(Problem 2-J \ Salven be Preble ae fo) Wn Ane acd poche sf ccechi wy ts Bere bey Wher tne fades of the Goewerd and feve Ceadians are equal ia 7 7 ae vee of He ence en dxeressian Stor thal ned reactien tole mosh coluen Ae te. Rew tu eq Oi \ertin onesies C The eguchbbrr ancomastin is We @ okt on ted wou: eal. rds Cee Ow case of chuwesl Peay RECS With rs Yo hentel Kader | Mere’ i () 20, = Fo, Lets vie tais sherchiomchere equctien as pur lab Sh wat .'We con vette “base care, and & pote Qeavelited theruronathete Guetan as ws 2 nV Ke =e Cn do) = Kreg j Rat 82 Att 487 Eqvilierion Yor \decl ge Exprusion Vv: AY eqailit Cam)CS a b Reena is K\ Pos ~\3 Pe Po 8 ° 3 q Pot fon 3 Age Ad (2) [ tes 7" mm Copace Awe te te ego thierion meres “wks ) ny wn 2) (x, ) [ fs. Po, Tx rie Sor the lend c teenies he be canststest wite eperieni ee expresses an ele @) -Qn =F AL @) a Coren Ger Sos = ee Ceackion AY oa - To, =o is +3 Go, —Ka fog 7° 3 Leradic wquctie, Celues to ° all (=) = feeb ele Loree of ‘ss ee . V 2 Men. equal bpiva— eee Lt Vested pra cali, Const sted }wz Yn BS) =b => be = t Bquctons Ca Ga) -a Ch) a-> oF Para Gr Course reacksn t S— Cis Mai Po, Pos, a TPs “fos 5 Credeiny Weereatynirmne wate : » /. Ke Pas — Ke fas Pes Ze tk fost %, Se \k is Tris is also on i = Pox accep. Gorn of Pe. Soe myer ee eee. o= Reasatts Cron wetting Hee 4 Cade. os: 2 os ned be 6 paar =e j (a ‘GS Pes Fox —_ : fot fos)& \ 6 : | “) _ ts Ole 5 gees edn \ iz a Pes” oe eo.) az fs ey bel; = % o ce lize -Cy ‘3 Pos fou 7 pe, + Kay) Sy eyo) VWeei un, OK gees wrt “| To. | VS nae oS = °(ella HL) Sawtienr ts Table. K-37 Gage a, *3) fC eee 70 0-5— ° -Kelkk Qo = Re QS Condction % ae “Hd Ow EEG Toes -Ga) Kai Geo fac iG dl -£(4-4 \ Vere -C.Q) -e RD OT (ee) Gl) Tere MOVIN Geer) = 90,002 Thue) (is lie) A —"n.Q) LEY (Thee) AF 573 c )] 2S ee ae FAG) : ATi 2b y be Rr(epermre) ao 72 Vas 2 2) ae a ssNo. 867) ye«3K, —= CA HEEEHEeE ae Sites _s) \«, eed cial EA cea en ws ere eee Cesous xk a! ORS CY bone, & _chees ae AEN Ane onker wan est AFable a7 1 4 Delvb. de a3 Coophea #7) cael rf aaa _ _ __* fe une a . Eck. eee este bbs ps) aeEeRate Constant,k (LA2/molec’2,s) Problem K2-4 Arrhenius Plot for NO Reduction 1000 T 7 T T | — y = 7.0828e+11 * e*(-23028x) R= 0.9941 100 E al c I 10 q e R*23,02! 00831 4(kJ/mole,K)*23,028(K) 91 kJ/mole 4 eee eae ge pe pe eee eee 0.00090 0.00095 0.00100 0.00105 0.00110 0.00115 Inverse Temperature, K7 Sa’ yy (ta TA)ae a-é6(Ke-s) BY equi liter: wen y nu 8 ee ll (ts i ee /~ 3 Pa. K = _ Pun, ye \ (& \- eee, i Reghaaite ta, oe _ : oN + nH, Aan Nig a) apilthew Expresstin: ay _ [Nw eo) hfe Eqaitibeo A, pressive Lee net gees orasts en G1: a . Nu, > ah aire | Nn > Kel yap Sara 8) aa ovemne apc amg ra Ohare peta Coe aah ere (+6 )= 1 Nas, ky /by, Uke kr) = Binn) oMolla ae eer noesntin Theatre Ente and K, ef ore eee eeu Te A a Bia, tee Unite oP ond =. _ (MPN Numerator, The vette ob Wenge wast be psles / vest 5 s ‘egies he Hac uta ot mo zi Hae A) a ten ee © CMRAY® the vats & Kore 7 fees MPe=).” i ® denominctbor is chimensionlas.MEHL auoep Rack 1: ‘ ey Wace wD inary Collisions = y oD OLN) A /d,) Nx /Na, = hg ag LW Cav SiN) 2. = o¢ Uigat) Gn ae a AE Lew ker Nay Zachalasy (= ae ) C) Colelebions done in otfached Spreadsheet Bint! )=2(0-n, 9 26-0, )*2N-N,) Zersrr) = 6. paxse*Caisns£ od) | Pat 2: Since the progertivs of © end Ny ore ver lar, — tlle eae eee a Epitan nt Aw eee Wat ls ee ane fis 0). GN AGS let ‘AN Cy =o. . 