massa keluar (produk)

delta H
massa masuk
T1=25C
delta H3

delta H1

delta H2
massa keluar (produk)
delta
Hrxn298

Hout - Hin = delta H =delta H1 + delta H2 +delta H3

delta H1 = 0

spesies Vi, mol deltaHf 298 (kJ/mol Vi * deltaHf

reaktan FeS2 6.84 -177.9 -1216.836
O2 18.81 0 0
-1216.836
produk spesies Vi, mol deltaHf 298 (kJ/mol Vi * deltaHf
Fe2O3 3.42 -822.156 -2811.77352
SO2 13.68 -296.9 -4061.592
total -6873.36552

delta H2 -5656.52952

Dinda Bazliah
02211640000070
 masuk
a keluar (produk) F
BM fraksi massa gram mol
FeS2 120 0.85 850 7.08
inert 0.15 150 0
elta H3
O2 32 0 0
N2 28 0 0
Fe2O3 160 0 0
SO2 64 0 0
massa keluar (produk) total 1000
t2 40
T1 25

arus P
a b c d n
SO2 38.91 0.03904 -3.104E-05 8.608E-09 13.68
N2 29 0.002199 5.723E-06 -2.871E-09 219.83
O2 29.1 0.01158 6.076E-06 1.311E-09 39.63

arus C T2 313 T1
a b c d n
Fe2O3 103.4 0.06711 -1772000 0 3.42
FeS2 78 0 0 0 0.24
inert 0.25 150

delta H3 -8485760027555 -8485760028

Q= -8485765684
masuk
U reaksi P
fraksi mol mol koefisien mol fraksi mol mol fraksi mass
0 0 4 -6.7968 0 0 0.04
0 0 0 0 0 0 0.21
0.21 58.41 11 -18.6912 0.15 39.7188 0
0.79 219.7328571429 0 0 0.8 219.73285714 0
0 0 2 3.3984 0 0 0.75
0 0 8 13.5936 0.05 13.5936 0
1 278.1428571429 1 273.04525714 1

delta H
8237.906511412
95881.65487174
17526.127204
121645.6885872
298 cp = a+bT+cT^2+dT^3
delta H integral = aT+b/2T^2+c/3T^3+d/4T^4
-8485760150044
280.8
562.5
-8485760149201
 C
gram mol
28.8 0.24
150
0 0
0 0
547.2 3.42
0 0
726
 In Out Reaksi
N2 2.82 2.82 0
O2 0.75 0.25 -0.5
CO2 0 1 1
CO 1 0 0

delta Hc j/gmol
Temp C Temp K CO O2 N2
10 283 291.7 292.8 291
25 298 728 732 728
426.7 699.7 12748 13225 12652
537.8 810.8 16221.6 16904 16076.5

Temp F CO O2 N2
50 125.4 125.8 125.1
btu/lbmol 77 313 314.7 313
800 5481 5685.7 5439.4
1000 6974 7627.4 6912

deltaHf
CO O2 N2 CO2
kj/gmol -110.52 0 0 -393.52
btu/lbmol -47589.912 0 0 -169449.712

deltaH
Produk CO2 N2 O2
-161820.812 14456.448 1292 -146072.364

reaktan CO N2 O2
-47777.512 18609.18 5626.2 -23542.132
delta Htotal -122530.232
Q= -4376.07971429

Cara II
product
mol a b c
co2 1 8.448 0.0028785 7.19666667E-07
n2 2.82 6.895 0.0003812 2.33633333E-08
o2 0.25 7.104 0.0003925 1.84266667E-08

reaktan
mol a b c
co2 1 6.895 0.0003812 2.45566667E-08
n2 2.82 6.895 0.0003812 2.33633333E-08
o2 0.75 7.104 0.0003925 1.84266667E-08
basis 1lbmol

CO +1/2 O2 = CO2

CO2
363.9
912
18656
24232.6

CO2
156.4
392.1
8021
10419

430.6

delta H delta Htotal

7564.936591732 -161884.775408
5214.841504666 14705.85304316
5375.638826548 1343.909706637
-145835.012658

delta H
-187.463993455 -47777.3759935
6719.672197999 18949.47559836
6928.746613215 5196.559959911 delta H total
-23631.3404352 -122203.672223
Q= -4364.41686512
 in
basis F 100 lb mol F fraksi mol
N2 0.6
O2 0
CO2 0
CO 0.2
H2O 0.00000000
H2 0.20000000
total

deltaHf
H2 H2O CO
kj/gmol 0 -241.826 -110.52
btu/lbmol 0 -104130.2756 -47589.912

produk -5471599.752
reaktan -951798.24
Q -4519801.512
Q/V = -3093.93682252 btu/ft3
 in reaksi out
F mol U fraksi mol U mol koefisien mol fraksi mol P
60 0.79 285.71428571 - 0 0.826446280992
0 0.21 60 0.5 -40 0.057851239669
0 0 0 1 20 0.057851239669
20 0 0 1 -20 0
0 0 0 1 20 0.057851239669
20 0 0 1 -20
100

O2 N2 CO2 430.6
0 0 -393.52
0 0 -169449.712

PV=nRT
14.69 psi
R = 10.73 psi ft3/lbmol R
20 Reamur
v= 1460.8577263 ft3
out
mol p reaksi 1 excess 200%
285.71428571 CO + 1/2O2 = CO2
20
20
0 reaksi 2
20 H2 + 1/2O2 = H2O
0
345.71428571
basis 100 lb mol in
F fraksi mol F mol U fraksi mol U mol
N2 0 0 0.79 1504.7619048
O2 0 0 0.21 400
CO2 0 0 0 0
CH4 1 100 0 0
H2O 0.00000000 0 0 0
100

deltaHf
H2O CH4
kj/gmol -241.826 -74.84
btu/lbmol -104130.2756 -32226.104

delta Hc j/gmol
Temp C Temp K H2O O2
25 298 837 732
260 533.15 8948.7 7858
1093.25 1366.4 41218.7 35276.37

Temp F H2O O2
77 360.4122 314.7
btu/lbmol 500 3853.31022 3383.6548
2000 17748.77222 15190.004922

Produk CO2 N2 O2
entalphy -14701888.785 21138624.4291 2975060.9844

enthalphy reaktan CH4 N2 O2

-2797899.7162 4474167.558095 1227581.92
Q= -10840436.2494 btu
Q= -677527.265587 -6775.27265587 btu/lb CH4
 reaksi out
koefisien mol fraksi mol P mol p CH4 2O2 =
- 0 0.7505938242 1504.7619048 100 200
2 -200 0.0997624703 200
1 100 0.0498812352 100
1 -100 0 0
2 200 0.0997624703 200
2004.7619048
2004.7619048

O2 N2 CO2 430.6
0 0 -393.52
0 0 -169449.712

j/gmol
N2 CO2 CH4
728 912 879
7632 10729.89 10742.23
33350.72 53002.75 67911.46

N2 CO2 CH4
313 392.16 378.4974
3286.3392 4620.290634 4625.604238
14360.820032 22822.98415 31259.645038

H2O
-17348383.116 -7936586.4875

2903849.761895
CO2 2H2O