Operating Manual Volume Section HEAT RECOVERY STEAM GENERATOR Page & Status :1.Feb.1996 TAMBAK LOROK BLOCK 1 & 2 4.6.5 Recommendation for chemical regime 4.6.5.1. General . Conditioning of the water and steam cycle will be performed in accordance with VGB- Guidelines (VGB-R-450 L, see Appendix 1) The conditioning of the water ard steam cycle shall be performed with volatile reagents (ammonia and hydrazine). This mode of operation is called Alkaline Volatile Treatment (AVT). -~ 4.6.5.2. Chemical conditioning of water/steam circuit Conditioning of cycle water and condensate ‘Ammonia and kydrazine will be fed to the condensate to maintain a pH value of approximately 9.5 and a dissolved oxygen concentration of less than 20 ppb respectively. Conditioning of the HP drum with chemical dosing is not required. Blowdown will be used to control buildup of salts and organic acids in the boiler water and steam Blowdown rate will be adjusted to maintain the boiler water below the set limits for cation conductivity and silica. Blowdown will also be used to control high steam conductivity. Provided herein are the control limits that will be used for monitoring and control of the feedwater-condensate-steam cycle chemistry. Those constituents noted in italic print in the tables are not required control points by the manufacturer's. These are suggested limits from EPRI (Electric Power Research Institute), and should be checked weekly to verify that chemistry for that constituent is close to recommended value. Note the steam turbine manufacturer has indicated the AES&E steam limits are acceptable for long term turbine operation HP Boiler Water Quality Limits Constituent ‘Normal Op. Minimum Limits Sampling Cation Conductivity, wSfem <5.0 Continuous Secific Conductivity, pS/em 3.0-60 Continuous pH - value at 25 °C 28.5 Continuous Silica (SiO2), ppm. 28 day Iron (Fe), ppm oa day EPRI Limits 60 Bar/88 Bar Silica, ppm 7.0/2.8 day Chloride, ppm 0,65/0.35 Wday Sodium, ppm 7.0/5.8 Vweek Sulfate, ppm 0.65/0.35, LrveekeSecific Conductivity, pS/em Sodium, ppb Silica, ppb Chloride, ppb Sulfate, ppb Condensate Pump Discharge Limits tie Cation Conductivity, pS/em Secific Conductivity, pS/cm Oxygen, ppb Silica, ppb Iron, ppb Copper, ppb Sodium, ppb Operating Manual HEAT RECOVERY STEAM GENERATOR TAMBAK LOROK BLOCK 1 & 2 Normal Op. Limits 0.20 Not controlled 20 20 20 3.0 6.0 Volume Section Page Status Minimum Sampling Continuous Continuous Continuous Vday LAveek Mi Samy Continuous Continuous Continuous Téweek week day Condensate After Chemical Feed Limits Secific Conductivity, pS/em pH Ammonia, ppm Oxygen, ppd 4.06.0 9.010 9.5 Approx.0.5 20 TABLE 1 Constituent Normal Op. Minimum Li ‘Sampling Continuous Continuous Uday Continuous V6 26/8 :1.Feb.1996Operating Manual Volume Section :4/6 HEAT RECOVERY STEAM GENERATOR Page 25/8 Status :1,Feb.1996 irene a TAMBAK LOROK BLOCK I & 2 HP Steam Quality Limits Normal Op. Minimum Limits Sampling Continuous Continous Constituent Cation Conductivity, wS/om Secific Conductivity, pS/em pH Uday Silica, ppb Continuous - Iron, ppb Livweek Copper, ppb Vweek Sodium, ppd Continuous Chloride, ppb Economizer Inlet Limits Constituent Normal Op. Minimum Limits Sampling Cation Conductivity, Siem 0.20 Continuous Secific Conductivity, pS/em_ 4,0-6.0 Continuous pH 9.01096 Continuous Iron, ppb 10 Lweek Copper, ppb 3.0 week Oxygen, ppb 20 Continuous Hydrazine, ppb 220 Continuous Cycle Makeup LimitsOperating Manual Volume: Section 4/6 HEAT RECOVERY STEAM GENERATOR Page 2718 Status :1.Feb.1996 aoe Ay TAMBAK LOROK BLOCK 1 &2 ‘normal operation: feedwater cond, 2, Cat. © 0,2 uS/em, oxygen < 0,020 mat fa Make up water: Cant se eae sta organic Sasa TET ea] —— fev 20 oo Feecwaters Akal. with NH {8k NHO (25%) for 1901 dosscoion 3 Condoroats ine Canacey = CER REATE EE Tse eas ‘Seaside ee igen) —[eo- a7 prwns at 35" sete Semana (NDT ag ae iran 6) [iret ea “cooper (Guy T Irngaif [= 0.003, Seiaen (O27 (rail [zou shes00 (S07) ce f te HP- Beilerwaterino additional seatmont ‘Cangucivi a eareneechanger 7S TSeay Conduciviy direct 28°€ fuser) pHevaige at 25" phorpaae POW] Tea sie 3819 (S102 [teed Live steam : Conducta #1 Slenexoranger 77E [sen] 1035 ‘Sonauetiity direct 25" [useem, 39-50 private at 25" 39-33 ‘aramania (NH Tag I-05) Trond Fe | ior re0.030 cesper (Guy grit 0.005 sie acta SOFT inary 0.020 ryeregen (HZ) ocrOperating Manual Volume Section HEAT RECOVERY STEAM GENERATOR Page Status :1.Feb.1996 ream e) TAMBAK LOROK BLOCK I & 2 TABLE 2 PH ~ value as function of conductivity ‘aicalinization wit NH pH ~ value as function of content alkalinization with NHS content Nia tert