Paper Industry: Resources & Fundamentals
Section 1
The Paper Industry
1.1.41 Overview of the Paper Industry
1.1.2 Location of the Paper Industry
11.3 The Paper Industry - International
1.1.4 The Paper Industry - Southern Africa
After studying this section a student will be expected to know about the basic
processes of the Pulp & Paper Industry, the Terminology of the Paper Industry, the
major Paper Making Countries of the World and the products, capacities, processes
and raw materials used by each of the Paper Mills in the South African Paper
Industry.
144Basis Mass
Black Liquor
Bleaching
Blow
Bone or Oven Dry
Bowl
Break
Breaking Length
Breast Roll
Brightness
Brown Stock
Bulk
Calender
Paper
Pulp
Pulp
Pulp
Paper/Pulp
Paper
Paper
Paper
Paper
Pulp/Paper
Pulp
Paper
Paper
The mass in grams of one square
meter of paper
The spent liquor of the alkaline
pulping process; called red liquor in
sulphite pulping
Chemically treating pulp to remove
the colouring matter
A term used to describe the
pressurised removal of pulp from a
digester
Absolutely dry paper or pulp
A calender roll usually made from
compressed fibrous material
A complete tear or break of the paper
web during the manufacturing
process
Refers to the tensile force at which a
piece of paper will break; breaking
length refers to the length of a piece
of paper which will break itself
The breast roll is one of the rolls
around which the forming wire is
moving; the breast roll is the roll just
prior to stock discharge onto the wire
Reflectivity of a pulp or paper sample
measured under standard conditions;
used to indicate the degree of
whiteness
Chemical Pulp which has not been
bleached
Inverse of density; the thickness or
caliper per unit basis mass of a sheet
of paper
Assembly of rolls at the dry end of the
paper machine improving the finish to.Cross-Direction
Crushing
Curl
De-inking
Doctor
Draw
Dregs
Dry End
Fibrils
Fines
Paper
Paper
Paper
Pulp
Pulp/Paper
Paper
Pulp
Paper
Pulp/Paper
Pulp
1.41.5
The direction at right angles to the
direction of running a paper machine.
Defect in the sheet (usually a thin
spot) caused by applying excessive
pressure during an early stage of
pressing before the sheet is
sufficiently de-watered.
Tendency of paper by itself to bend or
partly wrap around the axis of one of
its directions.
Removal of ink and other extraneous
materials (contraries) from printed,
reclaimed papers by mechanical
disintegration and chemical
treatment, with subsequent washing
or flotation separation.
Thin metal plate or scraper in contact
with a roll along its entire length to
keep it free from paper, pulp, size,
dirt, ete. Also used in performing
creping.
Difference in speed between two
adjacent sections of a paper
machine, The term also is applied to
the tension in the sheet caused by the
speed differential.
Settleable solids which comprise the
underflow from the green liquor
clarifier.
That part of the paper machine where
the paper is dried, calendered, and
reeled
Thread-like elements unravelled from
the walls of native cellulose fibres.
Very small fibres and fibre fragments
that readily pass through a filter wire
cloth.Mottle
Nip
Opacity
Open Draw
Permanganate Number
Pitch
Porosity
Profile
Pulpwood
Roe Number
Rope Carrier
Paper
Paper
Paper
Paper
Pulp
Pulp/Paper
Paper
Paper
Pulp
Pulp
Paper
11.7
Non-uniform colour of a paper sheet,
whether accidental or intentional.
Line of contact between two rolls,
such as press or calender rolls.
Property of a paper which prevents
“show-through" of printing from one
side of sheet to the other.
Transfer of an unsupported sheet as
it passes from one section of the
paper machine to the next section.
Chemical test performed on pulp to
determine the degree of
delignification.
Resinous materials present in wood
that carry over into the pulping and
papermaking systems to form
insoluble deposits.
Property of containing connected air
voids. The porosity of paper is
evaluated by measuring the air
permeability under standardized
conditions.
weight, moisture content or other
property from point to point in a paper
web, either in the machine direction
or cross-direction.
Logs cut and trimmed to size for use
by the pulp mill. Generally of poorer
quality than sawlogs.
Measure of the amount of chlorine
required for bleaching pulp.
Principal method of sheet threading
for the dryer section of a paper
machine, by means of two ropes that
run in grooves on the front side of the
dryer cylinders. The tail is placedStuff
Tack
Tackle
Top side
Watermarking
Web
Wet End
White Water
Wire Side
Wood-Free
Paper
Paper
Paper
Paper
Paper
Paper
Paper
Paper
Paper
Paper
14.9
papermaking furnish
Papermaking stock as it is ready to
be pumped to the headbox
Resistance of an ink film to being split
between two surfaces, as between
blanket and paper for an offset press.
Replaceable assembly of bars or disc
segments which provide the working
surfaces in a refiner.
Paper web side that has not been in
contact with the wire during
manufacture.
Design formed among the fibres of a
sheet as a result of the wet paper
web coming into contact with the
pattern of the dandy roll. The paper
becomes thinner and more
translucent where the fibres are
displaced by the raised design.
Term applied to the full width of the
paper sheet in the process of being
formed, pressed, dried, finished, or
converted.
Portion of the paper machine
between the headbox and the dryer
section.
General term for water removed from
a pullp slurry and containing fibre fines
and/or additives. On the paper
machine, the water that flows through
the fourdrinier forming fabric as the
‘sheet is formed.
That side of the sheet of paper which
was originally in contact with the
forming wire of fabric.
Pulp furnish without mechanical pulp.lower pH pulping using cheap limestone and sulphur was extensively
used; the resultant pulp tended to be weaker than Kraft pulp but it was
possible to dispose the waste liquor into large water masses without
major environmental damage but the process is very slow. Use of
higher pH's leads to quicker pulping and is common in the production of,
high yield chemical pulps for packaging papers. Recovery of the waste
liquors has been developed where viable. NSSC - neutral sulphite
semi-chemical where a mixture of sodium sulphite and sodium
carbonate is used at a pH of about 8.
The sulphite and Kraft processes are often denoted Si and Sa in the
literature.
The above processes are covered in Module 5 of the instructional
program.
Bleaching of Pulp
Pulps produced for Papermaking are often not sufficiently white for the
requirements of the paper products being produced, especially in the
case of Kraft pulps. In order to make them brighter, the pulps are
whitened, in the case of Mechanical pulps, and bleached, in the case of
Chemical pulps.
