2-136 PHYSICAL AND CHEMICAL DATA CRITICAL CONSTANTS ADDITIONAL REFERENCES 1977):367-885. For inorganic substances see Mathews, Chem. Rev 72 (1972):71-100; for organics see Kudchaker, Alani, and Zsvolinsk, ‘Other data and estimation techniques forthe elements are contained | Chem, Rev, 68 (1968):659-735, and for luorocarbons see Advances in Gates and Thodos, Am. Inst. Chem. Eng. J, 6 (1960):50-54; and | in Fluorine Chemistry, App. B, Butterworth. Washington, 1963, pp. ‘Ohse and von Tippelskirch, High Temperatures—High Pressures, 9 | YT3-175, TABLE 2-164 Critical Constants and Acentric Factors of Inorganic and Organic Compounds Cmpa Px 18.06 y, ‘Acentrie 20. Nawe re casino. | Mol we Pa wikinol |Z, factor 1 | Methane vases [_Is0as ‘a0 | o2ss | ool 2 | ethane vasa | an070 ods | 0279 | 009 3 | Propane tags | as097 200 | 0273 | 1s 4 | Butane oars | S8.123 025s | oz | o197 5 | mPentane oas6o | 72.150 oats | o2m | 03st 6 | mHexane nosas | 86.177 oars | ozs | oo 7 | mHleptine uazsas | 100.208 os | 0259 | 0516 & | toctine nies9 | 114.39 o4ss | 0251 | 0308 8 | mNonane tiisiz | 128.958 540 | 0252 | oats 10 | teDecane oars | 142.288 anor | 021s | 048s 1] tndecane nia | as6a12 oss | oz 12 | nDedecane tizaos | 170538 ons | 029 13 | wTidecane 20505 | 184.365, ova | oa 1 | neTetradecane s2ase4 | 198.392 asso | 0236 15 | frPentadecane 620609 | 212419, osss | oz 18 | mllexadecane sues | 296.446 oo | 0221 17 | nleptadecane a0 240473 oss | o2t9 1s | mOctadecane 50053 | 254.500 2.058 19 | fNonadecane 2005 | 268597 no 20 | nBicosane 12958 | 982.555 69 21 | 2Methylpropane wos | suas | aos.ia o2s | ozs 22° | 2 Medbyibutane ws | 2150 | 45093 oso1 | 0265 23 | 23-Dimethyibutene reoss | sary | 490) oass | 0268 24 | 2 Metisipentane 07535 | $6.1 497, o368 | o2s7 | 0270 25. | 25-Dimethypentane 65893 | 1on.20¢ | 537.38 396 | 025s | 0292 26 | 253-Thmetisipentine seo | 11425 S135 0455 | 0268 | 0289 27 | 22.4 tamethslpentane saosal | 114231 | 583.96 46s | o26¢ | 0301 28 | Ethylene asose | 282 oz | o2ss 29. | Propylene weost | 365 oss | 0256 30 | 1-Bitene S6108 | 41995 oz | oa BI | ci2Btene se108 | 43558 023s | ozs 32 | tane2-Butene cE seats | 56108 | 28.63 oar | oa 33 | 1-Pentene cH oar | o1se | 46a 78 9295 | o27 a | itesene cH. sete | S003 oasi | 0265 35 | Ltfeptene cH, ssiss | S3729 oats | 0261 36 | 1octene uizas | 566.5 25 460 | 0251 a7 | ENonene 126212 | 59a25 23a o52s | 0219 38 | LDecene 10269 | “sie 221 0584 30 | 2Metiyipropene se108 | 4179 398 0238 40 | Methylene 70.134 465 345 9.292 a1 | 2Medhyia-hutene 0.134 4m 338 0.202 42 | 12Bstadiene 092 2 435 9.220 a | 3Buudiene 06990 oo | 45.7 430, 0.290 44 | 2:Methy-1 S-butadione 775 | 68.119 84 385, 45 | Acetylene sasoz | 2603s | ose 46 | Methylacetylene 4997 6s | 402.39 47 | Dimotbyfacot s0s173 oo | 4732 48 | a-Medyit bu soso | 5.119 | 4632 49 | LPengme seviso | suis | asia 50 | ZPentyne seria | 68119, 319 st | LHtesyne sor | sous | stoa 0.335 52. | 2llegme eass2 | 82.145 39 0221 si | a Heme sassy | sous, m 0219 54 | uleptyne s2si1 96.172 359 oat 5 | Lote 29050 | 110.199, 85 0.325 56_| Vinslecestene ssovia | s2076 st 6.109CRITICAL CONSTANTS 2-137 TABLE 2-164 Critical