Bsn Chaitanya IIT Academy (03-08-2020. sc1CON ALLALT-Prop IAIAILINDIA.e TEST SERIES Jee-ADV(2018-P1)_AFT=10_Q.P CHEMISTRY SECTION 1 (Maximum Marks: 24) . rect NEOR MORE THAN ONE of hese four ot ofa) Selecting any incorrect opton 19, In 1.5 litre, 2M NaOH solution, 320 gm bromine and 0.5 mole acetone are added yee giving colourless dense bromoform liquid. Excess NaOH was back titrated against 0.5M HS, using phenolphthalein as indicator, Volume of H)SO4 required to reach end point is - (Br =80) (Assume that excess NaOH does not react with Br) left and bromoform formed) A) + tre B) _ litre ©) + iitre hi litre 4 2 3 20. Which of the following statements are true about Agl sol prepared by peptization of Agl with AgNO; (excess)? uid ets \ PYM electrophoresis, the disper phase will move towards cathode. B) AéC£; is more effective than Na3PQq for bringing about coagulation of the sol. \pyasP04 is more effective than AlCl for bringing about coagulation of the sol. wy Orerstn dialysis of the sol, precipitation of coloidal sol take place (coagulation) Ls Sadek fe C5") PLA Hoe oul of Sec: SR’s_All & LT _e-TEST_SERIES space for rough work Dh Ou Page 11 enn Paha cated gar. Nemaion Loti .Bs: Chaitanya IIT Academy (03-08-2020. sc ICON ALLALT Prop IAILAILINDIA.e TEST SERIES_Jee~ADV(2018-P1)_AFT=10_Q.P 21. Which of following reaction sequence is/are given correct set of reaction as major final product? » Excess oO 9 9 or : 22. Which of following is/ are correct regarding formation of osazone byhexose « |g ywth sugar? y-& ont a A) 2 mole of phenyl hydrazine consumed in osazone formation. +e y mole of phenyl hydrazine consumed in osazone formation. & nly C, and Cy carbon are involved in osazone formation due to formation of embered transition state , A epimer of reducing hexose sugar gives similar osazone. 7 Guo 23. Which of the following species have integral bond order, gerade type HOMO and paramagnetic nature. wor WE go Sec: SR’s_All & LT _e-TEST_SERIES Space for rough work Page 12 wy? Q Proky —Bsn Chaitanya IIT Academy (03-08-2020. scICoW ALLALT-ProgIRLAILINDIA.e-TEST SERIES Jee-ADV(2018-P1) AFT-10. QP 24. Which of the following properties is/are common amongst the oxy acids Hy$207, H4P:05 and H3P;09 A) Ajthave chain type open structure > ws (Wer), All have X -O -X type linkage (X =central atorn) . sk Mul Og C) Cefttral atom have it's highest oxidation state = ‘atleast one X =O bond is present (X = central atom) SECTION 2 (Maximum Marks: 24) ‘his section contains EIGHT (08) questions, The answer to each questions a NUMERICAL VALUE. For ec question, enter the comect numerical vale 06,-038, 30, 3.27, -127.30) using the mouse andthe on-screen +h question wll be evaluated according tothe following marking scheme (ndecimal notation, truncated tual numeric keypad inthe plac Full Matks #+3if ONLY the cortect numercal value 25. Equivalent conductivity of AgNO3, CaC/y and Ca(NO3), at infinite dilution are 1 as answer Zero Mates 0 val other 110, 230 and 196.507! cm? eqv-! respectively. Conductivity of AgCé(ag.) & HO is \ 2.4x10 Q em! and 1.4 x10 27! em respectively. Find solubility of AgCé in mg/litre. [Atomic mass: Ag = 108, Cé = 35.5] 26. In a parallel first order reaction starting with 1 mol'A’ as: Lm Q a? If A, B &C are optically active with standard optical rotation 15°,10°& — 20° degree ee = per mole respectively then give time in sec when solution will be optically inactive. Given : k = 0.024 sec 1, n2=0.7, In =1.60. Sec: SR’s_All & LT _e-TEST_SERIES Space for rough work Page 13,Bsn Chaitanya IIT Academy 03-08-2020 _scICoN ALLALT-ProgIILAILINDIA.e-TEST