The above processes are covered in Module 7 of the instructional
program.
Recycled Fibre Operations
There is a trend towards increased recycling of paper products back into
paper products, largely due to environmental and cost pressures.
Although it is not practical to recycle all products, most countries are
involved in paper recycling to some extent, depending on the cost and
availability of raw materials, the product range and the quality
specifications,
The above processes are covered in Module 8 of the instructional
program.
Papermaking
Papermaking is a broad term used to cover the manufacture of a wide
range of paper & board products eg Newsprint, Writing Papers, Bond
Papers, Tissue, Folding Boxboard, Linerboard Fluting and even higher
mass boards for the motor industry for example. A more concise
definition of the above products will be shown later in this chapter.
44.4441.2
Figure 1.1.1 Map of the World - size of Country proportional to it's GDP
Other aspects of the Paper Industry covered in the program are
Environmentand Corrosion (Module 10), various products produced
by the industry (Module 13) and Quality Assurance (Module 14).
Location of the Pulp & Paper Industry
As with most industries, the paper industry is located close to its raw
materials, close to its market and close to a source of labour or at least
the most economic combination of the above.
With regard to market for paper industry products, the market is the
product of population numbers and sophistication of economy. For
example China has a large population but a relatively unsophisticated
economy and hence the paper industry in that country is relatively small.
On the other hand Sweden has a highly sophisticated economy and a
high population and hence a relatively large paper industry. Figure 1.1.1
shows the relative size of the worlds economies which will determine
the paper requirements of the countries.
With regard to raw materials, which are largely trees and other fibrous
plants such as bagasse, bamboo, straw and kenaf, itis also noticeable
that the most treed nations are North America, Scandinavia and the
Tropical countries such as Brazil. European paper mills are largely
1.4.131.1.3.2
50000
40000
30000
20000
10000
EE Unbleached Kraft
EE supphite
=e
Figure 1.1.3 Tonnages of Different Grades of Pulp Produced for 1980 and
1990
The Paper Industry
The paper making capacity of various nations in the world is shown in
tables on the following pages and the per capita consumption of paper
of some countries is shown in figure 1.1.4. It Is clear that the majority of
the 300 million metric tons of paper and board made in the world is
made in North America, Scandinavia, Western Europe and Japan.
| China \ |
Zimbabwe ‘Bil = i
Argentina asa
South Africa 1] kgs/annum
Taiwan E
|United Kingdom
Japan Ean
SL Seer
‘Sweden
United States _Sieninnasieias ans RaEameenshiaGS
, '
oO 50 100 150 200 250 300
Figure 1.1.4 Per Capita Paper Consumption for Various Countries
1.4.15,THE WORLD'S TOP 30 PRODUCERS AND CONSUMERS 1997
pa 2 Precucton Pup Predation P&B Consumption
Senange %chonge % change
e077 19079706 107976
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tothe entrepreneur wo sels te waste to
resyling opportunites. Mond Recyeling
ne has eae aver 2.000 ee jobs as a
result of ts various colton naive.
OUTSOURCING ACTIVITIES
Pamsa memibrsconibue furthest the
Informal sctr othe aconemy by
cutgutcng actvtes such as ranspratln,
leering and catering te enboprenouss and
small businestas a mast oftheir operons
throughout the country.SUMMING UP
_ SOUTH AFRICAN.
_- FORESTS PRODUCTS
| INDUSTRY SUMMARY.
2000
‘forested area 13 million ha
Value of products [19 bilion
Value of exports |
Employment
Contribution to
Manvtacturing GOP 8%
Contribution to
totai GOP 27%
ISSUES.
Issues afecting the compebivenass of te
indusisy include
‘The impact of HIV/AIDS on etou and
sls;
he high oes of transport
= The anasto and eos fra mares,
and
* Investment percetins,
OPPORTUNITIES
The incstry wil grow trough vrcus
opportunites which are avalabl, Icing:
1 The avaiabiiy of be tobe covert ito
Value aed paparproduns trough
+ Additional atforstton;
+ Increased yields through research and
evecpment
+ Inorased ecyeling of used paver and
+ Avallbiity of bagasse as a bre source.
he low speci consumaton of paper znd
whi will row as the per capita BOP of
the coun an the continent gram
* South cas favourable ocation in ica
hich eres window to mexise
‘opportuni in Asia, Europe and South
ai,
Theft that South African pulp and paper
‘af produce fro high-yield, sustaable
plantalion forestry lve these products an
‘xtvantage trom an arvronmertat
perspective in nenationa! markers —
rmatels which are ineeasingly focused en
‘exvitonmenta sues.
ufone Sl ste are uae
forint wr atts ard unt fo Se
Tee Seg hah, Sip ee Sti: Lowe and
Sp he Stn Kaz a
25Paper Industry: Resources & Fundamentals
Section 2
Paper Industry Raw Materials
1.2.1 Tree species
1.2.2 Forestry operations
1.2.3. Transport of Forest products
1.2.4 Research & Development in the Forest Industry
1.2.5 Sugar cane and bagasse
1.2.6 Other fibrous materials
1.2.7 Other uses of wood
After this section a student will be expected to know the different raw materials used by
the Pulp and Paper Industry, how they are obtained and transported to the mills and the
development of fibre resources for the Paper industry.
1.24Research in the forest industry in Southem Attica is essentially carried out
at four main centres. The large paper companies have forest research
departments based in Natal; Sappi in Pietermaritzburg and Mondi at
Mitubatuba and Hilton.
The Department of Forestry at Stellenbosch carries out research in a
number of fields namely Forest Management, Silviculture, Forest
Engineering, Wood Science, Pulp & Paper Technology and Conservation.
The Forestek section of the CSIR in Pretoria conducts a wide range of
research work in all wood and allied products related fields.
1.2.5 Sugar Cane and Bagasse
The fibrous waste material from cane sugar production, bagasse, has been
used for the manufacture of paper in most countries where sugar cane is.
grown and South Africa is no exception.
In areas where the bagasse is not converted into papermaking fibres it is
combusted in a power boiler to generate steam used for concentrating the
suger juice. There is normally an excess of bagasse despite it's relatively
low calorific value.
