DATA PERCOBAAN

Berat boraks 0.2011 gram

Volume HCl titrasi 10.0000 mL

Berat NaOH 2.0339 gram

Volume larutan NaOH 0,1 N 500.0000 mL

Standardisasi NaOH
Volume larutan NaOH dititrasi 10.0000 mL
Volume HCL 10.2000 mL

Normalitas asam asetat yang diesterifikasi

Volume sampel asam asetat encer 25.0000 mL
Volume NaOH 0,1 N 3.7000 mL

Pukul Suhu, C Analisa kadar asam Vsampel encer, mL VNaOH, mL Perubahan warna
25 12.20
14.00 70 Asetat + Sulfat, t=0 25 12.10 bening jadi ungu
25 12.15
25 10.05
14.05 71 Asetat + Sulfat, t=5 25 9.90 bening jadi ungu
25 9.90
25 8.50
14.10 70 Asetat + Sulfat, t=10 25 8.40 bening jadi ungu
25 8.45
25 7.30
14.15 69 Asetat + Sulfat, t=15 25 7.35 bening jadi ungu
25 7.30
25 6.60
14.30 70 Asetat + Sulfat, t=30 25 6.40 bening jadi ungu
25 6.45
25 5.90
15.00 70 Asetat + Sulfat, t=60 25 5.95 bening jadi ungu
25 5.95
25 5.20
15.30 70 Asetat + Sulfat, t=90 25 5.20 bening jadi ungu
25 5.25

ANALISIS DATA
1. Normalitas HCl 0,1 N
2. Normalitas NaOH 0,1 N

3. Normalitas asam asetat yang diesterifikasi

4. Normalitas asam asetat mula-mula

5. Normalitas asam (asetat dan sulfat) t=t

6. Konversi asam asetat

7. Normalitas etil asetat pada setiap waktu

8. Jumlah mol asam asetat mula-mula

9. Jumlah mol etanol mula-mula

10. Jumlah mol air mula-mula

11. Konversi setimbang teoritis

 KP 2.19262561530603

12. Menghitung konsentrasi mula-mula

13. Menghitung nilai konstanta reaksi
a. Reaksi dianggap reversible
 b. Apabila reaksi ke kiri diabaikan

t Y tt ty
0 0 0.0000 0
5 0.24579824188 25.0000 1.2290
10 0.45649814928 100.0000 4.5650
15 0.6515516671 225.0000 9.7733
30 0.82396019341 900.0000 24.7188
60 0.95656363475 3600.0000 57.3938
90 1.16084365515 8100.0000 104.4759
Total 210 4.2952 12950.0000 202.1558

m 0.0110225
c 0.2829
k1s 1.1022.E-02 9.5074.E-04

Grafik
A vs t XA vs t
A t
1.0558 0
0.8646 5
0.7343 10
 0.6358 15
0.5634 30
0.5156 60
0.4533 90

0.8000
1.2000
Konsentrasi asam asetat, mgek/mL

0.7000

Konversi asam asetat, %

1.0000
0.6000
Konsentrasi asam
0.8000 asetat 0.5000

0.6000 0.4000
0.3000
0.4000
0.2000
0.2000 0.1000
0.0000 0.0000
0 10 20 30 40 50 60 70 80 90 100 0 10 20 30

Waktu, menit W
 0.2043 gram
9.9000 mL

10.1000 mL 10.2000 mL

3.7000 mL 3.6000 mL

Perubahan bau

cuka jadi balon

balon

balon

balon

balon

balon

balon

HCl 1 0.1055
HCl 2 0.1082
Rata-rata 0.1068
NaOH 1 0.1090
NaOH 2 0.1079
NaOH 3 0.1090
Rata-rata 0.1086

As asetat 1 8.0381
As asetat 2 8.0381
As asetat 3 7.8208
Rata-rata 7.9657

NAa 0.8773

t Vt=t, mL NNaOH Vc Vs* Vs

12.2 0.1086 25 100 5
0 12.1 0.1086 25 100 5
12.2 0.1086 25 100 5
10.1 0.1086 25 100 5
5 9.9 0.1086 25 100 5
9.9 0.1086 25 100 5
8.5 0.1086 25 100 5
10 8.4 0.1086 25 100 5
8.5 0.1086 25 100 5
7.3 0.1086 25 100 5
15 7.4 0.1086 25 100 5
 15
7.3 0.1086 25 100 5
6.6 0.1086 25 100 5
30 6.4 0.1086 25 100 5
6.5 0.1086 25 100 5
5.9 0.1086 25 100 5
60 6.0 0.1086 25 100 5
6.0 0.1086 25 100 5
5.2 0.1086 25 100 5
90 5.2 0.1086 25 100 5
5.3 0.1086 25 100 5

t NA,t=0 NA,t=t NAa XA

0 1.0558 1.0558 0.8773 0.0000
5 1.0558 0.8646 0.8773 0.2179
10 1.0558 0.7343 0.8773 0.3665
15 1.0558 0.6358 0.8773 0.4788
30 1.0558 0.5634 0.8773 0.5613
60 1.0558 0.5156 0.8773 0.6158
90 1.0558 0.4533 0.8773 0.6868

t NAa XA Netil asetat, t=t

0 0.8773 0.0000 0.0000
5 0.8773 0.2179 0.1912
10 0.8773 0.3665 0.3215
15 0.8773 0.4788 0.4200
30 0.8773 0.5613 0.4924
60 0.8773 0.6158 0.5402
90 0.8773 0.6868 0.6025

