Bsn Chaitanya IIT Academy (03-08-2020. sr1COW ALLALT-Prog A AILINDIA -TEST. SERIES Jee-ADV(2018-P2) AFT-10.QP CHEMISTRY SECTION 1 ‘on has FOUR options for correct answer(s). ONE OR MORE THAN ONE. these r tion. to each question wil be is (ae) chosen: 2 IF three or more options are corect ‘or ote options are correct out ONLY one option Marks:-2 nal but ONLY two options are chosen bath of which are S chosen and tis acorect option. Zero Marks Of none other cases. For Example: I fst, thd and fourth are the option, selecting only al the tree cor options} without selecting any ino options (either fst or third ny correct enton rest options. Partial 1g only one of the the correct bot wl resuin +7 marks, eoton() wl reauk 2 marks 1 option inth's case), with or without selection 19. Which statement(s) is/are correct — A) If 0.1M CHCOOH aqueous solution (Ka = 18x10) is diluted at25°C, then* - “wt [] willincrease AT) iw) \ -— Ve wer heating a sample of pure water [#"] and [ou] increases but the sample still remains neutral Yok yoryt - Nar a4 {04M HCI solution is less acidic than 0.1M HON(K, cn =10~ °) solution se 3 wet D) 10°* HCI aqueous solution will have pH exactly equalto8 0° ~ Ns 2 CHy f CH; | Aci rrobysis, | CHy —C-O-C— Ph Sate eS. OH, — C—O + Ph-C—CH ; ; C— CH I 20 CH; OH correct statements regarding the above reaction is/are Free carbocation is involved in the reaction as an intermediate \Y win oxygen bond cleavage takes place C) Acytoxygen bond cleavage takes place \pyheoe formed in the reaction will give immediate turbidity with Lucas reagent Sec: SR’s_All & LT _e-TEST_SERIES ‘space for rough work Page 11Bsn Chaitanya IIT Academy (03-08-2020. sr1COW ALLALT-Prog IA AILINDIA -TEST SERIFS_Joe-ADV(2018-P2) Al 21. Which of the following reaction is/are feasible? ee gal ee Aiken P +20H- + H30, > 2[ Fett), | +2040, 0% wah CN), Janes 1,504 > 2K; Bel CN) +250, 2! 230 aol indy sy 2KOH +2MnOy + 2H0 +30. os sand +2MnOy +2H,0 +30, D)ZKM Made + SHU +3450, -» 20, + KySOq +503 +8H,0 22. gee the correct statement(s)? - Byheaton of Hgly to aqueous solution of K/ increases the freezing point since a complex Haat] fre a coger Ww, ay wy * re aqueous solutions of ammonia labelled as A, B and C with ‘Didstseo 4} concentrations 0.1 M, 0.01 M and 0.001 M respectively, then value of Van't Hoff factor for these solution will be in order ~ i 2B(g)+C(g) the half life for decomposition of Ais 3 minute at 300K Calculate the time (in minute) in which partial pressure of ‘A(g) will drop from 2 bar to 0.5 bar at 400K. Given activation energy of reaction is 840 R. (TakeIn2 =0.7) 26. 2 moles of methane gas are compressed from (1 bar, 2L) to 2 bar isothermally 80 against constant external pressure. Calculate work done in Joules 27. For 10 minutes each, at 0°C, from two identical holes nitrogen and an unknown, gas are leaked into a common vessel of 4 litre capacity. The resulting pressure in p& vessel is 2.8 atm and the mixture contains Q4 moleaf nitrogen. What is the molar mass of unknown gas/mol? (Take R = 0.0821 L—atm—mol'K~!) oF & saN-o1 B80 sproducts. Produets C= 0B OH spr0d Product s Yoh cot 28. * yy ° rie) I “-_ Find out total number of final products? 