The main problem with processing of bagasse for papermaking is the
seasonal nature of the sugar industry, which for example in South Africa
is only milling cane from May through to December. These months may
vary according to the weather and the capacity of the crop. This means
‘that either the bagasse must be stored or the raw materials must be
changed. Despite the problems of storing a raw material which is open to
fungal attack, it is usually preferably to use bagasse than to incur the paper
property changes resulting from a raw material change.
The paper making properties of bagasse fibres are very similar to those of
hardwood fibres.
1.2.6 Other Fibrous Materials
There are many other fibrous materials which can be considered as a raw
material for the manufacture of paper and board products. In some
countries, which are relatively deficient in trees or do not have soils
‘suitable for growing trees, more than 50% of the fibre for paper making are
sourced from non wood origins.
The other types can be divided into a number of groups, such as
Vegetable, Textile, Animal and Waste Paper Products. Each of these
groups will be discussed briefly as to their suitability of purpose below.
12.3Paper Industry: Resources & Fundamentals
Section 5
Relationship between fibre and paper properties
1.5.1 Mechanism of polysaccharide interfibre bonding
1.5.2 Effects of water, fibre treatments and humidity on the fibrous bonds
1.5.3. Measurement of the mechanical properties of pulps
1.5.4 Relationship between the mechanical properties of paper pulps(tensile, tear
etc.) and the fibrous raw material and its treatment
1.5.5 Theories and correlations of fibre and sheet strength properties
1.5.6 The relationship between fibre types and the surface properties of the sheet
After this section a student will be expected to know the mechanism of hydrogen
bonding in cellulose, hemicellulose and water, the effect of water and fibre treatments
on this bonding mechanism, the measurement of the mechanical properties of pulps,
the relationship betwen th pulp, its treatment and the properties of the pulp and the
paper produced from it
1.54around the oxygen atom and a small positive charge around the
hydrogen atom.
These small positive and negative charges are then able to be attracted
to the small opposite charges of an adjacent hydroxy! group, be it
cellulosic or from water
Figure 1.5.1 Nature of hydrogen bonds in cellulose fibres
1.5.2 Effects of Water, Fibre Treatments and humidity on the fibrous bonds
Effect of Water
As shown in figure 1.5.1 the polar nature of water, where the hydrogen
atoms are relatively positively charged and the oxygen negatively
charged, enables water to hydrogen bond with cellulose (and
hemicellulose) molecules.
Water can therefore form bridge bonds between two wood fibres by
forming hydrogen bonds with the hydroxyl groups protruding from the
fibre surface.
The result of these bonds can be observed in the forming section,
where the sheet is still able to support itself despite consisting of up to
eighty percent water; in the press section where the maximum dryness
achievable is in the region of fifty five percent water: and in the drying
1.5.3Clearly a fibre surface which is already full of water cannot accept any
more water onto the surface.
In addition to the above there is an hysteresis effect when the relative
humidity rises or drops; so a paper sheet in contact with air at a certain
relative humidity will contain more moisture if the relative humidity is
dropping than if itis rising.
The control of the actual air humidity in the testing of paper is very
important. The paper needs to be conditioned for a fixed period before
comparative testing can take place. The humidity of the drier section will
also dramatically affect the effectiveness of the drying process.
1.5.3 Measurement of the mechanical properties of pulps
The mechanical properties of pulps are determined by measuring the
common properties of tear, tensile and burst at varying degrees of
beating (refining).
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Tear factor
Fig1.5.2 Tensile-Tear Relationship for various Kraft pulps;
Numbers refer to Density and Fibre Length
1.5.5The mechanical properties of Tear, Tensile, Burst and Fold are all
increased by the inclusion of softwood fibres. The length of the fibres
improves the tensile and burst whereas the tear and fold are improved
by the pliability of the softwood fibres.
The bulk is decreased by addition of softwood fibres due to the
increased ability to bend and shape with other fibres; the inverse of bulk
is density. In other words, softwood fibres make a more dense sheet.
1.5.6 The relationship between fibre types and the surface properties of the sheet
Softwood fibres will make the paper sheet less opaque due to the
pliability of the fibre and the conformity of shape to the next fibre with
chemical bonding; this reduces the number of woodfibre to air surfaces
within the sheet and reduces light scattering. The stiffness of hardwood
fibres will increase opacity, for opposite reasons.
The stiffness of hardwood fibres will also allow greater porosity through
the sheet and lead to a less smooth surface; however the use of
hardwood fibres as a filler within softwood stock will lead to lower
porosity, better smoothness and lower opacity.
Increase of refining will also increase smoothness whilst reducing
opacity and porosity.
1.5.7Paper Industry: Resources & Fundamentals
Section 6
Fluid Mechanics and Rheology of pulp suspensions
Fibre suspensions, turbulence, flocculation, formation
Fibre suspensions in motion, non-newtonian behaviour, friction losses, power
Fequitements in pumping
3 Heat and mass transfer in fibre suspensions and fibre matts
.4 Mass and Energy Balancing with Pulp Suspensions.
1
4
ao
Ro
After this section a student will be expected to know the nature of fluid mechanics of
fibre suspensions, calculation ofpressure loss, power requirements for pumping of fibre
suspensions, blending and mixing of fibre suspensions, calculations for blending and
standard design practices, simple mass and energy balances of pulp suspensions.
The study of this chapter requires a previous knowledge of the unit operations of fluid
flow and mixingeffect.
Recap on the flow of fluids:
The change of energy states in fluid flow is usually described by the
Bemoulli Equation which is shown in its expanded state, the constant
energy equation, below:
v y,
weet ee Bt Be
2 2g, e 2g,
where ——p - pressure
p - density
v - velocity
z - vertical height
W -work done cn the system
H,- Loss due to friétion
a,b coefficients referring to different positions within the
fluid
The term H, is the friction loss of the system and is defined by the
following equation:
2£Lv?
Da,
where L - length of pipe
v - velocity
D - diameter of pipe
f - friction factor
If SI units are used then the unit of H, will be metres of liquid. In order to
convert this term to pressure units, it is necessary to multiply by the
density of the liquid and the gravity constant, g,. This value will be equal
to the pressure loss due to friction. The additional power required to
overcome this pressure loss can be calculated by can be calculated by
multiplying by the volumetric flow rate.
