JEE Advanced 2015

QUE
ES
STIO
ONN PAP
P PER
R
(Pape
er-1, Code-5 | Paper
P r-2, Co
ode-6)
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JEE ADVANCED 2015
CODE-5 : QUESTIONS
PAPER-I
PHYSICS
1. A bullet is fired vertically upwards with surface of water are given by x2 = p2m22–d2,
velocity  from the surface of a spherical where  is the wavelenght of light in air
planet. When it reaches its maximum height, (refractive index = 1), 2d is the separation
its acceleration due to the planet’s gravity is between the slits and m is an interger. The
1/4th of its value at the surface of the planet. value of p is
If the escape velocity from the planet is
v esc  v N , then the value of N is (ignore
energy loss due to atmosphere)

2. Two identical uniform discs roll without

slipping on two different surface AB and CD
(see figure) starting at A and C with linear
speeds v1 and v2, respectively, and always
remain in contact with the surfaces. If they
reach B and D with the same linear speed
and v1 = 3 m/s, then v2 in m/s is (g = 10
m/s2)
6. Consider a concave mirror and a convex lens
(refractive index = 1.5) of focal length 10
cm each, separated by a distacne of 50 cm
in air (refractive index = 1) as shown in the
figure. An object is placed at a distacne of
15 cm from the mirror. Its erect image formed
by this combination has magnification M1.
When the set-up is kept in a medium of
refractive index 7/6, the magnification
M2
becomes M2. The magnitude M is
1

3. Two spherical stars A and B emit blackbody

radiation. The radius of A is 400 times that
of B and A emits 104 times the power emitted
7.
 A 
from B. The ratio    of their wavelengths
 B
A and B at which the peaks occur in their
respective radiation curves is
4. A nuclear power plant supplying electrical
power to a village uses a radioactive material
of half life T years as the fuel. The amount of
fuel at the beginning is such that the total
power requirement of the village is 12.5% of
An infinitely long uniform line charge
distribution of charge per unit length  lies
parallel to the y-axis in the y-z plane at
3
z a (see figure). If the magnitude of
2
the flux of the electric field through the
rectangular surface ABCD lying in the x-y
L
plane with its centre at the origin is n (0
0

the electrical power available from the plant permittivity of free space), then the value of
at that time. If the plant is able to meet the n is
total power needs of the village for a
maximum period of nT years, then the value
of n is

5. A you n g’s dou ble sli t in t erf eren ce

arrangement with slits S1 and S2 is immersed
in water (refractive index = 4/3) as shown in
the figure. The positions of maxima on the
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8. Consider a hydrogen atom with its electron 12. Consider a Vernier capplipers in which each 1
in the nth orbital. An electromagnetic radiation cm on the main scale is divided into 8 equal
of wavelength 90 nm is used to ionize the divisions and a screw grauge with 100
atom. If the kinetic energy of the ejected divisions on its circular scale. Inthe Vernier
electron is 10.4 eV, then the value of n is callipers, 5 divisions of the Verner scale
(hc = 1242 eV nm) coincide with 4 divisions on the main scale
and in the screw gauge, one complete
rotation of the circular scale moves it by two
9. A container of fixed volume has a mixture of
divisions on the linear scale. Then :
one mole of hydrogen and one mole of helium
(A) If the pitch of the screw gauge is twice
in equilibrium at temperature T. Assuming the
the least count of the Vernier callipers, the
gases are ideal, the correct statement(s) is
least count of the screw gauge is 0.01 mm.
(are)
(B) If the pitch of the screw gauge is twice
(A) The average energy per mole of the gas
the least count of the Vernier callipers, the
mixture is 2RT.
least count of the screw gauge is 0.005 mm.
(B) The ratio of speed of sound in the gas
(C) If the least count of the linear scale of
mixture to that in helium gas is 6 /5 . the screw gauge is twice the least count of
(C) The ratio of the rms speed of helium atoms the Vernier callipers, the least ount of the
to that of hydrogen molecules is 1/2. screw gauge is 0.01 mm.
(D) The ratio of the rms speed of helium atoms (D) If the least count of the linear scale of
the screw gauge is twice the least count of
to that of hydrogen moleucles is 1 / 2 .
the Vernier callipers, the least count of the
10. In an aluminum (Al) bar of square cross screw gauge is 0.005 mm.
section, a square hole is drilled and is filled
with iron (Fe) as shown in the figure. The 13. planck’s constant h, speed of light c and
electrical resistivities of Al and Fe are 2.7 × gravitational constant G are used to form a
10–8 m and 1.0 × 10–7 m, respectively. unit of length L and a unit of mass M. Then
The electrical resistance between the two the correct option (s) is (are).
faces P and Q of the composite bar is
(A) M  c (B) M  G
2475
(A)  (C) L  (D) L 
64 h G
1875
(B) 
64 14. Two independent harmonic oscillators of
equal mass are oscillating about the origin
1875
(C)  with angular frequencies 1 and 2 and have
49 total energies E1 and E2, respectively. The
2475 variations of their moments p with positions
(D)  x are shown in the figures. If a/b = n2 and a/
132
R = n, then the correct equation(s) is (are)
11. For photo-electric effect with incident photon p p
wavelenght , the stopping potential is V0. Energy=E1 Energy=E2
Identify the correct variation(s) of V0 with 
and 1/. b
x x
a R

(A) (B)

2 2
(A) E12 = E22 (B)   n
1
(C) (D)
E1 E2
(C) 12 = n2 (D)   
1 2

15. A ring of mass M and radius R is rotating

with angular speed  about a fixed vertical
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axis passing through its centre O with two 17. Two identical glass rode S1 and S2 (refractive
M index = 1.5) have one convex end of radius of
point masses each of mass at rest at O. curvature 10 cm. They are placed with the
8
These masses can move radially outwards curved surfaces at a distance d as shown in
along two massless rods fixed on the ring as the figure, with their axes (shown by the
shown in the figure. At some instant the an- dashed line) aligned. When a point source of
8 light P is placed inside rod S1 on its axis at a
gular speed of the system is  and one of distance of 50 cm from the curved face, the
9
light rays emanating from it are found to be
3
the masses is at a distance of R from O. Att parallel to the axis inside S2. The distance d is
5 S1 S2
this instant the distance of the other mass P

from O is. 50 cm d

2 (A) 60 cm (B) 70 cm
(A) R
3 (C) 80 cm (D) 90 cm
1
(B) R 18. A concutor (shown in the figure) carrying
3
3 constant current I is kept in the x-y plane in
(C) R 
5 a uniform magnetic field B . If F is the
0
4 magnitude of the total magnetic force acting
(D) R
5 on t h e con du ct or, th en t h e correct
statement(s) is (are)
16. The figures below depict two situtions in
which two infinitely long static line charges
of constant positive line charge density  are
kept parallel to each other. In their resulting
electric field, point charges q and –q are kept
Y
in equilibrium between them. The point
charges are confined to move in the x direc-
tion only. If they are given a small displace- x
ment about their equilibrium positions, then
the correct statement(s) is (are) 
(A) If B is along ẑ , F  (L+R)

