a a Gas Purge Find minimum Ny siento make (Conservation equation (1 aN o Fick's law foe (sig molar average veloc) ee Nam nln + i) = CB Das ds, tad) Toate eeeey ain — 24) = ay Integrate ome assuming C= cons. ef Lese2i] _ Mot T= 8400)" Ce Boundary daa: sal) = 1-0) =) zh) 0 “Thin is he minima value fo fo 9(0) = Ny ste laze 3-2, Reversible Heterogeneous Reaction in a Liquid 6612606 Cnnn) vat obiPy Reaction ate and equiva constant Reg =EsCHKL) = KCAL) = IRC G(L) ~ C46) Kaka {Conservation equations (i = A cB): £E 205.60) ons) ) “Ny lL-) = Roy a DaiGs(d) = LK CL) ~ Cut) (60) “Noy(E2) = Rp = Ro, or DyiiB(L) = A IR Cy(L) ~ C4(0). From (i) andi, 4 = Can De = Coo From i pos Gu), $5 + Dy ofa) +08 Daag + Dros =0 Pay From Gi), Peaeen) tate] ke C= Row +e) (Forward rection ory < Lro.ee fry > 1) ‘Rel for dimensionless concenions eu) a(s—a)e onan2s Reaction rte Rog =H ICAL) ECE se Ke Bx = 0,0) SSop0) = 040) = 70K) = 3-3. Oxygenation of Cell Aggregates (6) Desemine C1) Case 1: € > 0 tesughoa soese (r$ ac Coma ceo Integrate DE deed ad apy BCs: ‘An Opies ore wll exist when 6DC kr 1-H camnot be assumed tea that Ry = By everwhere Case 2: anoxic ere “The dein intrest ow re 0) a8 — 0, For > 1, their sphere becomes anoxic (x 1. (b) Maxima for fl oxyzention This is piven by = "ay =30 uM Da2xi0 as Su (body tse 62% 10° (SOU! SOuMs = 14x10 m= 0m For = 200M (quilted with i: eee w 3-4, Membrane Reaclor(6) Governing egstion Conservation of a: Conservation of B: Sane exept Roa = —Rva fe ae BCs fora 0 640. rf wena = a0 bom HEM=0 > om=0 Gi) Ng") = Nant = 2,(0)=0, where sth prion coetcient 1 py = bet) cea : rey. (')ooya-voen ste = pemey Summary Cay be race) 1) Salve or (9) and 8g(9) Do 4 fist Ox = aysinh in + och in 2=0 > m=0 emer > a= sinh 8 = Sib.28 Solve fore: e = (est) wah) aig | [or= (CE) a (6) Compute and dss late pry and rctioal covery of In product swear Bete pr oe Saino maies ” WOT) ma) Nat) + NeO), 2 Zoro a On See |. mar da (vtbsaaa) 8 -(CS*)-a em ean Gen) Fastresstion: 4 + 29 ca sabi > ost So “The fast cation consumes af the A, so oly enters the product.Slow reaction: +0. span sah and cosh: aha. +2400 os, aeoner tem an saan 2400) oe o> Trea oa 2 Ofer 0 “The slow reaction produces BA dfses across the membrane and dominates he produc. oo Recovery of B: ux of Bo product _ Nal) ie Neal) = Nn 84)» (Es ) = seat a. sinh Rows = GD. 7ST cosh = Ny + DF Ay OI eo ys — 2 +0) ip + Hieos =H Fastsiction: 1+ 59 Choos Aterms dominate) Slow ection: + 0 EE tok opt 00) Oo Tendsfe 20 For fst or slow kinetics, resovery depends strongly onthe peomebiity parameter (7), The results are best, ofcourse, fora coating tats nearly impermesbe 1 B (ey — 3:5. Facilitated Transport Kinetics By HRC CH) Difsivties: Dis Dy = D Sobbiltyel A: Cy-=eP,stoqulibium (a) Find x of A witout eacton Imegrate species conservation caution #e ae cs. 0) + 16x) ~ CAE CO mePio snd CL) = aPa Clea fos (ite si with, = 0) > war= Pica) —Cxtt))— Godependen of) Ma = Peo Mo (b) Deveonine ux of with ton With reversible rection, nx conservation egutions fr bah speciesAdd conservation equations Sie tein0 + C4G=mtok Cyaatot Cx (annot we BCs yet, Bocas Cy nt know st bounds) limite Cy from conservation equation fer 4 LO ce 0= 08S sues C0 2, +6 [K (w+arF)~ a+ eC) Reanange and comer to Bi, =k @ +052) Ce £E pa +0 £Ct — pald + KC, =—DaKlas+ 0. Latit = Da(l + 8). Now Seige = — tated, Parca solution: . agra, conep sey? ttt obit Eth “Tis completes the gener oton for Cy)-Te soon for Cy) then Cy = ay taik—Cy L pleat 7) — by sah 27 — yooh A We nou BCS to deena he constants Pi by The BCS ae C= ae (known pail psi as = 0) shit Reena w cayauhe (bao pai ese a wm naattheniieregimtatete i) y= 0 (ootus of Bats = Ser tg montana BL TeR Mame rig ~ha=o ° (roto Bate = 4) 3 aig —bikcosh besa = 02 “The osteo fA aso the embe as _ DCs aeeae [Although Nac = Nas) forthe reactive ese (0) = Nu (1 ue Ha oth sides of membrane). To se ‘his go back to elaoshipberween Cad Cy HCC Nive “Thos, we asd ta salve fr, Solving fro, wing ()-(¥) we get ave 0+. spy Teoma — N+ kasama P? Day Nutra = Naeer = = G+KysionA WD y ‘Teoh = Dy Kasia PP (6) Examine the bebavir ofthe eubancement ator, ln it reaction) ‘Nar (0 a (a K).ahd = See = 1+ Kash 5 Forslow rsctons 2+ OwithK xed sony = 25, 484 cosh ee ee cata-1> eee | inl" agheas (Ge. ao eabancement for very slow reaction mi, s expected) Foe fist eatons, + 90th K fot: ate WE” (en) +a ‘Thos, Eis lagest for} > | (ist ection) and3 Accum (Ro otha with K <1 the lot of present. This what least the age as enhancements 3-6, Bimolecular Reaction in a Liquid Film "rom te problem satement (a) The hey polo sti ork — 00, te homogeneous reaction can be weted mathematically asi it wee Ieterogencois. The locator of te reaction plane (& =p) i naan, Conservation ofA for0 = x= Po de cx Can. Cabin) cus) (Coasrvation of B or sy $x = Es Colm) =O, CL) Cu ) Satsfies BCs “To determines e tet the rection plane aan intrace an apply interfacial species balances Let my (coral interac) In pesea Apply to6 ‘The sane esl obtained om overall conservation of, Solving (3) and (4) smaltancouly ives ia,b Cae For Da =» co, the rection zone approaches plane as assumed in part (a) The onder-of magnitude analysis ingests how lange Da mus be fr theresa pat (af be acct, 37. Sieving Coefficient in Ultrafiltration (@) Evan © = C/G in theabsens of concentaton polation [wth Cx) = Cl ‘Conservation equation for sein membrane En au aD socyW av. nagla noo Nene Formulation for Cy) = dey x a (r= pe Be) ea0= C=, were (a Cul) desta sx Salve the ist-order liner ODE for Cu ain) = 804 uO) = cunmcaes Hoy Neem © em cuit) = Scum He) Bowne) =-ce a ww Ta We Culm) = Gee le) Guts) _ SL = = Wee G Taam Sra Weta 41 eee T=d-We a= meretn =a ie” Find Seving oot cr Guth) G ss stad, (Evaluate @ in general ‘Conservation equation for rte ms Cun) ‘The constans to be determi Cy and Cy se N and B. One con comes rom matching the concentaions seers Swe) =i] rer yen cain = caerermen s pwc ey — sJeton gM ‘The second codon come rom the ive conceneaton ety Macaminas Hig wom were Pe] Slama es) — weer a eee 3G” Wek WH er “ee = 6 asstated, “weso- WeQuattaveBohvion Sep 7 ght ee eteye ero au arora Fig, P37 Oth) = (witout) shows thst con entation polavzaion worsens the separate, bere {oemwih” Poy = Poy = Pe and W = 0. pa) and for “with.” Pey = Pe Pep and W = 1 oan a 3-8. Rate Constant for an Encounter-Limited Reaction (6) Stationary species 4 and sbi species B 282) 05 Cala +8) =0,C(00) = Ce