AGG Q U | i, CHEMICAL KINETICS SECTION - |: SINGLE CORRECT TYPE QUESTIONS 1. _Ina first-order reaction, the concentration of the reactant decreases from 800 mol dm” (which is not initial conc.) to 50 mol dm in 2 x 10*s. The rate constant of the reaction in sis (log 2 = 0.3010) (a)2x 108 (B)3.45 x 10% (C) 1.386 x 10° (D)2 x 10% 2. Fora zero order reaction, the time required for the completion of 75% of reaction is times the time required forthe completion of 50% of reaction. 3typ Sty at B)2tyy ae (D)3t,. 3. Forthe 1" order reaction, Ag) —> 2B(g) + Cis) ty» = 24 minutes. The reaction is cared out taking certain mass of A enclosed in a vessel having constant volume in which it exerts a pressure of 400 mm Hg. The pressure ofthe reaction mixture after expiry of 48 minutes will be (A) 700 mm Hg (B) 600 mm Hg (C) 800 mm Hg (D) 1000 mm Hg 4. The graph of log (ROR) vs log Cis found to be a straight line with y-intercept = 2 & slope = -1. Caleulate ROR at concentration of 0.2 M. [In the graph rate of reaction (ROR) in M min” and concentration (C) in m] (A) 102M min? (B) 500 M min? © Min (D) 5M mire 5. Forareaction A -> Products, the time for 75% completion of reaction is 5 times the time for 50% completion of reaction. The order of reaction is (ayo B)-1 (2 (D)3 6. Fortwochemical reactions: A+2B—33; AH = -400kJ/moleof A 2D+E—2F; AH = +300kJ/moleofE occuring ina container such that temperature does not change. What should be the rae of formation of 'F if rate of disappearance of Bis 10° Misec, (A) 10° Misec {B)8 x 10°M/min (0 $x10°M/min {D) 4 x 10° Misec 7. ForareactionA,, ->B,, + Cg, the rate constant for the reaction is3 x 10° M“* min". Atwhat concentration of Awill the rate of reaction be 2 x 107 M min. (aM (B)0.52M (c)082M 1) eu10. 11. 12. QUIZ Which of the following graphs represent correct disproportion of H,O, to giveH,O() and O,(a) ? HO, Pa, a) 8 IF t aA, be © ©) 1H,0,) {H,0,] Where [species] represents concentration of the species, Py, represents partial pressure of O, gas. ROA represents rate of appearance of O, and tp represents halflife of H,O,. Fora gaseous action :2A,, ->Biy + 2C, of the reaction may be : (a)1 (B)12 (C)1.5 (D) 0.75 gr the pressure changes from 10 atm to 15 atm in 10 min. Order Fora reaction: 2A, —»B.g +3Cg, rate constant of disappearance of Ais 10° M soc”. I initially 2M of A\is taken then what will be concentration of C after 5 min. ? (A)0.3M (B)0.9M (C)0.45M (D)1.5x 10®M For zero order reaction which is true ? (A) The rate constant is dimension less. (B) Amount of reactant remain same throughout. (C) typ & initial concentration of reactant. (0) Aplot of concentration of reactant vs time isa straight line with slope equal to K. Foran elementary reaction : nA -> Product tan '(2)=0 Find the value of ‘nt: [where a is initial amount of ‘8’ and ‘x’ is amount reacted in time ‘t') (a)2 (B)-3 (C)3 {D)113. 14. 15. QUIZ x IHforareactiont, represen time requited for, thfraction of reactant to reaet then dently the corectoption fora first order reaction: Statement : ty4 = ty. X 2 Statement] : tyre = typ X 4 Statement ty X2 StatementV : f.1,= by X 3 (A) Allstatements are correct {B) Only statement-| is correct (C)Statement-Il and Statement-IV are incorrect _(D) Statement-II and Statement-IV are correct SECTION - Il: ONE OR MORE THAN ONE CORRECT TYPE QUESTIONS For a reaction represented by A -> B, which of the following options do not give the value of order of the reaction. ROR = Rate of reaction C = Concentration of reactant A C, = Concentration of reaction A at t = 0 P = Concentration of product B tye = Halflife of A. log(ROR), ~ log(ROR), logt2 ~logtyz 1 (A) aC, loa, (8) "Teg, =leaC, (C) Slope of In ROR vs In C graph {D) “y-intercept” of log ROR vs log C graph ‘SECTION - Ill : MATRIX MATCH TYPE QUESTIONS Match the Column. ‘Column 1 Column II (A) Reactant can not be complete in finite time (P) 0 (B) Reaction may be elementary Q 1 (C) _Asreaction proceeds time required for reducing to halfofthe amount (R)_ 0.75 keeps on decreasing. (9) 5 eeaee