Q6 Q7 Qs as Qo Qu Qi2 Qi4 Ql6 Qi7 Qis Qi Q.20 SOREN CON [SINGLE CORRECT CHOICE TYPE] Select the compound which have same reason fornon existence as for NCl, (A)SCl, (B)Xell, oc (D) Clo, In the context of carbon, which of the following is arranged in the correct order ofelectronegativity (A) sp>sp?>sp'—(B) sp’>sp">sp (©) sp" > sp>sp'—(D) sp’ > sp> sp* * and Hell” is le,’ (C)HeH">He,* —_(D) Can'tbe predicted The bond energy order of H (A)He,"> Hel” (B) Heli” Among the following, van der Waals forces are maximum in (A) HBr (8) LiBr (uc (D)AgBr In ICI? , the shape is square planar. The number of bond pait-lone pair repulsion at 90° are: (A)6 (Bs on (D)4 Hybridization of carbon in C0, (A) sp (B) sp? Oy (D) sp'a PCh, exists but NCI, does not because (A) Nitrogen has no vacant d-orbitals (B) NCI, isunstable (©)Nitrogen atom is much smallerthan p —_(D) Nitrogen ishighly inert lar shapes of SF, CF, and XeF, are ume, with 2, Oand! lone pair of electrons respectively (B)the same, with 1, | and I lone pair of electrons respectively (C) different with 0, 1 and2 lone pair of electrons respectively (D) different with 1,0.and 2 lone pair of electrons respectively In theeyanide ion the negative charge is on (Aye (B)N (C)Both Cand (D) Resonate between Cand N A:tetracyanomethane B:Carbondioxide —C: Benzene D:1,3-buta-di-ene Ratio of 6 and x bonds is in order: ) oD (B) c (C)A=B=C=D (D)C Br“> Ch> (B) > Br'> F> Ct (QrS, OS\ CH,F > CHBr> CHyL (B) CHF > CHCl> CH,Br> CHI (C)CH,C1> CH,Br> CHy1> CHF (D) CHF > CHCl> CHy1> CH,Br ‘The phosphate ofa metal has the formula MHPO,, ‘The formula ofits chloride would be (AMI (B) MCI, (cl, (D) MCh, CHEMICAL BONDING AND MOLECULAR STRUCTURE Q28 Q29 Q30 Q3l Q32 Q33 Q34 Q35 Which of the following statement is not correct - (A) CH,* shows sp*-hybridisation whereas CH, shows sp*-hybridisation (B) NH," has aregular tetrahedral geometry (C) sp?-hybridised orbitals have equal s and p character (D) Hybridisation orbitals always form a-bonds Which of the following compound does not follow octet rule: (A)CO, (B) PCI, ore (cr, ‘The magnitude of the lattice energy ofa solid increases if (A) The ions are of large size (B) The ions are of small size (C) The ionsare of equal size (D) Charges on the ions are small Out of CHCI,, CH, and SP, the moleculeshaving regular geometry ar: (A)CHCI, only (B)CHCI, and SF, (C)CH, only (D) CH, ands! ‘The bond angle in H,O molecule is less than that of NH, molecule because’ (A) The hybridisation of O in H,O and N in NH, is different (B) The atomic radii of N and O are different (C) There is one lone pair of electrons on and two lone pairs of electrons on N (D) There are two lone pairs of electrons on O and one lone pairs of electrons on N ‘The bond angles of NH,,NHj and NH; are in the order: (A) NH > NH, > NH,* (B) NH," > NH, > NH- (C) NH, > NH, > NH,* (D) NH, > NH,' > NHy Which of the following compounds isnon-polar: (A)CH,CI (B)CH,CI, (CHC, (cel, Which of the following will be least polar: (A)N-H (B)C-H (C)O-H (D) HFQ.36 Q37 Q38 Q39 Q4o Qat Qa42 Q43 4a Qs Q.46 Qa7 Qas [MULTIPLE CORRECT CHOICE TYPE] Which have fractional bond order? a) (B)O> (NO (Dy Which of the following have planar structure? AI (B)H,0 rc, (D)XeF, In the structure of H,CSE,, which of the following statement is/are correct? (A) Two C-H bonds are in the same plane of axial S-F bonds, (B) Two C-H bonds are in the same plane of equitorial S-F bonds, (C) Total six atoms are in the same plane, (D) Equitorial S am 5 CHEMICAL BONDING AND MOLECULAR STRUCTURE ‘The linear structure isassumed by (A) SnCly (8) veo Ocs, (D) noz ‘Choose the correct option forthe following molecule in view of chemical bonding ON aes prereeeeK (A) non-planar (B) #0 (ARB both (D)w=0 Which of the following conditions apply to resonating structures ? (A) The contributing structures should have nearly similar energies (B) The contributing structures should be represented such that like charges reside on atoms that are far apart (©) The more electropositive element should preferably have positive charge and the more electronegative clement have negative charge (D) The contributing structures must have the same number of unpaired electrons Which of the following have a three dimensional network structure? (A) So, (B) (BN), (C) Puowhite) (D) ech, Which of the following donot exists? (A) SH, (B) HE, (©) Fel, (D) HCI0, Which of the following havean (18 + 2) electron configuration ? (A) Po (B) ca" (© Br () soz ‘The structure of XeF, is (A) pentagonal bipyramidal (B)distorted octahedral (C) capped octahedral (D) square pyramidal [PARAGRAPH TYPE] Paragraph for Question Nos. 46 & 48 ‘Sulphur forms a number of compounds in its different oxidation states including oxy acids. Theshape of the compound and the hybridization of sulphur also varies. ‘The shape of SF, and hybridization of Sin it are (A) Angular, sp* (B) Angular, sp? (C) Linear (D) Linear, sp'd Shape of SF, is (A) Tetrahedral (B)Square planar (C)Square pyramidal (D) See-Saw Oxidation state of S in H,SO, and H,S,0, are respectively. (A)+6,+7 (B) +6both (C)+7 both (D) None of theseCHEMICAL BONDING AND MOLEGULAR STRUCTURE ANSWER KEY EXERCISE-1 Ql C Q2 A Q3 C Q4 D QS B Q6 A QT A Q8 D Q9 A QA QUA QC QB A QB Qis C QI6 A QI7 Bo QI8 Bo QI9 B- Q2 A QA A Q22.B O23 C Q4 B QC Q% A Q27 BB QwC Q29 D Q30 BB Q31C Q32 D Q33B QM D Qs B Q36 ABCD Q37 ABD Q38 ACD Q39 BCD Q40 D Q4l ABCDQ42 AB Q43 ABC Q44 AC Q45 BC Q46 A Q47 D Q48 B