 oss 190 25672641163 oak 230 m9 896 = 20982 29.296 195025170 659956 2038237656 0 mm BT DOM 388 200 26865 T8884 37.283‘THERMODYNAMIC PROPERTIES OF OXVGEN 010 ‘Taoxe 10, Thermodynamic properties of saturated angen Temp. Pressure Density “Enthay "Entropy G Vel so. x MPa rol? Jim Simol K JimolK —__Yimot Kms SG 00016 “sie sina ea98 aes eu an? sna oma 0 5s 00179 ors 61592 57 a5 ss91106, ‘003906 15918 20899 mn 56 tones 008 61058 6453 2686 560 ‘nsi91 16007 20650 2 7 00323 wan 60523 aT 621 546 009821 16085, 20480 16 8 0048 0337 $9988 7040 3807 8B “zon8s70 167k m7 vat 9 nes60 o20 59653 132 sm 5331 130 ‘tous? mz rom us o 0738 40.064 58918 ma sa sss ones mse was 1 a ss 39926 58382 TRO 3450 ss “s01840 fon 19174 1 @ oust 39187 57846 1398 saan sat 8 “02306 13 19620, rd o 01499) 368 31310 483 3893 368 102866 i219 sr 150 6 01878 39507 36714 1888 Be sss 07 103835 13505 18330 181 « 02335 39367 36289 "631 2347 sas) 0h 103329 1890 9194 152 ones 0205 55700 733 826 361088 005264 sors 3083 183 o on3s33 20088 35163 TEs 2307 3369188 006359 19360, 13937 154 o -s0%302 a8982 ~54626 7a93 2288 3608 073s 19643, 1885 155 ® £05206 3879 54089 pn 3270 36 ‘si07 1926 13698 156 ~ 009262 38.686 $3552 9 as S87 1066, ‘10808 2a09 18585 158 a ores sasI5 S015 a5 sr 53701058 12788 18478 159 n ongo10 30) 5200 sa 37 10st 014963 1873 160 1" sins ery x76 seas Sn 108 “oT? 12.73 16 1" ona sea mT 3180 sm 1s “120316 181.75 1a > i> 1310 my sus sn Mm 23809 18082 18 %6 01657 3180 5490 3.0 an 1p “ares 1991 1st ” wn sina Sal sas sam 10 31082 1904 165, 8 ooo 37838 5630 aa 50% 103 35524 1819 166 » ses sist 8 sur sa 35 oes m7 167 » 012 sr 57456 suas sat 387 Das891 17658 168 a ase srass 38 sox sat vy a5188s 17581 169 2 3923 607 99 076 sus om nsb468 17507 m0 s oss sans 9.8 2089 svt sms 088679 17435 m cy 15039 36607 029 308 5396 555 “T3888 im3.6s m ss 13688 36457 3095, 3037 soi #0 -t82138 172.96 mB % 16391 36305 9136 sas sar 38 “wiser m0 1m ‘J. Phys. Chem. Ret. Data, Vol20, No. 5, 1991950 ‘STEWART, JACOBSEN AND WAGNER ‘asus 10, Thermodynamic properties of saturated axygen — Continued Temp. Premure Dein, Enthelpy Entropy c os x MPa ollie? Timo Simol K nol Snot K w as 36183 ~ aes s218 sat sa 330 0158 286 m6 m6 8 8011 3600 407 28) 299 5420 om 11253 2500 m3 175 ® 98933 38847 403 S341 81 5428 oe 12036 25040 17008, 176 * 09935 er ~ 4758 602 eas 5436 0s -3n0 23075 168.83 7 o 1102 35537 -an3 suse 203 sas or 13081 25707 16825 178 2 120 as 41065 9521, asi S455 0 “esse 2s 16869 1% % 107 ss a8 3580 39 5865 81 “asi 25158 15814 1» cS 1s 3503 aise 038 a8 5476 sn “19821, 26317 1610) 180 98 1631 sas -a0018 3695 aaa sss 64 21627 26331 167.08 180 ” rs st Ss 733 0% ssa 6 23883 26801 16635 ist ” 1958 34583 34912 98.10 2395 ssa 87 25606 zs 16.06 ie 271 mma 16557 2136 318s iz. 23 34257 37801 B23 2% ssa 30 - 0113 209 16508, 237 s201 1 29 71589 16461 2161 20 1 101 2160 33905 3082 10033 2333 is 3 35155, ama 164s 218s sear 184 12 a 39957 36120 10.8 23 395 05 7903 250 18.69 2170 ses 138, 103 28 33588 ~ 38556 1012 233 set 736 0836 28123 163.25 2136 3290 18s 04 x06 soar? 3990 10198 2528 Sass 181 43993 2289 1281 2182 sar 136, 10s; ames 38285 sor 10250 ais 5636 1 anst 250 1037 2.39 346 186, 106 4001 son 382 19.03 2305 3678 ™ ‘some. mao 161.95 297 a7 186, 107 483 32596 3219 103.56 2136 sta 764 51306 25a 16153 206 3a 187 “3006 2883 16112 nis 36 187 109 5069 32540 -n0s 1046 mp sre 13 50 roar 10.71 2s 3B 187 6506 256 16031 2236 3526 188 m 3318 32177 30960 105.65 me sa ns 70583, wna 15991 nar 3861 188 "73650 3841 15952 239 M12 18 13 646 311806 29783 10667 746 5875 m1 0635 2098 15913 zn 3600 188 a 700 1617 pies 10738 29 ea0 os ‘asm09 23997 18825 2288 srt 188 us 1886 31426 2859.2 10789 231 sar os 91288 288 18837 258 ars 189 6 son a m2 10820 me 26 ” 97006 ama 1519 aR xn 189 a a3 31037 -77387 10870 mu an ™ 10301 23847 15162 2326 3882 189 ne 9006 205% 279 10031 m0 an 1.0831 m3 15725 aa 19 19 9642 20838 26165 109.71 no 1 11592 er 15688 as 189 4. Phys. Chem Ret, Data, Vo. 20, No.6, 1991‘THERMODYNAMIC PROPERTIES OF OXYGEN 951 {AML 1, THermagmame proper of satratea angen ~ Contnes Top. Presure Deas, ‘Enshalpy Ensropy c. GV nd ‘MPa mol met Jims Kk Smal K io” ams ss 28508 oat 2598 oust 1228 ‘20 15682 an aust rts zt a7 nom 2492 aw 13010 oso seis ae 1.0 muse saa 2600 mat ia ais asm aoe 18579 2406 20 mas mane Bas un aaa an 1457 sons 15543 na 36 107 sos 15506 2a. an ms 13509 2360 2H 20 2571 648 Tess son 15070 1 615 1s ios sae 29 a ms 2ao1s et 137 2403 an vin. ‘Mon 15398, 2s aa i9tse s00K2 1502 338 st me 168s 2s ius erry 266 an “mae 9092 2s 2339 mo ams 1804 sis 2st "2 Beak a8 7) mas 21986 iss 1509 231 23541 29880 1251 ao 19 mse nm — 17601 630 0 i ns as 1987 28 506 29077 29668 69 18 Mum nan 1212 sae os Bs ame 26900 187 ne 3 2792 29517 25 1s m6 a 25027 i810 m0 a 2a 26338 10st st “a 31083 a ms 1 we 816 204 ~BB7 ms 4 32063 2D ne 13 19 06 ane ~ boa Bs os 3857 a9 74 1 wt sais ~1n2 26 a 36 23581 mn 2 sane Ans tn an a0 Sasa OK ma 1 1230 2738 30072 27 a” one 23 299 1 13109 766 Ba 10 1 asm 2398 Jan no ° 15685 Ba 1 san was 1% 1s ass aun 0 0 S16 wa im ans ant 6 a Sans 5s i% 156 228 28 08 ‘san 319 us wo 4aser 2170 2 BI 6209 an tm 10 dates aun 298 m eni7 ao m ist aa non 36 a 1245805 ast jas? 2m 15368 5ss8 1 4 Phys. Chem. Ret, Data, Vol 20, No.5, 1991‘STEWART. JACOBSEN AND WAGNER ‘Tass 10. Thermodynamic properties of saturated oxygen ~ Continued ‘Temp. -Promure Demis, ‘Entaley Entopy Ce G Vol od, x MPa oli Sinol Jimol K Jmol K Simo Km Ane 18650 240 1937 ae 2537 28 ssies wt 14037 srst os? 166 1449307 17096 ‘000 13087 Seis uus20s 18 10213 16589) 13549 as 103393 1 1sise $088 Be 103949 nee Ripe pin “Catal point. Tame 11, Tnteral ‘Velocity Temp. Density enecay Enthalpy Entropy c G of sound (2 MPa Taber 56 20.605 = 51059 = 6105.4 ess 386 sas 1130 3 40338 = 5999.0 = 3985 7090 S367 S348 ut @ 40.065 = 58919 ~Se914 nn 3a ass am a 39508 -sens -son0 1388 30 368 108 6 39226 =ssm2 255607 m3 as 5368 1095 @ 3a99e eae 5a ra33 mae Be 181 38687 53554 53549 ans 353 5370 1066 n 38370 52480 35 200 se2i 3370 1051 ™ saost sos suo ar 2150 sa suas % 37790 50332 50727 5450 3.0 573 1019 Tae 37830 W744 476 85.8 bite 5378 1010 mo “03150, 13832 22180 17355 165 * ‘3143 eon mao Yat 16 ® 3032 16469) 206 10.08 16 & 2957 16893 2838 1081 m oy ‘oeas 17313 paws e152 aa pa m 86 rst iB 24832 19221 2076 2326 116 % rst 18148, 247 12.88, 275 pe v8 2 02630 18981 26885 1848 2076 a2 1 % 573 19398 am 18481 a7 p24 184 96 02519 vais as6 185.8 2078 2 186 100 oui7 20649 29825 18682 20 pas a 2369 21087 23510 18720, 208i 2925 106, 278 21902 0480 18832 masz pas 08 2236 m9 31085 18887 an 3s 10 canes am asso seo ae pa 199 cry 218s isa Ras 18953, mm 22 2 ae 2117 23812 sr0 19045, 23 2s a3 us 2080 23989 sas 19096 2 wz 0s us ‘ames 2403 ange 9146 ae pm 206 0 2010 pasa sama 19155 sass 2 208 m 197 aut 33358 123 ma pn 210 me 1aas 25659 35003 sas na pm a 16 ‘ois 26076 36827 19338, na pa 23 ns ‘oussa 26493 amu sat mas 21 25 ‘J. Phys. Chem, Ret. Data, Vol 20, No.5, 1991THERMODYNAMIC PROPERTIES OF OXYGEN 953, ‘Taw 11. Thermodynamic properties of ongen Terma ‘Velsiy Temp. Densiy eneray Enthalpy Entropy c G of round x ollie inet mol imal K mol K mol K mit “B2 MPa Toba 0 piese 2910 31095 19429 Dose 20 aT ma ‘ais m7 hao 1973 me 2 ae 1 1789 aKa 38863 1517 mo 2920 Fy 136 oun 2161 39447 9561 a pis m 1 ‘ors 2518 om 19603, mos 29 2 0 aon 23995 soos 65 mos ns 12 ne a2 aus 19647 ma pis a 4 ‘ners 29829 41782 awi27 masz pis 2 1 18 30663 x9 19807 mast is a 150 1606 31079 8533 19847 2nsi par as 1s 368 31913 samo 19923, oni Bar 26 156 ‘aise 32329 13283 1961 ani par 28 158 ‘o1s24 ams $5366 199.98 208i par 2 1 isos 3163 46150 2035 ani 2916 a 12 1487 33579 4733 20071 2asi 2316 20. 