Iteracion 1

Especie C0 ka1= 1.00E-07

[H2S] = 0.09 =x1 ka2= 1.2E-13
[HS-] = 0.09 =x2 kw= 1E-14
[S2-] = 0.09 =x3 C= 0.09
[H+] = 9.00E-06 =x4
[OH-] = 9.00E-06 =x5

Iteraccion 2
J J inversa
1.00E-07 -9.00E-06 0 -0.09 0 3.69E+04 -3.69E+04 -7.38E+04 -9.96E-01
0 1.2E-13 -9.00E-06 -9.00E-02 0 -7.38E+04 7.38E+04 3.65E+04 -7.38E-03
0 0 0 -9.00E-06 -9.00E-06 3.69E+04 -3.69E+04 3.73E+04 3.69E-03
-1 -1 -1 0 0 -3.69E+00 -7.42E+00 -3.73E+00 -3.69E-07
0 -1 -2 1 -1 3.69E+00 7.42E+00 -1.11E+05 3.69E-07
Iteraccion 3
1.00E-07 -9.03E-06 0 -6.67E-04 0 -2.44E+06 -5.02E+06 -2.58E+06 -1.24E+00
0 1.2E-13 -9.03E-06 3.29E-04 0 4.95E+06 1.02E+07 5.11E+06 4.95E-01
0 0 0 3.18E-08 -9.03E-06 -2.51E+06 -5.16E+06 -2.54E+06 -2.51E-01
-1 -1 -1 0 0 -6.89E+04 -1.38E+05 -6.96E+04 -6.89E-03
0 -1 -2 1 -1 -2.42E+02 -4.87E+02 -1.11E+05 -2.42E-05
Iteraccion 4
1.00E-07 -1.86E-03 0 1.33E-01 0 9.99E+03 1.94E+04 9.46E+03 -9.99E-01
0 1.2E-13 -1.86E-03 -6.75E-02 0 -1.97E+04 -3.84E+04 -1.92E+04 -1.97E-03
0 0 0 -6.53E-06 -1.86E-03 9.72E+03 1.89E+04 9.72E+03 9.72E-04
-1 -1 -1 0 0 -2.68E+02 -5.36E+02 -2.68E+02 -2.68E-05
0 -1 -2 1 -1 9.40E-01 1.88E+00 -5.36E+02 9.40E-08
Iteraccion 5
1.00E-07 -9.49E-04 0 6.53E-02 0 1.89E+04 3.67E+04 1.78E+04 -9.98E-01
0 1.2E-13 -9.49E-04 -3.31E-02 0 -3.72E+04 -7.23E+04 -3.62E+04 -3.72E-03
0 0 0 -3.20E-06 -9.49E-04 1.83E+04 3.56E+04 1.84E+04 1.83E-03
-1 -1 -1 0 0 -5.26E+02 -1.05E+03 -5.26E+02 -5.26E-05
0 -1 -2 1 -1 1.77E+00 3.55E+00 -1.05E+03 1.77E-07
Iteraccion 6
1.00E-07 -5.46E-04 0 2.76E-02 0 2.44E+04 4.70E+04 2.26E+04 -9.98E-01
0 1.2E-13 -5.46E-04 -1.41E-02 0 -4.79E+04 -9.21E+04 -4.61E+04 -4.79E-03
0 0 0 -1.36E-06 -5.46E-04 2.35E+04 4.51E+04 2.35E+04 2.35E-03
-1 -1 -1 0 0 -9.13E+02 -1.83E+03 -9.13E+02 -9.13E-05
0 -1 -2 1 -1 2.27E+00 4.54E+00 -1.83E+03 2.27E-07
Iteraccion 7
1.00E-07 -5.28E-04 0 3.90E-04 0 1.77E+03 1.64E+03 -1.24E+02 -1.00E+00
0 1.2E-13 -5.28E-04 -4.59E-04 0 -2.59E+03 -1.40E+03 -6.98E+02 -2.59E-04
0 0 0 -4.44E-08 -5.28E-04 8.22E+02 -2.48E+02 8.22E+02 8.22E-05
-1 -1 -1 0 0 -9.46E+02 -1.89E+03 -9.46E+02 -9.46E-05
 0 -1 -2 1 -1 7.95E-02 1.59E-01 -1.89E+03 7.95E-09
Iteraccion 8
1.00E-07 -8.01E-04 0 -1.27E-03 0 4.40E+02 -3.69E+02 -8.09E+02 -1.00E+00
0 1.2E-13 -8.01E-04 2.36E-04 0 -2.56E+02 1.99E+03 9.93E+02 -2.56E-05
0 0 0 2.28E-08 -8.01E-04 -1.84E+02 -1.62E+03 -1.84E+02 -1.84E-05
