You are on page 1of 13

The 1925 Born and Jordan paper “On quantum mechanics”

William A. Fedak and Jeffrey J. Prentis

Citation: Am. J. Phys. 77, 128 (2009); doi: 10.1119/1.3009634


View online: http://dx.doi.org/10.1119/1.3009634
View Table of Contents: http://ajp.aapt.org/resource/1/AJPIAS/v77/i2
Published by the American Association of Physics Teachers

Related Articles
Spontaneous symmetry breakdown in non-relativistic quantum mechanics
Am. J. Phys. 80, 891 (2012)
Understanding the damping of a quantum harmonic oscillator coupled to a two-level system using analogies to
classical friction
Am. J. Phys. 80, 810 (2012)
Relation between Poisson and Schrödinger equations
Am. J. Phys. 80, 715 (2012)
Comment on “Exactly solvable models to illustrate supersymmetry and test approximation methods in quantum
mechanics,” Am. J. Phys. 79, 755–761 (2011)
Am. J. Phys. 80, 734 (2012)
The uncertainty product of position and momentum in classical dynamics
Am. J. Phys. 80, 708 (2012)

Additional information on Am. J. Phys.


Journal Homepage: http://ajp.aapt.org/
Journal Information: http://ajp.aapt.org/about/about_the_journal
Top downloads: http://ajp.aapt.org/most_downloaded
Information for Authors: http://ajp.dickinson.edu/Contributors/contGenInfo.html

Downloaded 02 Oct 2012 to 136.159.235.223. Redistribution subject to AAPT license or copyright; see http://ajp.aapt.org/authors/copyright_permission
The 1925 Born and Jordan paper “On quantum mechanics”
William A. Fedaka兲 and Jeffrey J. Prentisb兲
Department of Natural Sciences, University of Michigan–Dearborn, Dearborn, Michigan 48128
共Received 12 September 2007; accepted 9 October 2008兲
The 1925 paper “On quantum mechanics” by M. Born and P. Jordan, and the sequel “On quantum
mechanics II” by M. Born, W. Heisenberg, and P. Jordan, developed Heisenberg’s pioneering theory
into the first complete formulation of quantum mechanics. The Born and Jordan paper is the subject
of the present article. This paper introduced matrices to physicists. We discuss the original postulates
of quantum mechanics, present the two-part discovery of the law of commutation, and clarify the
origin of Heisenberg’s equation. We show how the 1925 proof of energy conservation and Bohr’s
frequency condition served as the gold standard with which to measure the validity of the new
quantum mechanics. © 2009 American Association of Physics Teachers.
关DOI: 10.1119/1.3009634兴

I. INTRODUCTION for work done in Göttingen in collaboration—you, Jordan,


and I, this fact depresses me and I hardly know what to write
The name “quantum mechanics” was coined by Max to you. I am, of course, glad that our common efforts are
Born.1 For Born and others, quantum mechanics denoted a now appreciated, and I enjoy the recollection of the beautiful
canonical theory of atomic and electronic motion of the same time of collaboration. I also believe that all good physicists
level of generality and consistency as classical mechanics. know how great was your and Jordan’s contribution to the
The transition from classical mechanics to a true quantum structure of quantum mechanics—and this remains un-
mechanics remained an elusive goal prior to 1925. changed by a wrong decision from outside. Yet I myself can
Heisenberg made the breakthrough in his historic 1925 do nothing but thank you again for all the fine collaboration
paper, “Quantum-theoretical reinterpretation of kinematic and feel a little ashamed.”23
and mechanical relations.”2 Heisenberg’s bold idea was to Engraved on Max Born’s tombstone is a one-line epitaph:
retain the classical equations of Newton but to replace the pq − qp = h / 2␲i. Born composed this elegant equation in
classical position coordinate with a “quantum-theoretical early July 1925 and called it “die verschärfte
quantity.” The new position quantity contains information Quantenbedingung”4—the sharpened quantum condition.
about the measurable line spectrum of an atom rather than This equation is now known as the law of commutation and
the unobservable orbit of the electron. Born realized that is the hallmark of quantum algebra.
Heisenberg’s kinematical rule for multiplying position quan- In the contemporary approach to teaching quantum me-
tities was equivalent to the mathematical rule for multiplying chanics, matrix mechanics is usually introduced after a thor-
matrices. The next step was to formalize Heisenberg’s theory ough discussion of wave mechanics. The Heisenberg picture
using the language of matrices. is viewed as a unitary transformation of the Schrödinger
The first comprehensive exposition on quantum mechanics picture.24 How was matrix mechanics formulated in 1925
in matrix form was written by Born and Jordan,4 and the when the Schrödinger picture was nowhere in sight? The
sequel was written by Born, Heisenberg, and Jordan.5 Dirac Born and Jordan paper4 represents matrix mechanics in its
independently discovered the general equations of quantum purest form.
mechanics without using matrix theory.6 These papers devel-
oped a Hamiltonian mechanics of the atom in a completely
new quantum 共noncommutative兲 format. These papers ush- II. BACKGROUND TO “ON QUANTUM
ered in a new era in theoretical physics where Hermitian MECHANICS”
matrices, commutators, and eigenvalue problems became the
mathematical trademark of the atomic world. We discuss the Heisenberg’s program, as indicated by the title of his
first paper “On quantum mechanics.”4 paper,2 consisted of constructing quantum-theoretical rela-
This formulation of quantum mechanics, now referred to tions by reinterpreting the classical relations. To appreciate
as matrix mechanics,7 marked one of the most intense peri- what Born and Jordan did with Heisenberg’s reinterpreta-
ods of discovery in physics. The ideas and formalism behind tions, we discuss in the Appendix four key relations from
the original matrix mechanics are absent in most textbooks. Heisenberg’s paper.2 Heisenberg wrote the classical and
Recent articles discuss the correspondence between classical quantum versions of each relation in parallel—as formula
harmonics and quantum jumps,8 the calculational details of couplets. Heisenberg has been likened to an “expert decoder
Heisenberg’s paper,9 and the role of Born in the creation of who reads a cryptogram.”25 The correspondence principle8,26
quantum theory.10 References 11–19 represent a sampling of acted as a “code book” for translating a classical relation into
the many sources on the development of quantum mechan- its quantum counterpart. Unlike his predecessors who used
ics. the correspondence principle to produce specific relations,
Given Born and Jordan’s pivotal role in the discovery of Heisenberg produced an entirely new theory—complete with
quantum mechanics, it is natural to wonder why there are no a new representation of position and a new rule of multipli-
equations named after them,20 and why they did not share the cation, together with an equation of motion and a quantum
Nobel Prize with others.21 In 1933 Heisenberg wrote Born condition whose solution determined the atomic observables
saying “The fact that I am to receive the Nobel Prize alone, 共energies, frequencies, and transition amplitudes兲.

