Salute. ds RO- 7 Ca-7) (Bolle 3-6 WA redtctle cra in Me. frdcal ditedige. , Weare As eokbcy in Ans preblil A erchs a qed Ya aheilin oadel” or Geedbie dtfdlion. buliceri, Cheese os a cordesl ack & Cylindecal shill of Netenuss br jas shown bile’, FeO-x) ae This shell Contens AW. poonts of etelysh 5 Tala amwleriet belonce on heed A over dae “Carte volumes Gy = maler Sad che EN Aa cracker : FQACWEARRACK OGr RAN Gerccbin RA Kecocaletinn = 6 RAL A Accomstthise® © Certo, sta} beh A Te = Hy Cex) Rae A Owl = Le Cl-x- doc) RACK Gaentan = dw Mare OY = td doceerra el A dick i chantenl ceackion Cus AP lb ok.) {ind7 TfexpheeVroblen 3-2 vee Cot onstect Ore HE NG. ce RT CTE Gy JC) pease — SEQ dG *kGlamor = 7 CEG)? P OT marinade \y. Table £ velves < Ts ‘Aty OSE 92a) 750 ORG) 0.75) Kn 0.27 (KCa(K) 0 CRp/ kee) 7.01 Ba 0. 2% (ka /K,) 00 (ERMC) 7.35/ Rp 0. 277(KG/K) KOS (Balle) A 80f Kp 0.270 (KCK) 27 (En/ ee) Pist C'/-m,) Versu3 Gt over the ob wve. foee See nett pase v aT aa » esign Egan. (liquid plaase > Constert dens t cae Mt ve is Ve Glee |) Gro 7 Go-G lex) Be = Cp leer) © =n Cextt) \ ete fue oss hatched ores (nod gage Vigan = Sten & LSW cross bere es (ned 7)Ny < 5 e a a (KC IK.) . Ovt\ + Concentration of A (C,*K,) xr ee Cencectrotian Cancertrakion Ww PER (alews) Cp Coed) Eee aes ICn a>Ve- AC, Fas Che GS oa Ge Peat Ae vader Cutve Vetwun inlel one! outed concetnctinns Chase PRR, Require Value &T is Newer Soe PRO then Mer CsteParte Inverse of Rate of Disappearance of A Concentration of A (C,*K,) Ostet TAY Concentra on Concectrcthen cnnesi zara oh rectangle. Vere Oren under Curve = Sus & thao cross -hetced orcas ccc a S om 1 / Chere CSTR. Vera * orta|Yooblenn 3-3 @) General Material Balance Conte renchor: a =H4G= SMe. f : ae ace wea) a eye GP CHING, we ayatiel rod acts: .) AG et COG) = Ven Ee BQ OE, N@= Var + oe eee Ila _ tr, 4 2 Gog) » Cu? Cre A.tart) 2 eto Vege Ey yak on = Tel) Semi- Belch Reectem Ie¢ =o Kurttoles dh C8ACES Aphex ater Nee A, B Wwe concede on Conbe wre thea in {X ae CA VS shot Kio nckr Nason Ta 7 Tatal Meorcr beet Recee ~ Fed — Reoeked Pras) = Ba ed) =Car + eG) Gh." Ts \{ BV ctard Cae Mets cn@ No Car Bor Sire Ge Hea) «(oar ho) b) be a equetiun\s suetic! wk ‘f feacker is iscthermal. (Ove, depts sk yorieble CGy)) TES cenckor vs ast iacthermel, WwW also ned an eng Volonce COnayter &) | { TH mare Then 4 feack: sn dolkes ol So will need additional materiel balances canes)Beton ecder Ctachion: —Gelk CQ>0) -G =O CCrso) Cn a lw Ceackion~ need te turn Peaction of nea lees ded ee 2 cose treo Ca os 0-50 di 5 ._—_—— \so> Ka Tris arcs “Giqro.se) poe — 6K Both PEQ and CSTR Pequice Ye same V Gr Sams Fo Vor y= 1, Pequited V/ Fro = ‘ke Dowling the Side of the Teactor 50 trot Ve has We affect) % ste & LoD : tH ha, CN is lah 