-1 -1 -1 0 0 -6.25E+02 -1.25E+03 -6.25E+02 -6.25E-05
0 -1 -2 1 -1 -1.78E-02 -3.56E-02 -1.25E+03 -1.78E-09
Iteraccion 9
1.00E-07 -1.11E-03 0 -9.29E-04 0 4.86E+02 7.46E+01 -4.11E+02 -1.00E+00
0 1.2E-13 -1.11E-03 -9.26E-05 0 -5.23E+02 7.48E+02 3.74E+02 -5.23E-05
0 0 0 -8.96E-09 -1.11E-03 3.73E+01 -8.23E+02 3.73E+01 3.73E-06
-1 -1 -1 0 0 -4.49E+02 -8.98E+02 -4.49E+02 -4.49E-05
0 -1 -2 1 -1 3.61E-03 7.22E-03 -8.98E+02 3.61E-10
Iteraccion 10
1.00E-07 -1.59E-03 0 -1.67E-03 0 3.07E+02 -1.56E+01 -3.23E+02 -1.00E+00
0 1.2E-13 -1.59E-03 3.93E-05 0 -2.99E+02 6.61E+02 3.31E+02 -2.99E-05
0 0 0 3.79E-09 -1.59E-03 -7.80E+00 -6.46E+02 -7.80E+00 -7.80E-07
-1 -1 -1 0 0 -3.15E+02 -6.30E+02 -3.15E+02 -3.15E-05
0 -1 -2 1 -1 -7.53E-04 -1.51E-03 -6.30E+02 -7.53E-11
Iteraccion 11
1.00E-07 -2.24E-03 0 -2.21E-03 0 2.25E+02 3.23E+00 -2.21E+02 -1.00E+00
0 1.2E-13 -2.24E-03 -1.62E-05 0 -2.26E+02 4.39E+02 2.20E+02 -2.26E-05
0 0 0 -1.57E-09 -2.24E-03 1.61E+00 -4.43E+02 1.61E+00 1.61E-07
-1 -1 -1 0 0 -2.23E+02 -4.46E+02 -2.23E+02 -2.23E-05
0 -1 -2 1 -1 1.56E-04 3.13E-04 -4.46E+02 1.56E-11
Iteraccion 12
1.00E-07 -3.17E-03 0 -3.19E-03 0 1.57E+02 -6.69E-01 -1.58E+02 -1.00E+00
0 1.2E-13 -3.17E-03 6.74E-06 0 -1.57E+02 3.16E+02 1.58E+02 -1.57E-05
0 0 0 6.49E-10 -3.17E-03 -3.35E-01 -3.16E+02 -3.35E-01 -3.35E-08
-1 -1 -1 0 0 -1.58E+02 -3.15E+02 -1.58E+02 -1.58E-05
0 -1 -2 1 -1 -3.22E-05 -6.44E-05 -3.15E+02 -3.22E-12
Iteraccion 13
1.00E-07 -4.49E-03 0 -4.48E-03 0 1.11E+02 1.39E-01 -1.11E+02 -1.00E+00
0 1.2E-13 -4.49E-03 -2.79E-06 0 -1.12E+02 2.22E+02 1.11E+02 -1.12E-05
0 0 0 -2.72E-10 -4.49E-03 6.93E-02 -2.23E+02 6.93E-02 6.93E-09
-1 -1 -1 0 0 -1.11E+02 -2.23E+02 -1.11E+02 -1.11E-05
0 -1 -2 1 -1 6.75E-06 1.35E-05 -2.23E+02 6.75E-13
Iteraccion 14
1.00E-07 -6.35E-03 0 -6.35E-03 0 7.87E+01 -2.87E-02 -7.88E+01 -1.00E+00
0 1.2E-13 -6.35E-03 1.16E-06 0 -7.87E+01 1.58E+02 7.88E+01 -7.87E-06
0 0 0 1.10E-10 -6.35E-03 -1.44E-02 -1.58E+02 -1.44E-02 -1.44E-09
-1 -1 -1 0 0 -7.87E+01 -1.57E+02 -7.87E+01 -7.87E-06
0 -1 -2 1 -1 -1.37E-06 -2.74E-06 -1.57E+02 -1.37E-13
 -fx S X % variacion
6.64E-01 8.01E-07 -3.38E-04 8.97E-02 3.76E-01
-3.28E-01 8.1E-07 -8.93E-02 6.67E-04 9.93E+01
-3.36E-01 8.099E-11 -9.03E-02 -3.29E-04 1.00E+02
3.36E-05 0.18 3.29E-08 9.03E-06 -3.66E-01
-3.36E-05 0.27 -9.03E-06 -3.18E-08 1.00E+02

