Section (J) : Structural Isomerism v1. J2. J-3, Jd. JP. J-10. dtm. Isomers have essentially identical : (1) Structural formula (2) Chemical properties (3) Molecular formula (4) Physical properties Compounds with same molecular formula but different structural formulae are called: (1) Isomers (2) Isotopes (3) Isobars (4) Isoelectric. Which compound is not the isomer of 3-Ethyl-2-methylpentane ? mA San arr sw Kw What is the correct relationship between the following compounds ? CH, - CH, -CH—CH, ~CH3 CH, — CH, —CH, ~CHp - CHa Hy Hs (1) Chain isomers (2) Position isomers (3) Functional isomers (4) Identical What is the relation between 3-Ethylpentane and 3-Methythexane ? (1) Chain isomers (2) Position isomers (3) Functional isomers (4) No relation (1) CHs — CHe— NH CHO ; (II) Cy -CH-GHOWhich type of isomerism is observed between I and II ? Nie (1) Chain isomerism (2) Position isomerism (3) Functional isomerism (4) Metamerism Which of the following pairs of compounds are chain isomers? (1) Isobutyl alcoho! and s-pentyl alcohol (2) Isobuty! alcohol and t-butyl alcoho! (8) Secpentyl alcohol and neopentyl alcohol (4) Ethyl alcohol and ethylene glycol Aposition isomer of 2-pentanone is : (1) 3-Pentanone (2) 3-Methyl-2-butanone (3) 1-Pentanal (4) 2,2-Dimethylpropanal o-Cresol & benzyl alcohol are : (1) Functional isomers (2) Positionisomers —_ (3) Chain isomers (4) All the above: Monocarboxylic acids are functional isomers of : (1) Alcohols (2) Ethers (3) Esters (4) Aldehydes and ketones. CHsCONHz & HCONHCHs are called : (1) Position isomers (2) Chain isomers (3) Tautomers (4) Functional isomersJ-12. Which of the following pair of compounds are not isomers ? (1) Propyne and cyclopropene (3) Propene and cyclopropene J-13. Saturated acyclic ethers are isomeric with (1) Aldehydes (3) Both aldehydes and ketones (2) Propyne and propadiene (4) 1-Propanol and methyoxyethane (2) Ketones: (4) Alcohols J-14z. Identify the relationship between the given compounds. “~™en and CN (1) Chain Isomers (2) Functional isomers (3) Homologs (4) Position Isomers J-15z. Identify the relationship between the given compounds. 9 H AY and AP, (1) Chain Isomers (2) Functional isomers J-16. and (1) Chain Isomers (2) Functional isomers +172. Identify the relationship among the followings : IH H, H.-OH and CH, 1 OL (1) Chain Isomers (2) Functional isomers J-18z.. Identify the relationship among the followings : and “nH~ mm (2) Functional isomers nt I (1) Chain Isomers Identity the relationship among the followings : ARO 0 ur (2) Functional isomers J-19. (1) Chain isomers 9 fo) . are : yo HK a Kas (1) Chain tsomers (2) Functional isomers Section (K) : Number of Structural Isomers K-1. Degree of unsaturation in (3 (2)4 (3) Homologs. (4) Position Isomers Identity the relationship between the given compounds. (3) Homologs (4) Position Isomers (3) Metamers (4) Position Isomers (3) Metamers (4) Position Isomers (3) Metamers (4) Position isomers (3) Metamers (4) Position Isomers is : (3)7 (4) 6.K-2n. K-32. K-43. K-Sa. K-6. K-82. K-9. K-10~.. How many positional isomers are possible for dimethylcyclohexane ? (1)3 (2)4 (3) 5 (4)6 How many aromatic isomers are possible for trichlorobenzene (CsHsCls) ? (12 (2)3 (4) The number of ether isomers represented by formula CsH100 is (only structural) = (4 (2)3 (3)2 (4)1 Total number of 2° amine