(B) If B is along x̂ , F= 0

(C) If B is along ŷ , F  (L+R)
x x 
+q –q (D) If B is along ẑ , F= 0

19. Match the nuclear processes given in column

I withthe appropriate option(s) in column II.
(A) Both charges execute simple harmonic Column I Column II
motion. (A) Nuclear fusion (P) Absorption of
(B) Both charges will continue moving in the thermal neutrons
direction of their displacement. 235
by 92 U
(B)
(C) Charge +q executes simple harmonic mo-
tion while charge –q continues moving in (B) Fission in a (Q) 60
nucleus
27 Co
the direction of its displacement.
(D) Charges –q executes simple harmonic nuclear reactor
motion while charge +q continues (C) –decay (R) Energy production
movi n g i n th e di rect i on of i t s in stars via
displacement. hydrogen
conversion to
helium
(D) y-ray emission (S) Heavy water
(T) Neutrino emission

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20. A particle of unit mass is moving along the x-

axis under the influence of a force and its
total energy is conserved. Four possible forms
of the potential energy of the particle are
given in column I (a and Uo are constants).
Match the potential energies in column I to
the corresponding statement(s) in column II.
Column I Column II
2 2
U  x 
(A) U1(x)  0 1    
2   a  

(P) The force acting on the particle is zero at
x=a.
2
U0  x 
(B) U2 (x)   
2 a
(Q) The force acting on the particle is zero at
x=0.
2   x 2 
U0  x 
(C) U3 (x)  exp    
2  a    a  
(R) The force acting on the particle is zero at
x=–a.
3
U0  x 1  x  
(D) U4 (x)      
2 a 3  a 
 
(S) The particle experiences an attractive force
towards x=0 in the region x  a .

U0
(T) The particle with total energy can oscil-
4
late about the point x=–a.

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CHEMISTRY

SECTION 1 (MAXIMUM MARKS :32)
• This section contains EIGHTS questions
• The answer to each question is a SINGLE
DIGIT INTEGER ranging from 0 to 9, both
inclusive
• For each question, darken the bubble corre-
sponding to the correct integer in the ORS
• Marking scheme:
+4 If the bubble corresponding to the an-
swer is darkened
0 In all other cases
26. If the freezing point of a 0.01 molal aqueous
solution of a cobalt (III) chloride-ammonia
complex (which behaves as a strong elec-
trolyte) is –0.0558 °C, the number of
chloride(s) in the coordination sphere of the
complex is
[Kf of water = 1.86 K kg mol–1]
27. The total number of stereoisomers that can
exist for M is
H3C CH3

21. The total number of lone pairs of electrons in

N2O3 is. H3C O
M

22. For the octahedral complexes of Fe3+ in SCN– 28. The number of resonance structures for N is
(thiocyanato-S) and in CN– ligand environ-
OH
ments, the difference between the spin-only NaOH
magnetic moments in Bohr magnetons (when N
approximated to the nearest integer) is.
[Atomic number of Fe = 26]
29. Fe3+ is reduced to Fe2+ by using
(A) H2O2 in presence of NaOH
23. Among the triatomic molecules/ions, BeCl2 ,
(B) Na2O2 in water
N–3 , N2O, NO2 , O3, SCl3, ICl–2 , I–3 , and XeF2, (C) H2O2 in presence of H2SO4
the total number of linear molecule(s)/ion(s) (D) Na2O2 in presence of H2SO4
where the hybridization of the central atom
does not have contri buti on f rom the 30. The % yield of ammonia as a function of time in
d-orbital(s) is the reaction
[Atomic number: S = 16, Cl = 17, I = 53 and N2(g) + 3H2(g) 2NH3(g), (g) H < 0
Xe = 54] at (P, T1) is given below

24. Not considering the electronic spin, the T2

degeneracy of the second excited state (n=3)
of H atom is 9, while the degeneracy of the T1
T1
second excited state of H– is
(A)
25. All the energy released from the reaction
X  Y, r G° = –193 kJ mol–1 is used for oxidiz-
time time
ing M+ as M+  M3+ + 2e–, E° = – 0.25V.
If this reaction is conducted at (P, T2), with
Under standard conditions, the number of
the % yield of ammonia as a function of time
moles of M+ oxidized when one mole of X is
is represented by
converted to Y is
[F = 96500 C mol–1]

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(B)
T1

T2
(B)

(C)
time

T1 (D)
T2

(C) 33. The major product of the following reaction

is
time

T2

T1

(D)
(A) (B)
time

31. If the unit cell of a mineral has cubic close

packed (ccp) array of oxygen atoms with m
fraction of octahedral holes occupied by alu- (C) (D)
minium ions and n fraction of tetrahedral holes
occupied by magnesium ions, m and n, re-
spectively, are
34. In the following reaction, the major product
1 1 1 is :
(A) , (B) 1,
2 8 4

1 1 1 1
(C) , (D) ,
2 2 4 8

32. Compou n d(s) t h at on hydrogenat ion

produce(s) optically inactive compound(s)
is(are)

(A) (B)
(A)

(C) (D)

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35. The structure of D-(+)- glucose is 37. The correct statement (s) about Cr2+ and
Mn3+ is (are)
CHO (A) Cr2+
H OH (B) Mn3+
HO H (C) Both Cr2+ and Mn3+ exhibit d4 electronic
H OH configuration
H OH (D) when Cr2+ is used as a reducing agent,
the chromium ion attains d 5 electronic
CH2OH configuration

