-3- M18/4/CHEMI/SPM/ENG/TZ1/XX Which is a homogeneous mixture? A. Oiland water B. Sand and water Cc. Ethanol and water D. Chalk and sand What is the molecular formula of a hydrocarbon containing 84.6% carbon by mass with a molar mass of 142.3g mot"? A CyHy BL CH CCH, DCH, Which graph shows the relationship between the volume and pressure of a fixed mass of an ideal gas? oa 2 Pressure Pressure Volume Volume Pressure Pressule Volume Volume Turn over-4- M18/4/CHEMI/SPM/ENG/TZ1/XX What is the percentage yield when 7g of ethene produces 6g of ethanol? M, (ethene) = 28 and M, (ethanol) = 46 C,H,(9) + H,0 (9) > C,H-OH (9) 6x7 «100 28x46 646x100 7 «28 6x28 746x400 628x100 7x46 Which shows the number of subatomic particles in 'P*? Protons Neutrons | Electrons A 15 16 18 B. 15, 16 12 c. 16 31 15 D. 3 31 15 Which are correct statements about the emission spectrum of hydrogen in the visible region? |. The red line has a lower energy than the blue line, Il. The lines converge at longer wavelength. Ill. The frequency of the blue line is greater than the frequency of the red line A. Land Il only B. land Ill only C. Mand Ill only D. I, Mand tl10. -5- M18/4/CHEMISPM/ENG/TZ1/XX Which describes the oxide of sodium, Na,O? Bonding | Soni afaeetety | atous A covalent as a solid and liquid low B. covalent as a solid only high Cc. ionic as a solid and liquid low D. ionic asa liquid only high Which statement is correct? A. Atomic radius decreases down group 17. 8. First ionization energy decreases down group 1 C. Atomic radius increases across period 3 from Na to Cl D. First ionization energy decreases across period 3 from Na to Cl. ‘What is the formula of ammonium phosphate? A. (NH,),PO, B. (NH,),PO, C.— (NH,),PO, D. —(NH,),PO, Which form of carbon is the poorest electrical conductor? A. Graphite 8. Graphene C. Diamond D. Carbon nanotube Turn over1. 12. 13. -6- M18/4/CHEMI/SPM/ENG/TZ1/XX What is the molecular geometry and bond angle in the molecular ion NO,-? Molecular geometry | Bond angle tetrahedral 109.5° trigonal planar 120° trigonal pyramidal 107° trigonal planar 109.5° What are the strongest intermolecular forces between molecules of propanone, CH,COCH,, in the liquid phase? A. London (dispersion) forces 8. Covalent bonding C. Hydrogen bonding D. _Dipole-dipole forces The enthalpy of combustion of ethanol is determined by heating a known mass of tap water ina glass beaker with a flame of burning ethanol Which will lead to the greatest error in the final result? A B. Assuming the density of tap water is 1.0gem? Assuming all the energy from the combustion will heat the water Assuming the specific heat capacity of the tap water is 4.18Jg"K" Assuming the specific heat capacity of the beaker is negligible-T- M18/4/CHEMI/SPM/ENG/TZ1/XX 14. What is the enthalpy of combustion of butane in kJ mol"? 15. 16. 