Calculation of the friction factor, f, is achieved by the use of graphical
relationships between the friction factor and the Reynolds Number of the
flowing liquid. The Reynolds Number, denoted N,,, is @ dimensionless
163Water is pumped through 30 m of smooth walled stainless steel pipe,
25mm e. The flow rate is 100 litres per minute. Calculate the pressure
loss due to friction and the power required to overcome this head loss.
SOLUTION
Velocity in pipe, V
Oa 4
60s (0,025)*m m?
= 3,4ms%
if density, p = 1000 kg m® and
viscosity, w= 1* 10° kg m* s" then
Reynolds Number,Na, = D*v* p/p
=8,5* 10°
using Figure 1.6.1 f = 0,0045
then calculate H,
H, =2*eL*v/D*g,
= 2* 0,0045 * 30 * 3,4?
0,025 * 9,81
= 12,7 mwater
Calculate pressure loss due to friction
AP =H,*g.*p
= 12,7* 9,81 * 10? Nm?
= 1,257 10° Nm?
Calculate Power required to overcome Pressure Loss
P =AP*Q
= 1,25* 10°*0,1/60W
1.6.5= 22,3 mliquid
Pressure loss due to friction
= 22,3*9,81* 10%
= 2,187 * 10° Nm?
Power required to overcome additional pressure loss:
= 2,187 * 10°* 0,1 /60
=365W
Consistency above 1%
At higher consistencies the flowing pulp exhibits non-Newtonian
properties, ie the viscosity is not directly related to the degree of sheer
in the fluid.
The flow properties are further complicated by the formation of a
turbulent annulus of pulp within which the central plug of pulp flows. As
the velocity increases the central plug is reduced in size to become part
of the turbulent periphery. A further study of this phenomenon can be
achieved by reading appended articles.
In most cases, pulps are pumped at relatively slow velocities, typically of
the order of 1 ms". increasing the velocity more than 2 m s* will lead to
very high head losses, although a higher rate of pulp mixing will be
achieved.
Although different pulps will have different effects on the flow
characteristics of pulp suspensions, the head loss (in metres pipe length
per 100 m pipe length) can be estimated from the flow rate, the
consistency and the pipe diameter using the following equation:
Loss of Head € metres per 100 metres
= 0/0121 * [D} 226 % [opt * (9]96
where D - pipe diameter, m
C - Consistency, %
Q- Flow Rate, m? hr
1.6.7Pumping of Pulps of Higher consistencies
Pumping of pulp suspensions in the higher consistency ranges with
conventional pumping equipment is not recommended due to suction
problems and potential higher power consumptions. MC type pumps and
positive displacement pumps are used
Mechanical Agitation of Pulp Stocks
The mechanical agitation of pulp stocks follows much the same rules as
those for pumping pulp suspensions ie for consistencies below 1 % treat
the system as Newtonian, at higher consistencies an apparent viscosity
must be developed to use in the Reynolds Number / Power Number
relationships.
Recap on Basi
ixing Theory
Once again those students who do not have a study background in basic
mixing theory should study, using references given at the end of this,
module.
The mixing of papermaking pulps is usually carried out at fairly low
consistencies ie in the range lower than 5 %. For example, prior to
pumping the contents of a high density chest, which has a bulk
consistency of say 12 %, the stock will be diluted in the dilution zone of
the chest to around 4% to make it fairly easy to pump.
In most cases, side entry marine type impellers are used for mixing pulp
stocks; however in some applications other impellers are used, eg for
repulping of dry fibres, where there is a chance of high impact between
the pulp and the impeller or the entanglement of binding wire, the
impellers tend to be closed and installed against the tank wall or base.
In some cases where chemical mixing is required then specially designed
impellers and mixing tanks are used eg chlorine mixers
Mixing of Newtonian liquids
The mixing theory of Newtonian liquids is usually based on the
relationship between the Reynolds Number and the Power Number,
described below. The important consideration about this method is that
the graphical relationships between the numbers is dependent on specific
design configurations of the equipment.
Reynolds Number of a Mixing Impeller
The velocity component of the Reynolds Number for a Mixing Impeller is
taken as the product of the Diameter and the Rate of Revolution ie n* D.
1.6.9Example of calculation of power requirements for mixing a caustic soda
solution
A flat blade turbine, diameter 0,6 m and turning at 90 rpm, is bein used
to agitate a tank 1,8 m in diameter and filled to a depth of 1,8 m with a
solution of caustic soda having a density of 1500 kg m” and viscosity of
0,012 kg m" s*. Calculate the power absorbed by the turbine.
SOLUTION
Calculate the Reynolds Number for the turbine
Nee = nt D?* p/p
(90/60) * 0,6? * 1500 / 0,012
= 67 500
from Figure 7.2.2, itcan be seen that the Power Number is equal to 6 for
a flat bladed turbine when Reynolds Number is equal to 67 500.
Noo = (P*g)/ (n° * DP* p)
= 6
P = 6*1,5°*0,6°* 1500/9,81
= 240,7 kgms"
= 24kW
These methods are based on standard dimensioned tanks and only
calculate the amount of power required to achieve mixing. There is no
time function and hence no energy requirement calculated to achieve the
mix.
The question arises, if standard tank sizes are used for the derivation of
the amount of power required to achieve mixing, what is to be done about
all the non standard tanks used in industry. Most text books avoid this
problem.
Mixing of Pulp Suspensions
The mixing of pulp suspensions is well covered in Fluid Mixing
Technology by JY OLDSHUE, from which appendix 1.13is copied, which
is the chapter on mixing of pulp suspensions. The mixing of pulp
suspensions can be divided up into a number of different types listed on
the next page:
1.6.11STOCK CHEST AGITATOR DESIGN PARAMETERS
Approximate Dimensions
H=25T1 Impeltor D = 0.3372
T2=0,6T1 c=0,75D
Z=0,5 100,772 19 to LOZ
Baeleaeel DESIGN of
Volume
to suit
Volume
her
PULP CHESTS
storage | Consistency
KC] 12%
4
oa
Kt 4
bel
= e
STORAGE CHEST MIXING CHEST
Design Guidelines
1
ak oN
o
For New Installations, choose a chest configuration to give the
following conditions
D:T = 0,33:1; Z:T = 0,7:1; Consistency = 4%
Consistency has a major influence on power consumption,
therefore avoid a consistency over 4,5%
Agenerously sized fillet opposite the agitator will promote vertical
movement and improve agitation
Blending will require more power input than keeping the stock in
suspension.
