of L2iagml"! af 20% : = ‘alculate_ the mole fraction of calcium nitrate and water inthe solutior ii Calculate _the concentration of the solution in ppm and ppb. 'b. Compound 2 consists of 5.64 ) 15.5 oe Detrine the enpical fra of compound 2 ii Dalorvine. the molecular foraula for compound Z if the molar mass iS 29a. & a.i. Forever tog of, GCNos)s solution, . _ thane is 185 gof CaCNos)s - Mass saistion = 1904 a [Mass cqcnonns = 15-5 . Mass #0 = 1tog-18.59 = 84.9 Numba of mole of CaCNOs = . Numbar of mole of Hs0 = —__|Nankar of noe of the fetal =o Oty5mol + 64 mol & =H: 1845 mol |". Mole fracton of CaCNOs) =~ eas — = 0.020 (asf), .'. Molefraction of Hi = -$hre5— 20.BCs-F.). ait. Gestion of thesaltion in ppm = “had —> w= 185000 2 1.64105 ppm Cas.f.) Concarttation of the Solution in ppb = “ras 10% = 1.55 x 10% pb > 1.68 loth G56). —=a Scanned with CamScanner[Mass of element i RUM of fhe anal formula. CtlwOa Elenant c an |e | Nib of moleS Enprical formula lecular formula of the op iS GoHluOa.. a Scanned with CamScanner344 3 of aluminium metal reacts with 25.0 ml of 0.75 M diluted sulphuric acid. | Write the balanced chemical equation for. the raxction.. - Galeulate. the number of moles of aluminium metal and diltad sulphuric acid. C: Deternine_ which reactant js the liniting reactant: = . Calculate the mass for all products. — ‘alculate how much the excess reactant remains. oe Tf the volume of actual gosous product is 315 mL, what is the pprantage —_|_yield_of the reaction Sat STP. : a a gp Calculate. the atom economy for the szaction by cesuning the desired ~_produet is the. gaseous product._ ee ~ Ja. AICS) + 34,504 Cot) — Als CSou)a Cn) 3H. Cg) b. Number of moles of aluninium mztal 21+ mol __\Nunbor of moles of diluted sulphuric acid «135 onl Flap] * 0 15 mal ot _ 025L% 0.T5molL"! __£ 0.01815 mol. C._Let Al ba te biting reactant __ Dilafad sulphuric acid, From the equation, = H:504 is the hmhng | Amol of ALCS) produces 3 mol of HaC3) raactont because C7 Hance, = = Mass oF hydrogen gas He O..01yTMol of AICS) produces 0.0NIImolof HaC3 » ___preducad is smallar Mass of Hs poducad = 0.01atinol x C1.0¥3) 3001" Co.051503). + 0.03834 - : het HS be Fhe lin tog waclant. From the 0, Tacos pedis Sf ESD (ee a ______ [0.01875 mol of HsS0+ Cas peduceS o.01si5mol of Haj) ____|Ma85 of Hs producad = 0.01875 nol x Chora) gnet—t | 031509 Scanned with CamScanner[From 4ye equation, _|Smolof is Gx) produ 10.1815 mol of HS0 MOSS aucsow)s = 1 _|.. Mass for all products = Mass aucsoes * Massu. Hence = 0.00625mol x 349.39 mal"! 139315 § Ee = 21393153 + 0.031509 = 2.166159 6 = 2119 CHF). matal, Al_is the excess reactant. Mas of tho excess reactant, Al ranainS = Mass of Al provided - Mass of @. Since diluted Sulphuric acid, HsSOH 1S the Limiting reactant, hance aluminium A\_used Mass of Al provided = 0.344g From the gquation, 3 mol of HaS0+ Cae) requires Imol of ALCS) Hence 0.01815 mol of HsS04 Cag ) requires O.015mol of AICS) Mass of Al used = 0.0135 mol * 21-0 g mol-! @ 20.33159 Mass CAmount ) of the excas6 reactant, Al remains = Mass of All provided - Mass of Al used = 0-344g - 0.33155 = 0.00659 Cex --... Scanned with CamScanneree eld of, ite ragction at Jeloma = kei = 8.2857 = 84.29%, CHsf). Cas it). 3. Mass of afons in the desired product, hydragen gas, H = 3xaxl0 = 5G (Calassupst) Cass unit). Mas8'of afons inthe reactants = Mass ox + [Mos ont = Caxa.Q) +[C3eax1.0)+ C3 321) # C4 16.09] = 348.3 aS Un OF FL era Prodaet, RySTEGRN gS Fa gp .”. Atom ecor = x 100% airs * 100%, = 1-122652885, 21.13% Caf. Scanned with CamScanner‘a. Given a. redox reaction : Balance the above redox reaction in acidic Determine which reactant is the orcas, and rg usa pagent ____|b. Givan a redox reaction = — | MnOuiC4)* ClOs"Gu) + MfnOs Cs)* ClO¥= eR —____| i. Balance the above redox reaction in basic solution. stata the oxidation number of manganese, Mn before andafter the reaction. ai, TOs" Can) + C9 BCH) HOD o- 203" > Is en 2703" + 1. *GH0 dI-> 1 - _ot Hos bH > BGO aro h TOs" +{2H* +1027 -» Ts +6420 QW > Ene] x5 Oo 30s" +H + pe (Dt SH Racombin the 4yo alf-raachons by adding oll foL- = the mactants fogcther ‘on one sce cod call tho a roductS ligt on the other side : [aos [atos" + tor" + pa* CT + GH.O | Bs “Ta +51, > ls GH’ > ata + 3H:0 cr asimtte ssp |". The balanced redox raqction in acidic solution : toe Coy) + BI" Coq) * GH CO) + 31 Cay 3H2OCLD * Tadata ion, 103" is the ox ding age a3t fakes elecron from the cfher substance | __ and undor loigpes. reduction. |." Todide idn, I” 15 the reducing gent QS itraleases glecton to the other Substance and undergoes oxidation Scanned with CamScanner' a Ta “| aMn #4” Cet) # 3C1O3~ CH) * HsOC1)2Ma02 C5)* 3C104 —_| MnO" > MnO: |_Clos + Clon" ClO3~ 2MnO#7 + 3C1037 /2MnO#~ + 3C1O37 pxeacayen! xett MnOw" * ais OM “Mn O#" +BH*+ GE 2MnOe + 4H20 | 3clOa" + BHO > 3ClO4" + GH" + “Ibi. MnOx = [bi MnO4 Can)# C105" Ca ) > MaOs Co) + C1O47Cmn ) |_MnOx" + MrQs + 2H:O _| ClOs™ + HO > C104" ° ° InOa + JHO t= ae Toba: + HO clon + 3HE 2MnOu” * 3CIO37 +2H* —? 3Mn0a * 3Cl0y" + HsO ya 40H aMnOa + 3C1Or + HAO + 208" + HzO 7 2Mn0a + 3C1O%" + HAO + 20H |aMaO#" + 3C1Os~ + H2O 7 2MnO2 * 3C1O¥ * 2047 _ |”. The balanced redox reaction in_ basic solution C After reachon: a xt 2C-2)70 x eth THE Seas MnOataO [22 + HsO > Clow” + QHt + 227 | *9 = : hii. bet Hho ondaton number of mangorese Mn bo x ee : | Before reaction: _ The o« dation cumbar of manganese, Ma before the reachon oe The oxidation nunbor of manganese, Ma afte tho reaction iS #4