2C,H,_ (g) + 130, (g)-> 8CO, (g) + 10H,0(\) C(s) +0, (9) > CO, (9) AH=xkJ H,(g)+ 40,05 H,0(0) AH=ykJ AC (s) + 5H, (g) > C,H,9(9) AH==kd 4x +5y—2 4x + 5y 8x + 10y—2= Br + Sy 425 Which statement is correct? In an exothermic reaction, the products have more energy than the reactants. In an exothermic reversible reaction, the activation energy of the forward reaction is greater than that of the reverse reaction. In an endothermic reaction, the products are more stable than the reactants. In an endothermic reversible reaction, the activation energy of the forward reaction is greater than that of the reverse reaction. Which change increases the rate of formation of hydrogen when zine reacts with excess hydrochloric acid, assuming all other conditions remain the same? 90 @ > Zn(s) + 2HCl (aq) —» ZnCl, (aq) + H, (g) Adding water to the hydrochloric acid Decreasing the temperature Increasing the volume of hydrochloric acid Decreasing the size of the zinc particles while keeping the total mass of zinc the same Turn over17. 18. 19. Which statements are correct? M18/4/CHEMI/SPM/ENG/TZ1/XX |. The activation energy of a reaction is not affected by temperature. Il. Acatalyst reduces the enthalpy change of a reaction, Ill, Catalysts provide alternative reaction pathways. Jand Il only and Ill only Wand Ill only 90 @ > |, land Ill The equilibrium constant for N, (g) + 3H, (g) = 2NH, (g) is K. What is the equilibrium constant for this equation? 2N, (9) + 6H; (g) = 4NH; (9) AK B. 2k a K Dak Which classification is correct for the reaction? H,PO, (aq) + H,0 (\) > HPO,” (aq) + H,0° (aq) Bronsted-Lowry Acid | Bronsted-Lowry Base A H,0 HPO, 8. HPO. HPO, c. HPO, HO" D. HPO, H,O20. 241. 22. 23. -9- M18/4/CHEMISPM/ENG/TZ1/XX What are the products of the reaction between sulfuric acid and sodium hydrogen carbonate? A. NaSO,+H,0+CO, B. Na,S0,+CO, Cc. Na,SO,+H,0 +CO, D. NaSO,+H,CO, Which equation shows oxygen undergoing reduction? A. 2F,+0,2F,0 8B. Na,O +H,0 > 2NaQH C. _H,O,+2HT > 2H,0 +1, D. 2CrO,*+2H*= Cr,0,7 +H,0 What are the products of electrolysis when molten calcium bromide is electrolysed using graphite electrodes? Product at cathode (negative electrode) Product at anode (positive electrode) A calcium bromine B. bromine calcium c. calcium ions bromide ions D. bromide ions calcium ions Which coefficients correctly balance this redox equation? aFe* (aq) + MnO, (aq) + bH’ (aq) > cFe* (aq) + Mn**(aq) + dH,0 (\) a b d A 1 8 4 B. 5 4 2 c 3 4 2 D. 5 8 4 Turn over-10- M18/4/CHEMI/SPM/ENG/TZ1/XX 24. What are possible names of a molecule with molecular formula C,H,,0? |. 4-Methoxypropane I 2-Methylpropan-2-o1 Ml. Butanal A. andl only B. land Ill only C. Mand It! only D. | Mand itt 25. What is the product of the reaction between hex-3-ene and steam? A. Hexan-1-o1 B. Hexan-2-0l C. Hexan-3-ol D. Hexan-4-ol 26. Which of these reactions proceeds by a free radical mechanism in the presence of UV light? A. CH,+ CL C,H,Cl + HCL BCH. +3H,> CH, ©. CH,CH,+ HBr —> CH,CH,Br D. (CH,CH, + Cl, -» CH,CH,Cl + HCL 27. Which compound could be formed when CH,CH,CH,OH is heated with acidified potassium dichromate(V1)? | CH,CH,CHO IL (CH,CH,COOH ML CH,COCH, Vand tl only Vand Ill only and II! only 9090p > 1, Hand Ill28. 29. 30. -1- M18/4/CHEMI/SPM/ENG/TZ1/XX Which value of g, in J, has the correct number of significant figures? q=meaT where m = 2.5009, ¢= 4.18Jg"K” and AT=0.60K. A 6 B. 63 Cc. 627 D. 6.270 What is the index of hydrogen deficiency, IHD, of 3-methylcyclohexene? ‘CH A 0 B41 c 2 D3 What is the ratio of the areas of the signals in the 'H NMR spectrum of pentan-3-ol? A. 6:41: B 6.22.2 C8514 D. 33:22:41