Hyper conjugation Number of Hyporconjugative structures of given cation is (A)5 (B)6 (c)7 (D)8 Choose the answer that has the following alkenes arranged correclly with respect to increasing stability (most stable alkene is on right). (a) (b) (c) (A) (a) < (b) < (co) (B) (b) < (a) <(c) (C)(c) < (b) <(a) (D) (b) <(c) < (a) (E) (a) <(c) <(b) ] Which of the following is the most stable cation (A) cH.CHEHCH, (6) CH- CH, (©) cH.CH,cH,GH, (0) CH CH, Among the given cations, the most stable carbonium ion is (A) sec-butyl (B) ter-buty! (C) n-butyl (D) None of these Which amongst the following is the most stable carbocation ee (8) CH, (©) CH, () CH, CH, Hy CH, (A) CH= o-0+ Which of the following is the MOST stable carbocation ? L9G Ck 8) (A) (B) . (Cc) (0) le Rank the following free radicals in order of decreasing stability (Cyt CHCgHs (@) CcHs -CH-CH= CH, (il) CH, -CH-CH, (I) C,H, - CH=CH, (V) CHJCH=CHCH, CH, wy CH, CH, E—cH, ‘ cH, (A) I> > > Vio I> v (8) Vi>v> > MIS I> 1 (C) I> I> Il>IV>V>VI (D) l>IV>VI>V>I> I Correctly matched option stability of alkene in each of the following pairs (A) 1-Methylcyclohexene > 3-methyicyclohexene (B) Isopropenylcyclopentane > allylcyclopentane © Co < | (D)All of theseWhich of the following options contain the more stable copmpound from the given pairs: (a) GgHy-CH> & (lI) CH,=CH-CH> (b)()CH,-CH2& (II) CH= CH cu Cy oly & oCy (d)(I) CH, -CH-CH, & a | CH,-G-CH, CH,-¢-CH, (A) ULL (B)LAW A (C)UA MD (D)LNT Correctly matched option stability of compound in each of the following pairs: Od 8) CH,CH = CHCHCH = CH, < CH,CH,CH,CH, CH= CH, “O-0) (D) CH, CHCH = CHCH, > CHjCH = CHCH, CH,(C.Q.)Challenging questions of Hyper conjugation ‘The hyperconjugative stabilities of tert-butyl cation and 2-butene, respectively, are due to (A) «> p (sigmayemply) and « > x* electron delocalisations, (B) oa" anda + nelectron delocalisations. (C) 0 pifilled) and « -> x electron delocalisations. (D)p (filled) > a* and « -rx* electron delocalisations. “The total nuniber of contribuling structure showing hyperconjugation (involving C-H bonds) for the following carbocations H.C @ CH,CH, (A)S (B)6 (7 (08 Hyperconjugation involves delocalisation of (A) electrons of carbon-hydrogen « bond of an alkyl group directly attached to an alom of unsaturated system (B) electrons of carbon-hydrogen « bond of alkyl group directly attached to the positively charged carbon som. (C)x{pi)elections of carbon-carbon bond (D)A&Bboth on Number of u-hydrogen in given compound is (Aya (B)5 (C)6 (D)7 Total number of hyperconjugelive hydrogens of the given following compound is ? (aya (B)5 (C6 (D)7 Hyperconjugation involves overlap of the following orbitals (A)o-o (8)o-p (c)p-p (O)x-x Consider the following carbocations and their resonance hybrids. Which is the MOST stable carbocation ? aeywr a. aa x + oye oye10. Sum of u-Hydrogen in A*B+C+Dis: or or ots = NA A B c on (A) 25 (B)23 v (C)46 (0) 22 Which of the following has maximum number of a-hydrogen: \ A B c (A)A (B)B (cc a (E)E Stability of which of the following compounds is NOT explained by Hyperconjugation? CO WO OD OO (A)A (B)B (Cyc {D)DHeat of hydrogenation(H. O. H.) & H.O.C (Heat of combustion) Rank the following reactions, A, B and C, in order of INCREASING exothermicity. 2H, 2H, WOO OO 2H, OO ( (A)arceb B)c>a>b (Carb>c (D)c>a>b Order of Heat of hydrogenation of the given following compound “) oa Ww AAe4 ow =>, (A) 1> tell (8) > met (© m>ton (0) I> > Which of the following isomers of the formula C,H,, would you expect to give the highest heat of combustion? (A) (B) | | (C) ) (D) CID Which of the following alkene have maximum heat of combustion? (A) 2, 4-Dimethyl-1-pentene (B) 1-Heptene (C)2, 4-Dimethyl-2-pentene (D) 4, 4-dimethyl-2-pentene CH, Libmole, [J wa Me Identify which isomer of Ais having maximum heat of combustion. ) | | | of I OAAAY The reaction of CHCH = or Y-on with HBrgives a) cycrerct, <_Y—o1 ® cr,cr,crer—<_Y—on © cu,crorcn<_\—er o cH,cH,crr_f_\—er Correct order of heat of hydrogenation of the below compounds ? IN Wad a) (2) (3) (4) (A)3>4>2>1 (B)1>2>4>3 (C)4>3>1>2 (D)2>1>3>410. The hydrogenation of alkenes is an exothermic process thal can be used to establish the relative stability of a carbon-carbon double bond, Which of the following compounds would you expect to have the largest heat of hydrogenation? wAK @ SON NO OA eA Give decreasing order of heat of combustion (HOC): @) O (b) Cy (A)b>a>c (B)a>boc (C)e>b>a (D)c>a>b Give decreasing order of heat of combustion (HOC): @ CO ) QO ) @ £N\ Ne (Ayer de arb (B)a>b>c>d (C)d>c>b>a (D)b>ard>c(C.Q.)Challenging questions of (H. O. H. ) Heat of hydrgenation & H.O.C (Heat of combustion) ‘Compare the heat of hydrogenation of given compound : (2) (b) () () (A)a>d>c>b (B)a>c>b>d (C)b>c>d>a (D)c>d>a>b ‘Compare the heat of combustion of given compound Oo a \ (a) (b) (c) (d) (A)a>c>b>d (B)d>c>b>a (C)b>c>d>a (D)c>d>a>b Decreasing order of heat of hydrogenation ? () Cr a) wf ( (A) (1) > (IIT) > (11) (B) (II) > (1) > dN) (C) (II) > (1) > (1) (D) (II) > (IH) > (1) ‘) Pdic (P) Le amolesofH, alot roduct @ jy eo It) o Cj) © n@) F s ca Which of following has minimum heat of hydrogenation. oI (B) of L of L6. Which of the following compounds gives off the LEAST heat per double bond when hydrogenated to cyclchexane? A O ° O ( O 97 Compare heat of combination of following compounds ~ ' m (A) 1> > HL (B)il> tat (cyl>tleit (D)iti> >t 8. —_Findoul the order of heat of combustion w x > >< (A) I> 11> I (B) I> 1 >I (cyte (D)> mt 9. Certain transition metals can catalyze both hydrogenation of alkenes and dehydrogenation of alkanes. Consider the following reaction and decide to which side the equilibrium would lie, and why. Note that where bonds are broken or formed, the approximate bond energies are given H H H H Plor Pd + H, ———— # H H, Lid CH Joss of HH He cH, loss of C = C 104 kcal/mol gain of 2C-H. 65 kcal/mol 2x98 = 196 kcal/mol (n bond only) (B) The equilibrium lies to the left (A) The equilibrium lies to the right (D) There is no way to tell which side will be favored (C) The equilibrium lies equally to each side (E) This reaction cannot occur