The structure of L.(–)glucose is

Q.38 Copper is purified by electrolytic refining of
CHO CHO blister copper. The correct statement(s)
about this process is (are)
HO H H OH (A) Impure Cu strip is used as cathode
H OH HO H (B) Acidified aqueous CuSO4 is used as elec-
HO H H OH trolyte
(A) (B)
HO H HO H (C) Pure Cu deposits at cathode
CH2OH CH2OH (D) Impurities settle as anode-mud

39. Match the anionic species given the Column

CHO CHO
I that are present in the ore(s) given in
HO H HO H Column II.
HO H HO H Column I Column II
H OH HO H (A) Carbonate (P) Siderite
(c) (D)
HO H H OH (B) Sulphide (Q) Malachite
CH2OH CH2OH (C) Hydroxide (R) Bauxite
(D) Oxide (S) Calamine
Q.36 The major product of the reaction is (T) Argentite
H3C CO2H
40. Match the thermodynamic processes given
under Column I with the expressions given
CH3 NH2 under Column II.
H3C NH2 Column-I
(A) Freezing of water at 273 K and 1 atm
(A)
(B) Expansion of 1 mole of an ideal gas into a
CH3 OH
vacuum under isolated conditions
H3C CO2H (C) Mixing of equal volumes of two ideal gases
at constant temperature and pressure in an
(B)
CH3 isolated container
OH
(D) Reversible heating of H2(g) at 1 atm from
H3C CO2H 300 K to 600 K, followed by reversible cool-
ing to 300 K at 1 atm
(C)
CH3 OH Column-II
(P) q = 0
H3C NH2 (Q) w = 0
(D) (R) Ssys < 0
CH3 OH (S) U = 0
(T) G = 0

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MATHEMATICS

Q.41 The minimum number of times a fair coin needs  1

For a  0, 2  , if F'(a) + 2 is the area of the
to be tossed, so that the probability of get-  
ting at least two heads is at least 0.96 is. region bounded by x = 0, y = 0, y = f(x) and
x = a, then f(0) is.
Q.42 Let n be the number of ways in which 5 boys
and 5 girls can stand in a queue in such a Q.47 The number of distinct solutions of equation
way that all the girls stand consecutively in
the queue. Let m be the number of ways in 5
cos22x + cos4x + sin4x + cos6x + sin6x = 2
which 5 boys and 5 girls can stand in a queue 4
in such a way that exactly four girls stand in the interval [0, 2] is
consecutively in the queue. Then the value
m Q.48 Let the curve C be the mirror image of the
of is. parabola y2 = 4x with respect to the line x +
n
y + 4 = 0. If A and B are the points of inter-
section of C with the line y = –5, then the
Q.43 If the normals of the parabola y2 = 4x drawn distance between A and B is.
at the end points of its latus rectum are
tangents to the circle (x – 3)2 + (y + 2)2 = r2,
Q.49 Let g : R  R be a differentiable function
then the value of r2 is.
with g(0) = 0, g’(0) = 0 and g’(1)  0.
 x
Q.44 Let f : R  R be a fucntion defined by  g(x), x  0
Let f(x) = | x | and h(x) = e|x|
[x], x  2  0, x  0

f(x) =  0, x  2 , where [x] is the greatest for all x  R. Let (foh) (x) denote f(h(x)) and

(hof)(x) denote h(f(x)), Then which of the
i nt eger l ess th an or equ al t o x,
following is (are) true?
2
x  (x2 ) (A) f is differentiable at x = 0
If I = 
–1
2  (x  1) dx, then the value of (B) h is differentiable at x = 0
(C) foh is differentiable at x = 0
(4I – 1) is.
(D) hof is differentiable at x = 0
Q.45 A cylindrical container is to be made from
certain solid material with the following   
constraints : It has a fixed inner volume of V Q.50 Let f(x) = sin  6 sin  2 sin x   for all x  R
mm3, has a 2 mm thick solid wall and is open   
at the top. The bottom of the container is a

solid circular dise of thickness 2 mm and is of and g(x) = sinx for all x  R. Let (fog) (x)
radius equal to the outer radius of the 2
container. denote f(g(x)) and (gof) (x) denote g(f(x)).
Then which of the following is (are) true?
If the volume of the material used to make
the container is minimum when the inner ra-  1 1
dius of the container is 10 mm, then the value (A) Range of f is – 2 , 2 
 
V
of is.  1 1
250
(B) Range of fog is – 2 , 2 
  
x2 
6
f(x) 
Q.46 Let F(x) =  2 cos2 t dt for all x  R and (C) Lim =
x
x 0 g(x) 6
 1 (D) There is an x  R such that (gof)(x) = 1
f : 0, 2   [0, ) be a continuous function.
 

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 
Q.51 Let PQR be a triangle. Let a = QR , Q.55 In R3, let L be a straight line passing through
      the origin. Suppose that all the points on
b = RP and c = PQ . If | a | = 12, | b | = L are at a constant distance from the two
  planes P1 : x + 2y – z + 1 = 0 and P2 : 2x – y
4 3 and b.c = 24, then which of the follow-
+ z – 1 = 0. Let M be the locus of the feet of
ing is (are) true? the perpendiculars drawn from the points on
 
| c |2 L to the plane P1. Which of the following points
| c |2  
(A) –| a | = 12 (B) + | a | = 30 lie(s) on M?
2 2
     5 2  1 1 1
(C) | a  b  c  a | = 48 3 (A)  0,– ,–  (B)  – ,– , 
 6 3  6 3 6
 
(D) a.b = –72
 5 1  1 2
 (C)  – 6 , 0, 6  (D)  – 3 ,0, 3 
| c |2     
(A) –| a | = 12
2

| c |2  Q.56 Let P and Q be distinct points on the
(B) + | a | = 30
2 parabola y2 = 2x such that a circle with
    PQ as diameter passes through the veriex O
(C) | a  b  c  a | = 48 3 of the parabola. if P lies in the first quadrant
  and the area of the triangle OPQ is 3 2 ,
(D) a.b = –72
then which of the following is (are) the
coordiantes of P?
Q.52 Let X and Y be two arbitrary, 3 × 3 non-
zero, skew-symmetric matrices and Z be an
arbitrary 3 × 3, non-zero, symmetric matrix. Then