Constants and Acentrie Factors of Inorganic and Organic Compounds (Continued) mpd rxie06 |v. ‘Aeentr uo Name Formula | caso | Mowe | nx Pe wiimot | 2 | “tector Cyclopentne Cally asroes| roam | 51176 130 oz | 0106 fethveylopentane Cat, scart | stiot | 5u279 318 az | 0230 deylopentane cin reinss7 | oss | 56052 340 ost | 0269 | oan Gycbtexane cams tioser | stiot | sas sho 30s | oats | 0212 Metieylohesane cn. toss: | Ss 1ss 19 38 6358 | 026 | o236 LiDimedylgetobexine | Cake saoeso | uazis | Solis 294 oso | oa | o2ss tvkyelohenane cit sisi? | 112215 | 600s sas aso | 0958 | 0246 Cyelopentene can i2290 | 68.119 07 SI 285 | oT | 296 Metislselopentene CH, ssss90 | 32s | 582 a3 30s | o27s | o2s2 eloherene City oss | szias | sos 439 oa | oan | a2i6 st] Beasene nus | rsa | seats ors 88 | Tauene ossss | saat | Sons 00362 6 | oXene sive | 106167 | 63033 0267 Xylene 1osiss | losis | 61705 02359 pailene tosis | tosicr | 162s 0.260 wloonzone oad sr | sir 0253 | ao. Propylbenzene roses | i210 | 6832 ozs | oad 124-Timethylbenzene seas | 120.94 | ions o2s0 | asso Ibopropyibenzene sss | Laois | “ost 1250 | 0322 13i5chmeteazene roses | i20104 | os7536 0397 p-lepropytaluene sus7e | tonal | 6535 0368 Kapithalene vam | iasim | 7483s 5208 Biphenyl sian | 79926 0367 Siyrone roowws | ionize | ose 0.295 re Terphens! soos | 250309 | ants 0561 82 sisi | azo | siass 0566 5 sims | aso | sis 288 84 | LPropent Cako miss | 60.0% | 53675 sit 5 | LButtnol CHO nie | This | 36808 9585 86 | 2 butanol Cano. yssnz | tas | ssus ost 87 | 2 Propel cxo rss | 60.006 | “5083 0670 88 | 2Metist2 propane Cano rsas0 | T4123 | 50521 083 89] LPestanl ct,0 nino | 38130 0592 * vi l-butanol cio sisas | $8150 08 a1 | SMeuicbutanel can. assis | $8.50 0386 92] texan Cato tines | woe 55 93 | LcHepeanct Cao 1irros | 116.203 0592 94 | Gctheranot Gio 13930} 100.161 oan 95 torzn | ‘6208 0487 9% srsse | Ta085 1102 n roses | sis | 9942s 0.438 98 seis? | 1os.40 | 6975s 0438 98 rosie | tosi40 | 70585 ast 10 iosias | i0s.140 | 70465 0307 ror | Dinetdy ethe uisios | aso | 4002 0192 102] Metist edi! ether sist | soos | 437s 0229 103 | Metist propyl ether Cato sri ui | 4763 0264 10d | Metslisoprpyletier | Cillyo sassas | Tuiss | ants 0280 105 | Metistndul ether Gino aszsi | 58150 310 0335 105 | Metis abut! eer car.0 srsass | $550 | 0310 tor | Metsltercbuytether | GitzO weaioas | ssis0 | ov 5264 10 | Diet ether Caro sozor | Tales | ee. 0281 105. | Ealyi propyl ether citi easizo | ssis0 | 50023 oT Ho | a hopper Car. ssis0 | "80 8.309 11 | Metist phew edher CH oso | ise 0353 12 | Dipbenjledier Gutixo woisss | roa | 668 oss ua | Formaldebyde cHo soo | soaxs | 40s ozs | o2se Tid | Acetaldeh ye wa | toss | 468 oat | S202 Us | LPropand zssse | 58.080 | soa 492 0239 | 0256 16 | 1-Butana v2sms | tenor | 5sr9 ts 0350 | 027s UT | CPestanal thoes | seis | 505. 