NAa Vas nAa

0.8773 25 0.0219

Konstanta perhitungan ρ C2H5OH 100% (Perry, 2008) Konstanta perhitungan ρ H

C1 = 1.6288 C3 = 514
C2 = 0.27469 C4 = 0.23178
 ρB 16.9421 mol/L ρD
ρB 0.7793 g/mL ρD
Vb ρB CBb MrB nBo
200 0.8407 0.72 46 2.6317

Konstanta perhitungan ρ CH3COOH 100% (Perry, 2008)

Konstanta perhitungan ρ H2O 100% (Perry, 2008)

C1 = -13.851 C3 = -0.00191
C2 = 0.64038 C4 = 1.8211E-06
ρD
ρD

Vea VB ρB ρE MrE CBb

12.5000 200 0.8407 0.9985 18 0.72

nAe nAa nBo nEo XAe

0.0185 0.0219 2.6317 3.3089 84.52%

Goal seek
K nAe nA0 nBo nEo
6.9508 0.018536 0.0219 2.6317 3.3089
lnK1 lnK2 ΔHr R T Tr
2.0786 1.9389 -2640.0000 8.314 343.0000 298

K2
6.9508

Referensi ΔHf dan ΔG pada suhu kamar (298 K)

Lange, 2005 Atkins, 2010
Zat
ΔHf, kJ/mol ΔG, kJ/mol ΔHf, kJ/mol ΔG, kJ/mol
C2H5OH (l) -277.6 -174.8 -277.69 -174.78
CH3COOH (l) -484.4 -390.2 -484.5 -389.9
CH3COOC2H5 (l) -479.3 -332.7 -479.0 -332.7
H2O (l) -285.830 -237.14 -285.83 -237.13
ΔHr -3130.0000 -4840.0000 -2640.0000 -5150.0000
ln K1 1.9525 2.0786
K1 7.0466 7.9937

Vetanol 200 mL
Vasam asetat 25 mL
Vasam sulfat 2 mL
V 227 mL
0.227 L
nA0 nB0 nE0 nD0
 0.0219 2.6317 3.3089 0

CA0 CB0 CE0 CD0

0.0966 11.5935 14.5765 0

α 1.1439
1.8
t Y tt ty XA 1.6 R² = 0.
0 0 0 0 0.0000 − 1.4
5 0.2867118102 25 1.4336 0.2179 l
10 0.5434006385 100 5.4340 0.3665 n⁡ 1.2

15 0.7932834129 225 11.8993 0.4788 〖 1

(
30 1.0274013983 900 30.8220 0.5613 1 0.8
60 1.2186875425 3600 73.1213 0.6158 −
𝛼 0.6
90 1.5398387548 8100 138.5855 0.6868
𝑋 0.4
Total 210 5.4093235573 12950 261.2956 2.9271 _
𝐴 0.2
m 0.0148896 )
0
c 0.3261 〗 0 10
k1 0.013016881 0.0011227703
k2 1.8727E-03 1.2848E-04
 1.4

XA 1.2 R² = 0.808540668827668
0.0000 1
−
0.2179 l
0.3665 n⁡ 0.8
0.4788 〖
0.6
0.5613 (
0.6158 1
− 0.4
0.6868 �
2.9271 � 0.2
_
� 0
� 0 10 20 30 40 50 60 70 80 90 100
Waktu, menit
)

Cestil asetat vs t
XA t
0.0000 0
0.2179 5
0.3665 10
 0.4788 15
0.5613 30
0.6158 60
0.6868 90

0.8000 0.7000

Konsentrasi etil asetat, mgek/mL

0.7000 0.6000
Konversi asam asetat, %

0.6000 0.5000
0.5000
0.4000
0.4000 Konversi asam
asetat 0.3000
0.3000
0.2000
0.2000
0.1000 0.1000

0.0000 0.0000
0 10 20 30 40 50 60 70 80 90 100 0 10 20 30 40

Waktu, menit Wakt

Na,t=t Rata-rata
1.0602
1.0515
1.0558 1.0558
0.8733
0.8603
0.8603 0.8646
0.7386
0.7299
0.7343 0.7343
0.6344
0.6387
0.6358
 0.6344 0.6358
0.5735
0.5561
0.5605 0.5634
0.5127
0.5170
0.5170 0.5156
0.4519
0.4519
0.4562 0.4533

nstanta perhitungan ρ H2O 100% (Perry, 2008)

55.4704 mol/L
0.9985 g/mL

55.4704 mol/L
0.9985 g/mL

NEo
3.3089
 1.8

1.6 R² = 0.848019175197183
− 1.4
l
n⁡ 1.2
〖 1
(
1 0.8
−
𝛼 0.6
𝑋 0.4
_
𝐴 0.2
)
0
〗 0 10 20 30 40 50 60 70 80 90 100
Waktu, menit
80 90 100

Cestil asetat t
0.0000 0
0.1912 5
0.3215 10
 0.4200 15
0.4924 30
0.5402 60
0.6025 90

0
0
0
0
0 Konsentrasi etil
asetat
0
0
0
0 10 20 30 40 50 60 70 80 90 100
Waktu, menit