SJ Mananquil BSCE3 Prelim

Problem : De Santis has derived a relationship for the compressibility factor for real gases of the form. If z = 0.892, find the
value of y using Method of Successive Substitution. Set e = 0 and use an initial value equal to 1

GIVEN:
z=(1+y+y^2y-^3)/(1-y)^3

Solution:

Iteration TA'(i) T(i+1) error Iteration TA'(i)

0 1 0.2122571 -371.1268 0 1
1 0.2122571 -0.09146 332.0753 1 1.337065
2 -0.09146 -0.000942 -9613.012 2 1.5953494
3 -0.000942 -0.040006 97.646301 3 1.7840897
4 -0.040006 -0.024406 -63.918 4 1.9184894
5 -0.024406 -0.030865 20.926263 5 2.0127554
6 -0.030865 -0.028228 -9.342655 6 2.0782589
7 -0.028228 -0.029311 3.6952639 7 2.1235071
8 -0.029311 -0.028867 -1.537334 8 2.1546431
9 -0.028867 -0.029049 0.6265558 9 2.1760137
10 -0.029049 -0.028975 -0.257528 10 2.1906567
11 -0.028975 -0.029005 0.1054836 11 2.2006785
12 -0.029005 -0.028993 -0.043268 12 2.2075323
13 -0.028993 -0.028998 0.0177373 13 2.212217
14 -0.028998 -0.028996 -0.007273 14 2.215418
15 -0.028996 -0.028997 0.002982 15 2.2176047
16 -0.028997 -0.028996 -0.001223 16 2.2190981
17 -0.028996 -0.028996 0.0005013 17 2.2201181
18 -0.028996 -0.028996 -0.000206 18 2.2208146
19 -0.028996 -0.028996 8.427E-05 19 2.2212901
20 -0.028996 -0.028996 -3.46E-05 20 2.2216149
21 -0.028996 -0.028996 1.417E-05 21 2.2218366
22 -0.028996 -0.028996 -5.81E-06 22 2.221988
23 -0.028996 -0.028996 2.382E-06 23 2.2220914
24 -0.028996 -0.028996 -9.77E-07 24 2.2221619
25 -0.028996 -0.028996 4E-07 25 2.2222101
26 -0.028996 -0.028996 -1.64E-07 26 2.222243
27 -0.028996 -0.028996 6.731E-08 27 2.2222655
28 -0.028996 -0.028996 -2.76E-08 28 2.2222808
29 -0.028996 -0.028996 1.132E-08 29 2.2222913
30 -0.028996 -0.028996 -4.64E-09 30 2.2222985
31 -0.028996 -0.028996 1.902E-09 31 2.2223033
32 -0.028996 -0.028996 -7.8E-10 32 2.2223067
33 -0.028996 -0.028996 3.198E-10 33 2.2223089
34 -0.028996 -0.028996 -1.31E-10 34 2.2223105
35 -0.028996 -0.028996 5.377E-11 35 2.2223116
36 -0.028996 -0.028996 -2.21E-11 36 2.2223123
37 -0.028996 -0.028996 9.046E-12 37 2.2223128
38 -0.028996 -0.028996 -3.7E-12 38 2.2223131
39 -0.028996 -0.028996 1.496E-12 39 2.2223133
40 -0.028996 -0.028996 -6.1E-13 40 2.2223135
41 -0.028996 -0.028996 0 41 2.2223136
42 -0.028996 -0.028996 0 42 2.2223137
43 -0.028996 -0.028996 0 43 2.2223137
44 -0.028996 -0.028996 0 44 2.2223138
45 -0.028996 -0.028996 0 45 2.2223138
46 -0.028996 -0.028996 0 46 2.2223138
47 -0.028996 -0.028996 0 47 2.2223138
48 2.2223138
49 2.2223138
50 2.2223138
51 2.2223138
52 2.2223138
53 2.2223138
54 2.2223138
55 2.2223138
56 2.2223138
57 2.2223138
58 2.2223138
59 2.2223138
60 2.2223138
61 2.2223138
62 2.2223138
63 2.2223138
64 2.2223138
65 2.2223138
66 2.2223138
67 2.2223138
68 2.2223138
69 2.2223138
70 2.2223138
71 2.2223138
72 2.2223138
73 2.2223138
74 2.2223138
75 2.2223138
76 2.2223138
77 2.2223138
78 2.2223138
79 2.2223138
80 2.2223138
81 2.2223138
82 2.2223138
83 2.2223138
84 2.2223138
85 2.2223138
86 2.2223138
87 2.2223138
88 2.2223138
89 2.2223138
90 2.2223138
91 2.2223138
92 2.2223138
93 2.2223138
94 2.2223138
95 2.2223138
m. If z = 0.892, find the

T(i+1) error
1.337065 25.209322
1.5953494 16.189831
1.7840897 10.579082
1.9184894 7.0054955
2.0127554 4.6834277
2.0782589 3.1518492
2.1235071 2.1308236
2.1546431 1.4450631
2.1760137 0.9820972
2.1906567 0.6684308
2.2006785 0.4553986
2.2075323 0.3104723
2.212217 0.2117659
2.215418 0.1444865
2.2176047 0.0986036
2.2190981 0.0673011
2.2201181 0.0459405
2.2208146 0.0313617
2.2212901 0.0214103
2.2216149 0.0146171
2.2218366 0.0099795
2.221988 0.0068134
2.2220914 0.0046518
2.2221619 0.003176
2.2222101 0.0021684
2.222243 0.0014805
2.2222655 0.0010108
2.2222808 0.0006902
2.2222913 0.0004712
2.2222985 0.0003217
2.2223033 0.0002197
2.2223067 0.00015
2.2223089 0.0001024
2.2223105 6.991E-05
2.2223116 4.773E-05
2.2223123 3.259E-05
2.2223128 2.225E-05
2.2223131 1.519E-05
2.2223133 1.037E-05
2.2223135 7.082E-06
2.2223136 4.835E-06
2.2223137 3.301E-06
2.2223137 2.254E-06
2.2223138 1.539E-06
2.2223138 1.051E-06
2.2223138 7.174E-07
2.2223138 4.898E-07
2.2223138 3.344E-07
2.2223138 2.283E-07
2.2223138 1.559E-07
2.2223138 1.064E-07
2.2223138 7.267E-08
2.2223138 4.962E-08
2.2223138 3.388E-08
2.2223138 2.313E-08
2.2223138 1.579E-08
2.2223138 1.078E-08
2.2223138 7.362E-09
2.2223138 5.026E-09
2.2223138 3.432E-09
2.2223138 2.343E-09
2.2223138 1.6E-09
2.2223138 1.092E-09
2.2223138 7.458E-10
2.2223138 5.092E-10
2.2223138 3.476E-10
2.2223138 2.374E-10
2.2223138 1.62E-10
2.2223138 1.106E-10
2.2223138 7.554E-11
2.2223138 5.158E-11
2.2223138 3.523E-11
2.2223138 2.404E-11
2.2223138 1.641E-11
2.2223138 1.121E-11
2.2223138 7.654E-12
2.2223138 5.236E-12
2.2223138 3.577E-12
2.2223138 2.438E-12
2.2223138 1.659E-12
2.2223138 1.139E-12
2.2223138 7.793E-13
2.2223138 5.196E-13
2.2223138 3.597E-13
2.2223138 0
2.2223138 0
2.2223138 0
2.2223138 0
2.2223138 0
2.2223138 0
2.2223138 0
2.2223138 0
2.2223138 0
2.2223138 0
2.2223138 0
2.2223138 0