337 ozs, | oat lis | Henan saat | 100.161 51 36 0950 | 9.387 119 | Hteptanal arar | iiss | ir 5s ozs | osz7 129 | 1octanl wa4iso | ias2ia | ost 2s7 oss | oat 121 | Nenana c i240 | 1az241 638 2m ozs | osid 122_| 1-Decan ee nissia_| 150268 | oraz 260 0269 | 0582,2-138 PHYSICAL AND CHEMICAL DATA. TABLE 2-164 Critical Constants and Acentrie Factors of Inorganic and Organic Compounds (Continved) mpd Px 18-06 V esate 2 Nate Fonwla | casino. | Mol we wikinat_ | 2 | Mector 3 | _Accune cio srear | 58080 o2i0 | 02s | 0307 24 | Meidahetts ketone cao sss | 2107 o2s7 | o2a7 | 03a 25 | 2-Pentanone cto ors | sie oxo | 0239 | os 26 | Metsiisopropylketone | Gilly0 seasor | S634 osis | 02s | 0349 at | 2Hlexnone cio soir | 10016 0300 | 0330 | 0395 23 | Metinfucbupttetose | CHAO asio1 | 10016 o3es | 025 | oss 135, L2-pentanone cro 565617 | tov i6t 53 ost | 0259 | 0386 30 | SPentanone Cio e220 | soise | soos 0335 | 0267 | 0340 131 | yt iopropy ketone cao 565655 | 100161 ser 0363 | 0262 | oso 32 | Ditopropst ketone cane ssesso0 | 114188 376 osis | 0259 | oat 135 | Cyclohexanone co rosa | 9345 | 655 ost | 0230 | 030s | Methyl pens! ketone Go sso | t20ist | wo0s 03s | 0282 | 036s 35 | Formic acid cH.o, suse | sox 388 ssi ous | ons | ost7 136 | Acetic sed GLO, sisr | aos | sores 37 oi | 0205 | 045s 7 | Propionic acid Cito, ‘ooo | 74079 | ao, it 02% | o2is | os 18] nBhiyie aid cio, ora | ss.i06 | “ss. 07 oat | 02s | 0682 39 | Tobutme aid cio: asi2_ | ssioe | ous 368 oat | o2is | osiz 140 | Benznc ac cio, sss | 122123 1 at osa7 | 028 | 0603 1 | scetie alyride CHO, seat | 102050 | 605 aut 0290 | 0229 | 0450 formate 00s 0254 acetate 74079 0325 propio 38.100 oa bute 102133 037s 46 0282 Lit | Ethyl acetate 35.106 0388 45 | Ells propionate 102133 oot 49 116.160 399 50 | n-Bropl formate ‘38.105 0310 St | m Bropl acetate 02133, 0300 152 | tBu scare 116160 aio 53 | Methyl benzoate Gao. ‘ass | 13es0 aay 151 | Eth bonate CLO, sass | 150a7 oar 55 | Vinglaceute cio, osast | “38090 0318 Methylaine cisos | 1037 o279 Dimetilarine 5.054 0235, Tiimethylamine sou 0310 Eylanine 35.054 0283 Dietbslanine 7338 0300 Tretamine ziaas | 10102 sie 162 | nPropslanine wos | sou o2s0 3 | door dopylamine asi? | 101192 oat6 64 | Lopropslanine wssio | Sout 0276 165 | Disoprepylanine sis | 101192 0388 66 | Anne sass | Shas 03s ier | NMethylanine woes | 107158 oso 8 Dimethslaine 2697 | tnt ise 0403 Ethylene oxide sos | sos 2s | o2ot Fonn sor | 9015 0397 | 0205 Thiophene saz | 57035 200 | 019s Pyridine Tio | 61995 oars | 0259 Formamide cHXo 450m m cist | os NNeDinettyformamide | GENO zis | 6196 oz2 | ose Acetaride CHLNO 38.088 0223 | oai9 N-Methylacetanide cinxo 73095 S00 2a | oas7 Acetone CaN 41053 ass iss | 0340 Propionitile 35079 419 205 | 032s neBugronitale 9.106 a7 0217 Benzontnle 103.123 42 0245 sasat_ | 48.100 0268 Ebi mere sos | $2136 0273 sPropy mereaptan cma | Toss 0355, tBu sereaphen 1osTss | on 189 0357 Teobutyt mereaptan sisuo | 90189 0288 see-Butyt mereaptan 3531 | 90189 oan Dimetis sade iss | 6.136 0355 Metis ets slide szisss | Toss 024s Diethyl sulide ssane_|_o0is0 oarsCRITICAL CONSTANTS TABLE 2-164 Critical Constants and Acentrie Factors of Inorganic and Organic Compounds (Concluded) 2-139 Gmpd Px IEG Ni 10, Name Formula | CAS a0 Mol. wt Pe wiKinal |Z. 190 | Fhuoromethane sess | 31033) 588 oase 191 | Chloromethane vasa | 50.488 0275 192 | Treboromethane 7663 | 119377 555, 9.296 193 | Tetrchloromethane geass | 153.822 456 0270 