1 01468 53996 7616 201.07 2st 2316 2 166 i451 3u2 8199 20142 ans 2316, 2s 168 1633 329 48783 mou st 2.16 a 10 ovis sss 49366 m2 st 16 28 m ‘1400 38062 9949 22.46 2st is 20 1m ‘13ke a3 50532 279 2081 is 2 16 01368 36495 sins. 2.13, at is = 8 1353, 36812 51098 203.46 2081 ois 2 180 ous 3728 sua 2.78 2081 pas ws 8s ‘ox301 38369 53739 Dose 231 ais 29 19 ‘ons Seat 58197 25.36 201 ais 22 195 ‘ou 40452 Sons 216.12 mos pis 266, 200 ‘om 4193 ss112 206.85 ms pis 6 2s ote 42535 ses70 mst ange a6 m 210 ‘onus 4576 eins, 20828 2ass 21s 26 as ‘ons 4618 eae 20896 nas Bis 7 20 1098 45660 ams 29.63 anss par 2 ns ‘01070 46703 02 21028 mse pear 2S 20 m10%6 amas 686.1 21093 znas aie = as 102s 58 a0 21156 2036 B19 m 20 ‘ions 92 oreo 2os7 B Bs 2s 0882 5087 mac 2277 anss 21 36 au ines sis20 mm 2136 m9 Bn Sot as 0988 50365 7162 zs 2ns0 wa a 20 082s S01 73623 21831 mez 2s om 23 0s sus mss 21507 mss 2925, 310 m0 0891 e105 73849 21562 mass 22 33. ms srs sns3 m1 216s 2096 Bp sis 0 iss saz asi 21968 mss vat 18 as ‘oss ss woot 21120 21.00 ps 2 20 0830 a0 aL 201 213 3s 4 25 0816 oss 18879 21821 nas cy a 500 ‘2 naw ssa zn am co a ‘J Phys. Chem, Ret. Data, Vol. 20, No. 5, 1991954 ‘STEWART, JACOBSEN AND WAGNER ‘TaMLE 11 Thermodynamic properties of erygen ~ Continued Internal Veloiy Temp. Density enerny Enthalpy Entropy c G ‘of sound x mollis? imal nol Simal K nol K Simol K ms (00 MPa Feobar ae “si? Tai 698 mae Bs 1B 56 ass = 61050 33 3686 sas 190 8 0338 = $9981 7080 3887 5348 1B o 0066 = 5910 nn Buse S356 m7 @ 3978 3738 nor 340 S361 m9 o 29509 ~30716 S666 508 20 sas 1108 66 39227 =55703 55603 ms w6 5368 1095 s 3890 5163.0 suet ma93 a8 5309 1081 0 Sass Teis56 T5545 a3 2S 58 1065 n 38371 52482 sn e200 sai 5370 1081 oy 38082 ~s1908 51397 ear s1s0 an suas 1% Ear ~ss34 50323 3450 31 an i019 % 37499 = 29259 19048 630 3131 5376 103 » 37208 = 48183 = 48173 5786 3103 5381 98r 2 36907 =4n07 47096 R95 5n76 S387 m. mus 6884 ~ams ams 09 sae S388 sm mis 05953 16809 m08 17496 10 a ‘sais rmis 24004 17564 m % ‘08 trea 2089 tos aun as 15 8 05540 168 2088 17103 ne 238 m *” sai 888 ase79 ne zaso par 1 34 ‘osi7s 1326 mms ra nm pat 16 96 05064 194s Zot 1959 279 2340 18s 8 9958 20163 mma 1019 mao 240 1 100 ss 20382 220 190.79 aust 2040 189 102 o1738 2100. 208 18137 ne 2040 1 108 Ass 21420 23005 1194 2085 240 193 106 ‘oust 21340 ase 19250 Doss 39 195 108 ‘owas 2ms9 sum 183.05 20s 2939 m as srs 31159 1359 anas 2038 17 2516 m4 18464 2085 2936 4173 2535 53821 15.15 mas 2936 04101 2054 sao 185.65 nas 2335 04031 2713 eos 186.14 nas ae 03964 25192 ssn 186.683 mass ps 03899) 23610 55368 snit ans p32 03716 26487 STO 18804 amas 231 v0 ont 2686.6 310.7 18.49 aaas 2330 216 1 03660 amas smi. 18894 anse pa 28 Be 03608 272 aaa 189.38, mass nm 2 6 ‘ssi 23120 sae 18981 mas nm za 1 02 28538 so09 19024 mse pa = 10 ous 23956 19046 anes 2926 as 1 103400 2374 191.08 mss 2326 2% 4 ims Dei wo aa pas = 16 103306 30209 19139 2n83 22s 20 8 ‘03280 30627 19229 ans 22 BI ‘J. Phys. Chem. Ret, Data, ol. 20, No.5, 1991‘THERMODYNAMIC PROPERTIES OF OXYOEN ‘Tague 1. Thermodynamic properties of oxygen ~ Continued Thermal Velociy Temp. Densiy energy Enthalpy Entropy G G of sound ® molt Smal 3imot Snot K Sirol mot K me (D0 MPa lobar — Continued 150 x21? S104 | 5180 i268 2am 2 2 12. 317 31462 44064 19307 ngs BB Be 186 03132 31879 44689 18345 anss 2 26 186, ‘082 m7 ane 19353 2nss pn a 138 “03052 ama S818 19420 ram an zo 10 03014 Bid ao02 19457 ans wn 20 12 oon ‘548 4687 19493 ange pa 22 166 2990 3966 a 19529 mag wa 23 66 2904 3383 iss 19564 zag pa 2s ae 2870 S00 BI 19 aus ba Be 10 02836 35017 23 19634 ons 0 28 m ‘2s02 3504 9507 196.68 mn 20 29 i zr sas sow wie fuse pa Est 16 O78 36468 suns 19735 ana is 2 v8 zor 58s S169 1168 masz 29 24 185, “805 384 $3702 19881 2082 19 259 190 12536 39387 $5162 1958 ong ais 22 15, ‘70 ‘0929 $6821 20034 an ais 26 20 ‘2408 aera ss060 2o1a6 mos Bis 2 0s 239 e513 59539 amo ana 2s m 210 as 43555 588 2ms0 aus 28 76 as ‘eam 498 aur amas au pe 2 0 iiss ‘5601 917 am36 anes 19 2 ns ‘240 ase a6 ms aus as ms 20 093 ama eo mss amas pa 20 Bs ‘2099 am om35 2089, mn36 a mm 240 ‘2006 ais os 20640 ans7 wa 25 as ‘niss 50859 m7 2n00 ons pn 28 250 ‘aims sine a9 oma ane 2 3 255 01888 52950 isa 2087 ano 24 Ey 2 ‘onssi S036 13803, 20874 msz 2925 xr ™ ‘ois 58080 7530 20885, mss 22 33 ms ‘o1730 S739 8S 21038 m7 230 ais 285 ‘o1689 SB 7 218 2101 Be 31 = ‘o1659 oas0 san 2114 2103 2335 3 Ds ‘ois ouaz 85863 maa 2.05 238 aa D6 MPa Taber mar Tone Tae Tass wan wae aa ma 56 40.506 61060 ~sims B82 3586 SAS 10 ES 40339 = ~s917 m0 3867 5348 u3t o 40.066 S021 ~s08 mai Bast sas m2 a 389 “sso ~srs nor sen ss a9 6 38510 -ser7 $6162 1367 09 ses 1108 6 39.208 =ssme = 55668 m2 3326, 5308 1095 a wou sae sus s na pa se sot ” 38.659 587 =z ss ase 309 1086 n aan 52483 “3268 00 ma 87 10st ‘J Phys, Chem. Ref. Data, Vol. 20, No. 5, 1991,956 STEWART, JACOBSEN AND WAGNEH ‘Tamu 11, Thermodynamic proper of oxygen ~ Continued Thermal ‘Veisiy ‘Temp. Density energy Entalpy Entropy ce G of sound x mola? Sot Simo! Sil K imo K Simol ws 16 MPa Isobar — Continued % 36085 | ~sia09 ~ site war 3190 Bm 1155 % wm sms =s0019 490 30 5373 10189 % 375300 49260 Teed 3630 3131 5376 1003 80 srams 48185 = 48169 5786 3103 S381 387 2 36.908 ~ani08 4792 39 3076 5337 om oy 36008 46030 4604 so29 soap 5396 3s aac 36387 ~48002 45226 su 5031 S408 98 aac 08633 1704 ard 17.66 13 88 ‘oases vse ast ras 4 % 08367 199 i580 135 1% 0 08171 1806 aug mm4a3 2096 pas 1» 2 “arses 1883.0 ras 17488 ans 2370 18 9 ‘07806 19352 2538 1852 nse par 18 96 7636 19673 230 6.4 2081 2339 185 98 on 20083 2si2 1635 2082 257 167 10 orst8 rns. ons amas 208s 2936 1 02 on oss pws isa ans 23s 181 108 ‘mz 21386 28s 17851 2anss 23s 193 106, 6860 m7 sos 107 203s ase 1s 08 06758 22198 aos 382 ans? ns w 10 6631 sis 31667 sos 208s as 198 im 4309 23039 aus7 203s 231 200 ue 352 23460 37 2nss nas m 6 06279 23881 3a7 2038 pas En ns ‘ne169 2601 3a 2088 pear 216 0 006s oni 34616 2088 p46 m 8962 25142 asm 2038 pas ma 8868 25562 3383, 2088 pas 125 05769 23581 36382 2087 par 8 ‘ser 26401 3670 237 pa 130 05558, 02 37588 1sa9 2087 216 1 ‘asso zo 38146 18553 2087 218 4 ‘osa18 2659 313 18858 2036 @ 16 ‘0837 078 se 18641 2086 2 18 ‘08258 287 3908 18688 2086 a 10 15182 2016 sos 18125 2086 » 12 ‘nsi08 as i081 151688 2085 2s ue 08036 arsa $1668 188.09 208s 2 16 ‘03906 soa 40054 18849 mass 2 18 ‘passe S38 ‘a 18839) aus a 10 04832 s103 a7 189.28 mast 230 = 12 9768 3127 sao12 189.67 rose 7 a 14 corms ais 3 19.06 aus pw 26 156 sss sansa sind 908 2s rt 2 158 sss 52682 $5169 1081 mass az 2 wo 952 ssiue 853 wit moss pai 20 1a 4470 33517 440 9134 83 2325 2a 1 iuats 53835 25 19190 2083 2325 2 166 34383 eit 1225, 2083 pas 2s 1s sera e098 or nas Ds 26 ‘J. Phys. Chom. Ret. Data, Vol 20, No.5, 1991‘THERMODYNAMIC PROPERTIES OF OXYGEN 957 ‘Taste 11. Thermodynamic propertics of exygen ~ Continued Thermal ‘Veliy Temp. Density enenny Enbalpy Entropy c. & ‘fod K alti? inc! inal Vinal K Jmol K Simal K ms “D5 MPa Tsar — Continsed 1 “pass 35188 orm 19295 28s Bas 8 m ‘bene ssn aes 1329 Dogs 2 2 mm ‘oas9 3023 soso m8 2083 Py BL 165 ‘oan St sus 19396 2083 pa co 18 ‘owes ass s1@0 19429 2085 aa se 180 019 sms smn 19402 2083 aa as 85 ‘o3010 sms, 5365 195.0 2083 an 9 199 ‘ase0s 962 S26 19620, 2083 an 22 00 03615 4169 S048 is.) 2033 221 8 ms 13526 42992 08 1982 moss 221 m a5 ‘3361 4578 ens 1981 mast 221 2 zm 3286 45622 esa9 2m0s8 mast 221 eo 2s x2. 