MATERIAL SAFETY DATASHEET

Conforms to regulation (EC) No. 1907/2006 (REACH), Annex II – Europe

Version: 11 June 2012 Tel: +31 (0)36 2000 300
1. Substance/preparation and company identification

Identification of the materials:

Cawiton® PR 712/1
This materials code is given on each minimal packaging size (bag or octabin).

Typical use of the materials:

The materials are suitable for producing plastic parts by injection moulding or extrusion

Identification of the manufacturer:

The materials have been produced by:

Wittenburg b.v.
Productieweg 12,
3899 AK Zeewolde,
The Netherlands
Phone: + 31 (0)36 2000 300

Emergency assistance:
24 hour emergency Assistance is available on the phone number: +31 (0)36 2000 300

2. Hazards identification

HMIS Hazard Class:

Health: 0
Flammability: 1
Physical Hazards: 0

Human Health Hazards:

Danger of burns while handling the hot product

Environmental Hazards:
None

Safety Hazards:
Electrostatic charges may be generated during handling. Risk of self-ignition of bulk products above certain
temperatures.

3. Composition/Information on ingredients

SUBSTANCES ARE NON HAZARDOUS AND NOT CLASSIFIED

Chemical nature: Thermoplastic elastomers based upon a styrene-ethylene-butylene-styrene triblockcopolymer

(SEBS). The materials may contain a mineral.

4. First-aid measures
MSDS Cawiton PR 712/1
Rubberfabriek Wittenburg BV www.info@wittenburgbv.nl ̸ www.wittenburgbv.nl
Productieweg 12, 3899 AK Zeewolde Tel: +31(0) 362000300/ Fax: +31(0) 362000301
The Netherlands Chamber of Commerce nr. 3200126

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 MATERIAL SAFETY DATASHEET
If inhaled:
After inhalation of decomposition products, remove the affected person to a source of fresh air and keep calm. Provide
medical aid.

On skin contact:
Areas affected by molten material should be quickly placed under running cold water. Burns caused by molten
material require hospital treatment.

On contact with eyes:

In case of contact with eyes, rinse immediately for at least 15 minutes with plenty of water. If irritation develops, seek
immediate medical attention.

On ingestion:
Rinse mouth and then drink plenty of water. If difficulties occur: Seek medical attention

Note to the physician:

Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.

5. Fire fighting measures

Suitable extinguishing media:

Dry extinguishing media, foam, carbon dioxide, water spray or fog, sand or earth may be used for small fires only.

Specific hazards:
The following substances/groups of substances may be released in case of fire: carbon dioxide, carbon monoxide,
styrene and traces of aliphatic and aromatic hydrocarbons including aldehydes and organic acids.

Special protective equipment:

Full protective clothing and self-contained breathing apparatus.

Further information:
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations

6. Accidental release measures

Personal precautions:
Avoid inhalation. Sources of ignition should be kept well clear.

Methods for cleaning up or taking up:

Sweep/shovel up. Avoid raising dust. Ensure adequate ventilation.

Additional information:
High risk of slipping in case of leakage/spillage of granulate.

7. Handling and storage

Handling:
Processing machines must be fitted with local ventilation.

Storage:
Protect against moisture. Avoid extreme heat (>60°C). Avoid all source of ignition: heat, sparks or open flame.
Specific use:

MSDS Cawiton PR 712/1

Rubberfabriek Wittenburg BV www.info@wittenburgbv.nl ̸ www.wittenburgbv.nl
Productieweg 12, 3899 AK Zeewolde Tel: +31(0) 362000300/ Fax: +31(0) 362000301
The Netherlands Chamber of Commerce nr. 3200126

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 MATERIAL SAFETY DATASHEET
Avoid dust formation. Dust can form an explosive mixture with air. Provide adequate ventilation. When the product is
ground (chopped), dust explosion regulations should be followed.
The process parameters must be set within the range as recommended in the technical datasheet.

8. Exposure controls and personal protection

Residual monomers
Residual monomers are not routinely measured. Analysis of representative products indicate that isoprene, styrene,
and 1,3-butadiene are not present at the detection limit of our instrumentation.

Ingredient agency value

Nuisance Dust OSHA-PEL 15 mg/m3
Respirable Dust OSHA-PEL 5 mg/m3

Personal protective equipment

Respiratory protection (only when dust has formed):
Breathing protection in case of dust. Particle filter Type P1 or FFP1 (low efficiency for solid particles e.g. EN143, 149).

Hand protection:
Use additional heat protection gloves when handling hot molten masses (e.g. of textile or leather).

Eye protection:
Safety glasses with side-shields (frame goggles) (EN 166)

Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical
protection suit (according to DIN-EN 465)

General safety and hygiene measures:

Avoid contact of molten material with skin. Avoid inhalation of dust/mists/vapours. Eye wash fountains and safety
showers must be easily accessible. Handle in accordance with good industrial hygiene and safety practice.

9. Physical and chemical Properties

Form : granules
Colour : translucent
Odour : odourless

Softening temperature : > 70°C

Density : approx. 900 kg/m3 (20°C, 1 bar)

Bulk density : 400 - 600 kg/m3 (20°C)
Solubility in water : insoluble

10. Stability and reactivity

Stability:
The material is stable under ambient conditions. It oxidises exothermically above ambient temperature.

Conditions to avoid:
Avoid extreme heat. Avoid all sources of ignition: heat, sparks or open flame.

Thermal decomposition:
MSDS Cawiton PR 712/1
Rubberfabriek Wittenburg BV www.info@wittenburgbv.nl ̸ www.wittenburgbv.nl
Productieweg 12, 3899 AK Zeewolde Tel: +31(0) 362000300/ Fax: +31(0) 362000301
The Netherlands Chamber of Commerce nr. 3200126

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 MATERIAL SAFETY DATASHEET
To avoid thermal decomposition, do not expose to temperatures above 270°C. See technical datasheet for appropriate
processing temperatures.

Substances to avoid:
Strong oxidizing agents and strong acids and strong base

Hazardous reactions:
The material is chemically stable.

Hazardous decomposition products:

The following substances/groups of substances may be released: carbon dioxide, carbon monoxide, styrene and
traces of aliphatic and aromatic hydrocarbons including aldehydes and organic acids. Monomers, oxides,
hydrocarbons, low molecular weight oligomers and/or gaseous/vapours products.

11. Toxicological information

If handled properly and in accordance with general occupational hygiene rules, the product
is unlikely to be harmful to health. There are no experimental data available for this product.

12. Ecological information

Basis for assessment

No ecotoxicological data has been generated for this product. The information below is based on raw material data
and/or on data of similar products.

Ecotoxicity
Persistence and degradability:
Assessment: No data available concerning biodegradation and elimination.

Bioaccumulation potential:
The product will not be readily bioavailable due to its consistency and insolubility in water.

Other ecotoxicological advice:

No data can be given due to the products insolubility in water

Acute toxicity –Fish

Expected to be practically non toxic, LC/EC/IC 50 > 1000 mg/l.

Acute Toxicity - Invertebrates

Expected to be practically non toxic, LC/EC/IC 50 > 1000 mg/L

Acute Toxicity - Algae

Expected to be practically non toxic, LC/EC/IC 50 > 1000 mg/L

Acute Toxicity - Bacteria

Expected to be practically non toxic, LC/EC/IC 50 > 1000 mg/L

Sewage Treatment
Expected to be practically non toxic, LC/EC/IC 50 > 1000 mg/L

13. Disposal considerations

Product Disposal:
MSDS Cawiton PR 712/1
Rubberfabriek Wittenburg BV www.info@wittenburgbv.nl ̸ www.wittenburgbv.nl
Productieweg 12, 3899 AK Zeewolde Tel: +31(0) 362000300/ Fax: +31(0) 362000301
The Netherlands Chamber of Commerce nr. 3200126

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 MATERIAL SAFETY DATASHEET
Recover or recycle if possible, otherwise; incinerate or use a licensed landfill.

Container Disposal:
Remove all packaging for recovery or disposal.

Local Legislation:
Consult local, state, federal, international or country specific regulations as appropriate.

14. Transport information

Statutory transport regulations

The product is not classified as hazardous under international transport law

15. Regulatory information

EU labelling regulations 1272/2008/EC (CLP)

This document is compliant with the Globally Harmonized System (GHS) for the classification, labelling, and
packaging (CLP) of substances and mixtures.

EU Regulation (EC) 1907/2006 REACH

Polymers are exempted from registration and evaluation. Therefore, Wittenburg products are exempted by regulation.
Annex V exempts from registration additives used in our polymers as antioxidants, defoaming agents, stabilisers, etc.,
and exempts substances that are naturally occurring that have not been chemically modified, Article 2(7)(b).

EU Directive 2011/65/EC, amending 2002/95/EC Restrictions of Hazardous Substances (RoHS) in electrical and
electronic equipment Restricted substances: Lead, Mercury, Cadmium, Hexavalent Chromium, PBB and PBDE
Not regulated.

EU Directive 94/62/EC as amended by 2004/12/EC (Packaging and packaging waste)

Not regulated. The product meets the requirement for the total amount of cadmium, chromium, lead and mercury to be
less than 100 parts per million.

16. Other information

In addition to the information given in the safety data sheet we refer to the products specific ‘Technical
Datasheet’.

Disclaimer
The information contained herein is based on the present state of our knowledge and does not therefore guarantee
certain properties. Recipients of our product must take responsibility for observing existing laws and regulations.

The information given in the Material Safety Data Sheet only applies to the described product in connection
with its appropriate use. All information is based on the latest state of our knowledge. In particular, it
describes our product under the aspect of possible hazards and pertaining safety measures. The information
does not constitute any guarantee of specific product and/or quality properties. The information given in this
Material Safety Data Sheet is not required according to article 31 and Annex II of Regulation (EC) No.
1907/2006. It merely serves the purpose of providing sufficient information on a voluntary basis to ensure
safe use of the compound/product. There is no obligation on the part of Wittenburg B.V. to revise this document.

MSDS Cawiton PR 712/1

Rubberfabriek Wittenburg BV www.info@wittenburgbv.nl ̸ www.wittenburgbv.nl
Productieweg 12, 3899 AK Zeewolde Tel: +31(0) 362000300/ Fax: +31(0) 362000301
The Netherlands Chamber of Commerce nr. 3200126

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