(A) 4,2 2  
(B) 9,3 2 
which of the following matrices is (are) skew sym- 1 1 
metric? (C)  4 ,


2

(D) 1, 2 
(A) Y3Z4 – Z4Y3 (B) X44 + Y44
(C) X4Z3 – Z3X4 (D) X23 + Y23
Q.57 Let y(x) be a solution of the differential
eqution (1 + ex)y’ + yex = 1. If y(0) = 2, then
Q.53 Which of the following values of  satisfy which of the following statements is (are)
the equation true?
(1  )2 (1  2)2 (1  3)2 (A) y(–4) = 0 (B) y(–2) = 0
(2  )2 (2  2)2 (2  3)2 (C) y(x) has a critical point in the interval
=–648? (–1, 0)
(3  )2 (3  2)2 (3  3)2
(D) y(x) has no critical point in the interval
(A) –4 (B) 9 (–1, 0)
(C) –9 (D) 4
Q.58 consider the family of all circles whose
Q.54 3
In R , consider the planes P1 : y = 0 and centers lie on the straight line y = x.
P2 : x + z = 1, Let P3 be a plane, different If this family of circles is represented by the
from P1 and P2, which passes through the differential equation Py” + Qy’ + 1 = 0,
intersection of P1 and P2. If the distance of where P, Q are fucntions of x, y and
the point (0, 1, 0) from P3 is 1 and the dy d2y
distance of a point (, , ) from P3 is 2, then y’ (here y’ = , y” = ), then which of
dx dx2
which of the following relations is (are) true? the following statement is (are) true?
(A) 2 +  + 2 + 2 = 0 (A) P = y + x
(B) 2 –  + 2 + 4 = 0 (B) P = y – x
(C) 2 +  – 2 – 10 = 0 (C) P + Q = 1 – x + y + y’ + (y’)2
(D) 2 –  + 2 – 8 = 0 (D) P – Q = x + y – y’– (y’)2

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Q.59 Column I Q.60 Column I

(A) In R2, if the magnitude of the projection (A) In a triangle XYZ, let a, b and c be the
lengths of the sides opposite to the angles
vector of the vector ˆi  ˆj on 3iˆ  ˆj is X, Y and Z, respectively. If 2(a2 – b2) = c2
3 and if a = 2  3 , then possible value(s) sin(X – Y)
and  = , then possible values of n
of || is (are) sin Z
for which cos(n) = 0 is (are)
(B) Let a and b be real numbers such that
(B) In a triangle XYZ, let a, b and c the
–3ax2 – 2, x  1 lengths of the sides opposite to the angles
the function f(x) =  2
is X, Y and Z, respectively. If 1 + cos2X –
 bx  a , x 1 2cos2Y = 2sinX sinY, then possible value(s)
differentiable for all x  R. Then possible a
value(s) of a is (are) of is (are)
b
(C) Let   1 be a complex cube root of
unity. If (3 – 3 + 22)4 + 3 + (2 + 3 – 32)4 (C) In R2, let 3iˆ  ˆj , ˆi  3j
ˆ and ˆi  (1 – )j
ˆ
+3
+ (– 3 + 2 + 32)4 + 3 = 0, then possible be the position vectors of X, Y and Z with
value(s) of n is (are) respect to the origin O, respectively. If the
(D) Let the harmonic mean of two positive distance of Z from the bisector of the acute
real numbers a and b be 4. If q is positive   3
real number such that a, 5, q, b is an angle OX with OY is then possible
2
arighmetic number such that a, 5, q, b is an
value(s) of || is (are)
arithmetic progression, then the value(s) of
|q – a| is (are) (D) Suppose that F() denotes the area of
the region bounded by x = 0, x = 2, y2 = 4x
Column II
and y = |x – 1| + |x – 2| + x, where
(P) 1 (Q) 2   {0, 1}. Then the value(s) of F() +
(R) 3 (S) 4
(T) 5

Page 11
ETOOSINDIA.COM MOTIONIITJEE.COM
JEE ADVANCED 2015
CODE-6
PAPER-2
PHYSICS
1. For a radioactive material, its activity A and 5. A large spherical mass M is fixed at one
rate of change of its activity R are defined as A position and two identical point masses m
dN dA are kept on a line passing through the centre
= – and R = – , where N(t) is the of M (see figure). The point masses are
dt dt
number of nuclei at time t. Two radioactive connected by a rigid massless rod of length l
sources P (mean life ) and Q (mean life 2) and this assembly is free to move along the
have the same activity at line connecting them. All three masses
t = 0. Their rates of change of activities at i n teract onl y th rough th ei r mu tu al
gravitational interaction. When the point
RP n mass nearer to M is at a distance r = 3l from
t = 2 are RP and RQ, respectively. If R = ,
Q e M, the tension in the rod is zero for m = k
then the value of n is -  M 
  . The value of k is -
 288 
2. A monochromatic beam of light is incident M m m
at 60° on one face of an equilateral prism of
refractive index and emerges from the
opposite face making an angle  (n) with the r l
normal (see the figure). For n = 3 the value
d 6. The energy of a system as a function of time
of  is 60° and = m. The value of m is - t is given as E(t) = A2 exp (–t), wher a =
dn
0.2 s–1. The measurement of A has an error
of 1.25%. If the error in the measurement of
60°
time is 1.50%, the percentage error in the
value of E(t) at t = 5 s is -

7. The densities of two solid spheres A and B of

3. In the following circuit, the current through the same radii R vary with radial distance r
the resistor R (=2) is I amperes. The value r
5
r
of I is - as A (r) = k  R  and B(r) = k   ,
  R 
R(=2) 1 respectively, where k is a constant. The
moments of inertia of the individual spheres
about axes passing through their centres are
8
2

2 IB n
6 IA and IB, respectively. If I = , the value
4

A 10
10 of n is -
6.5V

8. Four harmonic waves of equal frequencies

12
and equal intensities I0 have phase angles 0,
/3, 2/3 and . when they are superposed,
the intensity of the resulting wave is nI0.
The value of n is -