128 Am. J. Phys. 77 共2兲, February 2009 http://aapt.org/ajp © 2009 American Association of Physics Teachers 128

Downloaded 02 Oct 2012 to 136.159.235.223. Redistribution subject to AAPT license or copyright; see http://ajp.aapt.org/authors/copyright_permission
Matrices are not explicitly mentioned in Heisenberg’s pa- gang Pauli to collaborate on the matrix program. Pauli de-
per. He did not arrange his quantum-theoretical quantities clined the invitation.29 The next day, Born asked his student
into a table or array. In looking back on his discovery, Pascual Jordan to assist him. Jordan accepted the invitation
Heisenberg wrote, “At that time I must confess I did not and in a few days proved Born’s conjecture that all nondi-
know what a matrix was and did not know the rules of ma- agonal elements of pq − qp must vanish. The rest of the new
trix multiplication.”18 In the last sentence of his paper he quantum mechanics rapidly solidified. The Born and Jordan
wrote “whether this method after all represents far too rough paper was received by the Zeitschrift für Physik on 27 Sep-
an approach to the physical program of constructing a theo- tember 1925, two months after Heisenberg’s paper was re-
retical quantum mechanics, an obviously very involved prob- ceived by the same journal. All the essentials of matrix me-
lem at the moment, can be decided only by a more intensive chanics as we know the subject today fill the pages of this
mathematical investigation of the method which has been paper.
very superficially employed here.”27 In the abstract Born and Jordan wrote “The recently pub-
Born took up Heisenberg’s challenge to pursue “a more lished theoretical approach of Heisenberg is here developed
intensive mathematical investigation.” At the time Heisen-
into a systematic theory of quantum mechanics 共in the first
berg wrote his paper, he was Born’s assistant at the Univer-
place for systems having one degree of freedom兲 with the aid
sity of Göttingen. Born recalls the moment of inspiration
when he realized that position and momentum were of mathematical matrix methods.”30 In the introduction they
matrices:28 go on to write “The physical reasoning which led Heisenberg
to this development has been so clearly described by him
After having sent Heisenberg’s paper to the that any supplementary remarks appear superfluous. But, as
Zeitschrift für Physik for publication, I began to he himself indicates, in its formal, mathematical aspects his
ponder about his symbolic multiplication, and was approach is but in its initial stages. His hypotheses have been
soon so involved in it…For I felt there was some- applied only to simple examples without being fully carried
thing fundamental behind it…And one morning, through to a generalized theory. Having been in an advanta-
geous position to familiarize ourselves with his ideas
about 10 July 1925, I suddenly saw the light:
throughout their formative stages, we now strive 共since his
Heisenberg’s symbolic multiplication was nothing
investigations have been concluded兲 to clarify the math-
but the matrix calculus, well known to me since ematically formal content of his approach and present some
my student days from the lectures of Rosanes in of our results here. These indicate that it is in fact possible,
Breslau. starting with the basic premises given by Heisenberg, to
build up a closed mathematical theory of quantum mechanics
I found this by just simplifying the notation a little: which displays strikingly close analogies with classical me-
chanics, but at the same time preserves the characteristic
instead of q共n , n + ␶兲, where n is the quantum num-
features of quantum phenomena.”31
ber of one state and ␶ the integer indicating the
The reader is introduced to the notion of a matrix in the
transition, I wrote q共n , m兲, and rewriting Heisen- third paragraph of the introduction: “The mathematical basis
berg’s form of Bohr’s quantum condition, I recog- of Heisenberg’s treatment is the law of multiplication of
nized at once its formal significance. It meant that quantum-theoretical quantities, which he derived from an in-
the two matrix products pq and qp are not identi- genious consideration of correspondence arguments. The de-
cal. I was familiar with the fact that matrix multi- velopment of his formalism, which we give here, is based
plication is not commutative; therefore I was not upon the fact that this rule of multiplication is none other
too much puzzled by this result. Closer inspection than the well-known mathematical rule of matrix multiplica-
showed that Heisenberg’s formula gave only the tion. The infinite square array which appears at the start of
value of the diagonal elements 共m = n兲 of the ma- the next section, termed a matrix, is a representation of a
trix pq – qp; it said they were all equal and had the physical quantity which is given in classical theory as a func-
value h / 2␲i where h is Planck’s constant and i tion of time. The mathematical method of treatment inherent
= 冑−1. But what were the other elements 共m ⫽ n兲? in the new quantum mechanics is thereby characterized by
the employment of matrix analysis in place of the usual
number analysis.”
Here my own constructive work began. Repeating The Born-Jordan paper4 is divided into four chapters.
Heisenberg’s calculation in matrix notation, I soon Chapter 1 on “Matrix calculation” introduces the mathemat-
convinced myself that the only reasonable value of ics 共algebra and calculus兲 of matrices to physicists. Chapter 2
the nondiagonal elements should be zero, and I on “Dynamics” establishes the fundamental postulates of
wrote the strange equation quantum mechanics, such as the law of commutation, and
derives the important theorems, such as the conservation of
h energy. Chapter 3 on “Investigation of the anharmonic oscil-
pq − qp = 1, 共1兲 lator” contains the first rigorous 共correspondence free兲 calcu-
2␲i
lation of the energy spectrum of a quantum-mechanical har-
monic oscillator. Chapter 4 on “Remarks on
where 1 is the unit matrix. But this was only a electrodynamics” contains a procedure—the first of its
guess, and all my attempts to prove it failed. kind—to quantize the electromagnetic field. We focus on the
material in Chap. 2 because it contains the essential physics
On 19 July 1925, Born invited his former assistant Wolf- of matrix mechanics.

