644 Apéndice B Tabla BA _Constantes de la ecuacién de Antoine” login p* B T+C pt en mm Hg, Ten Ejemplo: La presién de vapor del acetaldehido a 25°C se determina como sigue: oBi0 Pe 11,25°O = => pPcgHyo(25°C) = 102.9551 = 902 mm Hg 00552 — 160.017 25+ 291.809 = 2.9551 ‘Compuesto Formula Rango (°C) 4 B c ‘Acetaldehido H,O =0.2.a34.4 8.00552 1600017 291.809 Acetato de etilo Cag 1562758 7101791244951 217.881 Acetato de etilo® CiHgO2 20 a 150 7.09808 1238.710 217.0 Acetato de metilo CH 62 18.0558 7.06524 157.630 219.726 Acetato de vinilo CHO 21.8720 721010 1296.130 226.655 Acetona CHO 1290553 717141210595 229.664 ‘Acido avttico H,0, 29.84 1265 738782 «1533313 222.309 ‘sido avétioo* H,O; 0036 718807 1416.7 22s Acido acrilico C3H,O 20.0.2 70.0 5.65204 648.629 154.683 Acido botirico CaHg02 20.0 a 150.0 8.71019 2433014. ——255.189 Acido férmico CHO; 37441007 758178 169.173.260.714 Acido propisnico CsHOr 72401283 7.71423 1733418 217.724 Agua” 130 0260 8.10763 1750286 235.000 Agua 30 60a 150 7.96681 1668210 228.000 ‘Amoniaco* NH; =83 2 60 7.55466 102.711 247.885 Anhidrido acético CiHOs 2.841394 7.14948 (1444718 199.817 Anilina CaN 102.6 a 185.2 732010 1731.515 206.049 Benceno CoH 14.5 280.9 6.39272 1203.531 219.888 Bromuro de metilo CHBr =70.0 03.6 7.09084 1046.06. 244.914 i-Butano iC yo 85.1116 6.78866 899.617 241.942 n-Butano neCHig =78.0a-03 6.82485 943.453 239.711 I-Butanol CHO 89.20 125.7 736366 1305.198 173.427 2-Butanol CHO 7240 107.1 7.20131 1157000 168.279 1-Buteno Cis <11$a-37 653101 810.261 228,066 Cianuro de hidrégeno HCN 16.4 0 46.2 7.52823 1329.49 260.418 Ciclohexano Cothia 19.9.4 81.6 6.84941 1206001 223.148, Ciclohexanol Coti0 93.7 a 160.7 6.25530 912.866 109.126 Clorobenceno CoHSCl 62.08 131.7 6.97808 1431053 217.550 Clorobenceno* CHCl oan 7.10690 1500.0 24.0 Clorobenceno* ColisCl 42.0230 6.94504 1413.12 2160 Cloroformo CHCl; 10.4.2 603 6.95465 1170966 226.232 Cloroformo* HCI; =30.a 150 6.90328 1163.03 274 Cloruro de etilo HCl 35.9.0 125 6.98647 1030.007——238.612 Cloruro de metilo CHSCI -75.005.0 7.09349 948.582 249,336 n-Decano nC 945.0175.1 6.95707 1503568 194.738, 1-Deceno CigHao 86.8 a 171.6 6.95433 1497527 197.056, 1,1-Dieloroetano GHC, -388.0 17.6 697702 1174022 229.060 1,2-Dieloroetano GH,CI =30.8.2.99.4 7.02530 127.254 222.927 Diclorometano CHCl, —40.0 2 40 7.40916 1325938 252.616 Dietileetona 5H 565 a 1113 7.02529 1310281 214.192 Dietilengticol CiHi002 130.0. 243.0 7.63666 1939359 162.714 Dimetilamina GH:N =11.8.6.9 7.08212 960.242 221.667 N.N-Dimetilformamida — C3H;NO——-30.0.90.0 6.92796 140.869 196.434 (continia)Tabla B4 (Comtinuacién) ‘Tablas de propiedades fisicas ‘Compuesto Formula Rango (°C), 4 B o 1.4-Dioxano CHO) 20.0.2 105.0 7.43155 1554679 240.337 Disulfuro de carbono CS) 3.62 79.9 6.94279 169.110 241.593 Estireno Gils 29.9.0 144.8 7.06623 1507.434 214.985 Btanol CHO 19.6 093.4 8.11220 1592.864 226.184 Etanolamina CHINO 65.44 170.9 7.45680 1577.670 173.368 Eter dietitico CH =60.8 0 19.9 692032 1064.06. 