46665 6350 mule ass wa 2S 20 sit ams ost 20178 2086 wn 20 2s ‘03074 4853 sz? amat 208s pn m 20 ‘ano 08 ons ama aust 2 as as ‘m8 08s mss ma moss a4 =e 230 2889 51888 7087 mz mns9 29.25 m1 as 732 so34 mug 20480 msi 2925 a 20 0278 53581 15383 asst m2 a7 m as ams S028 707 21892 mss om 310 m0 574 50006 Test nea 2098 2330 33 ms ‘625 sma ons aman 297 pa ais 20 0379 sais sist asa ns9 pas a8 2s ‘533, ns 509) 28.06 2101 235 zi 20 ‘02350 eas se77 2857 2103 px 3 25 ‘mur an 85847 2.07 2108 239 im 00 ‘2105 eB smu 2855 2108 pal cy (08 MPa Isbar ar ame ~ai933 ~aLa co mae BS ii 56 40607 61061 = 61082 eas 3686 sas 110 58 0300 39092 = 3973 7040 3867 sua8 32 @ 0067 39922 = $8902 na base 5356 um a 3790 = 5851 5841 nor 3020 330 ints o wasn 309 ~ 36758 1381 su 5365 % 39209 3576 ~ S504 TR saz 587 Beas 34682 34612 735 Sass 3308 » 38.660 53558 53538 sas sass 369 n B37 mss ~s264 5199 sz2i 3370 ™ s8084 sa -31390 sur 3190 sam % a3 50337 = 50316 90 360 sn m 50, 29262 ~asn4t 8629 3131 5376 » 37206 = 8187 465 e146 suas 3380 2 3600 =a = 47089 8 3a76 5387 & 36508 46032 46010 028 3050 5396 oss 6 6306 49982 493.0 oss om sar 38 S99 6002 49877 48854 29 299 5420 oz a9 11239 1008, 2687 i704 15 8 37 17881 2001 i710 15 4. Phys. Chem, Ref, Data, Vol. 20, No. 5, 1991958 ‘STEWART, JACOBSEN AND WAGNER “Tams 11, Thermodynamic properties of oxen ~ Continued Tntermal Veloiy Temp. Density eneray Enthalyy Entropy c G of sound x soltim? not aol Jmol K Soot K ool K ms “G8 MPa Tear — Coninsed 0 10867 119 25614 m7 2a 3037 me 2 ona 149 22213 ma 2100 nas 160 4 10469 wns 2681.7 04 m9 9 12 9% ‘30237 19599 2a i617 mass pai 18 8 ‘0016 20022 23009 17429 mas 2316 185 100 19808 204s 2304 17489 anas wm 18 102 ‘0303 20868 2199 11548 mas pn 19 104 ‘2909 21 2793 17608 288 an 192 106 ‘os223 ans 3038? 1682 ins Be 164 108, ‘03045 36 3008 mar 2050 B88 196 9 8874 D559 31574 mn 2030 Bs 198 i ‘970 2981 32167 17838 msi as ety ue 08550 204 32160 r7a78 msi Bs mm 116 (08398 236 33352 m9 31 psi 08 m8 ‘08250 24048 33044 130 m1 Bs ms 0 08108 24670 34536 18020 mst sr Pa m own 25001 38127 180.78 msi Bs 29 2 ‘0739 25513 3sn3 18125 290 Bs an 125, ‘omni 25934 x09 18178 m0 wee 2 15 7587 2355 3809 1220 m0 230 28 10 usr asns sm89 1265 m9 nas 216, mm ‘ont zs a7 prot a9 sar ais Bt 0739 207 ces ws m9 as 219 16 ‘7130 2308.7 39257 1599 moss pas a BB “07024 287 soa cay mas as a 140 6902 807 oa 1344 mss, aa ma w 96622 25 123 18525, maT pat 26 wt ‘oer ans sisi 1as7 ms7 ne 2s 10 ‘nos? souss. suis 18608 mos? 38 = 8 6581 5585 78s 18648 nas 231 a 150 6852 opr a3 18687 ans 236 m 134 ‘6282 31812 44s67 15764 mass 23s 26 156, 6200 zat asia 183.02 mass Bu ar 188 06120 32649 srt 198.39 maas Bs 2 10 16083 23068 46307 18876 mass Be 20 12 ‘05967 33486 46994 16913 oss pa 2a 168 ‘05993 3005s 27480 199.49 rose Ba 263 168 ‘as731 sama 4865.2 190.19 mos BD 26 19 05683 35160 49038 19054 most pp 28 i ‘a3616 3ssr8 ‘esas 19085 mat 28 26 174 ‘05880 35996 soos ia mat 28 at 176 (05487 sea 5585 19135 mat 221 2 18 ‘ast 36882 51360 i139 ma 2a ma 180 05363 sso sus 19221 ma aa 2s 185 ‘05217 sas 53629 19301 mm 2326 2 190 25078 sous. 5508.1 193.79 Ere pas 262 15 9947 ‘oss2 3033 19455 ne Eo 2s 20 4822 1426 Soo 19529 23 pu 8 4. Phva, Chem. * Data, Vol 20, No.5. 1991‘THERMODYNAMIC PHUFERIIES UF OXYGEN vee ‘Tass 1, Themmodynamic properties of agen ~ Continued Veli Temp. Density Enthaley Enuopy c G ‘of sound K molt? Timol Sinot K Simal K Simo K ms ‘08 MPa Ieobar — Coninaed 05 “or7o8| 20 a7 19602 mass B23 m 20 4591 asia 0839 19672 nse 2 76 ais, ass 488 00 wat ange 2 my 20 04381 48602 3862 198.08 ans 23 mm zs (283 6646 e324 198.4 ans 2923 25 20 04190 01 cores 1938 2086 2028 288 2s 0100 en ona7 2001 20s 2928 2 20 ‘wors 7d ono rons ans 2925 285 2s 13932 sons m2 22s as 202s 28 380 3883 sien mas am 290 2026 i as osm soos 708.8 amo ani a2 so 20 ‘osmo4 53965 13862 msr. ms 2928 x07 2s 3634 S013 7027 m3 nse 30 0 20 23567 56061 7392 zor ass 231 33 2S 801 smo 58 2st ast 233 as 230 41389 8160 suas 25.4 2ns9 23 a8 as ‘o3378 S921 582 2866, 2.01 2936 x 0 ‘n3320 ‘63, 8661 26.17 23 2038 a Bs 3263 sists 5580 2nes7 20s 2340 m7 0 309 avo erat amar 2108 bon cy 70 MPa lobar sar 89 ~ esas —ai909 98 Err Bs 56 saa 61062 = 61038 es 3686 Saas s 40s 9593 = 59969 m0 30 5347 @ a0 =e ~ssso8 na uae sas a BPI =s7s2 =51827 Ber 340 S00 o aes. ~s6r80 ~s6784 1881 sa0 sas 1108 fs sama Tm see mm nm S67 1s a 3946 54633 = 5408 mms 3289 508 1081 ” 38661 ~s3560 53534 amas wast 5308 1065, n sass ~s86 319 moat 369 1051 on 38.085 ~s12 a6 3190 5370 uss % 3174 ~s8 3450 310 san 09 ® 37502 ~a264 8529 3131 su7s 13 a 36910 <2 5858 3076 3387 om. a 35610 46034 sos 030 5395 ss 8% ree wins ass wu rg oe & 36002 72 9280 2399 si20 ox *” 35.692 Ons sm ss, 536 os soos 35.682 ~ams3 is 214 Siar 0s soo ass 1240 169.50 i” se ass 18665 as 1” 3 13163 19996 m0 201 so21 12 96 12868 19524 m4 masa soas 1st 8 2586 19950 295 m36 mas aor 185 100 12316 aas7s riod m6 ona 293 138 1. 12059 20000 23093 mss mas 299 10 10 ‘813 ams 23600 m3 ms0 2087 12 106, hus77 21689 0287 1470 mst pos 14 106 11380 ama 0884 17825, mez 283 196 4. Phys. Chem. Ret. Data, Vol. 20, No. 5, 1991ann STEWART, JACOBSEN AND WAGNER Taaur 11. Thermodynamic properties of oxygen — Continued Tieral ‘Veli Temp. Density enerey Entalpy Entropy cy G of sound x mold Jiro nol Jmol K no K nol K ws 10 MPa fotar — Comtinoed 10 err) 08 38 Tsai 35 Bal 188 m ‘oss mms 3077 11634 nse 2379 9 m4 hows aor 32572 17687 rose 2370 21 6 “10530 aro 3267 17139 mse 214 23 us 48 raise 33862 17130 mse pn En 20 sore 07 345.6 r7e40 mass pe ad m ‘5501 23000 35049 17839 mss Bsr co ne ‘5824 23463 35643 1937 ass mas 210 2s ‘5662 23886 360235 ra mss Bs 22 130 ss 23.0 37920 180.7 no ps 216 Be ‘oon mis e014 siz no Bsr ar 136 08830 905 33193 18210 2090 Bs za 18 08797 mais 97a 1253, 290 si m 12 ese 2358 40863, 18538, 099 Bas 26 us seni 23618 ass 18.79 2099 par a 6 05303 3098 ana 1849 2038 pas ms ue ‘ones desis am 1800 mse 244 a oso? 30939 «azo 18499 2088 pas mm 7968 31388 508 18538 ans pa za ‘ome ama 06 18576 mgr 2340 as 760 is ‘sos 13614 2087 2339 ar 7660 2617 45612 18652 236 2338 2 10 7802 ams 4260 anss nor 20 1a ‘aner ss 45847 2036 Bsr 2a 1 ‘oss sara 784 2036 2336 28 166 ‘arma 33 e021 oss 23s 2s 168 ‘ans ama 8608 anss nu Eg 10 amo 3513 ss195 oss ps 28 im ‘amas 550 “782 oss as 29 18 6364 3387 095.4 2n38 Bal 2 18 ‘srs 5805 Sisk nse 231 23 180 60 wma en7 su onsa rw me 185, 16826 3269 53592 Las ane Be 288 10 “383 said 5505.6 19133 ange xe m2 195, ‘6188 ‘ans9 56520 19299 ange pz 2s 20 ‘oa aos S783 198 nse an 20 20s 05883, aus soma ras 2nst 2326 m 210 ‘ast 04 908 19486 2ose 2326 76 2s 8607 as oma 9st ass 22s 2 20 ‘ose79 45583, eas 19622 2aass as mm Bs 15386 46028 6297 19687 2036 ps 2s 20 539 013 6760 9732 2n6 2326 28 2s siz ass 8223 1981s aos 2326 a 20 105019 164 9686 19876 2nss 2326 2s 2s 04916 0809 m4. 19837 2n39 px 238 20 4818 51856 nsi3 19836 290 pe so 4. Phys. Chem. Ret. Data, Vol 20, No.5, 1991‘THERMONYNAMIC PROPERTIES OF OXYGEN get ‘Taauz 11. Thermodynamic properties of aygen ~ Continued Tose Venn ‘Temp. Density ener Enthaly Entropy c G ‘of sound K mola Simot Tino! Amol K si K Sinot K ms Bs “pam ‘2903 77 20s 2091 29 Ey 20 ‘4631 53950 75842 2ouat 2092 2330 aor 2s oases 5498 77007 ove pose coer no 20 use 56067 m3 ami 2096 2m 33 zs 9078 5785 e040 am8 2097 2034 as 20 9099 e047 e107 ame 2099 sas ae ms ‘pans 33193 mrs 2330 2101 237 x = ‘oa1s0 0250 seu zat 2103 2939 au 25 ‘02080 61303 ssa14 zat 210s a m “TOIR25 MPa Tobar 36 acs 61062 = 6103.7 552 36.6 545 38 03a ~ 3983 = 59968 mao 3867 5387 o 004s, 59023 5899.8 mai 3a 5336 6 ses ~s6780 ~s6784 1387 3370 5365 66 39200 =s5m07 = 58681 m3 3327 5367 a saous 4683 54607 ma 20 360 ” 38661 = 53560 33834 ms 323s 5308 n mam =suss 52460 5199 a 360 ” sao ~s1an2 31386 46 3190 370 % a0 =a = 50312 90 3L@ gn ® srs 19264 = 49237 29 3131 5375 ” 207 =aai89 =48161 srs 3103 5380 a 36910 “a2 ~an8s 95 3076 5387 8 36610 4603.4 46005 028 s030 5395 86 36308 4954 = 44926 uss sn2s S406 8 36002 8872 ~ asst 9230 29 $420 0 35.692 2787 = 2758 san 2075 5436 ony 35663 ~m688 = 465.6 93 an 5438 soir 12960 m6 28519 won 7 o 13689 i883 2077 m3 8 Py 1303 1908.1 26684 1799 ua 3023 18 96 1308 3319 2787 me 2093 sa07 184 8 1087 9545, 27888 man 209 2398 186 100 as70 23487 ras 2099 2998 168 102 a9 