1 2)-PCM (Sol, JEE(Advanced)/20 FIITIEE JEE(Advanced)-2020 ANSWERS, HINTS & SOLUTIONS FULL TEST -1 PAPER-2 GN | Pavsics |[/6.Nor | “cHemistny | @.No. |) WatHewanies) re era ca (erate | eaca nie sr 48.0 ial eecoes oa cD 28 ABD Fine he AB 20 ABD | ana lies Bc Pr ac 5. AC 23. A,B,C,D 41. BC 6. B 24, ABC 42. BC 7. B,C,D 25, A,B,C,D 43. cD a7 ageoins |arg eaccwe lea ABCD 3 male, 8 i 8 cata aoe (ieee D «6. A fp oes D a D eae eae e e 8 13. 00004.44 31. 02390.00 49. 00003.00 14. 00000.50 32. 00113.00 50. 00006.00 15. 00004,00 33. 00224.53 51. 00003.00 16. 00000.04 34, 00121.95 52. 00006.00 18. 00006.25 36. 15688.00 ‘5A. a | 00005.00 Tite Lid, PTIRD Hewes, 1 Hal Saray, Servopriga Whar New Deh 110070, Pr 106000, 265 Tteteter meen comRIPF-FTA (Paper-2)-PCM (Sol) JEE(Advancedy20 Physics PART-1 4, Ac Sol. Since, sum and difference of physical quantities having different dimensions, are not meaningful. Sol. Sol. Sol So, (P - Q)and(R + Q)wil not be valid in(b, d),[PQ) possible. RR, is possible In (6), [PR] = [Qs cD Time taken by the ray Ato travel through the glass, t, = [d=1mmandy, velocity of light in glass =c /] LOm1Op ei Seariolern ain sea-t5-(8-!2) 0 For ray By ty = 2x10 a ‘The frequency of the light (oscilation per second) does not change inside the glass. t > t = ray A will make more oscillations. 1, = Number of oscillations for ray A= vt; Similarly, ng =Number of oscillations for ray B = vt, anzay—m =a -ta)=( 2a) 3x10 (5 >) = SH (2x10 500010" a(§ 000 ac Flux linked with loop due to its own magnetic field, borel ola? Seal emf induced Now, 10"%Ip = Ipe | 3x? Inl0. which gives * 10" AB At point A, potential energy of the ball At point B. potential energy of the ball ‘At point C, potential energy of the ball = mgh Total energy at point A,B, = Ky +mgh, Total energy at point B, Es, = Ka "atic Led, PUTIRE House 70:5 alu Sara, Sareapria Whar New Deh 110 teehee! egencon "Pe 46106000, 26560405, Pax 26519062RTPF. per-2)-POM (Sol) JEE(Advanced)20 Total energy at point C,E. = Ke +mghg According to the law of conservation of energy, E, Ey =Bo = hy > hoje > Ky tiv) Option (b) is correct. From eqns.(),(W) and (iv).we get ly >he;Kp > Ke ‘Option (a) is correct. Se Kx, | For ea. of Piston = Kxp + PaS+mg=PaS work done: Fao? +mgxy +PaSxy This equals to Decrease in intemal energy. mg BS ee) Sol. Let q be the instantaneous charge on the capacitor when a steady current I lows through the circuit. Appling KVL on the circuit, we have + 1R(: c= A) i) Differentiating eqn. (i) with respect to time, we get = ( ox), Tx rq -&($)4eo (eaelt) Ix ax ‘ orq= $= vetocity \.. awe ct) From eqn (i) substituting the value of q in eqn (J). we hav ts somasyan™ xX From eqn (i) and (v), we get testes) 20B,C,D Let dV be the volume flowing per second through the cylindrical shell of thickness dr then, 2-1-2) 2-2 le ect R%v5 Let, dK be the kinetic