228.799 ter dimetitico CHO =78.2a-249 6.97603 889.264 241.957 Etilbenceno CHhio 56.5 a 137.1 695650 1423.543 213.091 1,2-Btilendiamina CHAN 2650174 7.16871 1336235 194.366 Etilenglicol CoH,O2 50.0 2 200.0 8.09083 2088.936 203.454 Fenol CHO 107.20 1818 7.13301 1516.790 174.954 Formaldehido HCHO 1094-223 7.19578 970.595 244.124 Glicerol CFOs 183322604 6.16501 1036056 28.097 iHleptano iCHHig 18.5 290.9 6.87689 1238.12 219.783, n-Heptano nCoHis 259.2993 6.90253, 1267828 216.823, I-Hepteno Crs 2162945 691381 1265120 220.051 i-Hexano Cots 1282 61.1 6.86839 1151401 228.477 n-Hexano Calis 13.0269.5 688555 1175817 (224.867 I-Hexeno Cotta 159.2643 686880 154.646 226.046 Metacrilato de metilo CsHg0 39.2.089.2 8.40919 2050467. 274.369 Metanol CH,OH 1490 83.7 8.08097 182.271 239.726 Metanol* CH,OH 20a 140 787863 1473.11 230.0 Metilamina CHsN ~83.1a-62 7.33690 1011.532—233.286 Metilcictohexano Coty 25.62 101.8 6828271273673. 221.723 Metiletilcetona CHO 42.8 0884 7.06356 1261339 221.969 Metilisobutilcetona CaHli20 217 a 1162 667272 1168408 191.944 Naftaleno CigHe 80.3 a 179.5 7.03358 «1756328 204.842 Nitrobenceno CoHsNO> —134.1.0210.6 7.11562 «1746586 201.783, Nitrometano CHSNO, 55.70 136.4 7.28166 1446.937 227.600 n-Nonano CoH 703.1518 693764 1430459 201.808 L-Noneno Coty 66.62 1479 695777 1437.862— 205.814 i-Octano i-CyHs 4L7a 18s 6.88814 1319529 211.625 n-Octano Cots 52.9.0 126.6 691874 1351756 209.100 1-Octeno Chie 44.9 01222 693637 1358.79 213.022 Oxido de etileno OHO 030318 8.69016 2005.79 334.765 Oxido de propileno CHO. ~24.2a348 7.01443 1086.369 228.594 i-Pentano ECSHyy 16.3 028.6 6.73457 992.019 229.564 n-Pentano nCoHy 13.3 0368 6.84471 1060793 231.541 1-Pentanol CsH1;20 74.7 0156.0 7.18246 1287625. 161.330 I-Penteno CsHio 128.0307 684268 104.206.233.344 Piridina CSHsN 67.3 0152.9 7.04115 1373.799 214.979 1-Propanol CHO 60.2 a 104.6 774416 1437686 198.463 2-Propanol CHO 52.3. a 893 7.74021 1359517 197.527 Tetracloruro de earbono Clg 14.1 760 6.87926 1212021 226.409 Tolueno CoH 353 aS 6.95805 1346.73 219.693 1,1,1-Tricloroetano GHC ~3.42 169 8.64344 2136621 302.769 1,1,2-Trieloroetano GHCls 50.0 a 113.7 695185 1314410 209.197 Tricloroetileno GHC; 17.8 086.5 651827 1018603 192.731 m-Xileno m-CoHio 59.2. 140.0 7.00646 1460.183 214.827 o-Xileno o-Cetlio 3.5 0145.4 700154 1476393213872 p-Xileno PCsHio 58.3.4 1393 6.98820 1451-792 215.111 “ Adaptada de . Boublik, V. Fried, y E. Hala, The Vapour Pressures of Pure Substances, Elsevier, Amster- dam. Las constantes con asterisco (*) se tomaron de Lange's Handbook of Chemistry, 9a, edicién, Hand- book Publishers, Inc., Sandusky, OH. 645: