-3- M18/4/CHEMI/SPM/ENG/TZ2/XX What is the sum of the coefficients when the equation is balanced with the lowest whole number ratio? __Na,S,0, (aq) + __HClI (aq) -» __S (s) +__SO, (g) +__NaCl (aq) + __H,0 (|) A 6 B 7 cc 8 Dg What is the number of atoms of oxygen in 2.0 mol of hydrated sodium carbonate, Na,CO,*10H,0? Avogadro's constant, L or N), : 6.02 x 10% mol” A 6 B. 26 Cc. 36« 10" D. 1.6.x 10% What is the volume, in cm’, of the final solution if 100cm? of a solution containing 1.42g of sodium sulfate, Na,SO,, is diluted to the concentration of 0.020moldm*? 1M, (Na,SO,) = 142 A 50 B. 400 c. 500 D. 600 Turn overM18/4/CHEMISPM/ENG/TZ2/XX What is the percentage yield when 2.09 of ethene, C,H,, is formed from 5.0g of ethanol, CH.OH? M, (ethene) = 28; M, (ethanol) = 46 a 20, 5.0 28 ag “100 20 a By 28-100 46 28, 5.0 20° 46 28 20, DB x100 46 100 What is the composition of the nucleus of “Mg? Protons Neutrons. Electrons A 12 14 12 B. 14 12 0 c. 14 12 14 D. 12 14 0 Which electron transition emits energy of the longest wavelength?-5- M18/4/CHEMISPM/ENG/TZ2/XX 7. Which increase across a period from left to right? A ionic radius electronegativity B. atomic radius ionic radius c ‘st ionization energy atomic radius D. ‘st ionization energy electronegativity 8. — Which element is in the p-block? A Pb B. Pm Cc. Pt D. Pu 9. Whatis the formula of magnesium nitride? A. MgN 8. Mg.N, Cc. Mg.N D. Mg.N, 10. Which species has the longest carbon to oxygen bond length? A co B. CH,OH Cc. CH,CO, D. H,CcO Turn over11. 12. 13. -6- M18/4/CHEMI/SPM/ENG/TZ2/XX ‘What are the predicted electron domain geometries around the carbon and both nitrogen atoms in urea, (NH,),CO, applying VSEPR theory? Carbon atom Nitrogen atoms A trigonal planar trigonal pyramidal B. trigonal planar tetrahedral Cc. tetrahedral tetrahedral D. trigonal pyramidal trigonal planar ‘The compounds shown below have similar relative molecular masses. What is the correct order of increasing boiling point? ‘A. CH,COOH < (CH,),CO < (CH,),CHOH B. CH,COOH <(CH,),CHOH <(CH,),CO ©. (CH,),CO < CH,COOH < (CH,), HOH D. (CH,),CO <(CH,),CHOH < CH,COOH Which describes the reaction shown in the potential energy profile? products Enthalpy reactants Reaction coordinate The reaction is endothermic and the products have greater enthalpy than the reactants The reaction is endothermic and the reactants have greater enthalpy than the products. The reaction is exothermic and the products have greater enthalpy than the reactants, 90 @ > The reaction is exothermic and the reactants have greater enthalpy than the products.-7- M18/4/CHEMI/SPM/ENG/TZ2/XX 14. Whats the enthalpy change of combustion of urea, (NH,),CO, in kJ mo"? 2(NH,),CO (s) + 30, (g) > 2CO, (g) + 2N, (g) + 4H,0 (\) AH, / kJ mor” (NH,),CO (8) 333 CO, (g) =394 H,0 () 286, A. 2x (-333)- 2x (-394) - 4 x (-286) 8. ; [2 x (394) + 4 x (-286) - 2 x (-333)] C. 2x (-394) +4 x (-286) - 2 x (-333) D. ; [2 x (-333) — 2 x (-394) - 4 = (-286)] 15. Two 100cm” aqueous solutions, one containing 0.010mol NaOH and the other 0.010 mol HCl, are at the same temperature. When the two solutions are mixed the temperature rises by »°C. ‘Assume the density of the final solution is 1.00g cm”. Specific heat capacity of water = 4.18J g' K" ‘What is the enthalpy change of neutralization in kJ mol"? A, 200x4.18x5 “4000 «0.020 gp. 200x4.18xy * 1000x0.010 100% 4.18xy 1000%0.010 2004.18 x(y-+273) 7000%0.010 Turn over-8- M18/4/CHEMI/SPM/ENG/TZ2/XX 16. The potential energy profile for the reversible reaction, X + Y =Z is shown 17. 