129 Am. J. Phys., Vol. 77, No. 2, February 2009 William A. Fedak and Jeffrey J. Prentis 129

Downloaded 02 Oct 2012 to 136.159.235.223. Redistribution subject to AAPT license or copyright; see http://ajp.aapt.org/authors/copyright_permission
III. THE ORIGINAL POSTULATES OF QUANTUM position and momentum of classical mechanics. In the Bohr
MECHANICS atom the electron undergoes periodic motion in a well de-
fined orbit around the nucleus with a certain classical fre-
Current presentations of quantum mechanics frequently quency. In the Heisenberg–Born–Jordan atom there is no
are based on a set of postulates.32 The Born–Jordan postu- longer an orbit, but there is some sort of periodic “quantum
lates of quantum mechanics were crafted before wave me- motion” of the electron characterized by the set of frequen-
chanics was formulated and thus are quite different than the cies ␯共nm兲 and amplitudes q共nm兲. Physicists believed that
Schrödinger-based postulates in current textbooks. The origi- something inside the atom must vibrate with the right fre-
nal postulates come as close as possible to the classical- quencies even though they could not visualize what the
mechanical laws while maintaining complete quantum- quantum oscillations looked like. The mechanical properties
mechanical integrity. 共q , p兲 of the quantum motion contain complete information
Section III, “The basic laws,” in Chap. 2 of the Born– on the spectral properties 共frequency, intensity兲 of the emit-
Jordan paper is five pages long and contains approximately ted radiation.
thirty equations. We have imposed a contemporary postula- The diagonal elements of a matrix correspond to the
tory approach on this section by identifying five fundamental states, and the off-diagonal elements correspond to the tran-
passages from the text. We call these five fundamental ideas sitions. An important property of all dynamical matrices is
“the postulates.” We have preserved the original phrasing, that the diagonal elements are independent of time. The Her-
notation, and logic of Born and Jordan. The labeling and the mitian rule in Eq. 共4兲 implies the relation ␯共nn兲 = 0. Thus the
naming of the postulates is ours. time factor of the nth diagonal term in any matrix is
Postulate 1. Position and Momentum. Born and Jordan e2␲i␯共nn兲t = 1. As we shall see, the time-independent entries in
introduce the position and momentum matrices by writing a diagonal matrix are related to the constant values of a con-
that33 served quantity.
In their purely mathematical introduction to matrices
The dynamical system is to be described by the
共Chap. 1兲, Born and Jordan use the following symbols to
spatial coordinate q and the momentum p, these denote a matrix
being represented by the matrices