2085 rae 2039 aa 19 104 1973 2mo 23683 re 2091 2988 12 106 aT diets S028 i398 ans 2336 13 108 11504 070 30878 sas 2ns3 2384 16 sizes nuss aun 809 2093 aps 198 ‘hom noo 3070 17623 2096 2530 1» 10868, m3 32666 17636 2098 an 201 10672 167 3326.1 17128 2098 2935 ms 10883 aais0 3385.6 m8 mass 2073 ms 19 0301 614 34450 17828 209% 230 om m 1013s 23037 35084 177 2098 29.8 2» 14 ‘6856 23460 35638 11926 2093 23.6 210 135 ‘oor 23883, 36231 13 2093 2385 22 ne ‘aoa 2505 36823 16020 292 Bs 24 ‘J. Phys. Chem. Ref, Data, Vol 20, No. 5, 1991962 ‘STEWART, JACOBSEN AND WAGNER, ‘Taaus 11. Thermodynamic properties of eaygen — Continued te Tntemal co emp. Deity ney Entalpy Entropy ce G of son x all? Siok Tinol nol K Sn K sino K mt 5 Ma sbar — Coniaed 0 580 27 amas 10.85 nas 29 216 ia ‘oa mas 500 tt ast Bs 2 14 ‘89 sta 398 sass ns 55 29 136 ‘509 2992 3189 18199 mast 54 zi 8 os 23413 a3 1282 m9 32 m wo ‘ors 234 370 wos 2090 30 a 1 ous? ons 0960 1827 mass 249 2% 4 ss34 018 seo 18 ass nar 2 Mo oaie oss ane 1848 ins Be a us ‘898 sis ont 18448 ‘nas oat a 130 nas 093.6 nis 18688 mss ae m 154 ‘368 ams 93 15.65 2 Ba as 156 ‘am863 9s 5081 18605 2089 Ba a 158 anse ‘sis 15069 1641 2086 Be 28 1 7683 soos 46283 18678 2086 2838 20 1a 567 353 6548 174 2086 B31 20 164 ‘ers wer 981 18750 236 12336 8 168 or 34710 48605 18521 208s Ey 246 1m nas ssi29 wow2 185.56 2s 234 2 ms amo 55966 ‘65 19.24 2s 2932 250 1% 1956 30385 50982 19957 2as pa 2 ms 0687 3803 S1s38 19991 ms 2931 3 0 259 ama soa 190.23 no 2931 2ss 1s 613 3259 S589 19104 ost 229 Bs 190 4637 36313 5054 192 2st 28 x 210 ‘ota 1003 581 9332 2st Bn 28 208 13561 our sous 19404 mms 29% m as 05682 4337 e370 19543 2085 7926 2 zo 05882 45582 ans, 19631 nas 026 2 zs “a5i27 46526 6 19676 2086 25 2s x0 15309 asa, 1s wnat nse 226 8 Bs 15195 an 21 19804 ms 35 m 20 5086 762 68s 19865 2088 pn 2s 20 asst 51855 ‘6h 193s 2099 28 so as aes 902 rans m0 ant au 268 4604 i007 708 amiss ane a zm sis S046 mena 20210 2096 3 2s 04436 S705 7938 mn. ast bs 220 0056 sais sos 2oo7 a9 us 28s 0079 59199 ene 23.60 aot 2 = “orans ou 8043 20420 21.03 ea 00 0s 383 arma 21820 21.08 ms 4. Phys. Chem. Ref. Data, Vol.20, No.5, 1991IMEHMODYNAMIC PHOPEHIIES OF OXYGEN 963 ‘ants 11, Thermodynamic properties of exygen — Continued Thermal Velocity ‘Temp. Density eneray Enthalpy Entropy c G of sound © sol? Simel Yoo Simo imal K Swe K wh 5 MPa Taba sae 2080 61932 ~ 61895 98 Bz saa 1133 56 os 61065 ~61028 ex sas sat 130 3 ase 59996 = 59959 m8 3867 5347 u32 o 20070 58926 = 5888.9 ma bast 5354 7 a 39083, = 57855 57817 1336 sa 30 in9 66 3513 -s6783 sons 1881 330 5366 1108 6 am =s5710 35612 m2 aazr 5367 1085 a sae 34637 54598 m3 saa 5368 1061 n 38563, = 53563 733524 sr ns 3o 1066, n 36 T3208 T3283 a8 ma 30 ist ” 8067 sais 51397 a6 3150 370 103 6 3197 50342 50302 su bust 7 1019 w 31305 ~'9n68 #9228 8625 3132 5395 1003 0 37210 48193 = 48152 ras Sie 5380 367 2 36913, -a16 47016 mass sam 5386 m ss 36613 46039 45998 sos saso 5395 ss 86 36311 44959 = 4918 o135 sas St05 339 6008 43877 ~ aus 28 Be suis s2 %” 35686 292 280 3401 Bs 5435 506 we ore) mais ate. soz Bi 5454 0 a 35055 = 4061.1 0568 9638 pe 5476 sn 2 5506 = 40548 = 40505 9685 par sum m oele ‘ans 191 202 1138 0 96 19599 1927 208 16816 a2 2087 12 8 193 19763, 202 158279 2106 3081 1 100 70s 2093 mais soot 2.0 soso 18 i 18304 20828 221 ro 2038 3038 19 104 7018 21087 os me, 2038 3032 1 106, 17549, 287 3.4 m8 2099 5027 3 108 7196 ane sas3.9 im 2.00 5023 rr 10 asst mus 31243 m0 201 snap ra mm 6833 mma 31847 174 2101 boas 198 46 92 281 33052 13.90 2101 nos mm ue 1634 2058 33653 rat 2101 anos ES m 15000 812 353 1541 2101 aor as m4 9882 25339 35452 17590 21.00 a3 210 15 see 25165 30050 19638 m5 2390 a 10 saz 2661.6 amas ist ans rose as m2 13888 zu 37a 17736 2097 2480 27 be ben 26s 307 vat 2097 278 218 136 ‘361 27890 3032 1885 2036 235 zo 18 13058 23313 39027 1309 2095 an m 12061 2ema7 ama rst ane 2970 ma ‘ns70 23160 081s 194 mst ast zs 258s 29583 a0. 18035 ans nas m 2508 0005 ‘20. 19076 ans nas zm 0 noes 293 wii 2st pan = ‘J. Phys. Chem, Ret. Data, Vol.20, No.5, 1991208 ‘STEWART, JACOBSEN AND WAGNER ‘Taste 11. Thermodynamic properties of oxygen — Continued Tnveral Velocny ‘Temp. Density enerey Enthaly Entropy ce G of sound K molti? Jim Simol Jioot K Jimol K Simol K ms 15 MPa Tahar — Continued 50 a0 70850 wis Tai mar Dae Be 12. 11995 nna ‘e777 18195 mai 2937 BS 154 “1836 31083 4068 1234 250 2935 Bs 156, 1678 aus. 49959 mn 2150 234 zr 188 11526 na 48550 165.10 2050 ws Ea 10 11378 ss7 asit0 147 2n39 ps 20 12. 1334 aw7 46730 18 ange 249 am 164 11093 ams 47320 18420 mse 2oas ms 166 10956 sens 4708 ress moss ar Pm 188 03 a8 099 ists mass 2946 26 10 10652 359 45088 1825 ans 24s or m 056s sso9 9676 135.0 ans a3 20 1 ‘vest Ses 52083 1598 aust paz Bo 16 10320 e319 508s 3 18627 2ns7 aan ra 18 ‘ozo2 sens 51a 18681 ans pai 2s a5 ‘sao ans 53099 18774 2n6 38 288 190 9546 ses4 59958 18852 2086 2336 282 185 97 ‘at sous 18929 mass 2935 268 Es ‘08 prey 31902 1003 moss 3s 29 0s 06837 aes $3369 190.75, aoas 233 m 210 08624 uz ons 19146 ans 23 ms as ‘521 parry en01 asaas ans pa 2» zm ‘ona ass34 657655 19282 26 aa 22 2s 03 46881 232 19348 ans 31 ms Bs ones 8674 68162 1946 288 31 a 20 07535 ana 9827 19537 2ns9 231 25 2s 07380 0768 1083 195.98 2050 3 238, 20 ora sos 7859 19657 mast po so 25 oss 0363 ans ans masz 232 sot 20 06951 012 7501 win. mss 2933 a7 70 06692 ‘seo 15425 19633, 2096 2336 a2 2s 6570 ‘7063 94 19937 2058 237 35 28S oss38 S164 2832 2042 au 2940 RI 20 9628 7 81003 20.93 2104 par mt Bs 6i22 sua as714 2am. 2106 pa = “20 MPa Thar sa38 wos ‘aaa Gis ra 3a as na 56 ‘ost 61067 1018 Bi sas S344 11 8 su ~s988 = 59049 m9 3867 S347 132 @ oon ~s29 = 53879 nn dase 5353 7 @ 275 sss $790.7 796 deat 3300 m9 6 2wsis, S676 ~sons 1566 an 53.64 1108 66 peau 3513 = 55662 mat 3327 5387 1085 a 38050 mr “sise8 mot ne S68 1081 n 386565 53566 = 53515 7 mst S368 1066, 2 38378 3203 = S244 5198 nn 59 101 4. Phys. Chom. Ret. Data, Vol 20, No.5, 1991‘THERMODYNAMIC PROPERTIES OF OXYGEN ‘aur, TBemesmani proper of omyen ~ Camoed os = = +; 3 & ce og oo a — a — ee I > = = = & & 2 = : s & a oF RS eae er : oS x BS 8 ; & = = & 2 BE 8 5 ee ome wg 2 s B S 8 ae os SR om Soe OE 2 sme ue ea : 8 3 = 8 gs : s = a“ 2 : & s - = = & & 8 rr ee " 2: om moe & : & 2 2 & 2 3 ee ee eee = : = & 2 2 8 5 : = 2 & & x g 20 2 & mo RB z : ss = a 2 = OR ‘ee oes 2 os = BOE es! EG 2 & & SE ee my weet : 8 & a o£ 8 & : & & 3 2: F 8 : = & = : Es 3 SE 2 oR Og 3s = og ogs os os 3 2 £ & & & & & & 2 i mo BP oR og 8 3 uo Gy EP RS 4 Phys. Chem. Rt. ita, Vol 20 Mo. 5,881966 ‘STEWART, JACOBSEN AND WAGNER ‘Taaue 11. Thermodynamic properties of omgen — Continued Tnteral Velos Temp. Density every Enthalpy Enuopy G G of sound x snolda? imot ool Jimal K Swed K Joel K ms 20 MPa Teobar — Continued 70 1098 3587 “580 ma 2090 B36 2 m aa 35003 ‘es74 186 na Ds 28 m4 “asese 3sm29 soi62 1851 29 as 20 16 om. 3a2s0 sors iat ne na 21 v8 “i332 36671 512 1848 238 30 Ee 180 au s1082 siss2 18451 2038 a9 Po ws 13103 3143 ‘408 18531 nas ar 38 190 780 5193 ‘4879 18610 20st pas 22 5 “us a3 $651 18636, 2087 pa 2 200 2100 52 sma 18161 2087 pa cc as 199 4 9291 18834 2nst Be mm 210 11513 48389 rei 188.04 2087 B38 25 as ‘aia was 9 189.73, 2ns7 B37 2 za 10582 5086 S08 101 inst 336 22 zs 0738 6534 65166 9107 2087 2336 ES 0 10998 7862 66633 9171 2088 Bas 288 5 awn ‘8630 ‘si0 19235 axe Bs Bn 20 008s 49678 8569 19296 2089 3s Bs 245 ‘ose 50726 7036 19357 2050 3s 8 250 ‘D968 S775 04 19416 zai 2936 Et 285 ost 04 912 19474 as 936 0 260 ‘ova ser 15440 19531 2n9s px a 268 09087 sas 16808 19587 ans 38 310 2 ‘06927 so97a ris a2 297 Be 32 2s 08763 ‘5m26 B88 19695 2098 rd as 220 03606 59078 a3 1149 21.00 va 318 2 ‘9807 ois 051 19852 2108 Das me 2s ‘os16s 61239 aS734 19.03 21.05 286 ry 300 09028 