Honors Chemistry — Fall Final Exam NAME, Multiple Choice ~ Choose the right answer ‘True False Questions — Choose “A” for True and “B” for False See the last two pages for important reference material, 1) How many significant figures are there in the measurement, 60.040 cm? a)3 b)4 oS 06 ©) none of these 2) How many significant figures are there in the measurement, 6.0 x 10° m? a)3 4 os a6 ©) none of these 3) What is the best answer to report for the following? {G.478 x 1.164) /2.00] + 0.354 a) 24 b) 2 2.38 6) 23782 ©) 2378 4) Which of the following describes the approximate volume of a washing machine? a) Lm? b) Lom 1 mL, OIL ©) L km? 5) A unit of length called the “zither” (z) is defined by the relationship 7.50em = 1,00 zither. A 100.0m distance would be described as a) 1332 b) 75x 10'z, ©) 7502 ) 133 x10 x ©) 266 x 6) Which of the following contains the same volume as 1 liter bottle? a) Idm b) Lom? ©) 1dm? @) Im? 7) The density of water is correctly expressed as a) Lg b) Lkg/L, ©) 1 gimL, ) L mgimt ©) more than one of these 8) Express the density 17.5 g/mL is the unit [b/gt (4 qt = 3.784 Ls 1 Ib = 454 g), a) 3.65 Ib/qt b) 365 Ib/gt ©) 365 Ibiqt ) 0.365 Ib/qt 9) How many protons, neutrons, and electrons are there in the ion, *Ca"?? a) 42 protons / 40 electrons / 22 neutrons ) 22 protons / 20 electrons / 20 neutrons ©) 20 protons / 22 electrons / 22 neutrons 4) 20 protons / 18 electrons / 22 neutrons ©) 20 protons / 22 electrons / 18 neutrons 10) In order for Ra to be transformed into "Rn, what must happen? a) “*Ra must lose 4 protons, 2 neutrons and 4 electrons b) Ra must lose 2 protons, 2 neutrons and 2 electrons ©) Ra must lose 2 protons, 4 neutrons and 2 electrons 4) Ra must lose 4 protons, 4 neutrons and 4 electrons ©) **Ra must gain 2 protons, 2 neutrons and 2 electrons 11) When the secondary quantum number ("I") is 1 (one), the magnetic number (m) can have values of: )-1,0,1 b) 3,2-1,0123 ©) Oonly 123 ©) none of these 12) The orbital diagram for an atom of Oxygen (O) would contain___unpaired electrons. a) 3 b) 6 95 42 ol 13) Which of the following quantities is equal to the atomic number in a neutral atom: a) # of protons b) #ofelectrons ——_¢) # of neutrons 4, mass number oak 14) Atoms of the same element that differ in the number of neutrons in their nuclei are called: a) different elements _b) stereoisomers ©) isomers 4d) isotopes €) none of these15) An ion has 18 electrons, a mass number of 36, and a charge of -1. How many protons (p) and neutrons (n) does it have? a) 17 pand 36m b) 17 pand 17n ©) 17 pand 191 @ 19pand19n —) 19 pand 17 16) Which pair has the same electron configuration? a) Caand Tit b) Cl-and Nat ©) Nat and K+ d) Sand Ar e.none of these 17) What is the valence electron configuration of the sulfur atom in its ground state? a) 3573p* by 3s%3p* ©) 2s%2p* 4) 38%3p* €) none of these 18) The absorption of a quantum of energy by an atom: a) increases its energy by a quantity of energy equal to hy (note v= nu) b) decreases its energy by a quantity of energy equal to hv (note v = nu) ©) decreases its energy by a quantity of energy equal to Av (note v = nu) 4) causes no change in energy 19) Who first suggested the nuclear model of the atom? a) Heisenberg b) Rutherford ©) Avagadro 4) Thomson ©) Schrodinger 20) Who first suggested the idea of orbitals? a) Heisenberg b) Rutherford ©) Avagadro ) Thomson €) Schrodinger 21) Two electrons in the same orbital must have __ quantum numbers in common, a) 1 b)2 3 a4 00 22) Which of the following sets of four quantum numbers properly represents an electron occupying a p orbital of the fourth energy