冢 冣
a共00兲 a共01兲 a共02兲 . . .
共q = q共nm兲e2␲i␯共nm兲t兲,
a共10兲 a共11兲 a共12兲
2␲i␯共nm兲t
a = 共a共nm兲兲 = . 共5兲
共p = p共nm兲e 兲. 共2兲 a共20兲 a共21兲 a共22兲
] 
Here the ␯共nm兲 denote the quantum-theoretical fre- The bracketed symbol 共a共nm兲兲, which displays inner ele-
quencies associated with the transitions between ments a共nm兲 contained within outer brackets 共 兲, is the short-
states described by the quantum numbers n and m. hand notation for the array in Eq. 共5兲. By writing the matrix
The matrices 共2兲 are to be Hermitian, e.g., on trans- elements as a共nm兲, rather than anm, Born and Jordan made
position of the matrices, each element is to go over direct contact with Heisenberg’s quantum-theoretical quanti-
into its complex conjugate value, a condition ties a共n , n − ␣兲 共see the Appendix兲. They wrote35 “Matrix
which should apply for all real t. We thus have multiplication is defined by the rule ‘rows times columns,’
familiar from the ordinary theory of determinants:
q共nm兲q共mn兲 = 兩q共nm兲兩2 共3兲

a = bc means a共nm兲 = 兺 b共nk兲c共km兲 . ” 共6兲
and k=0

␯共nm兲 = − ␯共mn兲. 共4兲 This multiplication rule was first given 共for finite square ma-
trices兲 by Arthur Cayley.36 Little did Cayley know in 1855
that his mathematical “row times column” expression
If q is a Cartesian coordinate, then the expression
b共nk兲c共km兲 would describe the physical process of an elec-
共3兲 is a measure of the probabilities of the transi-
tron making the transition n → k → m in an atom.
tions n  m. Born and Jordan wrote in Postulate 1 that the quantity
兩q共nm兲兩2 provides “a measure of the probabilities of the tran-
The preceding passage placed Hermitian matrices into the
physics limelight. Prior to the Born–Jordan paper, matrices sitions n  m.” They justify this profound claim in the last
were rarely seen in physics.34 Hermitian matrices were even chapter.37 Born and Jordan’s one-line claim about transition
stranger. Physicists were reluctant to accept such an abstract probabilities is the only statistical statement in their postu-
mathematical entity as a description of physical reality. lates. Physics would have to wait several months before
For Born and Jordan, q and p do not specify the position Schrödinger’s wave function ⌿共x兲 and Born’s probability
and momentum of an electron in an atom. Heisenberg function 兩⌿共x兲兩2 entered the scene. Born discovered the con-
stressed that quantum theory should focus only on the ob- nection between 兩⌿共x兲兩2 and position probability, and was
servable properties, namely the frequency and intensity of also the first physicist 共with Jordan兲 to formalize the connec-
the atomic radiation and not the position and period of the tion between 兩q共nm兲兩2 and the transition probability via a
electron. The quantities q and p represent position and mo- “quantum electrodynamic” argument.38 As a pioneer statisti-
mentum in the sense that q and p satisfy matrix equations of cal interpreter of quantum mechanics, it is interesting to
motion that are identical in form to those satisfied by the speculate that Born might have discovered how to form a

130 Am. J. Phys., Vol. 77, No. 2, February 2009 William A. Fedak and Jeffrey J. Prentis 130

Downloaded 02 Oct 2012 to 136.159.235.223. Redistribution subject to AAPT license or copyright; see http://ajp.aapt.org/authors/copyright_permission
linear superposition of the periodic matrix elements was employed to find g from q, p.”42 Because e2␲i␯共nm兲t is the
q共nm兲e2␲i␯共nm兲t in order to obtain another statistical object, universal time factor common to all dynamical matrices, they
namely the expectation value 具q典. Early on, Born, Heisen- note that it can be dropped from Eq. 共2兲 in favor of the
berg, and Jordan did superimpose matrix elements,47 but did shorter notation q = 共q共nm兲兲 and p = 共p共nm兲兲.
not supply the statistical interpretation. Why does the Ritz rule insure that the time factors of
Postulate 2. Frequency Combination Principle. After de- g共pq兲 are identical to the time factors of p and q? Consider
fining q and p, Born and Jordan wrote39 “Further, we shall the potential energy function q2. The nm element of q2,
require that which we denote by q2共nm兲, is obtained from the elements of
q via the multiplication rule
␯共jk兲 + ␯共kl兲 + ␯共lj兲 = 0 . ” 共7兲
The frequency sum rule in Eq. 共7兲 is the fundamental con- q2共nm兲 = 兺 q共nk兲e2␲i␯共nk兲tq共km兲e2␲i␯共km兲t . 共10兲
k
straint on the quantum-theoretical frequencies. This rule is
based on the Ritz combination principle, which explains the Given the Ritz relation ␯共nm兲 = ␯共nk兲 + ␯共km兲, which follows
relations of the spectral lines of atomic spectroscopy.40 Equa- from Eqs. 共4兲 and 共7兲, Eq. 共10兲 reduces to