2.33E+01 -2.94E-09 2.46E-01 3.36E-01 -2.74E+02

-4.62E+01 -2.97E-09 -1.34E-01 -1.33E-01 2.01E+04
2.29E+01 -2.97E-13 6.78E-02 6.75E-02 2.06E+04
6.29E-01 -1.80E-01 1.85E-03 1.86E-03 -2.05E+04
2.21E-03 -4.30E-17 6.56E-06 6.53E-06 2.06E+04

-1.76E+01 -2.48E-04 3.27E-01 6.62E-01 -9.73E+01

3.57E+01 1.26E-04 6.79E-02 -6.53E-02 5.10E+01
-1.81E+01 1.22E-08 -3.44E-02 3.31E-02 5.10E+01
5.00E-01 -3.60E-01 -9.13E-04 9.49E-04 4.90E+01
-1.75E-03 0.00E+00 -3.32E-06 3.20E-06 5.10E+01

-1.69E+01 -6.20E-05 7.01E-01 1.36E+00 -1.06E+02

3.43E+01 3.14E-05 3.77E-02 -2.76E-02 5.78E+01
-1.74E+01 3.04E-09 -1.91E-02 1.41E-02 5.76E+01
4.99E-01 -7.20E-01 -4.03E-04 5.46E-04 4.24E+01
-1.68E-03 -1.53E-16 -1.84E-06 1.36E-06 5.76E+01

-1.23E+01 -1.52E-05 1.43E+00 2.79E+00 -1.05E+02

2.52E+01 7.68E-06 2.72E-02 -3.90E-04 9.86E+01
-1.28E+01 7.42E-10 -1.36E-02 4.59E-04 9.67E+01
4.99E-01 -1.44E+00 -1.79E-05 5.28E-04 3.27E+00
-1.24E-03 6.73E-16 -1.31E-06 4.44E-08 9.67E+01

6.55E-02 -4.85E-07 2.88E+00 5.67E+00 -1.03E+02

3.69E-01 2.43E-07 1.66E-03 1.27E-03 4.27E+02
-4.34E-01 2.35E-11 -6.96E-04 -2.36E-04 1.51E+02
5.00E-01 -2.88E+00 2.72E-04 8.01E-04 -5.15E+01
-4.20E-05 2.84E-17 -6.72E-08 -2.28E-08 1.51E+02

6.48E-01 4.53E-07 5.76E+00 1.14E+01 -1.02E+02

-7.95E-01 -1.89E-07 -3.45E-04 9.29E-04 2.71E+01
1.48E-01 -1.83E-11 3.29E-04 9.26E-05 1.39E+02
5.00E-01 -5.76E+00 3.14E-04 1.11E-03 -3.92E+01
1.43E-05 -2.17E-19 3.18E-08 8.96E-09 1.39E+02

4.58E-01 -1.08E-07 1.15E+01 2.29E+01 -1.01E+02

-4.17E-01 1.03E-07 7.37E-04 1.67E-03 -7.93E+01
-4.16E-02 9.97E-12 -1.32E-04 -3.93E-05 1.42E+02
5.00E-01 -1.15E+01 4.73E-04 1.59E-03 -4.24E+01
-4.02E-06 -1.08E-19 -1.27E-08 -3.79E-09 1.42E+02

5.12E-01 3.48E-07 2.30E+01 4.60E+01 -1.00E+02

-5.25E-01 -6.24E-08 5.44E-04 2.21E-03 -3.27E+01
1.24E-02 -6.03E-12 5.55E-05 1.62E-05 1.41E+02
5.00E-01 -2.30E+01 6.55E-04 2.24E-03 -4.13E+01
1.19E-06 0.00E+00 5.37E-09 1.57E-09 1.41E+02