level? a) (4,00,-1/2) b) 4,1,1-1/2) ©) (42,0412) 4) 433,12) ©) (41.2412) 23) Degenerate orbitals in an atom which contains only 1 electron are orbitals which are a) in the same energy level ) in the same sublevel ) in different energy levels d) more than one of these 24) The a.m.u, is based on what element? aH bo oc 4) He oF 25) One particular form of electromagnetic radiation has a wavelength of 27 jum. What is the smallest increment of energy that can can be emitted at this wavelength. In other words, what is the size of 1 quantum of energy at this wavelength. a) 737x103 0) 737x107 J 9737x1085 @)LALx 10°F ©) L1x 10°F 26) Consider the frequency, wavelength, and energy of a light source. Which of the following lists only those properties of light which are directly proportional to one another? a) frequency, energy ») frequency, wavelength ) energy, wavelength d) frequency, energy, wavelength €) none of these 27) What is the most common ion formed by Aluminum? a) Al? by al? oar ar eat 28) Which of the following compounds has the highest boiling point? a) methane b) ethane ©) propane 4) butane ©) pentane 29) Which of the following compounds would have the highest rate of evaporation? a) ethanol ') methanol ©) methane d) ethene ©) ethyne30) How many lone pairs of electrons are present in the Lewis structure of the nitrite ion? a)2 b)3 o4 as ©) none of these 31) Which of the following has the most highly endothermic 1" ionization energy? a) Sr b) Mg OK as eal 32) Which elements have the following characteristics? React violently with water Soft silver colored metals which can be cut with a knife React with halogens to form salts with the general formula M,X, Must be stored under oil to prevent reaction with oxygen a) alkali metals ) alkaline earth metals ©) transition metals 4d) p-block metals ©) halogens 33) Valence electrons belonging to which of the following atoms would experience the greatest shielding? a) Be b) Mg ©) Ca d) Sr ©) Ba 34) Which of the following processes releases the most energy? a) Nay + & => New b) Nay > Naty + ©) Clg = Chg + © d) Clot © > hy ) Sgt e > Sy 35) The equation below describes Oy = Oy + € a) the electron affinity process for oxygen ») the ionization energy process for oxygen ©) the electronegativity process for oxygen 4) anion formation in an oxygen atom 36) The energy value forthe process described in number 35 would be a) endothermic b) exothermic ©) both endothermic and exothermic 4) there is no energy value associated with the process described 37) Which of the following would have the highest ionization energy value for the removal of the third electron? a) Mg b)Si Ar aAl 9a 38) Sodium and potassium have very similar chemical properties. This is explained by the fact that sodium and potassium a) have very similar outer electron configurations ) are both active metals ©) both have relatively low ionization energies 4d) all of these ©) none of these 39) Which pair is most different with respect to atomic radius a)Na/ Ar b) At/Mg OCSIF 4) Sr/Br ©) Bal 40) Chemical reactions between metals and nonmetals primarily involve 8) sharing of electrons b) sharing of protons 6) transfer of electrons 4) transfer of protons41) How would the electrons in a bond between F and O situate themselves? a) exactly between the F nucleus and the O nucleus b) closer to the O nucleus ©) closer to the F nucleus 4) the electrons would actually be transferred completely from the O atom to the Fatom ©) the electrons would actually be transferred completely from the F atom to the O atom 42) The group(s) that normally form cations is (are) () alkali metals (2). halogens