29. How many of the following compounds given below have faster aromatic 9 et ee we "Cos ‘e nucleophilic substitution rate than 2 ~— Sec: SR’s_All & LT _e-TEST_SERIES ‘space for rough work Page 13ri Chaitanya ITT Academy 03-08-2020. sr1cow ALLALT-frop NAIL NDIA TES. SERIES Jee-ADV(2018-P2) F F NO, NO, 4 ‘i iv) 1) NO. NO, NO, Ss ad, oD 30. Find out total number of moles of Grignard reagent RMgX consumed when treated it with 1 mole of 'X' —_— am Qo 31. Find the n ROE of electrons having nl <1 = amb inPde=46). 32. During extraction of iron, CO is the chief reducing agent. If 72 Kg of carbon is In available and produced CO is completely used to reduce Haematite (present in yr ‘excess amount) then calculate how much Kg of Iron is obtained after reduction. (Given : atomic weight of C-12 g/mol, 0-16 g/mol, Fe-55.85 g/mol) SECTION 3 is secon cotains FOUR (0) avestions Fach aston has TWO (02) atching Iss LISTH.ad LIST. FOUR ootons ee gv e>resenng Sec: SR’s_All & LT _e-TEST_SERIES ‘space for rough work Page 14Bsn Chaitanya IIT Academy (03-08-2020. sr1CON ALLALT-Prog 11 AILINDIA -TEST. SERIES Jee-ADV(2018-P2) AFT-10.QP R) Concentrated aqueous solution of 3) | Ch NaCT — 3h My 33. 7 GW List=I bag List=i (Electrolysis using inert electrode) ‘} (Product at anode or cathode.) | P) [Aqueous solution of sodium acetate” |A) [7 7 Q) | Aqueous solution of sodium formate J 2) | CO, =e Say} §) | Dilute aqueous solution of HCI SY" 14) | Cal% Y 7S nbapdolts O 8 AYP 312,40 312:R 91,3551, 7a si >1,5;0 > 2,4;R 91,8 3,4 WU yrty (C) P14: > 2,4:R > 1,5;5 93,5 LA We (D) P+ 2,409 1,4;R 32,5;5 915 34. Match the list List-I List-Il 4) | lorie organometalic product is P) formed ) | Product can show electrophilic eT addition reaction with HBr (1 eq.) L 8 dh R) — f ateKotr, Ns Reaction involve free radical as = Qos | Beazer ne Number of carbon in parent 8) jaNHy( paraffin) 4) he chain of product is 4 Select CORRECT code for your answer A)P33,4,0>2;R 2,45 91,4 P3,4,0 >2;R>2, sx? M4 C) P>3,4,0 91,2; R > 2,4;8 91,4 D) P>2,3;0 9 2;R 9 2,4,5 91,4 Q) IA or Sec: SR’s_All & LT _e-TEST_SERIES ‘space for rough work Page 15Bsn Chaitanya IIT Academy (03-08-2020, sr1COW ALLALT Prop AILINDIA -TEST SERIES Jee-ADV(2018-P2) AFT-10.QP 35. Match the list: Mb List-I List-Il C (Complex Compounds) (Properties) a3 . Diamagnetic and low spin P) | [Core] a - 1) complex * —* 3. Paramagnetic and outer orbital Q) |[e(Cr0)P 2) complex _ Paramagnetic and inner orbital R) Mary dt 3) complex aT pH en) gy | Paramagnetic and low spin 8) | [Fe(cw), | aA 4) complex The CORRECT option is A) P3102; R 33:8 34 Who 20>38 21s +4 C) P32;091;R 33:8 34 D) P31:0 53;R>2;8 34 36. Match the list: por ' Lst-1 Lst=11 pte % (Complex Compounds) (Properties) 4 | P) | [Ni(#20) Jes x 1) | @SP3 hybridisation Ye [ Sie XZ |? CEI fur ) FE%(eN), (415), JOcatte 2) | lonisation isomerism 71 AMS art 1 AT 3 vy —283 os whevV® R) | [7rcle] 3) | #=2.83 BM 2 BY 7 se ° a s) [Reso Jon, AL 4) | Ay

3,4,0 91; R > 2,3;8 91,2 ‘AW oT = C) P1,2,3;0 9 1,4;R > 4,5;5 > 2,5 D) P>2,3:0>2;R 93,48 91 Sec: SR’s_All & LT _e-TEST_SERIES ‘space for rough work Page 16