MODELO DE WILSON

CONTRUCCION DE DIAGRAMA A t CONSTANTE USANDO WILSON

Constantes de Antoine Constantes de Wilson

i Compuesto Ai Bi Ci R a12 a21
1 1-propanol 16.12 3483.67 205.81 1.99 775.48 1351.90
2 agua 16.39 3885.70 230.17

Datos Variables
t= 60.00 C T= 333.00

t T x1 Wilson x2 Psat1 Psat2 Λ12 Λ21 ln(ϒ1)

60.00 333 0.00 1.0 20.27 20.01 0.0745 0.5390 3.06
60.00 333 0.05 1.0 20.27 20.01 0.0745 0.5390 2.18
60.00 333 0.10 0.9 20.27 20.01 0.0745 0.5390 1.68
60.00 333 0.15 0.9 20.27 20.01 0.0745 0.5390 1.35
60.00 333 0.20 0.8 20.27 20.01 0.0745 0.5390 1.10
60.00 333 0.25 0.8 20.27 20.01 0.0745 0.5390 0.91
60.00 333 0.30 0.7 20.27 20.01 0.0745 0.5390 0.75
60.00 333 0.35 0.7 20.27 20.01 0.0745 0.5390 0.62
60.00 333 0.40 0.6 20.27 20.01 0.0745 0.5390 0.51
60.00 333 0.45 0.6 20.27 20.01 0.0745 0.5390 0.42
60.00 333 0.50 0.5 20.27 20.01 0.0745 0.5390 0.34
60.00 333 0.55 0.5 20.27 20.01 0.0745 0.5390 0.27
60.00 333 0.60 0.4 20.27 20.01 0.0745 0.5390 0.21
60.00 333 0.65 0.4 20.27 20.01 0.0745 0.5390 0.16
60.00 333 0.70 0.3 20.27 20.01 0.0745 0.5390 0.12
60.00 333 0.75 0.3 20.27 20.01 0.0745 0.5390 0.08
60.00 333 0.80 0.2 20.27 20.01 0.0745 0.5390 0.05
60.00 333 0.85 0.2 20.27 20.01 0.0745 0.5390 0.03
60.00 333 0.90 0.1 20.27 20.01 0.0745 0.5390 0.01
60.00 333 0.95 0.1 20.27 20.01 0.0745 0.5390 0.00
60.00 333 1.00 0.0 20.27 20.01 0.0745 0.5390 0.00
 V Λ12 Λ21
75.14 0.074489
18.07

ln(ϒ2) ϒ1 ϒ2 Pcalc y1 Wilson y2 y1+y2 x1 x2

0.00 21.29 1.00 20.01 0.000 1.00 1.00 0 1
0.02 8.81 1.02 28.32 0.315 0.68 1.00 0.05 0.95
0.06 5.38 1.06 30.01 0.363 0.64 1.00 0.1 0.9
0.11 3.86 1.11 30.64 0.383 0.62 1.00 0.15 0.85
0.16 3.01 1.17 30.97 0.395 0.61 1.00 0.2 0.8
0.21 2.49 1.24 31.18 0.404 0.60 1.00 0.25 0.75
0.27 2.13 1.31 31.33 0.413 0.59 1.00 0.3 0.7
0.34 1.87 1.40 31.43 0.421 0.58 1.00 0.35 0.65
0.40 1.67 1.49 31.49 0.431 0.57 1.00 0.4 0.6
0.47 1.52 1.60 31.51 0.441 0.56 1.00 0.45 0.55
0.54 1.41 1.72 31.46 0.453 0.55 1.00 0.5 0.5
0.62 1.31 1.86 31.35 0.466 0.53 1.00 0.55 0.45
0.70 1.24 2.01 31.15 0.483 0.52 1.00 0.6 0.4
0.78 1.17 2.19 30.82 0.502 0.50 1.00 0.65 0.35
0.87 1.12 2.40 30.35 0.526 0.47 1.00 0.7 0.3
0.97 1.08 2.64 29.68 0.556 0.44 1.00 0.75 0.25
1.07 1.05 2.92 28.76 0.594 0.41 1.00 0.8 0.2
1.18 1.03 3.25 27.49 0.646 0.35 1.00 0.85 0.15
1.29 1.01 3.64 25.77 0.718 0.28 1.00 0.9 0.1
1.41 1.00 4.11 23.44 0.825 0.18 1.00 0.95 0.05
1.54 1.00 4.68 20.27 1.000 0.00 1.00 1 0
 Raoult x1 Raoult
P y1 y2
x1+x2 P Raoult y1 Raoult
1 20.01 0.00 1.00
1 20.02 0.05 0.95
1 20.03 0.10 0.90
1 20.05 0.15 0.85
1 20.06 0.20 0.80
1 20.07 0.25 0.75
1 20.09 0.30 0.70
1 20.10 0.35 0.65
1 20.11 0.40 0.60
1 20.13 0.45 0.55
1 20.14 0.50 0.50
1 20.15 0.55 0.45
1 20.17 0.60 0.40
1 20.18 0.65 0.35
1 20.19 0.70 0.30
1 20.21 0.75 0.25
1 20.22 0.80 0.20
1 20.23 0.85 0.15
1 20.25 0.90 0.10
1 20.26 0.95 0.05
1 20.27 1.00 0.00
 Diagrama a t=60 C
35