冋兺 册
tion 共7兲 is the quantum analogue of the “Fourier combination
principle”, ␯共k − j兲 + ␯共l − k兲 + ␯共j − l兲 = 0, where ␯共␣兲 = ␣␯共1兲 q2共nm兲 = q共nk兲q共km兲 e2␲i␯共nm兲t . 共11兲
is the frequency of the ␣th harmonic component of a Fourier k

series. The frequency spectrum of classical periodic motion It follows that the nm time factor of q2 is the same as the nm
obeys this Fourier sum rule. The equal Fourier spacing of time factor of q.
classical lines is replaced by the irregular Ritzian spacing of We see that the theoretical rule for multiplying mechanical
quantal lines. In the correspondence limit of large quantum amplitudes, a共nm兲 = 兺kb共nk兲c共km兲, is intimately related to
numbers and small quantum jumps the atomic spectrum of the experimental rule for adding spectral frequencies,
Ritz reduces to the harmonic spectrum of Fourier.8,26 Be- ␯共nm兲 = ␯共nk兲 + ␯共km兲. The Ritz rule occupied a prominent
cause the Ritz rule was considered an exact law of atomic
place in Heisenberg’s discovery of the multiplication rule
spectroscopy, and because Fourier series played a vital role
共see the Appendix兲. Whenever a contemporary physicist cal-
in Heisenberg’s analysis, it made sense for Born and Jordan
culates the total amplitude of the quantum jump n → k → m,
to posit the frequency rule in Eq. 共7兲 as a basic law.
the steps involved can be traced back to the frequency com-
One might be tempted to regard Eq. 共7兲 as equivalent to
bination principle of Ritz.
the Bohr frequency condition, E共n兲 − E共m兲 = h␯共nm兲, where
Postulate 3. The Equation of Motion. Born and Jordan
E共n兲 is the energy of the stationary state n. For Born and introduce the law of quantum dynamics by writing43
Jordan, Eq. 共7兲 says nothing about energy. They note that
Eqs. 共4兲 and 共7兲 imply that there exists spectral terms Wn In the case of a Hamilton function having the form
such that
1 2
h␯共nm兲 = Wn − Wm . 共8兲 H= p + U共q兲, 共12兲
2m
At this postulatory stage, the term Wn of the spectrum is
unrelated to the energy E共n兲 of the state. Heisenberg empha-
we shall assume, as did Heisenberg, that the equa-
sized this distinction between “term” and “energy” in a letter
tions of motion have just the same form as in the
to Pauli summarizing the Born–Jordan theory.41 Born and
Jordan adopt Eq. 共7兲 as a postulate–one based solely on the classical theory, so that we can write:
observable spectral quantities ␯共nm兲 without reference to any ⳵H 1
mechanical quantities E共n兲. The Bohr frequency condition is q̇ = = p, 共13a兲
⳵p m
not something they assume a priori, it is something that must
be rigorously proved.
The Ritz rule insures that the nm element of any dynami- ⳵H ⳵U
ṗ = − =− . 共13b兲
cal matrix 共any function of p and q兲 oscillates with the same ⳵q ⳵q
frequency ␯共nm兲 as the nm element of p and q. For example,
if the 3 → 2 elements of p and q oscillate at 500 MHz, then This Hamiltonian formulation of quantum dynamics general-
the 3 → 2 elements of p2, q2, pq, q3, p2 + q2, etc. each oscil- ized Heisenberg’s Newtonian approach.44 The assumption by
late at 500 MHz. In all calculations involving the canonical Heisenberg and Born and Jordan that quantum dynamics
matrices p and q, no new frequencies are generated. A con- looks the same as classical dynamics was a bold and deep
sistent quantum theory must preserve the frequency spectrum assumption. For them, the problem with classical mechanics
of a particular atom because the spectrum is the spectro- was not the dynamics 共the form of the equations of motion兲,
scopic signature of the atom. The calculations must not but rather the kinematics 共the meaning of position and mo-
change the identity of the atom. Based on the rules for ma- mentum兲.
nipulating matrices and combining frequencies, Born and
Postulate 4. Energy Spectrum. Born and Jordan reveal the
Jordan wrote that “it follows that a function g共pq兲 invariably
connection between the allowed energies of a conservative
takes on the form system and the numbers in the Hamiltonian matrix:
g = 共g共nm兲e2␲i␯共nm兲t兲 共9兲
“The diagonal elements H共nn兲 of H are inter-
and the matrix 共g共nm兲兲 therein results from identically the preted, according to Heisenberg, as the energies of
same process applied to the matrices 共q共nm兲兲, 共p共nm兲兲 as the various states of the system.”45