4. An electron in an excited state of Li2+ ion has

angular momentum 3h/2. The de Broglie 9. In terms of potential difference V, electric
wavelength of the electron in this state is current I, permittivity 0, permeability 0 and
pa0 (where a0 is the Bohr radius). The value speed of light c, the dimensionally correct
of p is - equation (s) is (are)
ETOOSINDIA.COM MOTIONIITJEE.COM
(A) 0 I2 = 0V2 (B) 0 I = 0V 13. A parallel plate capaitor having plates of area
(C) I = 0cV (D) 0cI = 0V S and plate separation d, has capacitance
C1 in air. When two dielectrics of different
10. Consider a u ni form sph erical charge relative permittivities (1 = 2 and 2 = 4) are
distribution of radius R1 centred at the origin introduced between the two plates as shown
O. In this distribution, a spherical cavity of in the figure, the capacitance becomes C2.
radius R2, centred at P with distance OP = a C2
= R1 – R2 (see figure) is made. If the electric The ratio C is -
1
 
field inside the cavity at position r is E(r ) , d/2

then the correct statement(s) is (are)

R2
S/2
P
a
R1 + –
S/2
O

d
 (A) 6/5 (B) 6/5
(A) E is uniform, its magnitude is independent (C) 7/5 (D) 7/3
of R2 but its direction depends on r

(B) E is uniform, its magnitude depends on
R2 and its direction depends on r 14. An ideal monoatomic gas is confined in a
 horizontal cylider by a spring loaded piston
(C) E is uniform, its magnitude is independent
 (as shown in the figure). Initially the gas is at
of a but its direction depends on a
 temperature T1, pressure P1 and volume V1
(D) E is uniform and both its magnitude and and the spring is in its relaxed state. The gas

direction depends on a is then heated very slowly to temperature T2,
pressure P2 and volume V2. During this process
the piston moves out by a distance x. Ignoring
11. In plotting stress versus strain curves for the friction between the piston and the cylider,
two materials P and Q, a student by mistake the correct statement(s) is (are).
puts strain on the y-axis and stress on the
x-axis as shown in the figure. Then the correct
statemetn(s) is (are)
(A) P has more tensile
strength than Q
(B) P is more ductile
than Q
(C) P is more brittle
than Q (A) If V2 - 2V1 and T2 = 3T1, then the energy
(D) Th e You ng’s 1
modulus of P is more stored in the spring is PV
4 1 1
than that of Q
(B) If V2 = 2V1 and T2 = 3T, then the change
in internal energy is 3P1V1
(C) If V2 = 3V1 and T2 = 4T, then the work
12. A spherical body of radius R consists of a fluid
of constant density and is in equilibrium under 7
done by the gas is PV
its own gravity. If P(r) is the pressure at 3 1 1
r (r < R), then the corect option(s) is (are) (D) If V2 = 3V1 and T2 = 4T1, the heat supplied
17
P(r  3R / 4) 63 to the gas is PV
(A) P (r = 0) = 0 (B) = 6 1 1
P(r  2R / 3) 80 U  nCV dT
P(r  3R / 5) 16 P(r  R / 2) 20
(C) = (D) =
P(r  2R / 5) 21 P(r  R / 3) 27
ETOOSINDIA.COM MOTIONIITJEE.COM

15. A fission reaction is given by  i less than a particular value im are confined
in the medium of refractive index n1. The
+ + x + y, where x and y are two numerical aperture (NA) of the structure is
particles. Considering to be at rest, defined as sin im.

the kinetic energies of the products are n1>n2

denoted by KXe, KSr, KX (2MeV) and Ky (2 MeV),
respectively. Let the binding energies per Air Cladding n2

nucleon of , and be 7.5 Core

MeV, 8.5 MeV and 8.5 MeV, respectively.
Considering different conservation laws, the
correct option (s) is (are)
(A) x=n, y = n, KSr = 129 MeV, KXe = 86 MeV
(B) x=p, y = e–, KSr = 129 MeV, KXe = 86 MeV
(C) x=p, y = n, KSr = 129 MeV, KXe = 86 MeV
(D) x=n, y = n, KSr = 86 MeV, KXe = 129 MeV
16. Two spheres P and Q of equal radii have
densities 1 and 2 , respectively. The spheres
are connected by a massless string and placed
in liquids L1 and L2 of densities 1 and 2 and
viscosities 1 and 2, respectively. They float
in equilibrium with the sphere P in L1 and
sphere Q in L2 and the string being taut (see
figure). If sphere P along in L2 has terminal

velocity VP and Q in L1 has terminal velocity
 index
VQ , then
 in water
| VP | 1
(A) | V  =  L1
Q | 2 P

| VP | 2
(B) | V  = 
Q | 1 15
L2
  Q (D) NA of S1 placed in air is the same as that
(C) VP.VQ  0
 
(D) VP .VQ  0
Paragraph-1
Light guidance in an optical fiber can be
understood by considering a structure
comprising of thin solid glass cylider of
refractive index n1 surrounded by a medium
of lower refractive index n 2. The light
guidance in the structure takes place due to
successive total internal reflections at the
interface of the media n1 and n2 as shown in
the figure. All rays with the angle of incidence
i n1
17. For two structures namely S 1 with n 1 =
45 / 4 and n2 = 3/2, and S2 with n1 = 8/5
and n2 = 7/5 and taking the refractive index
of water to be 4/3 and that of air to be 1, the
correct option (s) is (are)
(A) NA of S1 immersed in water is the same
as that of S2 immersed in a liquid of refractive
16
index
3 15
(B) NA of S1 immersed in liquid of refractive
16
is the same as that of S2 immersed
15
(C) NA of S1 placed in air is the same as that
of S2 immersed in liquid of refractive index
4
of S2 placed in water
18. If two structures of same cross-sectional
area, but different numerical apertures NA1
and NA2 (NA2 < NA1) are joined longitudinally,
the numerical aperture of the combined
structure is -
NA1NA 2
(A) NA  NA (B) NA1 + NA2
1 2
(C) NA1 (D) NA2
Paragraph-2
In a thin rectangular metallic strip a constant
current I flows along the positive x-direction,
as shown in the figure. The length, width
and thickness of the strip are l, w and d,

respectively. A uniform magnetic field B is
applied on the strip along the positive y-
ETOOSINDIA.COM MOTIONIITJEE.COM

direction. Due to this, the charge carries

experience a net deflection along the z-
direction. This results in accumulation of
charge caries on the surface PQRS and
apperance of equal and opposite charges on
the face opposite to PQRS. A potential
difference along the z-direction is thus
developed. Charge accumulation continues
until the magnetic force is balanced by the
electric force. The current is assumed to be
uniformly distributed on the cross section of
the strip and carried by electrons.