energy, within the above cylindrical shell. Then aK = Hlamy? Flearepy*ar ® = mlpv3| 1-22 42 lar z Hence, kinetic energy ofthe fd, + og wear Elena eee in pvG i none) Hence frictional force is the shearing force on the tube, exerted by the fluid, which onuns-n8 where iste uae een ote 2 Given, v=vo| 1-2 vf J) “and atr =, a Then, viscous force is given by, av ar = -wexra( 2) = aera 2a) Arnlvo R Taking a cyindrcal shell of thickness dr and radusr Viscous fore, F = -n(2nrl) Let, AP be the pressure diference, the net force onthe element = APxr? + 2enle$* But, since the flow is steady, Fey = 0 r) anion ar R? (We Led, HITUBE House, 28.4, Ral Surat, aureapriga har, New Delt 110016, Ph 40108000, 20705408, Fax 20513042 Seber ceaseRIF-FT- (Paper-2)-PCM (Sol,}JEE(Advanced/20 es BD. Sol. Taking a ring element its current is at = 2 anno = o(A~BryrieB ° 9. A 10. D Sol. {for $-10), After calculating total time of fight (0—+C) Koos sina 2Yo sinB fou = 72AS2, Rebound velocty at A—+ (esi) cette i Vea To at vn gin) YACDABD _ COB) omy (qsina) ~ (sina) dip Zhe Al Sol, (for 11-12). use I" law of thermodynamics and apply for different given process. 13, 4.444 Sol. Since no current is flowing through galvanometer foie OEE Cal) 045° 045-9 14. 08 Sol. Here C+ and G2 are the centres of the rollers. OC: Is the perpendicular difference between the height of centres of cylindrical roller the ground (UME Lt, FTW Hews, 244 ali Gara, Sareaoriya Vihar, New Dei-110016, Ph 46106000 26500409, Fax 6819042 iebote oe ijeccomRTPF-FT+ (Paper-2}-PCM (Sol) JEE(Advanced)/20 15. Sol. ce=Rer=2 D8) Let Ni be the normal reaction between the two rollers and Ne between the smaller cylinder and the horizontal plane. The larger cylinder can be pulled over the smaller one provided the latter neither rolls nor slides. There will be no rolling provided the sum of the moments of forces about Cris zero UN, = uNadsN, = Na There will be no sliding provided the sum of resolved parts of the forces in horizontal direction is zero IAN, + uN, c08(90 a) = N, coset BN, +HN, sina =N,cosa (As_N, =Nz) cosa, 1+sina es) =/2 (usingegns (and i) w/e cans! Hence the necessary condition is that Acie (oie 4 Here A and B are two identical balls suspended at point © as shown in figure 2 Teine = aa 3; 4) Teosd = mg From eqn. (i) and (ij), tan6 = z a a (Since for smatto = 2/2) 4nejamg L ete ii) 1 Droome ‘When one of the balls is discharged, the balls come closer and touch each other and again separate due to repulsion. The charge on each ball after touching each other is 4/2. Replacing q with q/2 in Gi, we get t fo Lid, FUTURES our, 290 a Bort, Sreapriga War, New Delhi 110016, “betncelcteyyeceon16. Sol. 17. Sol. 18. Sol. we a/2F L Qnegmg nace Fromeqns iijand iv), 5 = 4 0.036 NX, For refraction in surface A, [at M] q So image is formed at O,, a distance v, = 0.375 m from X and act