-3- M17/4/CHEMI/SPM/ENGITZ2IXX What is the sum of the coefficients when the equation is balanced with whole numbers? —CsH,3(9) +_O2(g) > _CO(g) +_H,0()) 265 30 53 909 > 61 How many moles of oxygen atoms are there in 0.500mol of hydrated iron(Il) ammonium sutfate, (NH,),Fe (SO,),*6H,0 (8)? A 4.00 8. 7.00 c. 8.00 D. 14.00 ‘What is the maximum volume, in dm?, of CO, (g) produced when 1.00g of CaCO, (s) reacts with 20.0¢m? of 2.00moldm™ HCl(aq)? CaCO, (s) + 2HCl(aq) > CaCl, (aq) + H,0(l) + CO, (9) Molar volume of gas = 22.7 dm? mot"; M,(CaCO,) = 100.00 1 20.0 x 2.00 A ox SAS 227 2 1000 pg 20.02.00», 1000 c 1 x a97 100.00 D. 1009x227 100.00 Turn over-4- M17/4/CHEMISPM/ENG/TZ2XX Which factors affect the molar volume of an ideal gas? 1 Pressure Il Temperature Ml, Empirical formula land Il only and Ill only and Ill only 99 @ > I, Mand Il ‘What does “Mg” represent? A. Anion with 12 protons and 24 neutrons B. Anion with 14 protons and 24 neutrons C. Anion with 12 protons and 12 neutrons D. Anion with 12 protons and 22 neutrons: Which electron transition emits radiation of the longest wavelength? a (—_ n=3 jo c —————— 2 a B A Which property increases down Group 1, the alkali metals? A. Atomic radius B. _ Electronegativity C. First ionization energy D. Metting point10. 1. -5- M17/4/CHEMISPM/ENG/TZ2XX Which element is a lanthanide? A Hf B Tb cou DY How many bonding electrons are there in the urea molecule? HON, Ne ae HN A 8 8 16 c. 2 D. 24 Which bonds cause the boiling point of water to be significantly greater than that of hydrogen sulfide? A. London (dispersion) B. Covalent Cc. lonic D. Hydrogen ‘What are the approximate bond angles and structure of crystalline SiO,? o-Si-0 Structure A 90 giant molecule B. 109 giant molecule c 180 small molecule D. 180 giant molecule Turn over12. 13. 14. -6- M17/4/CHEMISPM/ENG/TZ2XX Which metal has the strongest metallic bond? A B. c. D. i Na kK Rb What can be deduced from this reaction profile? 90 @ > Reactants Enthalpy Products Reaction coordinate The reactants are less stable than the products and the reaction is exothermic. The reactants are less stable than the products and the reaction is endothermic. The reactants are more stable than the products and the reaction is exothermic. The reactants are more stable than the products and the reaction is endothermic. Why is the value of the enthalpy change of this reaction calculated from bond enthalpy data less accurate than that calculated from standard enthalpies of formation? 99 @ > 2C,H,(g) + 70,(g) > 4CO,(g) + 6H,0 (9) All the reactants and products are gases. Bond enthalpy data are average values for many compounds. Elements do not have standard enthalpy of formation. Standard enthalpies of formation are per mole.15. -T- M17/4/CHEMISPM/ENG/TZ2XX What can be deduced from the facts that ozone absorbs UV radiation in the region of 340nm and molecular oxygen in the region of 242nm? A B. c. D. The bond between atoms in molecular oxygen is a double bond. The bonds in ozone are delocalized The bonds between atoms in ozone are stronger than those in molecular oxygen. The bonds between atoms in molecular oxygen need more energy to break. Questions 16 and 17 refer to the following reaction. 16. 17. CaCO, (s) + 2HCl(aq) > CaCl, (aq) + H,0(U) + CO, (9) Which change does not increase the initial rate of reaction when CaCO, (s) is added to excess HCl(aq)? A B. c. D. Decrease in the size of the CaCO, (s) particles, Increase in the temperature of the reaction mixture Increase in the concentration of HCl(aq), keeping the same volume Increase in the volume of HCl(aq), Keeping the same concentration Which methods can be used to monitor the progress of this reaction? 09 Oop > |. Change in colour of this reaction mixture Il. Change in mass of this reaction mixture Il Change in volume of gas evolved Vand Il only and Ill only I and Ill only 1, Mand ll Turn over18. 19. 20. -8- M17/4/CHEMI/SPM/ENGITZ2IXX What is the equilibrium constant expression, K,, for the following reaction? 2NH, (9) + 20; (g) = NO (9) + 3H,0(g) 3[H.O][N.O} * FINK, }2[0, INP LOF * Nolo 2{nt,]210.] “SMO D. Which of the following does not react with dilute HCl(aq)? Extract from activity series Na Increasing] zn activity) 4 cu A. Na,CO, B. cu Cc. Zn D. CuO Which of the following is correct? A. Aweak acid is a proton donor and its aqueous solution shows good conductivity B. Aweak acid is a proton donor and its aqueous solution shows poor conductivity C. Aweak acid is a proton acceptor and its aqueous solution shows good conductivity D. —Aweak acid is a proton acceptor and its aqueous solution shows poor conductivity2. 22. 23. -9- M17/4/CHEMISPM/ENG/TZ2XX Which element is reduced in the following decomposition? (NH,);,Cr,0; (8) — N,(g) + Cr,0;(s) + 4H,0(9) AON BOoOH Cc cr DB 0 Which of the following is not a redox reaction? A. CH,(g) +Cl,(g) > CH,CL(g) + HCL(g) B. C(s)+0,(g) > CO, (g) C. 260(g) + CO, (g) + C(s) D. CH,COOH (aq) + NaOH (aq) -> CH,COONa (aq) + H,0() What occurs at the anode (positive electrode) during the electrolysis of molten strontium bromide? A. Formation of bromine and oxidation B. Formation of bromine and reduction C. Formation of strontium and oxidation D. Formation of strontium and reduction Turn over-10- M17/4/CHEMISPM/ENG/TZ2XX 24. Which functional group is present in paracetamol? OH won CH; A. Carboxyl B. Amino Cc. Nitrile D. Hydroxyl 25. Which describes the reaction between a halogen and ethane? Mechanism Bond fis: halogen A free radical homolytic B. free radical heterolytic c addition homolytic D. addition heterolytic 26. Which conditions are used to convert ethanol to ethanal? A. Excess oxidizing agent and reflux Excess oxidizing agent and distillation. Excess ethanol and reflux 9909 Excess ethanol and distillation27. 28. 29. -n- M17/4/CHEMISPM/ENG/TZ2IXX Which compound contains a secondary carbon atom? A. CH,CH(CI)CHI(CH,), B. — (CH,),CHCH,CL C. (CH,),CCL D. CH,CH,CL Which information can be gained from an infrared (IR) spectrum? ‘A. Ionization energy of the most abundant element, B. Number of different elements in the compound C. Bonds present in a molecule D. Molecular formula of the compound What can be deduced from the following 'HNMR spectrum? (aes es Se ne ne Ss ne a 70 9 8 7 6 5 4 3 2 14 «0 Chemical shift / ppm There is only one hydrogen atom in the molecule. There is only one hydrogen environment in the molecule. The molecule is a hydrocarbon. oOo @ > There is only one isotope in the element. Turn over-12- M17/4/CHEMISPM/ENG/TZ2XX 30. Whats the graphical relationship between n and T in the ideal gas equation, pV = nRT, all other variables remaining constant? A B.