Design for adequate retention time (12 - 15 minutes) and ensure
a pumping rate that will turn over the stock 5 or more time within
the retention time.
For large chests, eg low or high density storage and blow tanks,
use controlled zone agitation. Treat the controlled zone as a
separate vessel with stock entering in a downward plug fiow.
Transition slopes between zones should not exceed 30° from
vertical.
1.6.13The Basic Process Number has been determined for a set conditions; ie the
consistency of stock is set at 4%; the chest is vertical cylindrical with the height equal
to the diameter; the temperature is 32°C and the retention time is 4 minutes for a batch
chest and 12 minutes for a continuous
chest. eer
In order to deal with differences from these
fixed conditions a series of factors are
used to modify the Basic Process Number
to a Corrected Process Number which is
used to calculate the Momentum Number,
M.
Calculation for the Shape Factor
The Shape Factor will be a function of the
shape of the chest ie whether it is vertical
cylindrical or square or rectangular.
The best mixing efficiencies are achieved
in vertical cylindrical vessels where the
height of fluid is 0,5 to 0,7 times the
diameter or slightly less in square chests.
Rectangular chests require more and more
energy to achieve good mixing as the
distortion from square increases.
The graph of shape factor gives the shape
factor for various shape configurations. Itis
not easy to express these lines in
mathematical formulae.
Dealing with Consistency Variations
As the consistency increases so will the
power required to achieve mixing increase.
This is largely a result of the pulp
suspension trying to reform as a “solid” as.
shown previously in this module, Only bone
dry (BD) consistency is used.
CONSISTENCY FACTOR,
The consistency factor is 1 at 4%
consistency, reduces to about 0,41 at 3%
consistency and increases to 2 at 5%
consistency. The following formula can be
used:
Consistency Factor=0,0142 [Consistency]?””
1.6.15,
2a
2
ene Bea.
32Temperature Effects on Power
The effect of temperature of stock on the power requirement is given by the following
formuta:
107 - 0,008
Power Ratio, F, =
where F, = Power Factor due to Temperature, t°C
Graphically it is represented as follows:
Ftemp = e(0,107 - 0.0041)
1.05
os |
&
‘Temperature Factor
85
20°30 40 50 60 70 80
Temperature
The reduction of power requirement as temperature increases is a result of the
reduction in viscosity of the water and hence easier movement of the fibres in the
suspension.
Clearly, as less time becomes
available for mixing of the suspension
more power will bw required for the
effect, Normally, 14 minutes are
required for mixing a continuous >
pulper (and high density chest). As =
the time available becomes less the
power required increases according
to a power relationship: of
Effect of Retention Time. :
F me = 3,5 [Retention Time] °°
ris ee a ey
For batch pulpers, the normal time
would be 4 minutes and the relationship is described by:
F sme = 2 [Retention Time] °°
1.6.17A high density chest is being used to store unbleached Kraft softwood
pulp (Kappa No = 38) for a paper machine consuming this pulp at a rate
‘of 200 OD tons per day. The dimensions of the chest are as follows:
Diameter of top section: 50 m
Diameter of bottom section: 30 m
Angle of conical section to vertical: 30°
Height of top section: 10 om
Height of bottom section: 20 m
Volume of bottom section taken up by filet: 22%
The pulp in the top section (temperature - 45°C and consistency 11%) is
diluted with machine back water (temperature - 35°C and consistency
0%) prior to pumping to the paper machine at a consistency of 3,5%.
Specific heats of water and wood pulp are 4,186 and 2,145 kJ kg'K"
respectively.
You are required to calculate the volume and temperature of the pumped
pulp suspension. (4)
Answer: The calculation will give the following results as shown in the table
below::
Temperature: 381°C.
Volumetric Flow: 0,066 m*s*
A Units HC Pulp LC Pulp Water
Consistency % 4 35 0
Mass Fraction 0.11 0.035 0
Temperature degC 45.0 38.4(2) 36.0
Mass Pulp kgis 2315 2.315 2.315
Vol Flow cubm/s 0.021 0.066(2) 0.045
Energy kw 3751.41 10358.1 6606.69
Q
Specific Heat
Water 4.186
Wood Pulp 2.145
Using the data provided, calculate the power required to achieve
successful mixing of the suspension prior to pumping. (8)
Answer:
Calculation of Factors:
1.6.196.3. Heat and Mass Transfer in fibre suspensions and fibre matts and
Psychometry of moist Wood Fibres
Transfer of Heat into Fibre Suspensions, 0 to 4% Consistency
Clearly, from the discussions of the previous sections, the transfer of heat into
fibre suspensions will be greatly dependent on the consistency of the
suspension and the nature of the flow conditions of the fibre suspension.
Heat transfer into a pulp suspension through a pipe wall.
The heat transfer coefficient for pulp suspensions was shown by Middis, Duffy
and Muller-Steinhagen to be defined by the following equation
(Neuf 2) pup = (Nya/ £17 ST Na! £) pater * AY
where Ny = Nusselt Number
= h*D/k
h = heat transfer coefficient, Wm? °K"
D = _ Diameter of Pipe, m
k = Thermal Conductivity, Wm °K
f = Fanning Friction Factor
and A is given by
A = @ (31323 + vB 0,658)
where C = Consistency
This formula is valid for Bleached Kraft Pulp at a consistency between 0
and 4%, and bulk flow velocity between 0 and 10 ms.
Transfer of heat into higher consistency fibre suspensions
Pulp suspensions with a consistency over 8% would normally be heated
in a mixer with steam. The amount of steam requires can be calculated
from and energy balance as shown in 6.4
1.6.21in the pulp and paper industry, most calculations are not chemical in nature and
therefore the use of kg moles is not necessary and mass flow is normally defined using
kilograms.
Nomenclature
Flow streams are normally given an upper case letter of the alphabet to denote the
__ stream, for these purposes F will be used to denote a full stream eg a flowing pulp
suspension or a water feed etc. In order to differentiate between different streams each
stream is given a subscript number which will define the stream, eg F,.
Components of the stream will be denoted by a lower case letter; the common letter for
mass fractions is x. This letter is also allocated to it's stream by using the same
subscript as the stream, eg x;
Other fractions can also be used. in these examples, the mass fraction of fibre will be
x; but it could be necessary to define long fibre and short fibre fractions; in which case,
land s may be used ete.