30

25

20
P / kPa

15

10

0
0.00 0.20 0.40 0.60 0.80 1.00
x1, y1
x1 Wilson y1 Wilson x1 Raoult y1 Raoult
 CONTRUCCION DE DIAGRAMA A P CONSTANTE USANDO WILSON

Constantes de Antoine Constantes de Wilson

i Compuesto Ai Bi Ci R a12 a21
1 1-propanol 16.12 3483.67 205.81 1.99 775.48 1351.90
2 agua 16.39 3885.70 230.17 0.00

P= 101.33 kPa Datos Variables

t= 60.00 C T= 333.00

t T x1 Wilson x2 Psat1 Psat2 Λ12 Λ21 ln(ϒ1)

99.99911 372.9991 0.00 1.0 112.58 101.33 0.0845 0.6710 2.80
91.0119 364.0119 0.05 1.0 79.74 72.90 0.0823 0.6415 2.04
89.32857 362.3286 0.10 0.9 74.57 68.40 0.0819 0.6359 1.58
88.68828 361.6883 0.15 0.9 72.68 66.75 0.0817 0.6338 1.26
88.3427 361.3427 0.20 0.8 71.68 65.87 0.0817 0.6327 1.03
88.11586 361.1159 0.25 0.8 71.03 65.30 0.0816 0.6319 0.84
87.95327 360.9533 0.30 0.7 70.56 64.89 0.0816 0.6314 0.69
87.8369 360.8369 0.35 0.7 70.23 64.60 0.0815 0.6310 0.57
87.76267 360.7627 0.40 0.6 70.02 64.42 0.0815 0.6308 0.47
87.73334 360.7333 0.45 0.6 69.94 64.35 0.0815 0.6307 0.38
87.75613 360.7561 0.50 0.5 70.00 64.40 0.0815 0.6307 0.30
87.84211 360.8421 0.55 0.5 70.25 64.62 0.0815 0.6310 0.24
88.00664 361.0066 0.60 0.4 70.72 65.03 0.0816 0.6316 0.19
88.27042 361.2704 0.65 0.4 71.47 65.69 0.0816 0.6324 0.14
88.66121 361.6612 0.70 0.3 72.60 66.68 0.0817 0.6337 0.10
89.21663 362.2166 0.75 0.3 74.24 68.11 0.0819 0.6356 0.07
89.98819 362.9882 0.80 0.2 76.56 70.13 0.0821 0.6381 0.04
91.04752 364.0475 0.85 0.2 79.85 73.00 0.0823 0.6416 0.02
92.49567 365.4957 0.90 0.1 84.53 77.07 0.0827 0.6464 0.01
94.47705 367.477 0.95 0.1 91.30 82.95 0.0831 0.6529 0.00
97.19941 370.1994 1.00 0.0 101.33 91.63 0.0838 0.6618 0.00
 V Λ12 Λ21
75.14 0.0745 0.0000
18.07