as a virtual object for the second surface, For refraction in the second surface B, [Pole v] 3 the vente 19 vw Ra 8) 1 3 > y, 2x(-0.25-0.3780) 2-05) pee tato vy 1” (0.625%3) v= 0.714 shit in point of observation 00, = YO-YO, =SR-v, = 0.750 -0,714 = 0.036 187 2 Q_2cESR s) 2 =5(8¢ Reais i) Sx2E le 6.25 v=2.5x10?m/s am om «16K, Ge 7 19ke/s (4100 - 16t)x10 = 2.5 «10° x16 4100 -16t=250x 16 = 4000 16t =100 +£100/16 = 25 4 =6.25see. (WG Led, FUTURE House 294, Kalu Barc, Brnaprine Whar New Bat! 100¥6, Pe AA106000, BEREDES®, Pox 3 Tesh cnnChemistry PART-II 19. A,B,D Sol. (A) Total nodal surfaces in 3s =2 Total nodal surfaces in 3p (@ Angular node in 3p, cos@=0 Angular node in 3p, 0 = x/2 Let 2- x % Radial nodes in 9s, (s ~txvS) = aS = (s-2x+2x")-0 = Q7-18x+2x7=0 = ,~18#v524-216 _182i08 2x2 4 9+3y3 ee 8S mee 2 Radial nodes in 3p, exo > x56 Hence their radial nodes are not same (D) Conceptual fact. 20. ¢,D Sol. NaBHs in EtOH and Raney Ni/Hz, THF do't reduce -COOH & ester group. 2. AB Sol: Ag’ +28,0;° —[Ag{S,0,),]'° —* + Ag,80,() "> Ag, S(t) x 22. B,C Sol. .(a) 8 Td voids are completely inside, rest Td voids comes from shared ones. On the centre of each comer atoms (12) there is 1 Td voids which is shared in 3 unit cells. 4 Total Td voids -8 + 14 Fi 2 (©) All octahedral are inside HCP unit cell (©) Each body diagonal has 2 Td voids. Therefore all 8 Td voids are completely inside. (@ FCC is ABCABC.... type arrangement of layers “ed, PUTORE House, 254 Keke Sart, Sereapris Waar, New Baht 110016, Ph ‘Seboner me fionconRIPF-FT- (Papor-2)-POM (Sol.) JEE(Advanced)20 23. A,B,C,D SOL) caro, omg come ty eth felon (om cu oR Seu sso, + res/o, es eee, ei 24. A,B,C ad feces Fytiey Ps, sp 8 ROL, ~ ot Sol bZG SF no-Po“Fe OH LASS ,H Pol,(s) —o[ Pete] [Pcie] PBr,(s) —>[PB4¢'] [Br°] noo, ML Hos cn Rene oO Hy Hs ° ern oo v4.00, i aa [ Ta (a ae ON oH, er I —~ 7 Br H mpc, te ce ose) Taree Lacy Farin ary 3A Rate Bae erepriga Wary NeW DAN LIDOTG Pr AORODN aeSOPIIG Foe TOSTODOT och eigenRTPr 4 (Paper.2)-PCM (Sol JEE(Advanced)/20 10 26. A,B,C Sol. All other reactions will give tert-butyl benzene as major product after the reaction except in case of (No rearrangement) with FeCl, rr 28. OD san (GO) An Ce a f on L2H i ‘CHLOH seo A ei fo iS Sat. : = a : i 2 mee, | acorcon can ae mM aa, ie if | nove te ee cH, (WRG Led, POTS owe, 45. alu Sarat, Sarvcpria War New Dent 110010, Fh 40106000, 20UGP499, Tax 26STO>H2 teteasoeeyrgenconRIPF-FT- (Paper-2)-PCM (Sol,) JEE(Advanced oH, Sat: | psovcon 2. D 30. Sol. (28, 30) Adiabatic 4H 0 Rev. AS, =O AS,, >0 Sue =O Surin > 0 Isothermal AH=0 rev. Y, ASys =nRin¥2 te v ‘Ltd FUTURE Howe, 254 Rat Sart, Sarvapriya Vihar New Behl 10016, Pr 40106000 BOSGDIDO, Fax DOSTOST? Thebans jcc3. Sol. 32, Sol. 33. Sol. 34, Sol. 02390.00 Ceol) + 600, (g) —> 60C0,,(g) AU = -25970KJ/mot AH = AU +AU + angkt 25970 KJ / mol Aan =604/HICO,)~ Ar HICoo4)~604;Fo, 9) A,H{Ceo) =60(-393) +25970 =2390KJ 00113.20 oy Rin) -20016180-8atsg( $825) =113.20 224.53 KPa oe Al0) MR B04 pe 0c ae Bo gRKa0a) ea P = BST - 04.83 KPa i 00121.95 mol. mass= 328 21x12%48 1 mol pyrethrini + 4molBr, melBy = 500x107 4 3: 28 00x10" 328x 0.05 121.95 ml volume of Br, = x 4x1000(m))13_RTPF-£T(Paper-2)-PCM (Sel) JEE(Advanced/20 35. 