131 Am. J. Phys., Vol. 77, No. 2, February 2009 William A. Fedak and Jeffrey J. Prentis 131

Downloaded 02 Oct 2012 to 136.159.235.223. Redistribution subject to AAPT license or copyright; see http://ajp.aapt.org/authors/copyright_permission
This statement introduced a radical new idea into main- ⬁

stream physics: calculating an energy spectrum reduces to 兺 ␶ 共q␶p−␶兲
␶=−⬁ ⳵J
共18兲
finding the components of a diagonal matrix.46 Although
Born and Jordan did not mention the word eigenvalue in Ref.
4, Born, Heisenberg, and Jordan would soon formalize the
with
idea of calculating an energy spectrum by solving an eigen-
value problem.5 The ad hoc rules for calculating a quantized

energy in the old quantum theory were replaced by a system- 1
atic mathematical program. 兺 共q共n + ␶,n兲p共n,n + ␶兲
h ␶=−⬁
Born and Jordan considered exclusively conservative sys-
tems for which H does not depend explicitly on time. The − q共n,n − ␶兲p共n − ␶,n兲兲, 共19兲
connection between conserved quantities and diagonal matri-
ces will be discussed later. For now, recall that the diagonal
elements of any matrix are independent of time. For the spe- where in the right-hand expression those q共nm兲,
cial case where all the non-diagonal elements of a dynamical p共nm兲 which take on a negative index are to be set
matrix g共pq兲 vanish, the quantity g is a constant of the mo-
equal to zero. In this way we obtain the quantiza-
tion. A postulate must be introduced to specify the physical
tion condition corresponding to Eq. 共17兲 as
meaning of the constant elements in g.
In the old quantum theory it was difficult to explain why
the energy was quantized. The discontinuity in energy had to h
be postulated or artificially imposed. Matrices are naturally 兺k 共p共nk兲q共kn兲 − q共nk兲p共kn兲兲 = 2␲i . 共20兲
quantized. The quantization of energy is built into the dis-
crete row-column structure of the matrix array. In the old
theory Bohr’s concept of a stationary state of energy En was
a central concept. Physicists grappled with the questions: This is a system of infinitely many equations,
Where does En fit into the theory? How is En calculated? namely one for each value of n.48
Bohr’s concept of the energy of the stationary state finally
found a rigorous place in the new matrix scheme.47 Why did Born and Jordan take the derivative of the action
Postulate 5. The Quantum Condition. Born and Jordan integral in Eq. 共15兲 to arrive at Eq. 共17兲? Heisenberg per-
state that the elements of p and q for any quantum mechani- formed a similar maneuver 共see the Appendix兲. One reason is
cal system must satisfy the “quantum condition”: to eliminate any explicit dependence on the integer variable
n from the basic laws. Another reason is to generate a differ-
h
兺k 共p共nk兲q共kn兲 − q共nk兲p共kn兲兲 = 2␲i . 共14兲
ential expression that can readily be translated via the corre-
spondence principle into a difference expression containing
only transition quantities. In effect, a state relation is con-
Given the significance of Eq. 共14兲 in the development of verted into a change-in-state relation. In the old quantum
quantum mechanics, we quote Born and Jordan’s “deriva- theory the Bohr–Sommerfeld quantum condition, 养pdq = nh,
tion” of this equation: determined how all state quantities depend on n. Such an ad
hoc quantization algorithm has no proper place in a rigorous
The equation quantum theory, where n should not appear explicitly in any

冖 冕 1/␯ of the fundamental laws. The way in which q共nm兲, p共nm兲,


J= pdq = pq̇dt 共15兲 ␯共nm兲 depend on 共nm兲 should not be artificially imposed, but
0 should be naturally determined by fundamental relations in-
volving only the canonical variables q and p, without any
explicit dependence on the state labels n and m. Equation
of “classical” quantum theory can, on introducing 共20兲 is one such fundamental relation.
the Fourier expansions of p and q, In 1924 Born introduced the technique of replacing differ-
⬁ entials by differences to make the “formal passage from clas-
p= 兺
␶=−⬁
p ␶e 2␲i␯␶t , sical mechanics to a ‘quantum mechanics’.”49 This corre-
spondence rule played an important role in allowing Born
共16兲 and others to develop the equations of quantum mechanics.50
⬁ To motivate Born’s rule note that the fundamental orbital
q= 兺
␶=−⬁
q ␶e 2␲i␯␶t , frequency of a classical periodic system is equal to dE / dJ 共E
is energy and J = 养 pdq is an action兲,51 whereas the spectral
frequency of an atomic system is equal to ⌬E / h. Hence, the
passage from a classical to a quantum frequency is made by
be transformed into replacing the derivative dE / dJ by the difference ⌬E / h.52
⬁ Born conjectured that this correspondence is valid for any
⳵ quantity ⌽. He wrote “We are therefore as good as forced to
1 = 2␲i 兺 ␶ 共q␶p−␶兲.
␶=−⬁ ⳵J
共17兲
adopt the rule that we have to replace a classically calculated
quantity, whenever it is of the form ␶⳵⌽ / ⳵J by the linear
average or difference quotient 关⌽共n + ␶兲 − ⌽共n兲兴 / h.”53 The
The following expressions should correspond: correspondence between Eqs. 共18兲 and 共19兲 follows from