62295 87007 19.52 2108 Das ey ‘25 MPa Isobar ae am 61930 Tai869 635 320 Bsr ie 38 0346 = 6000.1 39939 7038 3867 S346 1132 o soars 53831 ~ 58369 m0 base 5333 8 @ 301 37860 3797 7335 321 39 m9 6 west S678 sens 1356 a0 S368 1108 % 3926 55716 755662 mat am 3356 1085 a sues 54643 =54579 7331 S89 53.8 1081 2 saat 32097 -261 5198 nm 38 10st “ son 51923 -s358 was sist 30 1036 7% wa0e 50350 ~so2at or aust aa 1029 % 37510 49276 49009 628 3132 5378 1004 0 wris 48001 = 48134 arse 3108 5379 388 cy 36919 =an2s ~4m58 897 aa 85 m 8 36619 46088 ~ 45980 5026 ansi S398 os 86 36317 44969 44900 suse 502s S408 39 85 36012 43887 = 43818 9278 2000 sus om 0 3am 42903 =42n33 30 297% ae ae 2 35390 mains ~a1644 95.9 232 5132 80 J. Phys. Chem. Ret. Data, Vol. 20, No.5, 1991‘THERMODYNAMIC PROPERTIES OF OXYGEN 067 ‘Taste 11. Thermodynamic properties of orygen — Continued Terma ry Temp, Density enensy Enthalpy Entropy ce G of sound ca solider Siael inet Jmol K Jmol K imo K ms 35 MPs Tabar — Coninoed m son 10823 40352 3637 Be m % Burst = 39526 = 39854 srs 2306 886 = pene H3e04 = 352 56 mas =» vost 5a. =3m21 3748 on68 mas 2 esi 32102 sre 21553 164.70 2.90 13 100 om 1008 aes 16476 ast aan 12 Sra 259 2881 1639 2136 31st 104 sass 20s 2388.2 166.00 22 a1az 106 23601, 21a 23309 19660 2119 3125 0 23882 zm sors 19176 aur 3108 185 2 23009 268, aura 16831 aur 3096 17 16 23580 2313 32610 19.40 aut sos 2m us 25109 2780 ans 190 aut som mm im ss06 2465 3452 17095 21s 30 26 mt sss 208s 35063 m4 ais anse 28 5 ‘2asa0 2519 35073, 11193 aus aoa7 210 8 eno 25081 46082 mat an aoa 2 10 23s 20383, 38890 rms aut 3036 ae m2 as 2a 3196 ims 2110 3030 2s 136 268 ners 3376 ims 207 3020 29 18 za 210s 5a3.0 89 2.06 S016 nm “0 219m saa oma wsaz aias son m 1a 2160 2562 ‘asi M855 2108 anor mm mt ist 23380 1837 2102 500s 25 46 ‘2101 2817 ans 17638 2101 Be zs 18 2om0 soa amis 11679 ar00 2996 m9 10 20418 30670 as amas 099 eo a 2. ons 31096 asi2 ms9 209 2339 =m 1st "9860 22 ana 779 men goa ne 186 19385 31947 07 17336 a7 283 26 158 19333 32372 4503 34 2096 21 = 10 15080 2p6 asa09 rma mes 20m m= 12. 18833 33220 $685 iB 2095 2376 20 1st 18598 ‘oud 89 198s 2098 27 20. 165 18360 34068 a8 1021 2093 pan 2 18 18133 3a91 as 18057 mss Be 2s 10 ar aoa 49872 rmog2 m2 pet 2 im 17695. 35337 3465 18127 92 23.8 28 m4 Tass 435959 00538 sit 2a 23.6 0 18 a7 3681 5048.0 18195 ma par Fa 18 17078 sea sas. 192.28 91 20 Fs 10 1sss1 sms sus 1a 2090 Bs a 8s ‘oat 33079 su13 1B, an9 2336 3 190 15966 39132 5090 18121 89 233 261 195 15545 oss 50256 18498 ans 2930 2s 20 15148 41236 S740 uas73 nse 2988 28 J. Phys. Chom. Ret. Data, Vol 20, No 5, 1981,ose STEWART, JACOBSEN AND WAGNER ‘Taoue 11, Thermodynamic properties of oxygen ~ Continued Tera Velo Temp. Density energy Enthalpy Entropy ce. G of sound x molt Sirol ol Jiool K Simo K Simol K ws 25 1618 287 soa TES 208 Bas mm 210 seo 48337 60885 18716 nas pas 2S ais “008 44387 2s 15786 mas Bas a 20 7 45037 63629 133 mas par me zs 1381 46487 65100 319 mas pai as 20 ase ws es70 seat 2a 40 208 2s “2380 48585 62080 isa7 m9 B40 a 20 ‘ns79 49635 510 19108 2190 B38 Be 24s 8 685 ‘7980 i170 mst B39 2 285 119 ses res 1287 mass oy 20 1338 BS 15389 5348 mse aw mm “net 55938 78330 19455 2097 an 2S 10959 56990 9902 19508 2099 as 238 10571 59087 246 19615 2m a 20 10887 @ois2 e219 196065 2108 a 285 ‘so210 61207 8569.3 ars 2.07 pa a7 300 ‘toa38 sa rise 1976 2100 st Es “30 MPs Toba Seam os Tae Tease ae =a a0 we 56 ‘oss Soin 699.7 ea50 3685 S343 13st 3 40348 = 60003 59929 7038 3887 5346 132 o 40075 59934 5885.9 ns dass 333 18 a x70 Tres cere nes wer 50 m9 o sesi9 -s6791 -sons Bs 330 S363 1108 66 se238 =s5719 38642 m0 328 5366 1098 a was Teun Cease Rn 2m ‘367 1081 2 38670 =53573 53496 nas Bass 3.68 1067 n 53 ~52500 52022 as7 nn sa68 1051 % srs T5038 Sst a8 3.8 sm 100 8 ss = 49280 =#00 3627 3133 S373 104 » 37218 48005 48125 a8 ‘as 5378 988 ” on Cia ciate sa wn suas om a sear 46053 45904 5026 sast 3393 986 % 36300 4914 #991 133 sas soe 938 rs ears Tana an om sur 923 0 35.706 Taa808 399 316 5435 506 2 35385, =a 41685 95.9 ps 5431 0 o 38.076 06029 4.4 96.36 aa 5473 ws 96 3735 39533 Hous srs par 5498 86 8 34828 36081 ~3e344 98.65 235 5526 = 100 34096 3704 ~336 wn met 5539 2 ia 33157 309 =36120 10088 Et) 5595 ms sano 33253 36196 ~36107 10089 Be 5595 ao 020% 35083 20067 255 18.68 2170 sas 185 tot amr 20518 mse 18430 2146 mur 7 106 3601 20970 was 16491 24 3187 19 108 3308 ras 2870 16551 n128 31st‘THERMODYNAMIC PROPERTIES OF OXVGEN co ‘Tamu 11, Thermodynamic properties of omgen — Continued Trad Veiosiy ‘Temp. Density cneray Enthalpy Enuopy G G of sound x nol? Sot nol imal Smal K wot K oa Mia Tear — Coninsed 10 6 2186s 70502 16609 az Fey 1 m2 3a010 zo Susi 1665.85 2126 3140 196, ue Soai7 233 338 16121 226 3130 18 16 ‘Sasss 2196 32383 16135 as 3120 20 ne Som 23637 33008 16828 as suit am rr sias on 33027 toss. ae 20 1m ‘oss 24517 3047 169.32 aa ms rr sans 24985 34854 1698 an a 135 29738 25393 3548.1 1031 220 208 10 oars 20265 ams m2 a7 213 m2 nas 2670 am mmm 2116 as 16 2737 7367 Sasa iss 23 218 ry 29505 2798 soa m0 aut 3038 20 1 208 23362 an32 2108 3028 Ey ae 25005 19292 40857 207 23 2s 16 25317 m2 41572 2106 ae m ue 2i0st 41s ans aias moat = 150 24595 30580 an7 2108 sn10 20 152 2080 31008 4379 2m 506 cay 1 dois hes ‘o079 ao joo mo 156 23550 31862 44380 2100 Be 2s 18 ama 389 ‘5179 m9 2095 a 2967 23141 48375 2056 Dao 240 376 33567 “973 mer as 22 22083 33992 47570 2036 as 23 28t7 sais 167 96 ma Bd 1m 21868 48763 ans aa79 246 m 21286 $9359 mse an 28 16 mrs 50888 m3 Bn a1 178 20538 sas. mss an Foy 9 amor aos sin7 omer 2040 me us 197 38016 53220 291 Bas 28 150 “isi94 e071 sem m0 si 261 185 “i686 0128 S618. 290 Bs 2s 20 "ans ano 57689 oman mass one as ames 42233 59136 2089 ass m 210 ste 8285 0612 ans Bi 2s 2s i602 4037 62085 25 Be 2 mo 16509 45385 68350 2039 pat mm as 16134 4689 esis 2099 2346 as 20 4700 66307 19330 2030 nas 288 2s 8541 79 1534 2090 reas Et 20 9592 os 18956 20st ras 20 25, 50643 923 1906 mas pas or 230 51694 95 19076 m0s3 ras 301 4. Phys. Chom. Ret. Data, Vol. 20, No, 5, 1991970 STEWART, JACOBSEN AND WAGNER “Taae 11, Thermodynamic properties of axygen ~ Continued Tocca Valo ‘Temp. Deasity cnetsy Enthalpy Batropy c G of sound x sola? Sima aot nat mol K smal K ms ro a0 ‘sms Ta66 Tis "mast Bae 30H 20 ‘son 5397 38 19191 mass pa a7 2s ca sa e810 wa aas6 goss By 70 “304 55902 7283 193.02 296 as 32 2s 157 50555 786 19357 m9 2346 as 2s 22691 3063 a3, 1482 2103 Be sm 0 469 song s78 19513 210s 230 au Bs 12086 su7s B63 19864 2m pe = Es ‘0 an sm9 W868 at ms ms “40 MPa lobar Sar oss ass me Be 1m 5 ‘nsis 50 saat Ba iB 38 0381 mar 3861 sas 132 o 009 =sis39 54839 me at 5382 138 a 39.808 ~s7868 “S768 a4 Bat 5358 19 o sas 36192 56696 1388 sn 368 1103 6 3920 oss =55003 ns mae 5365 1086 6 138959 = sus2 54550 7350 290 5361 1062 m ao os3s80 “sus mas mass 5367 1067 2 33388 2807 5203 8196 a S367 1052 ™ e100 ~s1a4 ~sime aus aise S68 1036 Sisto Sas “Sons waar Sta 1020 B arse ~s088 e181 625 ey 1004 a a2 “aan 48107 wa bias 988 2 38927 4739 Ham mass 3078 om a %4609 42 45953 02s msn 9 956 a 3377 tesa ~aasra 12 3025 sean 30 = ar 0903 =a2 276 soot sus om ” a7 Tees 07 2398 76 oat oo x 35401 ~4732 618 55.18 23 5450 0 Oy 35.084 0641 = 40827 9638 2330 san am 98 3036 3s 35329 sat 736 $52 0 100 us “ama osm 9816 met 5536 ae 102 67 =a ~36106 10086 ma 5892 as 108 aa =38103 —3e884 10195 ma24 $633 m8 us.73 ue =3a2s csoa 289 a0 3672 m 108.73" as780 ms 28563 16206 ass Be 186 6 seas 21060 a9 1a 2146 303 1 n0 ara 293 ams 16337 ase 28s wm ma 473 288 373, 1633 2s ne 186 16 aaas 282 i916 16.09 28 m6 198 118 a aaa B56 165.64 aa 3191 20 20 859 234 3193, 1617 2.40 3178 om m “ans. 243 a7 16670 ae aus Ey mm a5 24680 aus 16720 a3 3133, 26 125 0191 6 ss08 197 as saz 28 cy 5465 25380, ans 16821 