l y

I K I
w x
S R
d M
z
P Q

19. Consider two different metallic strips (1 and

2) of the same material. Their lengths are
the same, widths are w 1 and w 2 and
thicknesses are d1 and d2, respectively. Two
points K and M are symmetrically located on
the opposite faces parallel to the x-y plane
(see figure). V1 and V 2 are the potential
differences between K and M in strips 1 and
2 , respectively. Then, for a given curent I
flowing through them in a given magnetic field
strength B, the correct statement(s) is (are).
(A) If w1 = w2 and d1 = 2d2, then V2 = 2V1
(B) If w1 = w2 and d1 = 2d2, then V2 = V1
(C) If w1 = 2w2 and d1 = d2, then V2 = 2V1
(D) If w1 = 2w2 and d1 = d2, then V2 = V1

20. Consider two different metallic strips (1 and

2) of same dimensions (length l, width w and
thickness d) with carrier densities n1 and n2,
respectively. Strip 1 is placed in magnetic
field B1 and strip 2 is placed in magnetic field
B2, both along positive y-directions. Then V1
and V2 are the potential differences developed
between K and M in st rips 1 and 2,
respectively. Assuming that the current I is
the same for both the strips, the correct
option (s) is (are).
(A) If B1 = B2 and n1 = 2n2, then V2 = 2V1
(B) If B1 = B2 and n1 = 2n2, then V2 = V1
(C) If B1 = 2B2 and n1 = n2, then V2 = 0.5V1
(D) If B1 = 2B2 and n1 = n2, then V2 = V1
ETOOSINDIA.COM MOTIONIITJEE.COM
(CHEMISTRY) P-2

SECTION 1 (MAXIMUM MARKS : 32) 25. The number of hydroxyl group(s) in Q is

• This section contains EIGHT questions.
• The answer to each question is a SINGLE
DIGIT INTEGER ranging from 0 to 9. both
inclusive.
P
• For each question, darken the bubble corre-
sponding to the correct integer in the ORS.
• Marking scheme :
+4 If the bubble corresponding to the Q
answer is darkened.
0 In all other cases.

26. A mon g t h e f ol lowi ng t he n umber of

21. Three moles of B2H6 are completely reacted reaction(s) that produce(s) benzaldehyde is
with methanol. The number of moles of
boron containing product formed is.
I.

22. The molar conductivity of a solution of a weak

acid HX (0.001 M) is 10 times smaller than
II.
the molar conductivity of a solution of a weak
0 0
acid HY (0.10 M). If  x—   Y — , the differ-
ence in their pKa values, pKa (HX) – pKa(HY),is
III.
(consider degree of ionization of both acids
to be <<1)

23. A closed vessel with rigid walls contains 1 IV.

238
mol of 92
U and 1 mole of air at 298K. Con-

238 206
sidering complete decay of 92
U to 82
Pb ,
27. In the complex acetylbromidodicarbonylbis
the ratio of the final pressure to the initial triethylphosphine iron (II) the number of Fe-
pressure of system at 298K is. C bond(s) is

24. In dilute aqueous H 2 SO 4, the complex

diaquodioxalatoferrate(II) is oxidized by MnO4–
. For this reaction, the ratio of the rate of
change of [H + ] to the rate of change of
[MnO4–] is.
ETOOSINDIA.COM MOTIONIITJEE.COM

28. Among the complex ions, [Co(NH2–CH2–CH2– 30. In the following reactions, the major
NH 2 – ) 2 Cl 2 ] + , [CrCl 2 (C 2 O 4 ) 2 ] 3– , product W is
+
[Fe (H2O)4(OH)2] , [Fe(NH3)2(CN)4], [Co(NH2– NH OH
2
CH 2 – CH 2 – NH 2 ) 2 (NH 3 )Cl ] 2+ an d , NaOH
NaNO2, HCl
[Co(NH3)4(H2O)Cl]2+, the number of complex V W
0°C
ion(s) that show(s) cis-trans isomerism is-

SECTION 2 (Maximum Marks: 32)

• This section contains EIGHTS questions
• Each question has FOUR options (A,) (B),
(C) & (D). ONE OR MORE THAN ONE of these
four options(s) is(are) correct (A) N=N OH
• For each question, darken the bubble(s) cor-
responding to all the correct option(s) in the
ORS
• Marking scheme:
+4 If only the bubble(s) corresponding
to all the correct option(s) is(are) darkened
0 If none of the bubbles is darkened OH
–2 In all other cases
(B) N=N
29. The major product U in the following
reactions is
+
CH2 = CH–CH3,H radical initiator, O2
T U
high pressure, heat
OH
H
N=N
O H3C CH3 (C)
O
(A) CH3
(B) O O H

HO
H
O CH2
O O O H
CH2
(C) (D)
(D) N=N

31. The correct statement(s) regarding, (i) HClO,

(ii) HClO2, (iii) HClO3 and (iv) HClO4 is (are)
(A) The number of Cl = O bonds in (ii) and
(iii) together is two
(B) The number of lone pairs of electrons on
Cl in (ii) and (iii) together is three
(C) The hybridixation of Cl in (iv) is sp3
(D) Amongst (i) to (iv), the strongest scid is (i)
ETOOSINDIA.COM MOTIONIITJEE.COM

32. The pair(s) of ions where BOTH the ions are

precipitted upon passing H2S gas in presence
of dilute HCl, is(are)
V(r)
(A) Ba2+, Zn2+ (B) Bi3+, Fe3+ (C) 0 r
(C) Cu2+, Pb2+ (D) Hg2+, Bi3+

33. Under hydrolytic conditions, the compounds

used for preparation of linear polymer and
for chain termination, respectively, are
(A) CH3SiCl3 and Si(CH3)4
(B) (CH3)2SiCl2 and (CH3)3SiCl V(r)
(C) (CH3)2SiCl2 and CH3SiCl3 0
(D) SiCl4 and (CH3)3SiCl r
(D)