Mass Balancing
ithas already been stated that the basis of mass balancing is that what goes in must
come out. In order to do calculations we need to define that streams entering the
system are positive and those leaving the system are negative.
By definition then
EF =0
The total flow of streams in equals the total flow of streams out,
And
ZF\x=0
The total fractions of a stream in equals the total fractions of a stream out.
By example:
1.6.23This is simple case where only three streams are present; more streams can be dealt
with by dividing the system up and creating false nodes, where a node is a mixing of
only three streams. In the example above, if the feed stream F, had been created by
mixing two other streams such that the example became a four stream problem, this
can be simplified by reducing it to two three stream problems.
By example:
if the stream F, had been formed by two other streams a and b; such that F, = 20 kg s.;
and x, = 0,04, calculate F, and x,
Mass Flow Balance:
Fat Fe tCFi)=
= 20+F, +(-60)
F,=40
Fibre Balance:
F,x+F, x +(F, x%;)=0= 0,8 +F,x, + (-0,90) =0
F, x, = 0,1 but F, = 40, therefore x, = 0,1/40 = 0,0025
In the above example the basis has been given the problem statement. The overall flow
rate and the mass fraction of the feed were given (F, = 60 kg s* ; x, = 0,015). This is
the basis of the equation. If for example, F;, was not given it would have still been
possible to calculate the split of the feed to the accepts as percentages or fractions by
assuming a basis of F; = 1, the answers to the mass flow of the accepts and rejects
would then be given as fractions of 1. F, would be 0,4 and F, would be 0,6.
It is offen a simple solution to more complex problems if a basis is selected; this is
specially the case when specific data (results per unit of feed or product) are required.
Dealing with streams where the data is given as consistency.
In mass balancing terms consistency is not nice to deal with. Firstly, itis expressed as
a percentage and secondly, the units of consistency are not strictly mass based. The
units of consistency are mass of fibre in grams per hundred millilitres of stock or mass
in kilograms per meter cubed of stock.
The problem is that the units are mass per unit of volume and mass balancing requires
mass per unit of mass. In order to deal with this problem it is necessary to convert the
denominator unit of volume to units of mass; ie multiply by density.
The conversion from consistency to mass fraction is:
1.6.25kJ kg* K*, The specific heat of paper and wood pulps will range from 1,35 to 2,7
depending on the content of the pulp. itis probably wiser to use values around 2,2 for
wood and mechanical pulps and then to reduce down closer to 1,4 for fully bleached
chemical pulps.
In order to calculate the energy of a stream it is necessary to add the energy of the
components.
As_an example, the pulp in a high density chest is diluted with machine back water
before pumping to stock preparation section.
The following apply:
The stock is stored at 12% consistency and 28°C, the machine back water is at 0,2%
consistency and 42°C; if the machine requires 1,40 kg s" of pulp to be drawn from the
chest and diluted to 4% consistency, calculate the amount of back water required and
the temperature of the pulp sent to the stock preparation section. The Specific Heats
of water and fibres are 4,186 kJ kg" K" and 1,918 kJ kg" K" respectively.
Mass Balance
Fibre Balance
1,40 + F, * 0,002 - F,*0,04=0
Flow Balance
11,667 + F,-Fa=
By Matrix Analysis or simultaneous equations:
F2 = 24,561 kgs"
F3 = 36,228 kgs"
Energy Balance
Ey Fy “ty * Our" Gy + py * Gy)
= 11,667 * 28" ((1 - 0,12) * 4,186 + 0,12 * 1,918)
= 1278,558 kW
EF, * te * uo" Cy #2" C)
= 24,564 * 42 * ((1- {808} 4,186 + 0,002 *4,018)
= 4313.439 kW
E,+E,-E,=0
Therefore E, = 5591,997 KW
1.6.27Appendix 13
CHAPTER 20 / SECTION F
PULP AND PAPER AGITATION
INTRODUCTION
‘The evaluation and selection of pulp and paper agitation equipment are very important
Gecisions, not only from capital and operating cost points of view but also in ensuring
the desired process performance. In other words, performing the function for which the
agitator is intended is very crucial in the overall successful operation of a particular
stock chest or process system within the mill,
Paperstock slurry behaves differently than other fluids. Referring to Fig. 20-40,
there is @ certain minimum horsepower required to produce motion throughout the
aperstock, If power is reduced below this point, complete motion of the paperstock
will not be maintained. Most of the correlations reported here are based on the effect of
mixer variables and paperstock variables on the power required to obtain complete
motion of paperstock. Associated with motion is blend time.
The following sections are intended to aid the mill’s engineering steff during the
Process of establishing agitation requirements, system designs and agitator selections
AGITATOR SELECTION -
When selecting a chest and agitator system to perform a specific operation in a mill,
there are a number of parameters to be evaluated.
25
7PULP AND PAPER AGITATION 527
Temperature Effects
In general, the higher the stock temperature, the easier it is to agitate. However, the
importance of temperature on equipment selection may not be too great if the normal
operating conditions result in the possibility of wide temperature variations. For ther-
imal mechanical pulp (TMP) ot :efiner groundwood stocks, the temperature is normally
high and constant so there is a saving in horsepower (Fig. 20-43).
Time
{f retention time is too short, the possibility of consistency variation and inadequate
blending can partially be compensated for by increasing the ievel of agitation. Howev-
cr, many chests require normal retention so that incoming fluctuations, such as free.
ness, can be dampened out, For these situations, increasing horsepower will be of litte
help.
Chest Configuration
‘The optimum chest configuration, with respect to agitator selection, is a vertical-
cylindrical chest with a width-to-height ratio slightly less than 1. With rectangular
40
2.0
2.0
5
PROCESS POKER RATIO
2
-1s|
a
15 20 3 4 5 678 10
STOCK CONSISTENCY % b.d.
Figure 20-41 Effect of stock consistency on process power ratio,PULP AND PAPER AGITATION $29
less power consumption while maintaining effective end results. Possible areas for
energy savings are discussed in the following sections.
Chest Function
Careful planning in the carly design stages can often lead to energy savings. For
example, a machine chest requires different agitation than does a broke chest. Surge,
holding, blending, storage and latency chests, to mention a few, all have differing
agitation requirements. The purpose of each chest should be carefully considered
before specifying the agitation requirement.