G) transition metals a)all form cations) 1 and 2 ©) Land 3 4) Lonly 43) What is the proper formula for mercury (1) oxide a) HgO b) Hg,0 ©) Hg0, 4) Hg,0, 44) What is the proper name for the compound Cu(BrO),? a) cupric bromite ) copper (1) bromite ©) copper (1) hypobromite 4) copper (ID) hypobromite ©) cuprous hypobromite 45) What is the proper formula for permanganic acid a) MnO b) HaMnO, ©) HMn0, d) HMn0, 46) What is the subscript of potassium in the formula for potassium dichromate? a1 b)2 03 a4 47) Which of the following oxyacid names and formulas are correct? 1) H,SO, / sulfuric acid 2) HCIO, / chlorous acid 3) HCO, / carbonous acid a) all are correct, b) Land 2 ©) Land 3 @) Lonly 48) Choose the name-formula pair that does NOT match a) perchloric acid / CIO, ») potassium hydroxide / KOH ) ammonitum carbonate / (NH,),CO; 4) sodium chlorate / NaClOy ) calcium hydrate / CaH, €)3 only €) none of these ©) H.MnO, 5 ©) 2only 49) The formula for zirconium phosphate is Zr,(PO,),. Based on this information, the formula for zirconium sulfide would be a) Zr(SO.)s b) ZS, ©) ZS d) ZxS0.), 50) Which of the following pairs of elements would exhibit polar covalent bonding? a) EF b) NaF MgO 4) Fes 51) The compound CH,CH,OCH,CH, belongs to the family of a) esters ) aldehydes o)carboxylic acids d) ethers 52) The appropriate name for the compound in number 51 is 1a) methoxymethane —b) methoxyethane ——_c)ethoxymethane.-—_d) ethoxyethane 53) The compound CH,COOCH,CH, belongs to the family of a) esters, b) aldehydes c carboxylic acids d) ethers ©) Zr 8s C0 ) ketones €) methoxypropane ©) ketones54) The proper name for the compound in number 53 is a)ethylethanoate —__-b) methyl methanoate ¢) methyl ethanoate _d) ethyl methanoate _¢) propyl propanoate 55) How many isomers of C,H,» are possible? (this is the type of problem you may want to save for later) a)l 2 03 a4 5 56) How many isomers of C,H are possible? (this is the type of problem you may want to save for later) a)2 b)3 04 5 ©)6 57) What is the proper name for the following compound? CH=*C~CH,-CH-CH,-CH, CH; CH-Cl=CH, a) 2-methyl-4-ethyl-I-hexane b) 2-methyl-4-ethyl- 4) 2-methyl-4-ethyl-1-heptene ©) 4-ethyl-6-methyl- heptane ©) 2-methyl-4-propyl-L-hexene ‘heptene 58) Which substance would be most soluble in the nonpolar solvent, pentane? a) silver bromide) lithium bromide) cesium bromide d) water ©) bromine 59) Which of the following would be most soluble in water? a) L-butanol ') methanol ©) methane 4) copper (II) hydroxide ©) carbon dioxide 60) Which of the following molecules exhibit hydrogen bonding? a) hydrogen fluoride —_-b) chloromethane c)ethene ——d) methoxymethane _e) more than one of these 61) Which of the following would have the highest melting point? ) magnesium chloride b) carbon tetrachloride ©) oxygen dichloride 4) nitrogen trichloride 62) Which molecule has the strongest bond? ah DF ON OO, och (63) Which of the following compounds has the highest lattice energy a) Nal b) Lio ©) Cas 4) Al, ©) AIF, 664) Select the molecule or ion which has square planar geometry? a) CR, b) BR, ©) PR. SF, ©) XeF, 65) Which of the following exhibits sp? hybridization? a) CF, b) PFs ©) Br, @ SF, ©) XeF, (66) The bond angles in ethane are equal to 2) 90° by 180° ©) 120° 60° ©) 109.5° 67) Which molecule is polar? a) CF, b) SF ©) XeF, 4) Be, ©) BR, 68) Consider the Lewis structure of the sulfate ion (SO). How many double bonds must be present in this ion in order to achieve a formal charge of “O” for the sulfur atom? a) 0 by 02 a3 4 69) Which of the following exhibits LDF's only? a) CF b) SE, ©) Bek, @) BR, ©) more than one of