194 | Bromomethane 74839 | 94959 800 156 | 931 195 | Fluoroethane asa | 48.060 501 oass | 0263 196 | Chloroethane wos | 645i4 5.46 oss | 9231 197 | Bromoethane 74964 | 108.966 639 oais | ose 19s | 1-Chloropropane siosas | 78.541 458 oss | 0270 199 | 2:Chloropropane 75286 S541 451 ost | 9274 a0 | Li-Diekboropropane qs09 | 112986 0282 | 0.265 201 | L2-Dickloroprepane 78875 oan | 0359 202 | Vinyl conde 75014 ome | 02s 203, | Fliorobenzene 452066, 454 0.269 | 0262 204 | CMlorobenzene 108907 4s aos | 0.265 205 | Bromobenone Caer 108861 452 osed | 9265 206 | Air aszasei00 | 28.951 0.092 | 931s | a0 207 | Tiydrogen 1 1asa740 2016 132 os | o307 | -o2i5 208 | Helmet We 40597 44005 033 05s | 9305 | o385 209 | Neon Ne rasoor9 | 20.180 267 oo | 0300 | aos 210 | Argon Ar vawost! | 39.948 490 0075 | o2s2 | a0 an | Fluorine y Tisza 37907 317 oos7 | 0287 | ose 212 | Chlorine 7782505 7o.905 oe | 0279 | oor 213 | Bromine rrasoss | 159808 1038, 0135 | 9286 | 128 ais | Oxygen sz4s7 | 31.999 5.02 coors | oas7 | 020 215 | Nivogen ram | as.014 330 059 | 928s | 037 216 | Ammonia resasi7 | 17031 1130 oor | oa | oss ait | Hydrazine sooz | 32045 1473 oss | 9439 | ois, 218 | Nivousexide roo2aa72 | 44.013 28 oss | o277 | alas aio | Natreoxide roiwza9 | 30.008 652 ooss | o2se | sss 220 | Cyanogen gooi9s | 52036 394 ois: | o3as | zr 321 | Chrbon monoxide 28010 349 0.095 | 0300 | oss 222 | Carbon dioside 44010 739 0.095 | o27r | oz 223 | Carbon dielfide 7618 S08 ors | 0280 | ous. 201 | Hydrogen fvonde 7661393 | 20.006 649 oon | oir | 038s 225 | tydrogen chloride yervow | 36461 8.36, oos2 | o2ss | ols 225 | Hydrogen bromide 10035106 86 e100 | 9280 | 0069 207 | Hydrogen cyanide 74908 535, ox | 019s | 407 228 | Hydrogen sulfide 7785064 9.00, 0.099 | 9287 | 006 a2 | sulfurdioxide 46005 786, oa | 0269 | oat 250, | Sulfur tronide 119 819 ou 0 0423 ast | Water qraiss | 1so1s 2198 ose | ozs | oss Allsibstances are Histed in alphabetical order in Table 2-6 supiled froma Daubort, F E., RP Danner HLM. Sibu, and Release. July 107, National Physical Laboratory, Inorder to ensure thermodynamic consistency in almost all cases these properties are calculated from T andthe vapo Stebbins, DIPPR Data Cora tion of Pure Cotapound Properties, Projet $01 Sponsor 1985, Design Iasttte for Plyscal Popesty Data AICAE, New York NY, and fm Ambrose, D. “VapoursLaquid Cated Properties. Report Chem eddington, UK, Geter 1979 ligt density comtation cook ficient listed in those tables, This means that there wil be slight differences between the values sted here and those in the DIPER tables. Most ofthe differences ste lese than 1%, and almost ll the ret are less than the estimated aceutucy of the quantity ia question. “The stomic weights used, taken from. Phys: Chem, Ref. Data 22(6), 79.908. and T= 126 9048 “The value ofthe gas constant, R used here s 831451 Jkinol K), ae given by E 35.4527, Br 18*K~45967 999, are C 2011 15.9994, N 4.00674, $ = 32.066, F 18.9984, Cl R Cohen and B.N. Taylor in Phys Chem. Ref. Dato 17, 1988. K~ 273.15 =°C; TF, Pa 9.850293E-06 ~ atm, Pa 1A80377E-04~ pra} toro] x (IE + OB/ml, wt) ~ cng Vkmol (L60848E + 01/mol wa) =