40.77 ON TerEwe oe nye O27 MQ O77 = %77%x00 ia nals. NL ) Ase Egat abeve Th cinasboston) Ca, isS %) eo oe ok crt a vit che, Bool. Se eee ee A Bose) Fa. 1 (R= Be Jose) Gia o6 ero A Jer Caledakion Bgp daar ix Kilo: € spcodshull | Cal Vstons wllistes/ 3 >. Z pp = 6.2) XO ( Nerr Crose !Problem 2-8 Part 1 t 300 K kB 1.38E-16 g-cm*2/s*2-mol-K R 82.1 cm*3-atm/mol-K NA 6.02E+23 molec/mol P 1 atm r(O2) 1.50E-08 cm r(N2) 1.60E-08 cm m(02) 5.32E-23 g/molec m(N2) = 4.65E-23 g/molec (02) 8.52619E-06 mol/cm*3 C(N2) 3.20747E-05 mol/em*3 alpha = {[811(kB)T]*0.5}*NA*2 alpha = 3.70E+41 (g0.5)(cm)(molec®3/2)/(s)(mol*2) Z(02-N2) 1.95E+28 — collisions/s-cm*3 Z(02-02) 2.35E+27 —collisions/s-cm*3 Z(N2-N2) 4.04E+28 — collisions/s-cm*3 Z(total) = 6.22E+28 _collisions/s-cm*3 6.22E+34 _collisions/s-m3 1.58E-08 cm 4796-23 g/molec 4.06009E-05 mol/em*3 6.21E+28 collisions/s-cm*3 VERY CLOSE TO Z(total) FROM PART 1! 6.21E+34 — collisions/s-m*3Yealolenn 2-9 Tre concentration & B does uct ogee Wwe fale. equabion. Trere ce, the order & Hd tenchion. with speck Xe Bis 3}. ao ot, EKG. akQ cyFecblem 27/0, M constadtT, K and IK, are contact ZT lmend= kCg AKAFeeblen. 2-i Pp A oo _ =o _ (Ne of <= Ke CG. Gocwerd Feaction, & spiboons, ec Kae * / Gc. oO Rate equations most red vce. to fas Priore expesston Whenleeadkion feadaes equilib bony hes, HC CGrwerd = Cy Creverse)= fh Cred) =O h& 4 \Wrian = Cp BRerword ) = Ty Crewerse ) 0) - BERGE = Keele Kee \= Yog ce Nek onsistteckd vitnthemo. Does nit feduce bo Eg. t Co doss rapper ne saphesnton Ge Qe /K-S. MERE Ce PMY, 2 Ce Hc? Net ontate wrtitiens, Gant be reduced te Eqn. 4 — gor of baw aides (ave ry)ce) Kh QGe kee (Melee\= e/g OK, Con aa equ bbc Se plesmion (Ear 4) _ vere! Cost SF loth sides. Qed = eee (Ke fie}= SEO /24 Noh consisted, Boesch cedyee te ba 4. Miceouer, Cannste Wave Tcettolust A COS in tan equ hberuas j Festian. Equilibetuay positinn ae aot ee om cohcertrchion aed e cele )= CIRG OHRGy Nok consisted with thermo. Cann bee Cedveed “ho Eqn. 4 by teleng O power of bela Shes. eiYeoblens 2-/2 TE A reaction Is In equilibriva ~) Ky = test /toewtt es in / rin) (venson ‘peNBene, ee Le NV be the ceaettor Volume. tes |= toys wreles Loes]= Ny, NN Teles, 7 _ (es sf) 7 Ws Ne DA ee A \lelies Keo Problens \= Us * OM ssvi9) FasFeblew 2-73 Krrhenius telobiashis : Ve Kexe -E/Rr ) Ince IAA - (F/er ) Te feck wht de Archenvs Celabrabkie ts obeyed plot lated vers Ar), Te cetdhiosity ys obud! shaald qk ao shrkt ba Slope will! ve cevay, OS x t Sen. Sothsnaen oa eked stica lds line, aldn ons doles ec tse bit Wighk. Atrkenis clabobhip obs tdasonabt, welt. & / Shee sE/R=- 5770 (R= 9.3/7 fide) Ee PROMI AdeODL 2€00'0 9¢00'0 g€00°0 yE00'°0 €£00°0 T eT Pat T J ire BYe8EO=H (Xr Z96S-)ve . O+8Z801°} = A—— L 1 2£00'°0 000" 00°01 0-001 y Jueysuog eyey I