4.96E-01 3.57E-07 4.61E+01 9.21E+01 -1.00E+02

-4.93E-01 3.64E-08 9.78E-04 3.19E-03 -4.42E+01
-3.62E-03 3.52E-12 -2.30E-05 -6.74E-06 1.42E+02
5.00E-01 -4.61E+01 9.32E-04 3.17E-03 -4.15E+01
-3.51E-07 1.63E-19 -2.22E-09 -6.49E-10 1.41E+02

5.01E-01 9.11E-07 9.22E+01 1.84E+02 -1.00E+02

-5.02E-01 -2.14E-08 1.30E-03 4.48E-03 -4.07E+01
1.06E-03 -2.07E-12 9.54E-06 2.79E-06 1.41E+02
5.00E-01 -9.22E+01 1.32E-03 4.49E-03 -4.14E+01
1.02E-07 -2.71E-20 9.21E-10 2.72E-10 1.42E+02

5.00E-01 1.70E-06 1.84E+02 3.69E+02 -1.00E+02

-4.99E-01 1.25E-08 1.87E-03 6.35E-03 -4.17E+01
-3.11E-04 1.21E-12 -3.95E-06 -1.16E-06 1.41E+02
5.00E-01 -1.84E+02 1.86E-03 6.35E-03 -4.14E+01
-3.03E-08 -6.57E-19 -3.82E-10 -1.10E-10 1.41E+02

5.00E-01 3.48E-06 3.69E+02 7.37E+02 -1.00E+02

-5.00E-01 -7.35E-09 2.63E-03 8.98E-03 -4.14E+01
9.12E-05 -7.12E-13 1.64E-06 4.80E-07 1.41E+02
5.00E-01 -3.69E+02 2.63E-03 8.98E-03 -4.14E+01
8.70E-09 2.54E-19 1.58E-10 4.73E-11 1.43E+02
pH [H+] [C6O7H8] Log[C6O7H8] [C6O7H7-] Log[C6O7H7-] [C6O7H62-] Log[C6O7H62-] [C6O7H53-]
0 1.00E+00 9.99E-02 -1.00E+00 1.15E-04 -3.94E+00 7.24E-06 -5.14E+00 1.51E-07
1 1.00E-01 9.89E-02 -1.00E+00 1.14E-03 -2.94E+00 7.16E-05 -4.14E+00 1.50E-06
2 1.00E-02 8.96E-02 -1.05E+00 1.03E-02 -1.99E+00 6.49E-04 -3.19E+00 1.36E-05
3 1.00E-03 4.48E-02 -1.35E+00 5.15E-02 -1.29E+00 3.25E-03 -2.49E+00 6.78E-05
4 1.00E-04 4.78E-03 -2.32E+00 5.49E-02 -1.26E+00 3.46E-03 -2.46E+00 7.23E-05
5 1.00E-05 9.32E-05 -4.03E+00 1.07E-02 -1.97E+00 6.75E-04 -3.17E+00 1.41E-05
6 1.00E-06 4.76E-07 -6.32E+00 5.46E-04 -3.26E+00 3.45E-05 -4.46E+00 7.20E-07
7 1.00E-07 7.45E-10 -9.13E+00 8.55E-06 -5.07E+00 5.40E-07 -6.27E+00 1.13E-08
8 1.00E-08 7.89E-13 -1.21E+01 9.06E-08 -7.04E+00 5.72E-09 -8.24E+00 1.19E-10
9 1.00E-09 7.94E-16 -1.51E+01 9.11E-10 -9.04E+00 5.75E-11 -1.02E+01 1.20E-12
10 1.00E-10 7.94E-19 -1.81E+01 9.12E-12 -1.10E+01 5.75E-13 -1.22E+01 1.20E-14
11 1.00E-11 7.94E-22 -2.11E+01 9.12E-14 -1.30E+01 5.75E-15 -1.42E+01 1.20E-16
12 1.00E-12 7.94E-25 -2.41E+01 9.12E-16 -1.50E+01 5.75E-17 -1.62E+01 1.20E-18
13 1.00E-13 7.94E-28 -2.71E+01 9.11E-18 -1.70E+01 5.75E-19 -1.82E+01 1.20E-20
14 1.00E-14 7.86E-31 -3.01E+01 9.03E-20 -1.90E+01 5.70E-21 -2.02E+01 1.19E-22
15 1.00E-15 7.22E-34 -3.31E+01 8.29E-22 -2.11E+01 5.23E-23 -2.23E+01 1.09E-24
16 1.00E-16 3.97E-37 -3.64E+01 4.56E-24 -2.33E+01 2.88E-25 -2.45E+01 6.01E-27