SERIES Jee-ADV(2018-P1) AFT-10. QP 27. Apoint source of light of power 3.2 milli watts emit energy of photon 5eV. If the source is located at a distance of 0.8m from the centre of metallic sphere of work function 3 eV and radius 8mm. Number of photoelectrons emitted in 1 sec if a efficiency is 1% is xx10¥ in significant number, then find value of 'y ae (lev=1.6 x 107193) 28. Which of following molecule shows optical isomerism. asa : en ce \ how ae pe CF Me . CHs oH 29. Total number of ore which copcentrated by magnetic separation method. Tin ey? stone consisting of Wolframite, ade Silver glance, Dolomite (in °C) 30. Any metal ‘A’ (sp.gr = 0.8) crystallises in ccp arrangement with atomic radius —— NY 2A then give no. of moles of unit cell in 307.2 gm metal [Use:Na =6 x 103 | Sec: SR’s_All & LT _e-TEST_SERIES ‘Space for rough work Page 14Bsn Chaitanya IIT Academy 31. (03-08-2020, s+1CON ALLALT-Prog BILAILINDIA,©-TEST SERIES Jee-ADV(2018-P1).AFT-10.QP How many of following reaction gives Hoffmann product as a major oon ct? ON te WY sae we Se Wwe gy OY OAc, Seiki ce «A 4) Pho te @ ce dil, HyS0, . Salt 'X" NO observation onc.H SO, . {h) (oe0.} w+ Coloured gas / vapours ous 0 A 9 we Total number of anions which will give coloured gas will be:- a P- ‘TON 3 (Maximum Marks: 12) ‘graph, there are TWO (02) questions, Each question has FOUR options, ONLY ONE»of + each question, enoose the epion coresponding tothe correct answer. An fellowing marang scherne: Full Marke +3 ONLY the corract options is chosen, Zero Marks: Of none Negative Marks : ~1 Inall other cases, This secton contains TWO (@2) paragraphs. Based on each these four options cores willbe evaluated aocoxding to coven (ie the questions un cr question the ations ie PARAGRAPH “xX” (There are two questions based on PARAGRAPH “X’, the question given below is one of them) Complex having same molecular formula but different orientation in space are known as stereoisomers, Answer the following questions ~ Sec: SR’s_All & LT _e-TEST_SERIES Space for rough work Page 15Bs Chaitanya IIT Academy (03-08-2020. sc1CON ALLALT-PropIAILAILINDIA.e TEST SERIES Jee-ADV(2018-P1)_AFT=10_ QP 33. For the octahedral complex Ma,b,c, total number of geometrical isomers is - (where a, b, c are monogentate ligands having achiral center. Aye o4 D)3 34. For the octahedral complex M(AB), (CD) (where (AB) and (CD) caw different bidgatate ligands) C- M—D angle will be in general - approx. 90° B) approx 180° CG 8 ie €) either 90° or 180° D) approx 120° % PARAGRAPH “A” ha et gti esd PARA sen groban SSW Electrophilic aromatic substitution is characterstic reaction of aromatic compounds where substitution of electrophile of reactant takes place under influence of +M/-M group +M group substitute electrophile on O/P position, while -M on —M position if both group present in same aromatic compound substitution takes place according to more activating group. 35. Which of following produce only mono substituted pro mono substituted product on nitration? é CH; “5 a Cols 2.” LD & £0 ys 36. Why acylation followed by reduction with (Zn- Hg / HC) is more suitable to get —_— alkyl benzene in place of direct alkylation in presence of Lewis acid? ~~ A) Digect alkylation not possible. \oY6re alkylation produce alkyl benzene which activates the ring for further alkylation and gives polyalkylated product Sef AO NeT RON . C) Alkylation follows free radical substitutions. D) Acylation followed by reduction give alcohol in place of alkyl benzene Sec: SR’s_All & LT _e-TEST_SERIES Space for rough work ge No Dr QhX ana Sy yet \ don, ay 4 gene MA ay