34. When O2 is adsorbed on a metallic surface,

electron transfer occurs from the metal to
O2. The TRUE statements(s) regarding this
adsorption is (are)
Q.36. In the following reactions, the product S is
(A) O2 is physisorbed
(B) heat is released H3C
i. O3
(C) Occupancy of 2p of O2 is increased
R
(D) bond length of O2 is increased ii. Zn, H2O

NH3
S
35. One mole of a monatomic real gas satisfies
the equation p(V – b) = RT where b is a H3C
N
constant. The relationship of interatomic V(r) (A)
and interatomic distance r for the gas is given
by
H3C N
(B)
V(r)
(A) 0 r
N
(C)
HC
3

(D)
HC
3
V(r)
(B) 0 r
ETOOSINDIA.COM MOTIONIITJEE.COM
SECTION 3 (MAXIMUM MARKS : 16)
H2O
 This section contains TWO paragraphs
 Based on each paragraph, there will be TWO HgSO 4, H2SO4
questions
 Each question has FOUR options (A), (B), i. EtMgBr, H2O
C8H8O Y
(C) and (D). ONE OR MORE THAN ONE of ORS ii. H+, heat
 Marking scheme:
+4 If only the bubble(s) corresponding to all
the correct option (s) is (are) darkened
0 If none of the bubbles is darkened 39. Compound X is
–2 In all other cases
O
PARAGRAPH 1
(A) CH3
When 100 mL of 1.0 M HCl was mixed with
100 mL of 1.0 M NaOH in an insulated beaker
at constant pressure, a temperature increase
of 5.7ºC was measured for the beaker and OH
its contents (Expt. 1). Because the enthalpy
(B) CH3
of neutralization of a strong acid with a strong
base is a constant (–57.0 kJ mol–1), this
experiment could be used to measure the
calorimeter constant. In a second experiment OH
(Expt.2), 100, mL of 2.0 M acetic acid (Ka - (C)
2.0 × 10–5) was mixed with 100 mL of 1.0 M
NaOH (under identical conditions to Expt.1 )
where a temperature rise of 5.6ºC was COH
measured. (D)
(Consider heat capacity of all solutions as
4.2 g–1 K–1 and density of all solutions as 1.0
g mL–1) 40. The major compound Y is

37. Enthalpy of dissociation (in kJ mol–1) of acetic CH3

(A)
acid obtained from the Expt. 2 is
(A) 1.0 (B) 10.0
(C)24.5 (D) 51.4
CH3
(B)
38. The pH of the solution after Expt. 2 is
(A) 2.8 (B) 4.7
(C) 5.0 (D) 7.0 CH2
ç; ksx 2 dsi ' pkr foy ; u dk pH gS
A CH3
(A) 2.8 (B) 4.7 (C)
(C) 5.0 (D) 7.0

CH3
PARAGRAPH - 2 CH3
In the following reactions (D)

Pd-BaSO 4 i. B2H6
C 8 H6 C 8 H8 X
H2 ii. H2O2 NaOH, H2O
ETOOSINDIA.COM MOTIONIITJEE.COM
(MATHEMATICS) P-2

Q.41 Let m and n be two positive integers greater

 k   k 
Q.45 For any integer k, let k =   + i sin  ,
n
 ecos( ) – e   7   7 
than 1. If   0 
lim  = –  e  then the
m    where i = –1 . The value of the expression
   2

m 12
value of is
n | 
k 1
k 1 – k |

3 is.
| 
k 1
4k–1 – 4k–2 |
1
9x  3 tan–1 x
 12  9x2 
Q.42 If  =  (e
0
)
 1  x2  dx
 

where tan–1x takes only principal values, then Q.46 Suppose that all the terms of an arithmetic
 3  progression (A.P.) are natural numbers. If the
the value of  loge |1   | –  is ratio of the sum of the first seven terms to
 4 
the sum of first eleven terms is 6 : 11 and the
seventh term lies in between 130 and 140,
then the common difference of this A.P. is.
Q.43 Let f : R  R be a continuous odd fucntion,
which vanishes exactly at one point and f(1)
Q.47 The coefficient of x9 in the expansion of
x
1 (1 + x)(1 + x2)(1 + x3)...(1 + x100) is.
=
2
. Suppose that F(x) =  f(t) dt for all x 
–1
x
Q.48 S uppose t h at th e f oci of t h e ell i pse
[–1, 2] and G(x) =  t | f(f(t)) | dt for all x  x2 y2
–1 + = 1 are (f1,0) and (f2,0) where f1 > 0
9 5
F(x) and f2 < 0. Let P1 and P2 be two parabolas
1
[–1, 2]. If lim = , then the value with a common vertex at (0, 0) and with foci
x 1 G(x) 14
at (f1, 0) and (2f2, 0), respectively. Let T1 be
1 a tangent to P 1 which passes through
of f   is.
2 (2f2, 0) and T2 be a tangent to P2 which
passes through (f1, 0). If m1 is the slope of
T1 and m2 is the slope of T2, then the value

 1 2

   of  2  m2  is.
Q.44 Suppose that p , q and r are three non-  m1 
coplanar vectors in R3. Let the components
   
of a vector s along p , q and r be 4, 3 and
5, respectively. If the components of this
      
vector s along ( –p  q  r ), ( p – q  r ) and
  
( –p – q  r ) are x, y and z, respectively, then
the value of 2x + y + z is
ETOOSINDIA.COM MOTIONIITJEE.COM

SECTION 2 (Maximum Marks : 32) Q.51 Consider the hyperbola H : x2 – y2 = 1 and a

 This section contains EIGHT questions circle S with center N(x2, 0). Suppose that H
and S touch each other at a point P(x1, y1)
 Each question has FOUR options (A), (B),
with x1> 1 and y1 > 0. The common tangent
(C) and (D). ONE OR MORE THAN ONE of
to H and S at P intersects the x-axis at point
these four option(s) is(are) correct
M. If (l, m) is the centroid of the triangle
 For each question, darken the bubble(s) PMN, then the correct expression(s) is(are)
corresponding to all the correct option(s)
in the ORS d 1
 Marking scheme : (A) dx = 1 – 3x2 for x1 > 1
1 1
+4 If only the bubble(s) corresponding to
x
all the correct option(s) is(are) darkened dm
0 If none of the bubbles is darkened
(B)
dx1
= 3
 x12 – 1  for x > 1
1