18. Enthalpy Reaction coordinate Which arrow represents the activation energy for the reverse reaction, Z —> X +, with a catalyst? Which factors can affect the rate of reaction? |. Particle size of solid reactant Il. Concentration of reacting solution Il Pressure of reacting gas A. Land Il only 8. landilionly C. Mand itl only D. land it Which factor does not affect the position of equilibrium in this reaction? 2NO; (g) = N-O, (9) AH =-58kJmol™ Change in volume of the container Change in temperature Addition of a catalyst 90 9 > Change in pressure-9- M18/4/CHEMI/SPM/ENG/TZ2/XX 19. Activity series of selected elements’ K, Ca, Al, Fe, H, Cu, Ag, Au greatest activity cu IL CuO Ml Cuco, and Il only Vand til only and Ill only 1, Hand Ill 20. Which statement is correct? Astrong acid is a good proton donor and has a strong conjugate base weak acid is a poor proton acceptor and has a strong conjugate base. Astrong acid is a good proton donor and has a weak conjugate base strong base is a good proton donor and has a weak conjugate acid. 21. Which element has the same oxidation number in both species? A B. c. D. Cin C,H, and CO, Hin H,0 and NaH Sin SO,” and SO, in H,0, and H,0 22. Which can describe oxidation? A B, c. D. Loss of hydrogen Decrease in oxidation number Gain of electrons Loss of oxygen Turn over23. 24. 25. 26. -10- M18/4/CHEMI/SPM/ENG/TZ2/XX What are the products of the electrolysis of molten zinc bromide? Negative electrode (cathode) Positive electrode (anode) A. zine bromine B. hydrogen bromine c bromine zine D. bromine hydrogen Which compounds belong to the same homologous series? A. CHCCH,CH,, CHCCH,CH,CH, 8. CH,CH,CH,CH,OH, CH,CH,OCH,CH, C. CH,CHCH,, CH,CH,CH,CH, D. CH,COCH,, CH,CH,OCH, ‘What is the name of this compound, using IUPAC rules? CH; H ° | | #7 ann CHy H OH 1,4-dimethyipropanoic acid 3,3-dimethylpropanoic acid 2-methylbutanoic acid 90 @ > 3-methylbutanoic acid ‘What is the mechanism for the reaction of propene with iodine in the dark? A. electrophilic addition 8. electrophilic substitution C. free radical substitution D. nucleophilic substitution27. 28. 29. 30. a1t- Which are structural isomers? 99 7 > |. CH,CH,OH and CH,OCH, Il, HOCH,CH, and CH,CH,OH Ill CH,COOH and HCOOCH, land Il only Vand Ill only Wand Ill only |, and Ill M18/4/CHEMI/SPM/ENG/TZ2/XX Which feature of a molecule does infrared spectrometry detect? A B. c. D. molecular mass bonds present total number of protons total number of proton environments How are the uncertainties of two quantities combined when the quantities are multiplied together? A B. c. D. Uncertainties are added. % uncertainties are multiplied Uncertainties are multiplied % uncertainties are added, The rate of a reaction is studied at different temperatures. Which is the best way to plot the data? xaxis ‘Type of variable on x-axis rate dependent rate independent temperature independent temperature dependent