-3- N16/4/CHEMI/SPM/ENG/TZOIXX Which change of state is exothermic? A B. c. D. CO, (s) > CO,(g) H,0(l) > H,0(g) NH, (9) > NH, () Fe(s) > Fe(l) Which volume, in cm?, of 0.20 moldm? NaOH (aq) is needed to neutralize 0.050mol of H,S (9)? A B. c. D. H,S(g) + 2NaQH (aq) -> Na,S (aq) + 2H,0(!) 0.25 0.50 250 500 The complete combustion of 15.0cm* of a gaseous hydrocarbon X produces 60.0¢cm’ of carbon dioxide gas and 75.0cm’ of water vapour. What is the molecular formula of X? (All volumes are measured at the same temperature and pressure.) A B. c. D. CH, CH, CH CHio Turn over4. -4- N16/4/CHEMI/SPM/ENG/TZOIXX 5.0mol of Fe,O, (s) and 6.0mol of CO(g) react according to the equation below. What is the limiting reactant and how many moles of the excess reactant remain unreacted? Fe,0,(8) + 3CO(g) + 2Fe(s) + 3CO,(g) Moles of excess reactant Limiting reactant es remaining A co 20 B. co 30 c Fe.0, 1.0 D. Fe,0, 20 Which is correct for the line emission spectrum for hydrogen? M 9 0p > Lines converge at lower energy. N Oo POR Line M has a higher energy than line N. Line N has a lower frequency than line M Line M has a longer wavelength than line N. What is the condensed electron configuration of the Fe® ion? AL [Arisa B. [Arj3d‘4s? Cc. [Arad°4s! D. [Arjsd°s?-5- N16/4/CHEMISPM/ENG/TZOIXX Which equation represents the first electron affinity of chlorine? A. Clig)+e > Ct) B. fey@+e >cr@ c. crig)+e > Clg) D. Clg) > cr@) +e Which solution forms when phosphorus(V) oxide, P,O,,, reacts with water? Product pH of solution A H,PO, <7 B. H,PO, >T7 c. H,PO, N,(@) +2H,O() AH? = -623kJ What is the standard enthalpy of formation of N.H, (l) in kJ? The standard enthalpy of formation of H,0 (\) is -286kJ A B. 623 - 286 623 + 572 872 +623 -286 + 62314. 15. -7- N16/4/CHEMISPM/ENG/TZOIXX In which reaction do the reactants have a lower potential energy than the products? A. CH,(g) + 20;(g) > CO,(g) + 2H,0(g) B. HBr(g) > H(g) +Br(g) C. Na‘(g) +Cr-(@) > Nacl(s) D. NaQH(aq) + HCI(aq) > NaCt(aq) + H,0(0) 5.35g of solid ammonium chloride, NH,Cl(s), was added to water to form 25.0g of solution The maximum decrease in temperature was 14K. Whats the enthalpy change, in kJmol”, for this reaction? (Molar mass of NH,Cl = 53.5g mot”; the specific heat capacity of the solution is 4.189" kK") |, 25.0 x 4.18 x (14 + 273) A AH= 0.1 1000 Baya 2504.18 x14 0.1 1000 CAM a + 20418 14 0.1 1000 D. aya + 2504.18 «14 1000 Turn over16. 7. -8- N16/4/CHEMI/SPM/ENG/TZOIXX For the reaction R — P, which letter represents the activation energy for the catalysed reverse reaction? Energy Extent of reaction ‘Which experimental methods could be used to observe the progress of the following reaction? Cr,0* (aq) + 6 (aq) + 14H" (aq) + 2Cr*(aq) + 31,(aq) + 7H,0 (1) 1. Change in colour I. Change in mass Ill Change in electrical conductivity land Il only and Ill only and It! only 9 0 @ > I, Mand tl18. 19. 20. 2. What happens when the temperature of the following equilibrium system is increased? -9- CO(g) + 2H,(g) = CH,OH (g) AH? =—91kd ‘th wlibri Reaction rates of forward Position of equilibrium 4 and reverse reactions A shifts to the left increase B. shifts to the left decrease c shifts to the right decrease D. shifts to the right increase N16/4/CHEMI/SPM/ENG/TZOIXX Which species behave as Bronsted-Lowry bases in the following reaction? H,SO, + HNO, = H,NO;" + HSO, A. HNO, and HSO,” 8. HNO, and HNO," ©. H,SO, and HSO,- D. _H,NO," and HSO,- ‘What occurs when solid sodium hydrogen carbonate reacts with aqueous sulfuric acid? A. Bubbles of sulfur dioxide form. B. Bubbles of both hydrogen and carbon dioxide form. ©. Bubbles of hydrogen form D. Bubbles of carbon dioxide form. Which is a correct statement for the reaction below? 2MnO,;(aq) + 6H’ (aq) + SNO,” (aq) —> 2Mn**(aq) + 5NO,” (aq) + 3H,0(\) A. MnO," is the reducing agent and the oxidation number of Mn increases. B. MnO, ‘is the oxidizing agent and the oxidation number of Mn decreases. Cc. NO, is the reducing agent and the oxidation number of N decreases. D. NO,” is the oxidizing agent and the oxidation number of N increases. Turn over-10- N16/4/CHEMI/SPM/ENG/TZOIXX 22. Avvoltaic cell is constructed from zinc and copper half-cells. Zinc is more reactive than copper. Which statement is correct when this cell produces electricity? Voltmeter Vv Salt bridge Zn cu Zn**(aq) Cur (aq) A. Electrons flow from the copper hatf-cell to the zine halt-cell. B. The concentration of Cu“ (aq) increases. Cc. Electrons flow through the salt bridge. D. Negative ions flow through the salt bridge from the copper halt-cell to the zine half-cell 23. The structure of a drug used to treat symptoms of Alzheimer's disease is shown below. ‘Which functional groups are present in this molecule? OH CHO. CHs A. Hydroxyl and ester B. Hydroxide and ether C. Hydroxyl and ether D. Hydroxide and ester24. 25. == N16/4/CHEMI/SPM/ENG/TZOIXX HsC—CH—CH,-OH CHs HgS—CH—CH)-CHs OH CHs —C—OH CHs Vand Il only land Ill only I and Ill only |, Mand Ill ‘Which monomer is used to form the polymer with the following repeating unit? (CH,CH=CHCH, CH,CH,CH-CH, CH,CH,CH,CH, (CH,),C=CH, Which alcohols are oxidized by acidified potassium dichromate(V1) solution when heated? Turn over26. 27. 28. -12- Which type of reaction occurs when methanol and propanoic acid react together in the presence of a catalyst? A Addition B. Condensation Cc. Redox D. Neutralization Astudent carried out a titration to determine the concentration of an acid and found that his value had good precision but poor accuracy. Which process explains this outcome? A 8. c. D. Consistently overshooting the volume of solution from the burette into the flask. Collection of insufficient titration data. Reading the meniscus in the burette at a different angle each time. Forgetting to rinse the flask after one of the titrations. What is the index of hydrogen deficiency (IHD) for this molecule? NS30. -13- N16/4/CHEMI/SPM/ENG/TZOIXX Astudent measured the change in mass on heating a sample of calcium carbonate, CaCO, (s) ‘What is the mass loss? 001 001 Mass before heating: 2.347: Mass after heating: 2.001 A. 0.346g + 0.001 B. 0.346g + 0.002 C. 0.35g+0.002 D. 0.359 + 0.001