-3- M17/4/CHEMISPM/ENG/TZ1XX Which compound has the greatest percentage by mass of nitrogen atoms? A B. c. D. NH, NH, NO, NaNo, Which statements about mixtures are correct? 99 @ > |. The components may be elements or compounds. IL All components must be in the same phase. lil. The components retain their individual properties. land Il only and Ill only and It! only I, Mand Il 5.0cm? of 2.00mol dm”? sodium carbonate solution, Na,CO, (aq), was added to a volumetric flask and the volume was made up to 500cm* with water. What is the concentration, in moldm”®, of the solution? A. 0.0050 B. 0.0040 Cc. 0.020 D. 0.010 Turn over-4- M17/4/CHEMISPM/ENG/TZ1UXX What is the expression for the volume of hydrogen gas, in dm*, produced at STP when 0.30g of magnesium reacts with excess hydrochloric acid solution? Mg(s) + 2HCl(aq) > MgCl, (aq) + H, (9) Molar volume of an ideal gas at STP = 22.7dm’mol* A, 0:30 x 2% 22.7 24.31 0.30 x 22.7 24.31 0.30 x 24.31 22.7 0.30 x 22.7 24.31% 2 In which set do all the species contain more electrons than neutrons? A N,"0,"C *N,0, "C* B. c. D. Which electron transition in the hydrogen atom emission spectrum emits radiation with the longest wavelength? A n=23n 1 Bo n=1—n=2 Cc n=45-5- M17/4/CHEMI/SPM/ENGITZ1UXX The full electron configuration of an element is: 48° 2s? 2p° 35° 3p" To which group and period does the element belong? Group Period A 2 3 8. 3 2 ©. 3 4 D. 14 3 Which oxide, when added to water, produces the solution with the highest pH? A. Na,O B. SO, Cc. MgO D. co, substance has the following properties: Elect Molten Solid 1414 poor poor Melting point /°C. What is the most probable structure of this substance? A. Network covalent B. Polar covalent molecule C. Ionic lattice D. Metallic lattice Turn over10. 11. 12. - M17/4/CHEMISPM/ENG/TZ1UXX Which two atoms form the most polar bond? A. CandF B. Candcl Cc. SiandF D. Siandct Which combination describes the sulfate(IV) ion, SO,* (also known as suffite ion)? vlmoine steunds. | geomet" | Molecular geometry | 0-8-0 angle A 3 trigonal planar trigonal planar 120° 8 3 tetrahedral trigonal pyramidal 1095 c. 4 trigonal pyramidal | trigonal pyramidal 107° D. 4 tetrahedral trigonal pyramidal 107° Which correctly states the strongest intermolecular forces in the compounds below? cH, CHCl CH,NH, A dipole-dipole London forces hydrogen bonding 8. London forces, dipole-dipole hydrogen bonding c. hydrogen bonding London forces dipole-dipole D. London forces hydrogen bonding dipole-dipole13. 14, 15. -T- M17/4/CHEMISPM/ENG/TZ1XX Which expression gives the mass, in g, of ethanol required to produce 683.5kJ of heat upon complete combustion? (M, for ethanol = 46.0, AH? = ~1367kJ mor") 683.5 1367 x 46.0 1367 683.5 x 46.0 683.5 x 46.0 1367 1367 x 46.0 683.5 Which expression gives the enthalpy change, AH, for the thermal decomposition of calcium carbonate? Caco,(s) AH , = Cad(s) +CO,(g) 2HCl(aq) 2HCl(aq) AH, AH; CaCly(aq) + H,0W0) +CO,(a) A. AH=AH,—AH, 8. AH=2AH,— AH, ©. AH=AH,-2AH, D. AH= AH, + AH, In which order does the oxygen-oxygen bond enthalpy increase? A. H,0,<0,<0, B. H,0, <0, <0, ©. 0,<0, ZnSO, (aq) + H, (9) Why does copper affect the reaction? A B. c. D. Decreases the activation energy Increases the activation energy Increases the enthalpy change Decreases the enthalpy change 10cm’ of 10% hydrogen peroxide solution decomposes at 298K to form water and oxygen. 1,0,(2q) > H.0() + 30.9) ‘The dotted line graph represents the volume of oxygen produced. Volume of oxygen gas / cm? Time /s Which graph represents the decomposition of an equal volume of a 20% solution under the same conditions?18. 19. 20. -9- Consider the equilibrium between N,O, (g) and NO, (g) N,0, (g) = 2NO, (g) Which changes shift the position of equilibrium to the right? 1. Increasing the temperature Il. Decreasing the pressure Ill, Adding a catalyst A. Land Il only 8B. landill only Cc. Mand III only, D. I,lland it Which is an acid-base conjugate pair? A. O/H” B. H,S0,/S0, C. CH,COOH/H,0° D. CH,NH,* / CHNH, Which 1.0moldm” solution has the highest pH? A. Ammonium chloride B. Sulfuric acid C. Sodium chloride D. Ammonia AH = +58kJ mol” M17/4/CHEMISPM/ENG/TZ1XX Turn over2. 22. 23. 24. -10- M17/4/CHEMI/SPM/ENGITZ1UXX What is the order of decreasing reactivity of the metals (most reactive first)? Zn(s) + Sn’*(aq) > Zn** (aq) + Sn(s) Cu(s) + Zn® (aq) > No Reaction ‘Sn(s) + Cu**(aq) »Sn* (aq) + Cu(s) ‘Ag(s) + Cu**(aq) > No Reaction A. Zn>Cu>Sn>Ag B. Sn>Zn>Ag>Cu ©. Ag>Cu>Zn>Sn D. Zn>Sn>Cu>Ag What is the oxidation half-equation in the redox reaction? 28,0," (aq) + 1, (aq) > $0," (aq) + 2 (aq) A. I(aq) +2e° > 2(aq) B. 21 (aq) > 1,(ag) +2" C. 28,0," (aq) > 8,0,"(aa) + 27 D. S,0,* (aq) + 2e — 28,0," (aq) Which statements are correct for a voltaic cell? |. Aspontaneous redox chemical reaction produces electrical energy. IL Oxidation occurs at the cathode (negative electrode). UL Electrons flow from anode (negative electrode) to cathode (positive electrode). A. Land Il only B. Landi only C. Iland Ill only D. 1, Mand Il What is the order of increasing boiling point? A. C,H, |. Mand Ill 26. What is the name of the compound with this molecular structure applying IUPAC rules? OH ‘1-methylpropanoic acid 2-methylpropanoic acid 2-methylbutanoic acid 99 @ > 3-methylbutanoic acid Turn over27. 28. 29. 30. -12- M17/4/CHEMI/SPM/ENGITZ1UXX Which molecule has a tertiary nitrogen? A. (CH,),NH 8. (CH).NT ©. C.H,NICH,), D. C.H.NH, ‘What can be determined about a molecule from the number of signals in its 'H NMR spectrum? A. Bonds present B. Molecular formula C. Molecular mass D. Number of hydrogen environments ‘What is the density, in gem’, of a 34.79g sample with a volume of 12.5¢m°? A 0.359 B. 0.36 Cc. 2783 D. «278 ‘What is the Index of Hydrogen Deficiency (IHD) for 1,3,5-hexatriene (C,H,)? A 4 B83 a 5 D.