7 a ye Oe =o nom) 4 Ceackwt “ORIN OY Naw oOweed 4s Versa how VG) Varies wits M we \ ~ GOK NOg|0) Teeblenn 3-6 So,* AWS PIs + ato rool [Faas 4S : oe) We askd Pa bicken “Vs ase°c a wrole H,3,0 1000 A Sons /N = (A/757 nD lan Eqn. CH chemgencous) 2 Des Eq CH 3 ) * oe 2 7H som Fas )/ Figs o F, 2 HS,0 Ts Ete b. cE -F ole —O se ( , C/b00-v15 X= ) ( Co tinued — nevet i )0) Siiclromckre Table Rass: lege roots HS i} = exter of reaction ‘Dyecies : WK oe — is és ) 4,3 7ooo s000-2¥ Croso- a $5250" 2F) to, Soo Sb0-¥ (Se0-$/saseras ) N, 37500 3750 S750 (5050423 ) S ° 3s I5/l saso+2$) Ho ° ag AE/G250428) Sasa Fase as a B= Ky WA, roma) Rasome idee! qom te Goto presser) e v 7 s low: zz SS Scene , CR /ex ) CPfery=u S/sa0 le o.oras (SEE )=o.0ase(%*) Spee: es Ne Cr Case AL) hs 0.0/9? £ebxio? So, a, 007 Do Kre”% > oarg 57.3 xro% H,0 Onley 36.7 xo? Ny 9.64 256 xo” 0.97797 QSSK/O’ (mle A) ©)©) °) Solution fo Problems 3-7 W=/o win verve FOaS a DEPvC Kpernct 7% O07 rarrrsles Pack \ he “ a Wypthess -Gesse™ KL0EDCY Ke road? Use ena ieee ato calculate cote Ge ee, Coleslare ce Coperrc). Thea use these, Cakes /ConesAmtiaes tp dalolabe Wi lkc eae uctton: | 4 >| i Fir Pe (0 win) Groat co 203 lmmles /L)x0.a7/, = Banyo? (es eae 10¢pean)~ iia ZS Qa G, Com) = 0.20 C-8.a/) = Q2.A37 (ER) se Conskat a Fac We Po min, Xe 0. 472 -(L= OB KOVY {30 = yee (ete min Cr = 0:30 0.97) = 0. FP (mrs /L\ce - n ) —{evete) 6 2x07 — eee wy See = 43) 2397 Se hoy -GUM30 KA YK/oF O88 Toke ae \ \ks 63x70 (SA. pn \/o.aa7 CO Ke 266 x70 Fain! len Hrepa mas le wain) 0, ARCHES | = 26a%d? mic! Por S 2 0) Ae ree yee fe a \Kot!) _ Re ae tr.) Renn = Sei i \tasre) cei . 13a, 000Chede) —\ \«C7e'c ) B.3/9 (Shae) aS THT = exe ¢ 1.9397 ) \Wles°)/ lc (70%) = 6.957 \eCaste) = 260? (mit! 6.957 klaste)= /Bowe ein )Problen 3-7 g ) Ty Design Eq Sqm x dt X Cine outlet conversion) oe should werecase os W ae = LN Increases 2) Tt mos be that te reachon hes reached Cant b se naeie — ? anes sh et tq oll. Mo - wit Weve m -GaAcA a aoa osction of So lacceasi ae brignas cake CH = Oo aa er +h a) Etnyl benz Veen) Styrene G) From” Handbo dc oF Chun sh "= 398 \«q ‘ Specie Se eS q Sf = ae ake — Heal Jace EB B32) ZIm — FObF eK col Jrale Ss: TAD FS.22 271E My ° ° 6.39 AGS (a98) = ZY, 2G. = 79.29 \eal frsle In ig Cave = -aGe (29d) /ROPP) ‘4 = “9 Pro Yo W/i #7 (OM te) 290 («) = -33.59 AH, (ave)= ZY, alg = 28. / keel Juste dau : sr) ZY cp =F 3P cal /mdei 2H OT) = atiicove + Vo vy, dT ae * SHR CT) = 26, se0t S.3FT “4h = SAT) Cagsoots 38 T] rr yr ary eT Fegan Yooke _=24, 50°07 \ Ba (673\«\ - aia) aoa [os an + 22. (423) = RV. PVA QAI=QT IS zm 98 \nagle73 \=33.59 + aZss-= -6.4¥ Te. e73)2 4x57 Assume KE, abe —ewuil Conrtat bused oP Calevlebe equrlibrun Conesion ab 673K = Pstu 7 3 Ky — L.E%/0 ohn, Let Key = equil. Conversion o& EB vaste chien eS Ka Geoohad Equil. Gls) Q Ss \ \la% 4 To xeg VG) H © MS vay / Been Toth \ : acre) la Me \PRO a/ Kee _ P Xa BC1-Xeq (14 %eq) Vax ‘as PY Er/)) 5 Pe late. a “3 a -3 %eq = 1b YL gxcd )® ZEKE Key = 0.07 Eq thbe | ao Vs ay v%\, Muck lower m Coco in CMerenee. A “a ; Caleglato shous Pet feackian Could eosc\ ove. sk o ed short c& Complete Convers: Bel beca vse iT Chemical quill bees Was Cracked. 3) Ve ceackian wow becomes = ae EB+ FO, > S+ ho The. as sqpilibrt eae dus Cemckron TS mela more Kavorable. CTH aere thrive of Raw. 4 _ driven to th anes bub the Conversion of I, inte Hy oO: |= 0.054/ oe solv a ye An exekucts ell Rens) Gack 0.653%/0 "wof/tain — 4.933 «08 T m/min Sgeeies! Te Ot Warp CT) & &- 4 a ) ene Pyne Bee 8 ene se ! hyS ° < eS cep) ° = Fer -Ve-F = O.07”F L * = t= =/3 = 0.7 <. ©.0s7/ a 3) a a aa e iG B= ¥-0.7€ Ver oor7e= St ____.. 4 Terrace FB SSPE RIO" AE -O7FAE, 00078 = 0. 7b E /(S, SPéx0"—2.7922, )=k 0. = e 9.91% 2.0470 © } are F . F GP 4 «00 Ly 097 = 0, B3TKD Yona ae a= Oo AS AKO min es y Eqn cesta hdteagerense Ceackion ) Wo ces se BE te tee ea) Fr - e -6 Bieriectirnnmorg Mr teettveaines ves a Ww W B18 rain ay cer Poctiol Pressures : Vo evi > 83mm) 4% zt Ww —o.anrnxe 7 De vb ub” Sgesies Mi fi Cormda) ae Fy -% /Z Go.068) Sb.7 HL Fy 36-2 /D (0.798) bse GE F-¥ /z (-0.0/78) 2 Cy BR/Z (= 0.05% ) ¥S0 WS a /Z (= 0.07/2) 59.8 PBX -¥ “7 For “AE ~ EAS SBbxr0 — Ax 0. 3378Veoblen. 3-/o a) : ee -tafkes KIM) LEMMA, 2] Shoicwiomdre Veblet Seectes Ew Cx a erase, E lest) Eo €,c-x) nots Eo E,Q-%) a Wo AR laid) co EX Blaledad ) = EX Tre voher of x «, ond EQ are kawe Subotive Noles of Kb, hele volus of-fe . Bee Qa sing seceadslheck. AA a) yA he ok ‘PCs vysus Ke te gwen tA Th atte 4 5 3\ We smellest total Coactor Volume. cecurs When WESTH and ATER ore used iQ Sertes. Te CSTR comes Gest, and is designed he ooectte ct tre velue of KE HH ohich Ce a minions Cca. Ke 0. SoTL PER Gtous te CSTR The second Nagce ashenss The a eal Sroka oR Anis combination,Rate of Ester Hydrolysis ceo xE 0 O.1 0.2 0.3 0.4 0.5 0.6 0.7 k 0.01 0.03 0.05 0.07 0.09 O11 0.13 0.15 1.0 mole/L. [CEO*(1-x)]42 1 0.81 0.64 0.49 0.36 0.25 0.16 0.09 (KO + k1*CEO*xE) (L/mole-h) 0.01 L/mole-h 0.2 LA2/mole*2-h -1E = K*CEO*2*(1-xE)42 oe 0.01 0.0243 0.032 0.0343 0.0324 0.0275 0.0208 0.0135 a/-re 100 41.1522634 31.25 29.154519 30.8641975 36.3636364 48.0769231 74.0740741gO v0 £0 00°0r 00°09 00°08 o°00L o0clMA] 72 NY ad ot rere z Lu A) New BlS>D peti 000°0 00°02 00°0r 00°09 00°08 o°00r oOdL ahFroblem, 3-77 a) a a Coot) Coen) po) b) CSTR? Consk. Nope no - Ge) WG.Cst) “y Fe ~Glewt) ~ -G 1G, Cow's) Fre: Gos) NGe a AC, Ete SO Cp Cot) Choose since CSTR CT cross mal be shaded oreo obsvel\. PER cequires! Wigher TW Crore Wine Sar Fate Cae, Mao.