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ae (suew = uopsanb 20} 1201) (eu | = uonsanb 14 e104) apvewe Yours wn soessiaen oC] (onto + enol 8 eee ol WoO GlOH+ Or 9 ae seazaeysa}en (GeroNeN = (91OB + (ENDEN + @EFONOY 8] vayn ancco Sy waists sao fdamne 9a SECO (ot «Gera Gein + OehoN ¥ eS y (warehs atp 204 aBuRYD AdoqUa enysod sou o1R Sey YORTEDD LORNA (sew b= vonsen® 0} 1201) 7 (eu j uonsant 0) 961) vexen Fa pamephy Moreh 9 IS oq mmoaseO SR Wrote TDW 20 rem Rane BY) “H 200 unos oxo vos jo Kaas oc nde Bury KEL UP Sey UORZeR RNA aot eyo Kdoqus tg apt anpssp seek slau uRWoU LOL 0 » (aura 5 suoqsenb syne) (aw |, = wonsonb 40} jer01) ca - a|a axnedsu my gh + - a/a aaneiou micy O00 - + a/o earisod Semmicog g ( + He v| oO eanisod ay vo Sepmonigy | oaoy 8H + be osh z+ © Di vogr ve sobuaue Mdanus ain o susie ow ase eA Gye + eos <— beyonT + © 3w ee _ tape ess erase oj wos Uo! SRN Bi 5 UNO 0 OH >¥ 60S paeey Lepr uojess aUegoPLO Ue Wy sesceoo9p seUoRED Leg ~~ uray Charges > Elan 42 quasron, (sew 94 = wogsenb 203 04) a semoaou ou wowanow a4 Teak 018 Suto @ wo w wo ‘snoaugwods ATeoeUfpoULeIN YORDED! SUL -amsue nok y syun pue vis ® sprout -uoqes: aos aBueND ‘donve prepuEis 0 aM EINE Oh doy sveNsie ok asn (A) semegy a1noIe0, “J 4 gPOL~ 81D, 67 UOHDe®! 9u Jo @BUBLD Kote PrepUEIS OL (0) ‘watueo ojeshoeuvaiy@u| snosuewuods jo BUUBEL ea WEIS (2) (format <— Bor + (Sear ‘snowueuods s vaBAKo Jo e2ue86:d usu UOH 0 voREAD OU, ~ as. Citric acid is found in lemon juice. The structure and formula of citric acid are shown below. H | ve ett HO—C—COOH | H—C—COOH | H CHO, 4 (a) In the presence of a small amount of moisture, cittic acid reacts with sodium hydragencarbonate as shown in the equation below. C,H,0,{s) + 3NaHCO,(s) -> Na,C,H,0,(s) + 3CO,(g) + 3H,0() Use the structural formula of citric acid to explain why one mole of citric acid neutralizes three moles of sodium hydrogencarbonate. “ (b) You should use the values given below in the calculation that follows. Compound 37S mor" Kt NasCeH.O; (8) 200.5 ‘CeHe07 (5) 199.9 NaHCOs (3) 101.7 CO (g), 213.6 0 (a) 69.9 (Calculate the standard entropy change of the system, AS*ean, for the reaction in a) at 298K. Include a sign and units in your answer. (2) (i). Explain how the sign of your answer to (b\() could be predicted from the equation for the reaction between citric acid and sodium hydrogencarbonate. (@) (ii) Given that AH?2a9 for the reaction shown in (a) is +70 kJ mol’, caloulate the standard entropy change of the surroundings, AS*syroundngs, for this reaction at 298 K. Include a sign and units in your answer. (2) (iv) Calculate the total entropy change, AS", for this reaction at 298 K. (a) (v) What does the sign of AS*sa suggest about this reaction at 298 K? (ay (Total for question = 9 marks)

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