Diagrama de distribución de especies de [C6O8H8]

0.00E+00
0 2 4 6 8 10 12 14 16 18
-5.00E+00

-1.00E+01

-1.50E+01
Log [C]

-2.00E+01

-2.50E+01

-3.00E+01

-3.50E+01

-4.00E+01
pH

Log[C6O7H8] Log[C6O7H7-] Log[C6O7H62-] Log[C6O7H53-] Log[C6O7H44-]

Log[C6O7H53-] [C6O7H44-] Log[C6O7H44-]
-6.82E+00 9.99E-18 -1.70E+01 C= 0.1
-5.82E+00 9.89E-17 -1.60E+01 ka1= 1.15E-03
-4.87E+00 8.96E-16 -1.50E+01 ka2= 7.24E-05
-4.17E+00 4.48E-15 -1.43E+01 ka3= 1.51E-06
-4.14E+00 4.78E-15 -1.43E+01 ka4= 1.00E-16
-4.85E+00 9.32E-16 -1.50E+01
-6.14E+00 4.76E-17 -1.63E+01
-7.95E+00 7.45E-19 -1.81E+01
-9.92E+00 7.89E-21 -2.01E+01
-1.19E+01 7.94E-23 -2.21E+01
-1.39E+01 7.94E-25 -2.41E+01
-1.59E+01 7.94E-27 -2.61E+01
-1.79E+01 7.94E-29 -2.81E+01
-1.99E+01 7.94E-31 -3.01E+01
-2.19E+01 7.86E-33 -3.21E+01
-2.40E+01 7.22E-35 -3.41E+01
-2.62E+01 3.97E-37 -3.64E+01
 g Pb(NO3)2/100 g
T (C°)
de H2O
0 38.8
10 48.3
17 54
20 56.5
25 60.6
30 66
40 75
50 85
60 95
100 138.8

Grafica de solubilidad de Pb(NO3)2

160
g dePb(NO3)2/100 g de H2O

140
120 f(x) = 0.994595729051892 x + 36.7902303373734
R² = 0.997149623027307
100
80
60
40
20
0
0 20 40 60 80 100 120
T (C°)

Column D Linear (Column D)

 Valencia 1 2 3 4

Especie LogKps Kp PH [OH-] Log[Ag] Log[Al] Log[Be]

Ag(OH) -7.71 1.95E-08 -1 10
Al(OH)3 -33.50 3.16E-34 0 1.00 6.29E+00 8.50E+00 6.70E+00
Be(OH)2 -21.30 5.01E-22 1 0.10 5.29 5.50E+00 4.70E+00
Ca(OH)2 -5.19 6.46E-06 2 0.01 4.29 2.50E+00 2.70E+00
Cd(OH)2 -14.35 4.47E-15 3 0.00 3.29 -5.00E-01 7.00E-01
Co(OH)2 -14.90 1.26E-15 4 0.00 2.29 -3.50E+00 -1.30E+00
Co(OH)3 -44.50 3.16E-45 5 0.00 1.29 -6.50E+00 -3.30E+00
Cr(OH)3 -29.80 1.58E-30 6 0.00 0.29 -9.50E+00 -5.30E+00
Cu(OH)2 -19.32 4.79E-20 7 0.00 -0.71 -1.25E+01 -7.30E+00
Fe(OH)2 -15.10 7.94E-16 8 0.00 -1.71 -1.55E+01 -9.30E+00
Fe(OH)3 -38.80 1.58E-39 9 0.00 -2.71 -1.85E+01 -1.13E+01
Mg(OH)2 -11.15 7.08E-12 10 0.00 -3.71 -2.15E+01 -1.33E+01
Mn(OH)2 -12.80 1.58E-13 11 0.00 -4.71 -2.45E+01 -1.53E+01
Ni(OH)3 -15.20 6.31E-16 12 0.00 -5.71 -2.75E+01 -1.73E+01
Ti(OH)4 -53 1.00E-53 13 0.00 -6.71 -3.05E+01 -1.93E+01
Zn(OH)2 -16.46 3.47E-17 14 1.00E-14 -7.71 -3.35E+01 -2.13E+01