Stock Consistency
One of the most critical parameters affecting agitator horsepower is stock consistency.
To select an agitator based on a higher than normal operating consistency will lead to
excessive power consumption plus the possibility of poor agitation performance and
shorter equipment life (Fig. 20-44),
Controlled Zone Agitation
A very effective technique that can be employed to save energy is controlled zone
agitation. Contrélied zone agitation design is based on the fact that it is not always
fk
bh
PROCESS POHER RATIO =
20 120 160 7200
TEMPERATURE (°F)
Figure 20-43 Etfect of temperature on process power ratio.
a7 ny 74HPULP AND PAPER AGiTATioN S3I
000 cesT
CONFIGURATION
Figure 20-45 Normal configuration fer effective use of power in blending.
should be evaluated during the agitator evaluation stage. As energy costs climb. it is
becoming easier to justify spending more money on the initial cost of the equipment to
achieve power savings
A second consideration is efficient propeller design. Naturally, not all propellers
of equal size perform equally. The propeller efficiency depends on proper design of the
hub, blade profile, and pitch setting (Fig. 20-48).
LARGE-TANK AGITATION
Agitation of large stock tanks provides a real challenge for the engineer. With mill
production rates constantly increasing, it is not unusual to be confronted with tanks
)
5
)
\
\
J
a
DS
t
S
(f
z
POOR CHEST CONFIGURATION
Figure 20-46 (Lefi) Tank that is 100 tall relative to a small diameter for effective use of power.
Figure 20-47 (Right) A tank that is too long relative to the liquid level for effective use of power.PULP AND PAPER AGITATION $33
Figure 20-49 Typical flow patter: side-encering mixer, complete motion
across the length or diameter of the tank and to a height that will provide the desired
amount of blending. The upper part of the chest is not agitated but is designed so that
continuous plug flow occurs, preventing any dead areas. By using such a system, the
entire contents of the tank are always in motion.
‘The alternative, based on the same principle, is “end zone" agitation, which is
typically employed in a longer rectangular chest where the stock can be introduced at
one end and a blending zone established at the other. The same design criteria must be
PLUG FLOH
Figure 20-50 Iustraton of concept of controlled zone agitation with vertical cylindrical tank,PULP AND PAPER AGITATION 535
agitation power is required because the system is set up with the chest consistency
higher than the desired downstream set point.
Ideally, consistency should be controlted in the chest so that the agitator can
provide the desired downstream requirement without pipeline adjustment. One con-
sistency control system uses the agitator flow and an ultrasonic sensing device to sense
consistency. This arrangement works on the principle that the flow developed by an
agitator is very sensitive to slight changes in stock consistency. If the consistency
increases, the stock movement within the chest decreases which signals for dilution.
The consistency then decreases until the desired set point is reached (Fig. 20-54).
‘The advantages of this system include controlling and adjusting consistency in the
chest, obtaining good mixing in the chest (thus not relying on the pipeline to mix), little
or no time delays, simple instrumentation, and most significantly, an energy saving, as
the consistency in the chest is not higher than the downstream requirement.
BLOW TANKS AND HIGH-DENSITY STORAGE
In addition to providing a system to sense consistency and control dilution water, itis
imperative that these towers have proper agitation desiga in the lower zone. The stock
PLUG FLOW
ourtet
Figure 20-52 Method of splitting incoming feed to achieve beter uniformity.PULP AND PAPER AGITATION 537
in the upper portion of the tower, which could be up to 20% consistency, must travel in
plug flow downward and drawn into the agitated zone (Fig. 20-55).
The lower portion of the tower is critical and must be designed to have sufficient
volume to handle the design production rate and to ensure the high consistency stock is
drawn uniformly into the agitaced zone to prevent channeling in the upper portion.
_Filleting is frequently used in the bottom zone for the purpose of conserving enecays
and providiag more effective resulis. ~~
Dilution water 1s added“in the turbulent area of the impeller to provide a low-
density zone of 3.5 to 5%, depending on downstream requirements. Lower consisten-
cies require less horsepower, so it is normally desirable to design in the lower con-
sistency range. As the low-density stock is pumped out of this zone, high-density stock
the zone from above and is reduced in consistency with recycled dilution water
entering the zone. Thus, the small diameter in the bottom of the tower results in better
control of the agitated zone and uniform pump out, whereas the larger diameter section
provides stock capacity.
This operation hes the advantage that low-pressure dilution water is added to the
suction side of the propeller, eliminating cost and maintenance for high-pressure
pumps, dilution rings, and mining nozzles. Aiso, it is not necessary to have inverted
‘cones in the bottom which were traditionally used with the old-style circulator units in
downflow bleach towers.
IN-LINE MIXING
‘Continuous process pulp and paper operations generally require the blending of che:
cals into a stock line or the blending of two stock lines together on a continuous basis.
In response to this need, the development of mixers in the pipeline has come about.
Lon pressure:
OILUTION MATER
‘CONSISTENCY
poe SR econcer.
CONTROLLER
CILUTION
VALVE
N
fee
SENSOR stock PuMP
Figure 20-55 Schematic of flow diagram for reliabie consistency control on well-agitated paperstock tank.PULP AND PAPER AGITATION 539
Figure 20-57 Impeller-type two-stage in-line mixer,
For continuous under-machine pulping, it is important that the system be set up so
the pulping unit will not allow the sheet to build up on the surface but to be drawn
down rapidly by the pulper. The pulper horsepower, along with the proper location of
dilution and shower waters, are the critical items for successful performance. Typ-
ically, for couch and couch-press pit operations, the open-type propeller pulper will
provide very effective performance (Fig. 20-58).
For dry-pulp pulping, either continuous or batch, high-energy attrition-type units
are necessary. These generally consist of a tank and a high-intensity, high shear
mechanical pulping impeller to disintegrate or defiber while minimizing fiber damage.
The puiper consists of a casing bolted to a flange on thé bottom or side of the tank. The
casing holds the special pulping impeller designed to create flow throughout the tank
along with providing the necessary breaking and defibering action (Fig. 20-59). The
pulping impeller also incorporates a pumping unic that will deliver the pulp slurry
without the need for a stock pump.
BLEACHING
In the bleach plant, there are three important areas requiring special consideration for
the selection of mixing equipment:
1, Bleach chemical mixing
2. Upflow towers
3. Downflow towersPULP AND PAPER AGITATION SdI
stock | must
Figure 20-60 Multistage chlorinaor. (Courtesy izing Equipment Co.)