these70) Which of the following structures are not possible Lewis structures forthe thiocyanate ion (SCN})? \S-C=N @ =c-N 6) 2) 23,4 bia O34 145 91s 71) Ina sigma bond the electrons are situated a) on the internuclear axis ) above and below the internuclear axis ©) in front of and behind the internuclear axis @bore 72) How many sigma bonds are in the Lewis structure forthe nitrate ion? a0 bI 2 3 o4 73) The NO molecule has ___ pi bonds) and has molecular geometry. (Remember: the least electronegative element should chosen as the central atom) a) one / bent b) two / bent ©) one / linear @) two /Tinear ©) none of these 74) Which of the following compounds of manganese contains Mn with a +7 oxidation number? a) MnO; b) Mn,0; ©) Mn0 4) KMn0, e) Mns. 75) Flammability (reactivity with oxygen gas) is a a) chemical property b) physical property ©) cannot be determined 76) Dissolving sugar in water is a ) chemical change ») physical change ©) cannot be determined 77) T ot F, A chemical change such as combustion results in a substance with no new identity. 78-81) Are the following... ? a) homogeneous mixtures _b) heterogeneous mixtures ©) elements ) compounds 78) fresh squeezed orange juice with pulp 79) table salt(NaCl) 80) iron 81) clear and colorless sample of salt water 82) A compound differs from a mixture in that the compound: a) has two or more identities ») has only one identity ©) is composed of only one kind of atom 4) can be separated by physical means, 83) Which is the estimated digit in the following measurement? 24.5 em. a) 2 4 5 4) none of these were estimated 84) Which of the following is by definition "pure"? a) salt water b) soda ©) carbon dioxide @) air ©) alll of these85) A sample of matter is inthe liquid state. It is clear and colorless and does not exhibit the Tyndall effect. This, sample is heated and you observe that the liquid in the mixture evaporates, leaving a white solid in the dish! How can ‘you best describe the original sample of matter? ) homogeneous mixture ) asolution ©) compound 4) none of these €) more than one of these 86) Consider the process described in number 85. How can you best describe the change which took place? a) chemical ) physical ©) homogeneous d) none of these 87) Which of the following would exhibit the Tyndall effect? a) pure water ) colloid ©) solution ) oxygen ©) all of these 88) What are the products ofthe reaction of solid zine metal and hydrochloric acid? (Hint: consult solubility rules) a) solid zinc hydroxide and gaseous hydrogen ) aqueous zinc hydride and gaseous chlorine ©) aqueous zine chloride and gaseous hydrogen @) solid zinc hydroxide and gaseous chlorine ¢) solid zinc oxide and hydrogen chloride gas 89) When the chemical equation for the combustion of 1-propanol is written correctly (with whole number coefficients) the coefficient in front of the oxygen is a5 07 045 9 €) none of these 90) What are the products of the reaction of aqueous lead (II) nit solubility rules) a) aqueous sodium nitrate and aqueous lead (11) phosphate? b) solid sodium nitrate and aqueous lead (11) phosphate? ‘c) aqueous sodium nitrate and solid lead (II) phosphate? 