Short questions

I) Why real gases shows deviations from ideal behavior?

II) What is critical temperature and critical pressure?
III) The horizontal portion in the isotherm of CO 2 at 21.5OC correspond for?
IV) What is collision mean free path and collision diameter?
V) What will be the collision no of one mole of O 2 molecule move with avg velocity of 5234m/s
and have collision diameter of 3.60x10-10 m.
vi) A gas has VC 12.81X10-2 dm3mol-1 and Pc is 73.33 atm find the values of a and b?

Long Question
Derive the van der waal equation for real gases.
2.5 mole of H2 gas occupying 40dm3 of volume is kept at 300K .
Find its pressure if it behave ideally
Find its pressure if it does not follow general gas equation (a=0.244dm 6 atm mol-2
b=0.0266dm3 mol-1)