2133 331 210 4 Phys. Chem, Ret, Data, Vo. 20, No.5, 1901‘THERMODYNAMIC PROPERTIES OF OXVOEN ora ‘Taste 11, Thermodynamic properties of orygen — Continued Teral Velosny Temp. Density ceneney c G of sound x sold? Sima Simot K Simol K ms ro 3768 2024 aaa 18.69 231 3a 2 ro 38100 25165 36864 10.17 2 aun a6 Bt 31456 208 37585 19.83 aun sian ais 16 30835 rr sams 1.09 2128 nse ar 18 e236 ams 38823 03s 22 sss 29 10 35659 ona 39439 mss aa sure za 1 3si01 289 aos ma 29 so a Me See 284 20663 mas aur anes ms M6 300 29 480 mas aus as7 26 188 esse Dns aie tees as rei aa 130, 007 sa336 22900 rao aun nas 20 132 sn sams 43109 m0 2.10 nao BL 156 31688 5ieb a3, 429 21.08 3030 2s 158 Suns mp2 ana 468, 2106 saas 26 12. S006 ‘8 46137 103 2108 sar a 164 0008 suo amo 17380, 203 ms a 166 2502 as ama 17617 aun moo 28 18 ae 3ece prey 17653 2.01 Big 2a 10 23880 004 asta 7688, 2.00 soas 46 m as 3s ous ma. 299 000 2 i are ssa7 wus ise 298 bn 20 178 21 074 S43 ims 298 ma 230 178 so 36100 ‘542 17825 anst ps1 a 180 amet eens sisto 160 2096 29 23 18s ‘26812 sre 5332 iat ass DB 27 10 ‘35084 3049 5123 18021 ans 278 261 5 26m ‘08 sa010 110.98 mass ay 264 20 en ‘062 S188 173 ans 270 2s 2s aro ena 580 247 ans 2046 m 210 aus 180 162 18.18 2a pas Zs 20 2000 45390 en3 18456 msi Bs a1 ms 2856 6345 6602 185.22 mai 37 as 25 20616 852 ores 18651 ms Bs BI 20 ‘20174 95065 o33 18113, ans B33 2 2s 9783 50859 7080.9 8174 ass aa Ea as 18962 525665 33161 188.92 ans ast a3 250 591 sno 1336 19.49 2096 ps1 306 26s es ana en mas. 2st ost 20 20 17890 55529 rai88 19061 2138 2 3 2s 17889 6584 16.8 91s 2.00 232 ais os ima sr sia 10168 am wa ae 2s 16034 S006 wsi7 19220 2104 23s Et 20 16638 aus3 3408.4 m7 2106 23s a bs 168352 ena ass72 2 2108 237 ar 4. Phys. Chom. Ref. Data, Vol. 20, No.5, 1991972 STEWART, JACOBSEN AND WAGNER ‘Taste 11, Thermodynamic properties of oxygen ~ Continued Tavera Veleciy Temp. Density coe Enthalpy Entropy cy G of sound K rollin? Simal ool Siool K imal iol K ms “50 MPa Taber ‘seam 7087 Tass Taia03 6696 mae a7 125 36 40622 61080 = 095.7 889 3686 5341 131 58 40355 0013 = 59989 736 3S61 344 13 o 40088 Tsao44 ~se19 nis sae 5331, 18 e 39807 os sma 7395 sai 5338 120 o 39528 $6803 $6618 1583 an 3a 1108 6 39246 S571 35004 m8 a S305 1086 6 33963 54659 54530 739 za 3366 1082 ” 38679 53586 753457 anss 56 5366 1087 n 38392 52514 ~ S284 8195 na S367 1082 cm 383104 sit -siat war ass s36t 1086 % 3781s 50369 50037 486 38 30 1021 B 31523 49296 - 9163 8625 bie san 1005 2 37209 48223 48083 Bri 316 3876 38 2 36933 ans =4m12 R98 579 ssa om 8 36635 46072 ~ 45935 so2s ans S391 356 Bs 36333 Thies Taa8s.8 513, an S01 30 ro 361028 43913 ~ ans 9275 soa sats 924 0 35.720 42830 = 2600 9397 am 5630 oor 2 35408 nam = 41603 95.16 Bs suas 1 9 35.092 40653 ~ 40514 96.38 2330 5808 om 96 am 39558 sous 9788 2308 Sase 7 98 3a = 3858 38313 983 2886 sz 0 100 3a =3ms2 =3m05 075 as 3 ca 12 3376 36040 = 36092 sos mas 5589 6 104 san -asn19 -xo70 101.94 maas 5629 78 106 33081 S391 T3340 a0) 2806 5675 m™ 108 nm 32852 o Ey as ar 87 ss 1703 095 nso xs 20 ‘as56 5613 wis i651 st 38 6 29 as Sew sors 1817 as Bas aw m0 as S156 73082 188.72 21.00 Bs 32 ns 21870 6813 12 169.27 2101 Bs 5s as ‘uae sem28, e551 19032 aias Do m 20 ‘0812 53587 01 1084 2.07 Bei a 2s anise 61007 8502 191 2108 pe a MPa Taber mar wom Tome Tourn 056 Try a6 as 56 sogs ~ 61085 6093.7 has 3683 530 rd 8 0359 = 6001.7 598659 736 3367 533 1133 o 0087 59949 = 35799 nn base 5330 i e yea “S787 “sms ne wa S37 129 o ssw $6808 = $668.7 18 aan sae 10 pest =35737 S554 me ap S366 1096 os 35506 54663 su r338 ma Bas toa ” 38 53593 3388 ms ast 5366 1068 n 38397 “32821 “S365 B94 ao S66 1082 4. Phys. Chom. Rot. Data, Vo. 20, No. 5, 1991,974 ‘STEWART, JACOBSEN AND WAGNER ‘Tas 1, Thesmodmami properics of cmygen — Continaed Thera Velosiy Temp. Deny ery Enalpy Entropy c G ‘ot sound ® soli Set ‘inet Simo Simo ms HPs Tatar ~ Coninaed 7 a8 “sag sae ea 398 Be 7 = 3138 Tasos Lagu ak 313s sn 100s a 31238 cami Leora ne a0 535 cs e 3499 nae 593 mae sa m3 a 36041 ~s917 sos mass 09 3 % 36339 8 5130 Pr $400 oat Ss 303s 987 sm a HB ou so asm Sass 396 Pa 528 a a Aas Sass Sisk 558 Be sus a o 35099 mses 0995 sa Ba sist 5 56 3a ec) 108 Boe seo a ms 3 ry) Seat Be Sas oa 10 Min csr Loa 533 66 Ss. mx m2 ms ssass 307 1008 as 5386 a” tat mun wae 38 tos ass 036 = 106 3am Thos Se 10300 a0 sn m 108 au cami “87 10406 nae on 8 u0 52367 cma Luisa tos un a7 ms mae ‘2003 Sets 0083 105.8 58 5825 a mae um 223 2330 1s ns ss 188 mm 92 2159 sas 1991 ba B00 1 1 sot ase wos 10s zn HB wi ie ioe ato 3919 ish ns sao Be us ‘950 ns 31001 iain 218s 301 186 1 061 asa ams tems au» 3s 8 i canis miss 2610 137 290 8 a3 5 ‘a0 us ace 189) 16 2s eo 8 fos? 2506.1 Mos eta 26 ne on 10 9668 asa ass aon 19 230 2» ie S50 29 3025 sa 2156 233 an be ‘S88 reas 370 16590 as 20 23 16 So 2889 1512 166538 20 2m 2 8 ‘Sot mat Bast tas 2s 3 a 10 5565 m2 see 1930 ne 3176 2 18 Sse 2240 jaa 16775 20 33 a i am es ‘ss 18815 an 3152 m 16 ‘Sis 2133 ‘est? 1 a3 sa. 2 18 2578 009 16906 12 a31 5 1 “0s a6 ‘e558 10039 an 312 B 1 875 503 ‘180 1029 2124 3108 a 18 67 31363 ‘00 m8 un 196 2 1 aon? sas 035 mas a8 mn 26 12 ‘7s 686 5651 has a0 307s 28 164 asset m2 dens ipa bes no 20 I oat 27 ‘ena rot BB sas Er 168 asi 3962 90 1st un st 26 4 Phe. Cham, Raf ate, Va. 20, & $008‘THERMODYNAMIC PROPERTIES OF OXYGEN 975 “Tam 1. Thermodynamic ropes of exygen ~ Continued Toteral elon ‘Temp. Density energy Enthalpy Eauopy c G of sound x ml? Jimot “ol Siaot K imal K Sieh K ws “W MPa lobar — Continued i am 385 “wi0t 13 210 sos 2s 1m as 35081 x0 m4 2108 sna 28 15 a9 35083 9928 1439 207 3038 28 18 163s sera 50535 m7 2106 ans 1 10 aus 16555 sua 1507 20s 3030 2 us 538 3180 515s 17390 aim so 256 19 ‘8808 3a702 54162 17671 2190 303 20 20 Sans 083.9 57168 17825 nse BS 2 as asm asa 3066 m9 2nst r394 m 210 Se ‘a6 eaie2 re71 n96 zoa9 mm ais Sus 02 a1ess ‘oat 2nss nas 78 20 Sans 84 e3ie7 181.10 205 pai 21 ms Hs ais 64635 mi77 2095 237% 2 20 sit ams era m2 mss 27s 28 Bs ‘i029 ans oro 183.06 2nss prs at 0 89 ou 07 15.68 mss 237 Be ae gone sone nea 1430 2096 29 a 20 2108 Sus0 086 18490 98 ber 0 as 2516 08 ns49 15.49 ans 2966 203 20 2981 S566 75032 18606 2ns8 2386 106 2s nao Sens 76815 185683 25 2s a0 m0 26899 8083 797 16738 201 205 an ms 28 142 m80 wT aim ss 35 20 23508 ran 1862 18826 2108 25 318 as seat 58861 mus 18878 2106 266 xl 0 “93 smi mm 18930 aor 86 Ey Bs 24801 0562 ast 1981 2.10 261 = 300 2anee ema 6885 19031 End a8 Ey 70 MPs lobar sar or Tama = arts ws E Be Ts 56 sn609 61089 = 691.7 oar 3685 5338 13 3 030 ~eon2 = 30849 ms 3887 sa 113 o 20050 39954 38780 nas baat 5350 1129 a seals 5758S “sms 1391 ae 3530 129 o 9336 S084 $663.7 1302 an 61 1108 6 eas asa 55565 na mp 364 1097 3 on = S67 Tseasi2 7881 sexe 330 13 ” R08 -s3a00 = S419 me sr sas 1068 2 saa - 2828 S046 s1s3 sas 5365 1083 " sane -3180 suns 00 aise 3300 1097 6 sims Hams S000 Base aust 5367 sat w srsse a2 313s 5370 sos =» 320 a9 aur 5378 39 « sm m2 saxo 3380 om a 6607 ~45899 soa ost 5388 981 % 3636 na4821 91.8 sas 5398 oat 0 sm 1065.6 5334 237% 525 os 2 asa 41569 55.4 Dis seat r 4. Phys. Chom. Ret. Data, ol. 20, No.5, 1991,970 STEWART, JACOBSEN AND WAGNER, ‘TanLe 11, Thermodynamic properties of orygen — Continued Terma Velosny Temp. Density eneray Enthalpy Entropy c G of sound x smolts Simot ‘ol hol K ol K. imal K ms JO MPa Yoobar ~ Continued 38 35107 ~a0s78 wos 9631 Da sas mS 96 340787 ~aesa4 39383 746 Dm 5489 588 % 362 Seas 3082 98.60 2387 58.7 se 10 Sut 3381 =3n76 wn 2356 5548, me m2 as =3az70 3063 002 2846 ssa3, wo 104 saase 35152 3942 i191 2326 623 ny 106 sa103 02s 33813 10298 2307 567 m 108 as 32889 = 30675 040s 299 srs 184 10 3p 3142 31826 105.10 mn 5174 Be i Bri) 3584 T3368 1061s ns 38 cy 13.80 s1ass 29829 2008 ors 20 sss ™ 138 A714 aa 278 1583 ne x01 188 me ‘54550 21373 25652 15889 zn a8 19 16 297 21883 3579 15852 2» 3890 191 18 ‘an392 282 31080 1603, 28 3823, 16 ™ rsa zona sing wa mas un 16 m 06 259 peo 16129 2196 ut 9 ™ 8076 rer) 33163 asias 259 so 2 15 385 2616 s840 19239 se an m3 re 71983 20789 Sas sae 28 3340 as 10 mss 25259 35179 168.43 as sa oo m ‘om ans 35842 1856 an Bol 2» 136 ‘66687 28853, ams 1492 aus na 23 18 “e546 ami ‘3805 16539 2138 sas as 10 ise zo 352 103086 ais na9 ar 12 ‘e277 ans 30856 16632 2131 2B 219 1 ‘a2 23078 378 16676 2st 3199 za 16 ‘su137 23930 40376 16721 2a bias ms 1 ‘ars a0 #1012 srt 2a bus zs 150 59036 aes 41646 168.06 ae aie m 152 ‘53326 sams 42217 1688 as ast a 156 56598 31165 533 18.30 2130 33 m 158 isms 31008 4458 16970 an iz a 12. ‘S208 52081 45404 iar ap 31.06 Br 166 S61 m0 46024 amas 221 3098 2 165 mms s369 46643 mas. ost 21 1m 1347 sia 417 im36 2116 3078 me m 150683 34680 48492 ma ae sana 286 mm so7 dns 49106 rma aus sae oar 176 49408 S881 ons i308, aun wast 8 18 4597 ssa 50330 ims 210 sass 230 10 4201 rene soo4 mn 2.0 mast as 185 4679 3099 5063 mass 21.06 sao 286 199 45403 38577 5356. 