4) solid sodium nitrate and solid lead (11) phosphate? ) cannot be determined rate and aqueous sodium phosphate? (Hint: consult 91) Which of the following shows the unbalanced equation for the decomposition of plumbic nitride? a) PbN, = Pb + N b)PbN => Pb + Ny ©) PbN, => Pb,+ Ny @)PbN, = Pb + Ny ©)PbN; = Pb + N 92) When the equation from number 91 is properly balanced, what is the coefficient in front of plumbic nitride? a)2 by3 o4 as ) none of these 93) When solutions of sodium chloride and calcium nitrate are a) two insoluble products form ») two soluble products form, which means there really was not a reaction at all! ©) one soluble product and one insoluble product form ) two gases form €) cannot be determined from the information given ixed (consult solubility rules) 94) The reactants in a chemical reaction are written on the of the arrow. a) left side by) right side ©) top of 4d) Is this a trick question??? No its not. So please don’t miss it! 95) Honors Chemistry Class has been a) Fun! b) Challenging! c) a major pain in the you know what! d)all of these HINT: Answer “a” if you want a free point!IMPORTANT EQUATIONS AND CONSTANTS: c=av E=hv i=himv 3.00 x 10% m/s = 6.63 x 10 Js 4.2 | Precipitation Reactions “TABLE 4.1. Solubility Guidelines for Common fonic Compounds In Water. | | Soluble Compounds Important Exceptions | “Compounds containing NO,- None | Hi0," None Cl" Compounds of Ag’, Ha", and Pb" Br- Compounds of Ag”, Har, and Pb" Compounds of Ag’, Hg", and Po ‘Compounds of Sr, Bat", Hg, and Pb? Insoluble Compounds Important Exceptions Compounds containing S* Compounds of NH,*, the alkali metal cations, and Ca¥, Se, and Bat CO Compounds of NH," and the alkali metal cations PO," — Compounds of NH,” and the alkali metal cations OH Compounds of the alkali metal cations, and Ca", St, and Ba m1=i ~~ WebElements: the periodic table on the world-wide web http://www.webelements.com/ 1 2 3 4 6 6 7 ee ee H St. Louis College of Pharmacy yo | #1 4588 Parkview Place |e St. Louis, Missouri 63110 Li | Be 314.367.8700 800.278.5267 ace Treas, wwwstlcop.edu 4 Uuq na ee ee | oe etn) | ma | we [tee | ves |e | er] ee [we | Se “lanthanoids | La | Ce | Pr | Nd |Pm|Sm| Eu | Gd| Tb | Dy | Ho| Er | Tm| Yb “actinoids | AC! Th | Pa} U | Np| Pu |Am|Cm) Bk | Cf | Es |Fm|Md|No zone | mo |e | on | ae | sae | en | om | on | eo | pon | se | en ‘Senrrant: 290 OMe J Wi: nebo ac, Waders Lan Uetsy of Sates opal Te Unversity Sai S376. Egand ‘Theater wean xorg on is Waar prepa ute, eu ened ona narexcue basa ate eb fu Gb hot nn he WEBELEMZ POF fae conyigh caer eee its wore2B @ °O &O —°@ 9© HO &© 9O HO @-@-O@-O-O-O-@ -© -O -© 5 28 -@ 6@ 2@ NO NO 9O 9 AO WO HO ws “© -@-@-©-O-@-@-6- & 8S 8 $$ 8 8 & B 2@ 9© ©© © E© o© oO o@ “@ @ © © &© 6© »© 2© © »@ HG wi 2B °O © 2B -O© OO 0© 0G m@ oO 8© 1@ GO 8 W© VO WO w@ VO WO “© -©-@-@-@-@-8-© -©-@ 8 RR k 2 8 RB 8 8 8 °@ &© MO &© © #O oO o@ o® =© -® -© +B -O -@ -B OO © 2G HO |} oO -O oO oO HO oH HO HO HO HQ a © WO WO 5G © =O WO 1 VO oe © © 9 6@ 6@ WO nG Ona a “© -@-@-@-9-O@-O© +O -6 ~ “O-O-@-@-O-©-O-0-O-@ = eee eat 53 8 3 885 88 8 = 3| [0999000 0855555O00 055055555 53] - }~R29992990090990000805000008 |,|3 .|Floeoooeoe | = =} (0299999809 O99HHOOHOOOHHOHHOOS # /g500000000 | = F309 ©0000080080800000800008008) | Od/8é - N2090060009000080000000000000 | [>| OS55OSOOOS _ J 09090090 0000900000000888869 |,|-| loOOOeeo0 = £[_090000000000080000006000069 |fz}—~fooooooonoo| 3 2O9OO9OO09GO9HOHHOOOGHHOHOOG [3|eo| OOOOQOOOOG = “[QI0S9008900099008000000000064) [gu [2990000000] = Rosso soos Coco ST Tee Ree 5e[ l©o@0000000/ jm |_099909000008009906000008060) Fal lOo@OOOO0OO 1m | 02929909908008088000000908064 [Ele| lOO@OOOO0OG) = | AP ©90O0O0090999HH0OOO0HOHHOOG |®la| JOOOOOOOOG |_sOOO090O0000999OO000G990H0HG] | |<|jOOCOOOSOOe) |_40O000008008080000000008084 | |x| OO0OOOOO0O IRS oo 0009000099000000900068 ult] (0900900000) — 9000009899 098O00HH90800069) [Elz| [O00OOOOOOG| 4 0020000000008080000000000004) (8 Z| _(0900000000000000000000000060) [E gL (0e@0000ee009008000008000068) |*1F “| Cee0eoseadaeosaqoaeqqq08008 | f SEE INSTRUCTIONS ON SIDE 2