Diagrama de precipitación de hidrox

0.00
-1 0 1 2 3 4 5 6

-1.00
Log [Me+]

-2.00

-3.00

-4.00

pO
-4.00

pO
 Log[Ca] Log[Cd] Log[Co2+Log[Co3+] Log[Cr] Log[Cu] Log[Fe2+] Log[Fe3+]

22.81 13.65 13.10 -2.50E+00 1.22E+01 8.68E+00 1.29E+01 3.20E+00

20.81 11.65 11.10 -5.50E+00 9.20E+00 6.68E+00 1.09E+01 2.00E-01
18.81 9.65 9.10 -8.50E+00 6.20E+00 4.68E+00 8.90E+00 -2.80E+00
16.81 7.65 7.10 -1.15E+01 3.20E+00 2.68E+00 6.90E+00 -5.80E+00
14.81 5.65 5.10 -1.45E+01 2.00E-01 6.80E-01 4.90E+00 -8.80E+00
12.81 3.65 3.10 -1.75E+01 -2.80E+00 -1.32E+00 2.90E+00 -1.18E+01
10.81 1.65 1.10 -2.05E+01 -5.80E+00 -3.32E+00 9.00E-01 -1.48E+01
8.81 -0.35 -0.90 -2.35E+01 -8.80E+00 -5.32E+00 -1.10E+00 -1.78E+01
6.81 -2.35 -2.90 -2.65E+01 -1.18E+01 -7.32E+00 -3.10E+00 -2.08E+01
4.81 -4.35 -4.90 -2.95E+01 -1.48E+01 -9.32E+00 -5.10E+00 -2.38E+01
2.81 -6.35 -6.90 -3.25E+01 -1.78E+01 -1.13E+01 -7.10E+00 -2.68E+01
0.81 -8.35 -8.90 -3.55E+01 -2.08E+01 -1.33E+01 -9.10E+00 -2.98E+01
-1.19 -10.35 -10.90 -3.85E+01 -2.38E+01 -1.53E+01 -1.11E+01 -3.28E+01
-3.19 -12.35 -12.90 -4.15E+01 -2.68E+01 -1.73E+01 -1.31E+01 -3.58E+01
-5.19 -14.35 -14.90 -4.45E+01 -2.98E+01 -1.93E+01 -1.51E+01 -3.88E+01

tación de hidroxidos

4 5 6 7 8 9 10 11 12 13 14

Log[Ag]
Column G
Column H
Column F
Column U
Column T
Column S
Column R
Column Q
Column J
Column L
Column M
Column N
Column O
Column Q
Log[Co2+]
Column L
Column P
Log[Ni]

pOH
 Log[Ni]

pOH
Log[Mg] Log[Mn] Log[Ni] Log[Ti] Log[Zn]

1.69E+01 1.52E+01 1.28E+01 3.00E+00 1.15E+01

1.49E+01 1.32E+01 1.08E+01 -1.00E+00 9.54E+00
1.29E+01 1.12E+01 8.80E+00 -5.00E+00 7.54E+00
1.09E+01 9.20E+00 6.80E+00 -9.00E+00 5.54E+00
8.85E+00 7.20E+00 4.80E+00 -1.30E+01 3.54E+00
6.85E+00 5.20E+00 2.80E+00 -1.70E+01 1.54E+00
4.85E+00 3.20E+00 8.00E-01 -2.10E+01 -4.60E-01
2.85E+00 1.20E+00 -1.20E+00 -2.50E+01 -2.46E+00
8.50E-01 -8.00E-01 -3.20E+00 -2.90E+01 -4.46E+00
-1.15E+00 -2.80E+00 -5.20E+00 -3.30E+01 -6.46E+00
-3.15E+00 -4.80E+00 -7.20E+00 -3.70E+01 -8.46E+00
-5.15E+00 -6.80E+00 -9.20E+00 -4.10E+01 -1.05E+01
-7.15E+00 -8.80E+00 -1.12E+01 -4.50E+01 -1.25E+01
-9.15E+00 -1.08E+01 -1.32E+01 -4.90E+01 -1.45E+01
-1.12E+01 -1.28E+01 -1.52E+01 -5.30E+01 -1.65E+01