17536 2108 3030 29 ws 487 33682 55084 16.6 20 ma 28 200 “001 wona ‘$7003 17691 2100 sae 267 4. Phys. Chem, Ret. Data, Vol. 20, No. 5, 1991‘THERMODYNAMIC PROPERTIES OF OXVGEN 077 ‘Tasix 11, Thermodynamic properties of angen — Continued Terma ‘Velosty Temp. Density energy Enthalpy Entropy G G of sound K moltin? nel mol Siot K mot K. Jick K ws 25 rast as ‘eso ms 99 3008 m0 20 0821 42363 oo. 1838 2098 som mm as ory as ott 1908 aust asi an 2 ‘aenat 4495 008 1.7 mns7 292 2a Bs 37883 46059 61303 10.44 2096 a8 24 20 3708 anz2 00990 18110 2096 poss a7 23s 3e83 8185 ons 18174 095 a En 240 ‘sa 9u6 3979 19237 ast pe 2 24s ma 50308 70468 182.98 mst an a 285 33310 209 Tat3 1847 2n98 wm m3 260 Sts 3489 4930 18475 m9» pn 306 ™ 3101 ‘Sss10 702 18537 am pn 32 2s ose S664 388 18542 aun an 35 28s 2904 593 12359 18748 2106 an x = pip 59855 sats 18800 2108 wn me 295, 28673 os as331 15350 20 wn 0 MPa Tobar sua an —aion0 Tama oor a0 ae a8 sé fogs 61093 = 099.7 oar 363 535 1132 58 90366 002.7 59829 mse 3861 S342 14 @ soaps = 59959 =se760 nis base 5308 19 e aes come =s7688 not un 356 131 6 3500 56820 1561 an 300 10 66 39259 = 3519 7128 3330 5383 1097 a aon ase mma po Set 1093 ” ms S306 wat 5258 S368 1068 n 306 -285 ais ss S368 1053 16 37830 750382 sia Sus 536 1022 % 37539 = 49320 622 3136 38 1006 0 37246 48048 3738 518 an 30 8 35653 5020 sae S387 988 86 36352 ~asn3 sar sn29 397 oa 0 37 5393 Es) sis, 08 2 3430 98.3 ss 53 = Py asate - 0690 9630 ey set 16 56 395 739597 oras 210 S887 59 38 370 38899 9859 2a88 ssi a 100 3140 =3785 =3n61 970 281 sas ws 102 133804 = 38085 36048 10.20 wat 5580 8 108 348 35168 -uns 019 asm 5619 70 106, sus 34082 ~33800 iar 2808 5668 ™ 108 32156 32907 32663 0403 29 513 8 10 mae. 31162 =31515 11508 mn 578 26 m. sis 3004 suas. 106.13 ms 3 18 ‘Phys. Chem, Ret Data Vo. 20, No. 5, 1991ves STEWART, JACOBSEN AND WAGNER “Tams 11, Thermodynamic properties of oxygen ~ Continued Tera Velocity Temp. Density eneray Enthalpy Entropy G G of sound x molt? Simo Sol imal K Sioat K Swot K me BOMPa Tahar — Continued i 3080 — pase ~pie1 i077 78 ‘9 # uso 31250 =2e300 = ao 1oaas ns 5982 0 uso 6497 aura aes 2 3816 189 ue 96382 2098 a8 208 3810 139 us, 93856 mins masts 264 3693 1 0 sists 2536 sins. 13931 238 3612 134 m sm331 2038 sis 159.90 nz 3533 re 4 7280 ssa smo 10.48 zu 3506 199 15 55348 2023 x07 161.03 mo 3467 2 ta S22 24508 3087 1618 list 332 ao 80 si) 289 sma 10 291 3a 26 1B 0187 23465 ssa 122 2186 3375 28 im TESS 540 36120 18.13 281 350 20 16 7050 2410 36788 18.2 2176 326 22 18 15665 25878 58 1641 an 4305 28 asa rms, sano 16458 a7 sus 28 72595 nso 76s 16505 2s 3267 218 me mss seu 16550 2138 20 0 70838 23 06 165.55 ase m3 m ‘se ai wna 10.) uk sels a aes 29633 au3s2 16682 nT so04 26 ens saws 1982 16104 Das S191 zs 0133 30 rer) 11.20 aia Sus, ze ‘esiss| anes ex 16807 238 3s a 8188 3a p65 16847 2138 31ST 2 10 sa ists ais 1sa7 ux sar as 12 uo m3 isa 169.25, 2130 3137 ar 164 1473 sm87 “S781 19.64 uz 38 28 16 ‘628 sa09 sins 1002 2125 320 20 168 ‘55500 53a51 ams 17039 a . 22 170 5001 a0 7680 nai so 268 im Sans Sasa az 219 mor 2s 176 a) 3607 9507 2116 sae 28 18 ‘seas ssa 0123 aus 378 20 185 53619 S68 gm 2110 5080 2s 190 8 Bes s8 2107 so 29 195 50670 aen2 ssm0 210s 5038 263 2s 8001 aes sass 21a soz ca 210 4675 ars 59859 2.00 01s mm as as 3927 ses 2.00 3n08 m 20 “stl 448955 2369 2098 3008 2a 2 3464 15964 oa70 2098 B98 24 x0 sates ammo 008 17995 2098 2995 = zs 1316 8085 7365 19059 2098 92 ea 20 0608 $9160 360 12 2098 2999 Ey as Sen 50223 TSA 1818 98 2986 Ea 250 e012 587 nes wat m0 Das a0 J. Phys. Chem. Ret. Data, Vol.20, No. 5, 1991THERMODYNAMIC PROPERTIES OF OXYaEN 979 ‘Tams 1, Thermodynamic properties of oxygen ~ Continued Tateral ‘Velocity Temp. Density Enthalpy Entropy G G ot sound x oli? Sina Siaot K Sloat Siwot mie “HO MPa ober — Contoued Bs “37 sao 787 183083 72.00 we = 20 Srs6 a2 mo 13.61 2.01 ao 6 bss 3ea05 Sura 7319 1848 aim ae Ey 20 Asn 57 07 18473 203 27 32 ms S328 56600 786 18528 2104 am is 20 0 mez ssa sa 206 wn a8 as ioe sms a3 2.07 am x 250 un sma 761 2.09 an ma 5 apt ags.3 35350 aut BR ey 90 MPa Taber ae Toms ory ~aiee7 57 Saas wae Tia 56 40535 a8 ~ais75 or 3682 337 133 38 40370 eons ~sse09 m3 3567 S381 uM @ 40.098 58564 ~sem80 mie as 5348 79 6 56508 30 35 360 110 6 ~sss06 mas 3300 S38 1097 @ sus meas 3293 Be 4063 ” — 53380 040 5258 S366 1068 n “snos sist 3226 S36 1053 %6 ~s0i62 seal 3ues S365 maa * =n 621 3136 5398 1006 a ~aa01s srs 3108 7 550 ” errr sao wos 5078 om 48363 sas aoss 536 988 86 ames o16 5029 5396 oa 0 = 482 ss a0 S23 508 2 486 5s. 2336 stat 3 9 aim -am2 ~ anus «20 co seat 6 96 34805 = 35009 = 3381 ore al si8s 0 98 3ur9 35812 31 a7 2539 ss 88 10 3a =3109 =a 59 268 5503, 5 1a asia =39300 30084 10079 maT 377 8 104 aan ~ssin wes 10138 2528 S616 Bt 106 aus 34089 3707 10295 2808 560 7 108 761 Sums =ms0 04a 20 sum 6 no sas oar 31803 108.06 nn Stas a m2 S08 - mes as 6.1 2136 3827 79 m4 susie 2388 ana amas 20 5358 x0 16 3207 Lam aro 188 ae an oo mse saan =267 26875 1093 zm case oa mse 1.0829 21893 2903 15931 Be ws 19 us ‘Logos 2186 2365 15736 nu wa 189 10 oss una son 1801 2286 s7a9 ry 1m ow zm june 138.63 2st 3697 185, ma 99977 aia ams 159.22 ne 3628 i 135 97683 ans ams 15930 ns 374 20 18 95489 2217 33646 100.36 zw 3829 am J. Phys. Cher Ret. Dat, Vol 20, No. 5, 1981980 ‘STEWART. JACOBSEN AND WAGNER ‘TaRLE 1. Thermodynamic properties of exygen — Continned Tater Vel Temp. Density cnerny Enthaly Entropy cy G of sound K solder Snot Tino! Smal K Io K Soot K we 30 MPs tar — Comtinand 0 "33380 20 3a 16090 me 3490 Ey re suze 23198, 38042 16.8 zo Buss 26 Be ose 28692 35730 16195 219% we an 16 57799 25161 36412 162.45 2190 95 a 18 ‘368 26638 ‘mes 16295 ais a8 28 0. ust oma a60 ws an as as 1a 50580 288 302.7 168.90 276 Ba 2 ut ‘s1812 204 55089 16437 2189 sam 29 6 0108 asia bons eta 21s eas ma Pm TRI ors aun en mat was mm 150 mass 204 an0s4 165.70 2136 s9 Bs 12 e206 23082 41702 166.3, 2183 ns a st "same crus pur Mase n40 29 m0 136 388 nwo ‘2000 16697 2186 sas Zo 138 cams sus 600 16138 rae 3193 2m 10 nee arms 467 161.78 a9 sat a 1a ‘ass isa 4902 16k 2136 3170 6 1 ‘ose 3202 45535 16836 23 3159 28 M6 ‘sass a0 46166 16894 231 3130 2 18 ‘67660 33093 695 169.32 2129 340 a 170 6181 33937 waa 1693.09 227 aia 23. m 3809 380 49007 17006 2128 323 ey m4 ‘sos 22 807. rma 2s 3116 26 16 ue 35262 oa r.7 a2 3108 ae 17% fas 3502 ons mn 2118 301 9 180 280 seis 0534 mar aur sass 2 us 20836 amas 52078 maz 21s saxo 2s 150 ‘sa863, sas S015 mms aun wast 28 185 S199 soa 5145 rss, 21.08 3056 22 200 S303 a3 56670 1490 2106 nas 26 2s sass asia aio. 17848 2108 sos7 0 210 761, 22549 swm07 17619 2193 5029 ms ais ‘S19 ana smo 17690 2a on m 