0003.4 Sol. LetVitres of PRCH.COOHIHA, containing ~5- ~ 0.0368 mole is added 101 lire of HOAC (HAs) containing 2 1667 molefitre HA, == H’ +A; 0.1667 ce 4 SASSTE® 1.5105 1+V ee 1+V HA, =H" +A, (0.0368-y)v | 5 y-a_w ive inv Henee, 1.510% x _%_ is 86x10 0.1667 I+v x _1.86x10 0.1667-x ~ 1.5x10> Neglecting x in composition to 0.1667 a 24x10? = x =2.07x10 Tie7 7124x107 = x =2.07%10 in, 1.5x107xyv s gain, 153x107 WV 5 42,105 epee (O.OStaEyyap ae Neglecting *y" in to 0.0368 33x10 -5x108 2.07 x10 +1.33x10°V TV 5x10 36. 15688 years 2.908%5.73 109), (a 0.693 0.158, = 15688 Sol. t Hd PERE Howe 254, Kan Sart Sreapriga Var, New Dall 110016, Pk 46106000 DeteDeoa Pes reer aeee “tebe epee38, Sol. 39, Sol. 40. Sol. a. Sol. 42. Sol. 43. Sol. 0 _ BW —NY-9-G"=y) _ 30y" 31 +4 t42y+8y +40. y-9? oP Puty=(1 +x) 1420429 491 #92 orn #BOCE + 720 = SOUL S114) 44 x at 20 + agge20 = 20014-91144 mag tant ane? F a = 30.315 ~ 34.30¢, 89 +84 Fant OD 14 = 30.3163 - 31.30 cq, 30.231 — 31,230 + 1 = 29 x 23044 (A, B,D) Here b= ae (A, B, D) Consider the function 909) = 1) — x2 9(0) = a(n) = g(2n) = 0 : = FQ) ~ 2x= 0 has two real roots in (0, 2n) and f"(x) - 2 = 0 has atleast one root in (0, 2) {A,c) AB = AC = BC |s parallel to the angle bisector of AB and AC = Possible equation of side BC are xt+y=5andx-y+1= (B,C) ass, -2s,esp-Ls.nan-5,7) 30= 5x17 -x)>x=512 “SP =12, 8,P=5=>8,8, = 5? +12? =13 (B, C) 109 23 and 1(0) = 2 = f(x) 2 3x+2V xe (0, 10] (G, D) Let diagonal elements be x4, Xp. X3.oXp 4 #2 + sess Xq = 10 and 22 4 FG HQ 1G oe Hey O= A Given that Cio. = 126 = °C, = Cy ‘Hedy PUTED Howes, 450 Hl Gard, Srvapriga Var, New De 1I00I6, Ph 106000, 2680409, Pax 26819062 debt ne lana15 _RTPF-FT- (Paper.2)-PCM (Sol,}JEE(Advanced)/20 44. (A,B,C, 0) aa leh ‘ vaa-11-y2 | 10 1 45. B 46. A 48. B 49. 3 Sol. xP taxtb=artoxte = (1-o)x2 + (a—o)x+ (0-0) =1-c=a-c=b-c=0 has 3 real roots, 50. 6 Sol. £"()- sinx fx) 20 = 0098K F(x) 2 e080 (OV x20 SfO20Vx20 But (is non increasing => (0) =0V x20 = 10) =6 eee 3 Sol. For continuous function two consicutive maxima or minima can not occure. Cha G Sol. Let h(x) = f(x) - (@x+ 2) = O has 5 roots NO)=F@)=3=0 — 4 roois ne) =P) =0 3 roots = (F0)-3)F@)=0 7 roots 53.8 m2 Sol. I(r) = [ ne®* (n sinnx— cosnx cosx) dx 2 Wa) =-ne8* cosnaft’? = n=n (o=%Je é M27) = 27; (3) = 3. 54, OS Sol. 2 f(x) ie 2 0%), 6) oe = 4 Pax put xt he (ae = [rode ‘el Led, PUTIEE Roun, 504 Ras Saray Serepriga Vor, Ww Def 0046, M46 100000, TESOPAPD, Fox TOSTIONE eoocel oweytngeconm