ln(ϒ2) ϒ1 ϒ2 Pcalc y1 Wilson y2 y1+y2 x1 x2

0.00 16.45 1.00 101.33 0.000 1.00 1.00 0 1
0.02 7.72 1.02 101.33 0.304 0.70 1.00 0.05 0.95
0.06 4.86 1.06 101.33 0.358 0.64 1.00 0.1 0.9
0.10 3.54 1.11 101.33 0.380 0.62 1.00 0.15 0.85
0.15 2.79 1.16 101.33 0.395 0.61 1.00 0.2 0.8
0.20 2.32 1.23 101.33 0.407 0.59 1.00 0.25 0.75
0.26 2.00 1.30 101.33 0.418 0.58 1.00 0.3 0.7
0.32 1.77 1.38 101.33 0.429 0.57 1.00 0.35 0.65
0.38 1.59 1.47 101.33 0.440 0.56 1.00 0.4 0.6
0.45 1.46 1.57 101.33 0.453 0.55 1.00 0.45 0.55
0.52 1.35 1.67 101.33 0.468 0.53 1.00 0.5 0.5
0.59 1.27 1.80 101.33 0.484 0.52 1.00 0.55 0.45
0.66 1.20 1.93 101.33 0.504 0.50 1.00 0.6 0.4
0.73 1.15 2.09 101.33 0.527 0.47 1.00 0.65 0.35
0.81 1.11 2.26 101.33 0.555 0.45 1.00 0.7 0.3
0.90 1.07 2.45 101.33 0.589 0.41 1.00 0.75 0.25
0.98 1.04 2.66 101.33 0.631 0.37 1.00 0.8 0.2
1.07 1.02 2.91 101.33 0.686 0.31 1.00 0.85 0.15
1.15 1.01 3.17 101.33 0.759 0.24 1.00 0.9 0.1
1.24 1.00 3.47 101.33 0.858 0.14 1.00 0.95 0.05
1.33 1.00 3.78 101.33 1.000 0.00 1.00 1 0
 Raoult x1 Raoult
y1 y2 y1+y2
x1+x2 P t Raoult Psat1 Psat2 P Raoult y1 Raoult
1 101.33 100.00 112.58 101.33 101.33 0.00 1.00 1.00
1 101.33 99.84 111.93 100.77 101.33 0.06 0.94 1.00
1 101.33 99.69 111.29 100.22 101.33 0.11 0.89 1.00
1 101.33 99.54 110.67 99.68 101.33 0.16 0.84 1.00
1 101.33 99.39 110.05 99.15 101.33 0.22 0.78 1.00
1 101.33 99.24 109.44 98.63 101.33 0.27 0.73 1.00
1 101.33 99.10 108.84 98.11 101.33 0.32 0.68 1.00
1 101.33 98.95 108.25 97.60 101.33 0.37 0.63 1.00
1 101.33 98.81 107.67 97.10 101.33 0.43 0.57 1.00
1 101.33 98.67 107.10 96.61 101.33 0.48 0.52 1.00
1 101.33 98.53 106.54 96.12 101.33 0.53 0.47 1.00
1 101.33 98.39 105.98 95.64 101.33 0.58 0.42 1.00
1 101.33 98.25 105.43 95.17 101.33 0.62 0.38 1.00
1 101.33 98.11 104.90 94.71 101.33 0.67 0.33 1.00
1 101.33 97.98 104.36 94.25 101.33 0.72 0.28 1.00
1 101.33 97.85 103.84 93.80 101.33 0.77 0.23 1.00
1 101.33 97.71 103.32 93.35 101.33 0.82 0.18 1.00
1 101.33 97.58 102.82 92.91 101.33 0.86 0.14 1.00
1 101.33 97.45 102.31 92.48 101.33 0.91 0.09 1.00
1 101.33 97.33 101.82 92.05 101.33 0.95 0.05 1.00
1 101.33 97.20 101.33 91.63 101.33 1.00 0.00 1.00
 Diagrama a P=101.33 kPa
102

100

98

96
T /C

94

92

90

88

86
0.00 0.20 0.40 0.60 0.80 1.00
x1, y1
x1 Wilson y1 Wilson x1 Raoult y1 Raoult
 t T x1 x2 Psat1 Psat2 Λ12 Λ21 ln(ϒ1)

Cálculo de Burbuja P con Solver Datos Variables

60.00 333 0.80 0.2 20.27 20.01 0.0745 0.5390 0.05

Cálculo de Burbuja T con Solver

60.00 333.0027 0.80 0.2 20.28 20.01 0.0745 0.5390 0.05

Cálculo de Rocio P con Solver

60.00 333 0.80 0.20 20.27 20.01 0.0745 0.5390 0.05
1.0000
Cálculo de Rocío T con Solver
60.0032 333.0032 0.80 0.20 20.28 20.01 0.0745 0.5390 0.05

Cálculo de flash

60 333 0.058244 0.941756 20.27 20.01 0.0745 0.5390 2.08

60 333 0.799835 0.200165 20.27 20.01 0.0745 0.5390 0.05
ln(ϒ2) ϒ1 ϒ2 Pcalc y1 y2 y1+y2 x1 x2