20 S087 88 ens ins aot ants ey 2s 4897 48867 oa 17827 2100 sn10 28 20 47865 4637 eno rms 21.00 3006 ea 2s 46786 48005 67282 17938 2100 at Ey 20 ‘5188 9073 rot 18021 2.00 2398 Be 4s ams S039 39 8082 2100 a4 a 230 A386 srs 136 1818 210 er 00 285 42936 smo rat 12.02 2101 299 3 260 ‘ome S35 ams 120 aia er 6 2s a8 51389 7219 1.17 213 23386 8 m0 “aotse sst64 mma 198.73 2108 oss su ms 35001 56528 mm03 18428 210s se a5 230 357 57393 ans stat no7 aa a8 2s Sas 58658 wi87 mas 21.08 xs mu 230 210 973 673 188.5 210 as aa 235, 3014 ans 85170 18637 aur BE ar 300 30281 e155 8665.1 18687 aie se 3 4. Phys. Chem. Ret. Data, Vo. 20, No.5, 1991‘THERMODYNAMIC PROPERTIES OF OXYGEN 981 “Taste 1, Thermodynamic properties of oxygen — Continued Thera Velociy Temp. Density nergy Enthalpy Eawopy c G of sound ® olde? Sima Timo! Soot K Simot K Sit me To MPa obar mar m7 =a =a ear 3806 Sa a7 56 on 61102 856 as sa 5336 1133 s an Heo. ~s789 m2 3556 540 11M ry aim 53569) 580 ne bas sua8 1130 @ 39805, S750 57650 ne sas 5334 na 6 ess 568841 $6518 89 aap 39 m0 ra 39267 35761 ~ss506 m4 331 S302 1097 a 38085 suo 334 maa 338 Sa 1084 2 sa701 300 33361 a9 29 Se 1068 n ear Ha 589 150 sa26 5383 156 ™ ee) -sur8 -siis wa 3196 sas 1038 16 a0 =s008 S043 3430 316 53s 102 ® 31550 ry -eu maa ast Sa07 1007 o wast ~am5 = a6 86 10 san 1 a 36902 =an92 46922 S938 sor sa mS & ies sous ~ame sous 3038 sass 238 % 36364 4503 468 suas 30 5a94 oa. s 6061 ~a65 688 58 nas sur 25 0 35754 ams ~ ams 391 Bm 5422 510 w sss aim Tass 9510 Dat 338 cy 9 asn9 ama ~s009 9627 wae suse a 36 aan 39822 erry oa aut 5483 so 98 37 “asn me one ae 5510 ee. 100 Mise waa =a sa8t 2868 5540 5 m2 RB “15 36018 100.77 m8 5578 8 106 ss uns -um4 1293 30 5656 ne 108 a7 = 043 ~nas 10400 31 570s 156 0 ate =3im0 ~3082 105.08 na 5780 18 12 ‘moa sos 30333 10608 6 sez 0 1 31657 -pos ~29162 0733 no suse mo 16 3120 236 -m78 10316 ms 57 oat 196 sia “sit 5783 11002 z00 6148 os 960 12018 21682 0003 18686 Ber 2036 189 im 1105 242 sms 15948 no 3876 m 1% 11328 ne8 aims 15806 nn 317s 195 126 11083 01 as 15865 ns 3698 186 130 1.0536 pen 3012 13979 na 3887 m8 1 10% 221 as 1034 220 3543 2s 16 e808 23506 3627 16138 nus 0 28 1 6941 25394 sent 16199 2198 3438 22 wo ours mae x02 1038 aa um mu 12 33183, 281 001 10286 2135, Bas 216 a 91453 mms sa56 1833 ist ase 28 16 “867 207 seas 1879 2176 m6 2 we a0 e166 ‘08.0 6425 an 33s m 4 Phys. Chem. Ret. Data, Vol. 20, No.5, 1991‘9n2 ‘STEWART. JACOBSEN AND WAGNER ‘Tague 11. Thermodynamie properties of oxen — Continued Tater Vali Temp. Density enerny Enthalpy Entropy G G of sound K sola Siok ‘no! rol K Simol K smal K ms TO MPs tbor Continued 150 “B68 2 075 14 2166 3296 mt 132 85379 B06 4108 16813, 218 ed ns 134 3998 aos 42082 16555 aise wast ze 156 52669 30616 ana 1897 2184 as 20 158 81389 airs 43360 16638 2130 3230 BI 10 s01s3 nso 100 16679 nar m6 m 12 “79960 31982 44687 1679 213 a0 as 168 “7008 a4 45286 16158 2140 3192 Br 165 76693 sms 45924 16191 237 3180 a 1m 14869 37a ang 168.72 ae 3160 2 im 173886 3027 47922 2130 3130 24 16 762 3516 49079 2126 3133 7 18 ‘70694 38859 ns me 3135 co m8 soz sian m7 2118 3101 284 ‘58680 sais 300 mas aie 4oas 288 ‘ar sono 5970 ims aut 073 2 ‘209 ‘asrs 56503 mm 2.08 3081 266 ms 0347 a6 sa03. ins 297 2031 ™ 210 ‘3378 2542 59555, 17525 21s 3043 ms 2s sr a0 sors m7 2104 03s mm 2 3887 4057 8390 687 2103, 3028 280 zs 54853 sma 6102 17735 2a 2 ae zo s3zse sous ssi rao 2.01 301s 231 Bs ‘52076 ais emis 1786 2101 ou 20 20 ‘50024 565 68822 13.29 2101 ‘007 Bs ms ase24 0s mons 17391 2101 003 ww 250 23773 sin3 926 ims zum 2000 300 2s a6 suis mes sit 2a B97 303 20 “as80¢ 5287 11823 18170 2103, 398 306 2s 45880 sa24 16120 127 2104 393 co Z0 44993 55390 6s 1s 2tas oi 3 2s aaa 568.7 und 1837 2390 as 20 a3 s123 anos 391 2989 38 ms ase 58300 e201 teat 389 Bt 20 ars 587 995 18496 238 a 25 “1083 ors 88089 15847 2938 aI x00 0337 61792 86883 18597 239 x 15 MPa lobar S58 wom —a1806 ~ 61539 a9 wer 34 19 56 0657 rena ass seat 3580 S31 134 8 40391 = 60060 = 59689 728 3555 $336 1136 @ 40x20 = 58095 58601 708 bass sat 1 a 3984s ~sm8 57881 ne 3a Sst 123 o 3508 ~3686.0 = 3648.1 ast 3375 356 nn ra 30288 “5571 =55009 mas 3333 5359 1099 a son =si2 750337 me 3296 60 10s ” sare 5363 “53265 03s ist 360 10 n 3809 52884 =32193 5186 329 39 1055 4 Phys. Chem, Ret. Data, Vol. 20, No. 5, 1991‘THERMODYNAMIC PROPERTIES OF OXYGEN 983 ‘Tame 11, Thermodynamic properties of angen — Continoed Tera Ves Temp. Density nergy Enthalpy Enuropy c G cof sound fs ollie ‘mol iol Jinot K imal K Jim K mie 7% 31S =sisi3 Ts wR 3138 aa 100 1% 37865 sos 50050 aus 318 500 102 * 357% Ha9376 409727 eas 3u40 be 408 2 37284 48307 ~a704 8730 a2 5346 om 2 36991 4736 4693.1 cry 08s sm om” a 26604 46165 45956 voas m9 am at % 36396 4808. 4619 9139 Eirrs S38 oat 8 35.04 Hons 800 os 3008 s.00 378 %0 35.70 2038 2519 sas pat sud on 35167 «ons = 40347 621 wx s4s0 0 % 34880 39685 = 39255 9736 ot 5472 a 100 3420 3704 3753 30 wn 3827 a a2 357 A 36389 35947 0070 2331 5580 #2 so as a8 see 10178 man sso 7s 106 3186 =31160 =3m3 1028s an 5638 7% 108 nan 33032 32575 10391 94 ‘Seas 7m 110 a7 31885 31833 10496 2136 337 a 1 suns 29887 -i4 10703 ms 5863 ns 16 sis m3 108.06 ma 938 5, ue ane soak mn on tar 20 ase Cason i040 zoo 6133 or m Sass =24787 m2 2681 ext os m4 2633 834 2028 unis 2676 on om 126 2160 -2u3 =21789 n38 2661 sar 52. 12598 23919 =21612 21003 130 268 66 mn 2698 LISS 21817 30080 18.99 2498 a 18 8 1768 24s 30852 15436 24st sm 1 10 196 ama 313 18505 ast ar 193 1m 15798 2365 396 15590 26 4136 196 Be 1530 2p BBI20 15632 mus ag 9 16 ism 280. 33923 13631 aa Bas 2 18 15532 25019 3am 15149 mal am as “0 15168 23387 38077 18504 2s aa am 12 1487 sits 363 15858 ass 333, 210 mt 14506 26987 3078 1910 2s 3699 2 16 14003, ams ams 139.0) 235 best 24 18 13017 21661 3889 10.10 m5 3608 an 130 13648 28164 seis 16058 nus 3508 29 152 1397 23662 35867 16105 m0 333 2 1 rat pass “40570 16151 zo 3800 Ey 156 T06 Dott 41287 18196 ast 300 Bs 188 12581 30180 41958 12.0 2191 ae a © 12466, 0612 as 102.83 2ias sur 2 12 12260 S100 ans 16325 2179 nas BL st 12062 51566 0. 1897 2174 an 2 166 118 ammo 03 16408 2.70 3350 2s 168 11689 ss09 au 644s Dias a1 2 4 Phys, Chem. Re. Data, Vol 20, No.5, 1961,‘STEWART, JACOBSEN AND WAGNER: ‘Tams 11, Thermodynamic properties of orypen ~ Continued Temp Densy coon Enhnpy = Eopy & c ofsound x olde? Soot ‘oot Wool = Nat KS me TS 6 ar = Coan i Tis we wane aa Ha Ba Be im tna aa ‘tea 123 hist nor an ri tine sons ms teat ast Bal 28 te Hin ieee ims ieeot ae es he 8 ows bes an 168 nar 2s 6 1 1m 989 sos 1664 nae 20 28 is ts sea Sos ina is Bn 3 0 10188 9 582 seas ne bras 6 195 sas 5eer0 ser 10930 hz soe Ea 2 3507 ams Sas imi0 na na oe ns oisss 40883 sas ma am 318 268 0 ‘e381 4983 Sores ms a aus m as om 607 ans ima ais xm 26 2B sm m3 rd thay Fir xe » ms a0 ‘05 oa) 13% an a7 28 0 089 aso 964 mse a0 ne 286 B 0 St hs iio aD Sst = 20 “res ‘ese eons i504 28 ost = is san pao os 637 hue oar 26 250 Best sono fans 698 2m oat » ass rio sino ns ims ace x31 x3 20 “oss Sas ano ras 2 soxt 30s 2s ‘ous se 1a ms aio» 2D Py ™ om sas ims tna aio sos ae as ‘sie San 550 ine au Ey aS 220 65086 sus sors ime aun som is Eo ‘aoe Se fiero ios Bie sole m Ea ‘om sons ers ia ais sous cy 2s ‘ret ‘ont ea ie nn sous a7 5o0 ‘oss ana fais 50 2119 zt 30 20M bar aw Taws 01 za aa iis0 S Son cs aor is Sas red se ‘oato = ‘nae Ba Ba in @ wo Ts nos 3486 Bat im @ was i518 na as Ba iat “ 9598 =s083 1380 an 38 ni 6 wa T12 nis 35 B36 iio & Som “sau mas nes 336 186 = xn She a sa se in 2 mae “saps nat ba Bs 1037 * xan -swa7 na no 336 wo Ea Sao Toone na a Fed ions ® Hen cian far0 na Bs i010 © wan Tina mas 3s Sat oo ® sro wiry an 3oae See * & ere ~s068 soo oa sn 99 oy sean? =t00 aise 236 Sa 37 ® deia6

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