132 Am. J. Phys., Vol. 77, No. 2, February 2009 William A. Fedak and Jeffrey J. Prentis 132

Downloaded 02 Oct 2012 to 136.159.235.223. Redistribution subject to AAPT license or copyright; see http://ajp.aapt.org/authors/copyright_permission
Born’s rule by letting ⌽ be ⌽共n兲 = q共n , n − ␶兲p共n − ␶ , n兲, ġ = 2␲i共␯共nm兲g共nm兲e2␲i␯共nm兲t兲. 共22兲
where q共n , n − ␶兲 corresponds to q␶ and p共n − ␶ , n兲 corre-
sponds to p−␶ or p␶*. If ġ = 0, then Eq. 共22兲 implies the relation ␯共nm兲g共nm兲 = 0 for
Born and Jordan remarked that Eq. 共20兲 implies that p and all 共nm兲. This relation is always true for the diagonal ele-
q can never be finite matrices.54 For the special case p ments because ␯共nn兲 is always equal to zero. For the off-
= mq̇ they also noted that the general condition in Eq. 共20兲 diagonal elements, the relation ␯共nm兲g共nm兲 = 0 implies that
reduces to Heisenberg’s form of the quantum condition 共see g共nm兲 must equal zero, because it is assumed that ␯共nm兲
the Appendix兲. Heisenberg did not realize that his quantiza- ⫽ 0 for n ⫽ m. Thus, g is a diagonal matrix.
tion rule was a relation between pq and qp.55 Hence, to show that pq − qp is a diagonal matrix, Born
Planck’s constant h enters into the theory via the quantum and Jordan showed that the time derivative of pq − qp is
condition in Eq. 共20兲. The quantum condition expresses the equal to zero. They introduced the matrix d ⬅ pq − qp and
following deep law of nature: All the diagonal components of expressed the time derivative of d as
pq − qp must equal the universal constant h / 2␲i.
What about the nondiagonal components of pq − qp? Born ḋ = ṗq + pq̇ − q̇p − qṗ. 共23兲
claimed that they were all equal to zero. Jordan proved They used the canonical equations of motion in Eq. 共13兲 to
Born’s claim. It is important to emphasize that Postulate 5 write Eq. 共23兲 as
says nothing about the nondiagonal elements. Born and Jor-
dan were careful to distinguish the postulated statements ⳵H ⳵H ⳵H ⳵H
ḋ = q − q+p − p. 共24兲
共laws of nature兲 from the derivable results 共consequences of ⳵q ⳵q ⳵p ⳵p
the postulates兲. Born’s development of the diagonal part of
pq − qp and Jordan’s derivation of the nondiagonal part con- They next demonstrated that the combination of derivatives
stitute the two-part discovery of the law of commutation. in Eq. 共24兲 leads to a vanishing result59 and say that “it
follows that ḋ = 0 and d is a diagonal matrix. The diagonal
elements of d are, however, specified by the quantum condi-
tion 共20兲. Summarizing, we obtain the equation
IV. THE LAW OF COMMUTATION
h
pq − qp = 1, 共25兲
Born and Jordan write the following equation in Sec. IV of 2␲i
“On quantum mechanics”:
on introducing the unit matrix 1. We call Eq. 共25兲 the ‘sharp-
ened quantum condition’ and base all further conclusions on
h
pq − qp = 1. 共21兲 it.”60 Fundamental results that propagate from Eq. 共25兲 in-
2␲i clude the equation of motion, ġ = 共2␲i / h兲共Hg − gH兲 共see Sec.
V兲, the Heisenberg uncertainty principle, ⌬p⌬q 艌 h / 4␲, and
They call Eq. 共21兲 the “sharpened quantum condition” be- the Schrödinger operator, p = 共h / 2␲i兲d / dq.
cause it sharpened the condition in Eq. 共20兲, which only fixes It is important to emphasize the two distinct origins of
the diagonal elements, to one which fixes all the elements. In pq − qp = 共h / 2␲i兲1. The diagonal part, 共pq − qp兲diagonal
a letter to Pauli, Heisenberg referred to Eq. 共21兲 as a “fun- = h / 2␲i is a law—an exact decoding of the approximate law
damental law of this mechanics” and as “Born’s very clever 养pdq = nh. The nondiagonal part, 共pq − qp兲nondiagonal = 0, is a
idea.”56 Indeed, the commutation law in Eq. 共21兲 is one of
theorem—a logical consequence of the equations of motion.
the most fundamental relations in quantum mechanics. This
From a practical point of view Eq. 共25兲 represents vital in-
equation introduces Planck’s constant and the imaginary
formation on the line spectrum of an atom by defining a
number i into the theory in the most basic way possible. It is
system of algebraic equations that place strong constraints on
the golden rule of quantum algebra and makes quantum cal-
the magnitudes of q共nm兲, p共nm兲, and ␯共nm兲.
culations unique. The way in which all dynamical properties
of a system depend on h can be traced back to the simple
way in which pq − qp depend on h. In short, the commuta- V. THE EQUATION OF MOTION
tion law in Eq. 共21兲 stores information on the discontinuity,
the non-commutativity, the uncertainty, and the complexity Born and Jordan proved that the equation of motion de-
of the quantum world. scribing the time evolution of any dynamical quantity g共pq兲
In their paper Born and Jordan proved that the off- is
diagonal elements of pq − qp are equal to zero by first estab- 2␲i
lishing a “diagonality theorem,” which they state as follows: ġ = 共Hg − gH兲. 共26兲
“If ␯共nm兲 ⫽ 0 when n ⫽ m, a condition which we wish to h
assume, then the formula ġ = 0 denotes that g is a diagonal Equation 共26兲 is now often referred to as the Heisenberg
matrix with g共nm兲 = ␦nmg共nn兲.”57 This theorem establishes equation.61 In Ref. 2 the only equation of motion is Newton’s
the connection between the structural 共diagonality兲 and the second law, which Heisenberg wrote as ẍ + f共x兲 = 0 共see the
temporal 共constancy兲 properties of a dynamical matrix. It Appendix兲.
provided physicists with a whole new way to look at conser- The “commutator” of mechanical quantities is a recurring
vation principles: In quantum mechanics, conserved quanti- theme in the Born–Jordan theory. The quantity pq − qp lies at
ties are represented by diagonal matrices.58 the core of their theory. Equation 共26兲 reveals how the quan-
Born and Jordan proved the diagonality theorem as fol- tity Hg − gH is synonymous with the time evolution of g.
lows. Because all dynamical matrices g共pq兲 have the form in Thanks to Born and Jordan, as well as Dirac who established
Eq. 共9兲, the time derivative of g is the connection between commutators and classical Poisson