1.07 1.05 2.92 28.76 0.5943 0.4057 1.00 0.8 0.2

1.07 1.05 2.92 28.76 0.5943 0.4057 1.00 0.8 0.2

1.07 1.05 2.91 28.76 0.5941 0.4059 1.00 0.799835 0.200165

1.07 1.05 2.92 28.76 0.5943 0.4057 1.00 0.800034 0.199966

0.03 7.98 1.03 28.76 0.3278 0.6722 1.00 0.058244 0.941756

1.07 1.05 2.91 28.76 0.5941 0.4059 1.00 0.799835 0.200165
x1+x2 P y1 y2 z1 z2 K1 K2 nV

1 28.76 0.5943

1 28.76

1 28.76 0.5943

1 28.76 0.2 0.8 5.628364 0.713756 0.525856

1 28.76 0.7 0.3 0.742804 2.027727 0.48531
 y1 y2 y1+y2

0.327816 0.672184 1
0.594121 0.405879 1
Cálculo de Rocío T manual

t T x1 x2 Psat1 Psat2 Λ12 Λ21 ln(ϒ1)

60 333 0.60 0.40 20.27 20.01 0.0745 0.5390 0.21

60 333 0.70 0.30 20.27 20.01 0.0745 0.5390 0.12
60 333 0.76 0.24 20.27 20.01 0.0745 0.5390 0.08
60 333 0.78 0.22 20.27 20.01 0.0745 0.5390 0.06
60 333 0.79 0.21 20.27 20.01 0.0745 0.5390 0.06
60 333 0.80 0.20 20.27 20.01 0.0745 0.5390 0.05
60 333 0.80 0.20 20.27 20.01 0.0745 0.5390 0.05
60 333 0.80 0.20 20.27 20.01 0.0745 0.5390 0.05
60 333 0.80 0.20 20.27 20.01 0.0745 0.5390 0.05
60 333 0.80 0.20 20.27 20.01 0.0745 0.5390 0.05
60 333 0.80 0.20 20.27 20.01 0.0745 0.5390 0.05
60 333 0.80 0.20 20.27 20.01 0.0745 0.5390 0.05
60 333 0.80 0.20 20.27 20.01 0.0745 0.5390 0.05
60 333 0.80 0.20 20.27 20.01 0.0745 0.5390 0.05
ln(ϒ2) ϒ1 ϒ2 Pcalc y1 y2 y1+y2 x1 x2

0.70 1.24 2.01 31.15 0.5943 0.4057 1.00 0.7388 0.3137

0.88 1.12 2.41 30.33 0.5943 0.4057 1.00 0.7918 0.2556
0.98 1.08 2.67 29.59 0.5943 0.4057 1.00 0.8025 0.2249
1.03 1.06 2.80 29.14 0.5943 0.4057 1.00 0.8025 0.2107
1.05 1.06 2.87 28.92 0.5943 0.4057 1.00 0.8013 0.2045
1.06 1.06 2.90 28.83 0.5943 0.4057 1.00 0.8006 0.2018
1.07 1.05 2.91 28.79 0.5943 0.4057 1.00 0.8003 0.2007
1.07 1.05 2.91 28.77 0.5943 0.4057 1.00 0.8001 0.2003
1.07 1.05 2.91 28.76 0.5943 0.4057 1.00 0.8001 0.2001
1.07 1.05 2.92 28.76 0.5943 0.4057 1.00 0.8001 0.2000
1.07 1.05 2.92 28.76 0.5943 0.4057 1.00 0.8000 0.2000
1.07 1.05 2.92 28.76 0.5943 0.4057 1.00 0.8000 0.2000
1.07 1.05 2.92 28.76 0.5943 0.4057 1.00 0.8000 0.2000
1.07 1.05 2.92 28.76 0.5943 0.4057 1.00 0.8000 0.2000
x1+x2 P y1

1.0525 28.76 0.5943

1.0473 28.76 0.5943
1.0274 28.76 0.5943
1.0132 28.76 0.5943
1.0058 28.76 0.5943
1.0025 28.76 0.5943
1.0010 28.76 0.5943
1.0004 28.76 0.5943
1.0002 28.76 0.5943
1.0001 28.76 0.5943
1.0000 28.76 0.5943
1.0000 28.76 0.5943
1.0000 28.76 0.5943
1.0000 28.76 0.5943