Sistema metanol - agua

T °C T ºK x CLA MWA CLB MWB CL . Mwprom D Hs HL KJ/Kmol y CLA MWA CLB MWB l A MWA lB MWB
100.0 373.15 0.00 92.27514 75.44551 75.44551 0.00 4347.9250 0.000 92.27514 75.44551 32442.6409 40799.2135
96.4 369.55 0.02 91.76757 75.42013 75.74708 -110.31 3982.3040 0.134 91.76757 75.42013 32748.4521 40966.6520
93.5 366.65 0.04 91.36311 75.40069 76.03919 -209.70 3678.1821 0.230 91.36311 75.40069 32991.2832 41099.8456
91.2 364.35 0.06 91.04513 75.38594 76.32549 -296.56 3430.4144 0.304 91.04513 75.38594 33181.7150 41204.4307
89.3 362.45 0.08 90.78433 75.37420 76.60701 -371.86 3223.3032 0.365 90.78433 75.37420 33337.6254 41290.1359
87.7 360.85 0.10 90.56602 75.36464 76.88478 -436.56 3048.6231 0.418 90.56602 75.36464 33467.9546 41361.8294
84.4 357.55 0.15 90.11955 75.34586 77.56192 -557.82 2702.1069 0.517 90.11955 75.34586 33734.0429 41508.3327
81.7 354.85 0.20 89.75805 75.33148 78.21679 -631.61 2444.6610 0.579 89.75805 75.33148 33949.1029 41626.8533
78.0 351.15 0.30 89.26822 75.31323 79.49972 -681.09 2151.4828 0.665 89.26822 75.31323 34240.0714 41787.3425
75.3 348.45 0.40 88.91482 75.30101 80.74653 -655.32 2003.6658 0.729 88.91482 75.30101 34449.7517 41903.0756
73.1 346.25 0.50 88.62940 75.29176 81.96058 -595.29 1923.3590 0.779 88.62940 75.29176 34618.9971 41996.5306
71.2 344.35 0.60 88.38472 75.28430 83.14455 -516.32 1880.7411 0.825 88.38472 75.28430 34764.0295 42076.6390
69.3 342.45 0.70 88.14174 75.27732 84.28242 -416.16 1853.5658 0.870 88.14174 75.27732 34908.0310 42156.1957
67.6 340.75 0.80 87.92577 75.27151 85.39492 -287.76 1866.7522 0.915 87.92577 75.27151 35036.0159 42226.9156
66.0 339.15 0.90 87.72374 75.26641 86.47801 -136.54 1906.9345 0.958 87.72374 75.26641 35155.7438 42293.0809
65.0 338.15 0.95 87.59808 75.26341 86.98135 -62.76 1905.6233 0.979 87.59808 75.26341 35230.2199 42334.2416
64.5 337.65 1.00 87.53543 75.26196 87.53543 0.00 1937.1591 1.000 87.53543 75.26196 35267.3568 42354.7668

CLi . Mwi = (C1 + C2 . T + C3 . T2 + C4 . T3 + C5 . T4)/1000 kJ/kmol -º K C2 + C3 . Tr + C4 . Tr2

T = ºK li . Mwi = C1 (1 - Tr ) /1000 kJ/kmol

C1 C2 C3 C4 C5 C1 C2 C3 C4 Tc °K
Metanol 1.0580E+05 -3.6223E+02 9.3790E-01 0.0000E+00 0.0000E+00 Metanol 5.2390E+07 0.3682 0 0 512.64
Agua 2.7637E+05 -2.0901E+03 8.1250E+00 -1.4116E-02 9.3701E-06 Agua 5.2053E+07 0.3199 -0.212 0.25795 647.13

DHs = -6348.6164 x6 + 10345.5832 x5 + 5571.5608 x4 - 21789.6758 x3 + 18218.6411 x2 - 6002.3764 x + 2.6229 KJ/Kmol mezcla

DHs = A -6348.6164 MwA = 32.042 kg / k mol

B 10345.5832 MwB = 18.016 kg / k mol
C 5571.5608
D -21789.6758 to = 42.37 °C
E 18218.6411 to = 315.52 °K
F -6002.3764
G 2.6229
 Sistema metanol - agua

HV KJ/Kmol T °C x HL BTU/lbmol y HV BTU/lbmol

45147.1385 100.0 0.00 1870.5234 0.000 19422.7775
44058.7185 96.4 0.02 1713.2294 0.134 18954.5277
43277.8301 93.5 0.04 1582.3929 0.230 18618.5812
42679.0706 91.2 0.06 1475.8007 0.304 18360.9886
42188.7478 89.3 0.08 1386.6992 0.365 18150.0465
41766.5036 87.7 0.10 1311.5500 0.418 17968.3926
40976.8364 84.4 0.15 1162.4750 0.517 17628.6694
40472.7457 81.7 0.20 1051.7191 0.579 17411.8042
39782.4663 78.0 0.30 925.5907 0.665 17114.8387
39276.0775 75.3 0.40 861.9983 0.729 16896.9849
38882.4332 73.1 0.50 827.4494 0.779 16727.6349
38525.7728 71.2 0.60 809.1148 0.825 16574.1958
38178.9124 69.3 0.70 797.4236 0.870 16424.9728
37838.4719 67.6 0.80 803.0966 0.915 16278.5117
37516.0606 66.0 0.90 820.3835 0.958 16139.8069
37355.8871 65.0 0.95 819.8193 0.979 16070.8986
37204.5159 64.5 1.00 833.3864 1.000 16005.7771