1 | Enthalpy Worksheet Enthalpy Worksheet 4. The combustion of methane, Cs, releases 890.4 kJ/mol of heat. That is, when one mole of methane is bumed, 890.4 kJ are given off to the surroundings. This means that the products have 890.4 kJ less energy stored in the bonds than the reactants. ‘Thus, AH for the reaction = —890.4 kJ. A negative symbol for AH indicates an exothermic reaction CHayg) +2 Ong) + CO) +2 H2O 2 AH = ~800.4 kJ A How much energy is given off when 2.00 mot of CH, are burned? B. How much energy is released when 22.4 g of CH are burned? C. If you were to attempt to make 45.0 9 of methane from CO2 and #20 (with 2 also being produced), how much heat would be absorbed during the reaction?2 | Enthalpy Worksheet Use the following heat of formation table in questions 2 — 6. The Standard Enthalpy and Entropy of Various Substances Substance AH; (kJ/mol) S° (J/K - mol) CF, —126 310 Calas) —63 70. CalOH)x 987 83 CoH 207 201 COxs) —394 214 Hay 0 131, FO%p) —242 189 FO) —286 70. i —46 193 90. au uc oe 240. 5 82 220. 0 205 143 239 2. Using data from the heat of formation table above, calculate the enthalpy of reaction for 3 Hag) + Osig) > 3 H2Oqy- 3. Using data from the heat of formation table above, calculate the heat of reaction for 2 NO + Ong + 2 NOr- 4, Using data from the heat of formation table above, calculate the heat of reaction for N20 1g) + NOxg > 3 NO3 | Enthalpy Worksheet 5. Using data from the heat of formation table above, calculate the heat of reaction for Cal, +2 Hex) + CalOH)a;4 + C2Hais)- 6. Many cigarette lighters contain liquid butane, C110. Using the heat of formation table above, calculate the quantity of heat produced when 1.0 g of gaseous butane is completely combusted in air.| Enthalpy Worksheet Enthalpy Worksheet 1. The combustion of methane, CH, releases 890.4 kJ/mol of heat. That is, when one mole of methane is burned, 890.4 kJ are given off to the surroundings. This means that the products have 890.4 kJ less energy stored in the bonds than the reactants. Thus, A# for the reaction = —890.4 kJ. A negative symbol for AH indicates an exothermic reaction CHyy) +2 Ong) + CO) +2 H2Ouy AH =-800.4 kJ A. How much energy is given off when 2.00 mot of CH are bumed? Zao » PMET . _pzg0 Key teal B. How much energy is released when 22.4 g of CH are bumed? , (rol = Zada cle « atc ~ —BPOMkT . aye kT a 16a, Unel . C. If you were to attempt to make 45.0 g of methane from’ CO2 and H2O (with O2 also being produced), how much heat would be absorbed during the reaction? Con4+ 2H ae —> CHy + 205 AH= +890.4¢E7 ee ae, lea lea +2503 EJ dS cu *Use the following heat of formation table in questions 2-6. The Standard Enthalpy and Entropy of Various Substances Substance AH? (kJ/mol) S°KI/K - mol) Cr Foie) —126 CaCl.) 63 Ca(OH) as) —987 CoH) 227 COxs —304 Has) 0 FOje) —242 FRO) —286 NH) —46 NOG, 90. NOx) > 34 F N20(o) 82 Orx5) 0 Oxs) 143 2. Using data from the heat of formation table above, calculate the enthalpy of reaction for a +ld> eda 3 Hag Ow ae tO, aH: - 869 ey 3 (- e42.3)) - (4 4>k5) 3. Using aiairom the heat ofeépgmation table above, calculate the heat of reaction for w Jew feos ( Bus -u2 ky 4, Using Ser from te ha orf ‘Dion table above, calculate the heat of reaction for N20 (q+ NOx > 3 NO. au= fs (70 ex) \ — [a2key + s4es) 4isqKs| Enthalpy Worksheet 226 IBC 63 2eT 5. Using ya from the het of fom ate above, edfculate the heat of reaction for CaCo,4) + 2 Heir) + Ca(OH os, + CoHy5)- [-982eys 2273) - [-oses + 2C z8ce3) | Aks -l25 &F €. Many cigarette lighters contain liquid butane, C110. Using the heat of formation table above, calculate the quantity of heat produced when 1.0 g of gaseous butane is completely combusted in air. 2 Cy Hie - (SO, —> (04202 4 ca, I ee 0 S - 126 o -242 - 39 [a Cs ey) + te(-2v2)) | a3 7 L2Cices 4 xa) | 4H = -§320 eT