The important parameters to be taken into consideration in the selection ofa
System are gas dispersion, chemical blending, reaction temperature, retention time,
and intensity of mixing. There are two basic mixing devices in use. The first is «
‘multistaged chlorinator as shown in Fig. 20-60, and the second is a motionless mixer.
‘The multistage chlorinator has the advantage that the retention and mixing inten-
sity can be designed to provide the right chemical contact. It also allows for fluctua.
tons in mass flow resulting from changing tonnage rates and/or consistency and for
variations in bleach chemical feed because of sensor response time. This system uses
mechanical mixers to produce the high fluid shear necessary for efficient mass transfer,
‘The use of static vanes in a pipeline does not create the same maximum shear levels,
and they are very sensitive to changing flow rates. This can lead to improper contact-
ing, troublesome gas bubbles causing upsets in the retention tower, excessive cheiical
consumption, and higher operating costs,
Two important parameters in the selection of a suitable system are retention time
and intensity of mixing. For illustration, refer to Figs. 20-61 and 20-62, which show
the effects of time and mixing intensity parameters. Note the effect of mixing time and
increesed mass transfer resulting in lower chlorine residuals. Naturally, there ere
optimums for both these parameters, so that the fibers are not overbleached and there is
fo excessive energy consumption,
Upfow towers. Figure 20-63 shows the typical upflow tower employing an agitator at
the bottom and one at the top to provide uniform retention time and to prevent stock
channeling. The side-entering stock agitator near the bottom of the tower provides a
uniformly blended zone and establishes a well-defined intecface so that the pulp begins
2 uniform plug flow up the tower.
At the top, there is a specially designed agitator which again creates a uniformPULP AND PAPER AGITATION S43
Figure 20-63 Typical upflow chlorination tower. (Courtesy Mixing Equipment Co.)
MECHANICAL DESIGN
Equally important to the process selection of an agitator is the mechanical design. The
total cost of agitation includes not only the initial equipment cost and the efficiency of
‘operation but also the amount of downtime, the cost for maintenance and operating
Personnel, 25 well as inconvenience end loss of product when equipment is out of
service.
Many mill personne! have specific ideas as to the basic type of equipment which is
most suitable for their operation: there are two basic models that are available. The
integral permanently aligned factory-assembled model and the pillow block field-
Vahey
Figure 20-64 Typical high-density downflow bleach tower. (Courtesy Mixing Equipment Co.)PULP AND PAPER AGITATION S45
Figure 20-67 Modular design permits fast bearing replacement. (Courtesy Mixing Equipment Co.)
. Type of bearings, use of sleeves to prevent shaft damage and ease of on-chest
replacesnent (Fig. 20-67)
4, Reliable shutoff device with the ability of changing packing and/or bearings without
removing the agitator or draining the chest (Fig. 20-68)
5. Removable stuffing box hub construction to allow easy shaft inspection
Figure 20-68 Iiustrating operation of shutoff device. (Courtesy Mixing Equipment Co.)Fig. 11 pee
Shear stress-rate curve fora jiber
suspension.
10
Reaction products are transported away {tom the fiber surface, when reactants
are displaced through the fiber mat. The fiber is thus continuously exposed to.
fresh reactants, The driving force remains high and also the overall conversion
rate,
The practical difference between the used cocurrent and cross-current systems
is thus that the cross-current system requires considerably less retention time due
toa higher conversion rate, Reaction vessels become smaller
The fiber suspension and shear forces
Fibers suspended in water show visco-elastic properties which can be
expressed as in figure 11 in terms of non-Newtonian flaw engineering,
The shear stress-rate diagram indicates that Newtonian properties, that is, the
properties ofthe liquid phase are achieved when exceeding a shear stress value
(Td) corresponding to complete disruption o' the fiber nenwork structure, This
value is dependent on consistency and fiber characteristics like fiber dimensions
and stifiness. The consistency dependence of the disruptive shear stress value ior
4 softwood kraft pulp as shows in igure 12, demonstrates that the same basic
mechanism is valid over the whole range of consistencies iram below one per
cent up to at least fifeen,
SHEAR STRESS, T
ot
RATE OF SHEAR, ¥Although the nerwork of a medium consistency jiber suspension isa fairl
rigid structure it will crack along any fine, where the disruptive shear stress
value is exceeded. individual fibers can be put into such e turbulent mation,
that the suspensions hydrodynamic properties equals that of the submerging
liquid whenever the shear siress and rate conditions exceed a certain limit. The
mechanism is reversible.
It is essential, that equipment utilizing these mechanisms are designed so.
that turbulent volumes are minimized in order to avoid excessive energy use.
since the shear stress level needed iairly high in the medium consisiency range.
Prolonged exposure to the turbulent state involves beating elfects
Practical applications
MC-mixing, MC-separation, MC-discharging and MC-centriiugal pumping are
exampies on ulization of these principe. The internal low patterns is impor-
tant in this context. The geometry of turbulence generators is chosen according
10 demand. Centrifugal forces are to be avoided in mixing processes and parti-
Cularily those involving gases, while fast rotting bulk motion s necessary, im
Separation processes
The wall riction ofa c¥lindrical medium consistency down ilow tower or
reactor is generally 100 small to break the fiber aensork, while conical and ot
hemispherical bottom sections leading tothe point of discharge might generate
conditions, where the net effect of friction, acceleration through flow area con-
vergence and possible reaction iorces exceeds the disruptive shear siress value
This is why areas of flow stagnation are detectable in almost every pulp storage
bottom section. The generally small volume ol these siagnant zones is of course
dependent on tank geometry, but also on flow velocity, consistency and fiber
characteristics. An example of this i shown in figure 13 showing the resulting
stagnant stock profile under certain conditions in 3 dows tlow tower with MC~
discharge. The volume will decrease with increasing throughput. itis quite
evident that a tower bottom configuration allowing full volume utilization in
all situations does not exist, — nature is picking its own ideal design to suit pre-
vailing conditions.
All pulp mill operators know, that already a smal! hole in a thick stock line or a
thick stock tower does result in a flood of stack pouring out virtually as water,
The explanation is simply that pressure conditions gives enough shear forces
over the hole to disrupt the fiber network and to set the fibers in turbulent
motion.