–2 In all other cases

d 1
 6  4 (C) dx = 1 + 3x2 for x1 > 1
1 1
Q.49 If  = 3sin–1   and  = 3 cos–1   , where
 11  9
dm 1
the inverse trigonometric functions take only (D) dy = for y1 > 0
the principal values, then the correct 1 3
option(s) is(are)
(A) cos > 0 (B) sin < 0 Q.52 The option(s) with the values of a and L
that satisfy the following equation is(are)
(C) cos( + ) > 0 (D) cos < 0

4
t 6
 e (sin at  cos4 at)dt
Q.50 Let E1 and E2 be two ellipses whose centers 0
are at origin. The major axes of E1 and E2 lie 
=L?
t 6 4
along the x-axis and the y-axis, respectively.
Let S be the circle x2 + (y – 1)2 = 2. The
 e (sin
0
at  cos at)dt

straight line x + y = 3 touches the curves S, E1 and e4  – 1

E 2 at P, Q an d R, respect i vel y. (A) a = 2, L =
e – 1
2 2
Suppose that PQ = PR = . If e1 and e2 e4   1
3 (B) a = 2, L =
are t he eccent ri ci t es of E 1 an d E 2 , e  1
respectively, then the correct expression(s)
is (are) e4  – 1
(C) a = 4, L =
e – 1
43 7
(A) e12  e22 = (B) e1 e2 =
40 2 10 e4   1
(D) a= 4, L =
e  1
2 2 5 3
(C) e1  e2 = (D) e1 e2 =
8 4
ETOOSINDIA.COM MOTIONIITJEE.COM
Q.53 Let f, g : [–1, 2]  R be continuous func- 192x2 1
Q.55 Let f'(x) = for all x Î R with f  
tions which are twice differentiable on the 4
2  sin x 2
interval (–1, 2). Let the values of f and g at
1
the points –1, 0 and 2 be as given in the
= 0. If m 
following table:  f(x) dx  M, then the possible
1/2

x=–1 x=0 x=2 values of m and M are

(A) m = 13, M = 24
f(x) 3 6 0
g(x) 0 1 –1 1 1
(B) m = ,M=
4 2
In each of the intervals (–1, 0) and (0, 2) (C) m = –11, M = 0
the function (f – 3g)" never vanishes. Then (D) m = 1, M = 12
the correct statement(s) is(are)
(A) f'(x) – 3g'(x) = 0 has exactly three
solutions in (–1, 0)  (0, 2) Q.56 Let S be the set of all non-zero real numbers
(B) f'(x) – 3g'(x) = 0 has exactly one a such that the quadratic equation ax2 – x +
solution in (–1, 0) a = 0 has two distinct real roots x1 and x2
(C) f'(x) – 3g'(x) = 0 has exactly one satisfying the inequality |x1 – x2| < 1.
solution in (0, 2) Which of the following intervals is(are) a
(D) f'(x) – 3g'(x) = 0 has exactly two subset(s) of S?
sol utions i n (–1 , 0) and exactly two
solutions in (0, 2)  1 1   1 
(A)  – 2 , –  (B)  – , 0
S  5  5 

Q.54 Let f(x) = 7tan8x + 7tan6x – 3tan4x – 3tan2x  1   1 1

(C)  0,  (D)  , 
    5  5 2
for all x   – ,  . Then the correct
 2 2
expression(s) is(are).
 /4  /4
1 SECTION 3 (Maximum Marks : 16)
(A) 
0
xf(x)dx 
12 (B) 
0
f(x)dx  0
 This section contains TWO paragraphs
 Based on each paragraph, there will be
 /4  /4 TWO questions
1
(C) 
0
xf(x)dx 
6 (D) 
0
f(x)dx  1
 Each question has FOUR options (A), (B),
(C) and (D). ONE OR MORE THAN ONE OF
these four option(s) is(are) correct
 For each question, darken the bubble(s)
corresponding to all the correct option(s)
in the ORS
 Marking scheme :
+4 If only the bubble(s) corresponding to
all the correct option(s) is(are) darkened
0 If none of the bubbles is darkened
–2 In all other cases

PARAGRAPH 1
ETOOSINDIA.COM MOTIONIITJEE.COM

Let F : R  R be a thrice differentiable PARAGRAPH 2

fucntion. Suppose that F(1) = 0, F(3) = –4 Let n1 and n2 be the number of red and black
and F'(x) < 0 for all x  (1/2, 3). Let f(x) = balls, respectively, in box I. Let n3 and n4 be
xF(x) for all x  R. the number of red and black balls, respectively,
in box II.
Q.57 The correct statement(s) is(are)
(A) f'(1) < 0 (B) f(2) < 0 Q.59 One of the two boxes, box I and box II, was
(C) f'(x)  0 for any x  (1, 3) selected at random and a ball was drawn
randomly out of this box. The ball was found
(D) f'(x) = 0 for some x  (1, 3)
to be red. If the probability that this red ball
1
was drawn from box II is , then the cor-
3
3 3 rect option(s) with the possible values of n1,
2 3
Q.58 If x
1
F'(x)dx = –12 and x
1
F"(x)dx = 40, n2, n3 and n4 is(are)

then the correct expression(s) is(are) (A) n1 = 3, n2 = 3, n3 = 5, n4 = 15

(A) 9f'(3) + f'(1) – 32 = 0 (B) n1 = 3, n2 = 6, n3 = 10, n4 = 50

(C) n1 = 8, n2 = 6, n3 = 5, n4 = 20
3
(D) n1 = 6, n2 = 12, n3 = 5, n4 = 20
(B)  f(x) dx = 12
1
(C) 9f'(3) – f'(1) + 32 = 0
3
Q.60 A ball is drawn at random from box I and
(D) f(x) dx = –12

1
transferred to box II. If the probability of
drawing a red ball from box I, after this trans-
1
fer, is , then the correct option(s) with
3
the possible values of n1 and n2 is(are)
(A) n1 = 4 and n2 = 6
(B) n1 = 2 and n2 = 3
(C) n1 = 10 and n2 = 20
(D) n1 = 3 and n2 = 6