isomers of CsH11N would be (only structural) : (4 (2)3 (3) 5 (4)2 Find the number of total structurally isomeric 3° amides with molecular formula CsH11NO : (4 (2)3 (3)2 (4)5 How many structural isomers of all the tertiary alcohols with molecular formula CeH14O ? a2 (3) 4 The number of structural isomers for CsHto is : (18 (2)6 (3)9 (4) 10 Molecular formula CsH100 represent : (1) Two primary alcohol (2) One secondary alcohol (3) One tertiary alcohol (4) All of these The number of isomeric aldehydes and ketones with formula CsHi0O are (structural isomers) ()7 (2)6 (3)5 (4)8The IUPAG name of the following compound is : [JEE(Main) 2017 Online (08-04-17), 4/120] (1) 4, 1-Dimethyl-2-ethylcyclohexane (2) 2-Ethy!-1,1-dimethyleyclohexane (3) 2, 2-Dimethyl-1-ethyleyclohexane (4) 1-Ethyl-2,2-dimethyleyclohexane The IUPAC name of the following compound is : [JEE(Main) 2018 Online (15-04-18), 4/120] a (1) 3-ethyl-4-methylhex-4-ene (2) 4,4-diethy!-3-methylbut-2-ene (3) 4-methy!-3-ethylhex-4-ene (4) 4-ethyl-3-methylhex-2-ene What is the IUPAC name of the following compound? Che, (CHa [JEE(Main) 2019 Online (10-01-19), 4/120] (1) 2-Bromo-3- methylpent-3-ene (2) 3-Bromo-1, 2-dimethyibut-1-ene (3) 4-Bromo-3- methylpent-2-ene (4) 3-bromo-3-methy/-1, 2-dimethyprop-1-ene PART - : JEE (ADVANCED) / IIT-JEE PROBLEMS (PREVIOUS YEARS) * Marked Questions may have more than one correct option. 1 Allyl isocyanide has : (A) 9c and 4x bonds (C) 96, 3x and 2 non-bonded electrons [IT-JEE 1995(S)] (B) 8c and 5x bonds (D) 80, 3x and 4 non-bonded electrons Which of the following represent the given mode of hybridisation sp2-sp*_sp-sp from left to right. [T-JEE 2003(S), 3/144] CH, of (A) HoC=CH-C=N (B) HC=C-C=CH (C) HzC=C=C=CH2 —(D) H.N’"| 10. n Write IUPAC name of the following [T-JEE 2004) Cn, Write IUPAC name of the following [T-JEE 2005] SOH cH, The IUPAC name of CeHsCOC! is : [NT-JEE-2006, 3/184] (A) Benzoyl chloride {B) Benzene chloro ketone (C) Benzene carbonyl chloride {D) Chioro phenyl ketone ‘The number of structural isomers for CsHis is : [IT- JEE 2007] (A)3 (B) 4 (C)5 (D)6 The IUPAC name of the following compound is : [NTT-JEE 2009, 3/160] OH ‘CN Br (A) 4-Bromo-3-cyanophenol (B) 2-Bromo-5-hydroxybenzonitrile (C) 2-Cyano-4-hydroxybromobenzene (D) 6-Bromo-3-hydroxybenzonitrile The total number of cyclic isomers possible for a hydrocarbon with the molecular formula C4He is / are : [IT-JEE 2010, 3/163] (ays (8)3 (4 (0)6 In allane (C3Hs), the type(s) of hybridisation of the carbon atoms is (are) : [IT-JEE 2012, 3/162] (A) sp and sp? (B) sp and sp? (C) only sp? (D) sp? and sp? The carboxyl functional group (- COOH) is present in : [T-JEE 2012, 3/162] (A) pictic acid (B) barbituric acid (C) ascorbic acid (0) aspirin The IUPAC name(s) of the following compound is (are) [JEE-Advanced 2017, 3/122] Wee? (A) 4-methyichlorobenzene (B) 4-chlorotoluene (C) 1-chloro-4-methylbenzene (D) 1-methyl-4-chlorobenzeneAnswer Keys: st. (3) v2. (1) J-3. (2) 4. (1) 5. (1) 36. (3) v7. (3) v8. (1) +9. (1) v10. (3) Jt. (4) J12. (3) J-13. (4) d44. (1) v5. (2) 16. (3) s17. (2) J-18, (2) J19, (4) 20. (2) K4. (3) K-2 (2) K3. (2) K-4. (2) K-5. (2) K-6. (4) K-7. (2) K-8. (4) Ko. (4) K-10. (1)ONLINE JEE-MAIN (2) 2 4) 3. @) PART-II (Cc) 2. (A) 3. 3-Aminobenzoic acid 4-Methylbenzenesulphonic acid 5. (c) 6. (c) 7. (8) (A) 9. (8) 10. (0) 11. (BC)