133 Am. J. Phys., Vol. 77, No. 2, February 2009 William A. Fedak and Jeffrey J. Prentis 133

Downloaded 02 Oct 2012 to 136.159.235.223. Redistribution subject to AAPT license or copyright; see http://ajp.aapt.org/authors/copyright_permission
brackets,6 the commutator is now an integral part of modern commutators and derivatives in Eqs. 共31兲 and 共32兲 are now
quantum theory. The change in focus from commuting vari- standard operator equations of contemporary quantum
ables to noncommuting variables represents a paradigm shift theory.
in quantum theory. With the words, “Denoting the matrix Hg − gH by 兩 Hg 兩,”
The original derivation of Eq. 共26兲 is different from Born and Jordan formalized the notion of a commutator and
present-day derivations. In the usual textbook presentation introduced physicists to this important quantum-theoretical
Eq. 共26兲 is derived from a unitary transformation of the states object. The appearance of Eq. 共36兲 in Ref. 4 marks the first
and operators in the Schrödinger picture.24 In 1925, the printed statement of the general equation of motion for a
Schrödinger picture did not exist. To derive Eq. 共26兲 from dynamical quantity in quantum mechanics.
their postulates Born and Jordan developed a new quantum-
theoretical technology that is now referred to as “commuta-
tor algebra.” They began the proof by stating the following
generalizations of Eq. 共25兲: VI. THE ENERGY THEOREMS

h n−1 Heisenberg, Born, and Jordan considered the conservation


pnq = qpn + n p , 共27兲 of energy and the Bohr frequency condition as universal laws
2␲i
that should emerge as logical consequences of the fundamen-
h n−1 tal postulates. Proving energy conservation and the fre-
qnp = pqn − n q , 共28兲 quency condition was the ultimate measure of the power of
2␲i the postulates and the validity of the theory.63 Born and Jor-
which can readily be derived by induction. They considered dan began Sec. IV of Ref. 4 by writing “The content of the
Hamiltonians of the form preceding paragraphs furnishes the basic rules of the new
quantum mechanics in their entirety. All the other laws of
H = H1共p兲 + H2共q兲, 共29兲 quantum mechanics, whose general validity is to be verified,
where H1共p兲 and H2共q兲 are represented by power series must be derivable from these basic tenets. As instances of
such laws to be proved, the law of energy conservation and
H 1 = 兺 a sp s , the Bohr frequency condition primarily enter into
s consideration.”64
The energy theorems are stated as follows:65
H 2 = 兺 b sq s . 共30兲 Ḣ = 0 共energy conservation兲, 共37兲
s

After writing these expressions, they wrote62 “Formulae 共27兲 h␯共nm兲 = H共nn兲 − H共mm兲 共frequency condition兲. 共38兲
and 共28兲 indicate that
Equations 共37兲 and 共38兲 are remarkable statements on the
h ⳵H temporal behavior of the system and the logical structure of
Hq − qH = , 共31兲
2␲i ⳵p the theory.66 Equation 共37兲 says that H, which depends on
the matrices p and q is always a constant of the motion even
h ⳵H though p = p共t兲 and q = q共t兲 depend on time. In short, the t in
Hp − pH = − . 共32兲 H共p共t兲 , q共t兲兲 must completely disappear. Equation 共37兲 re-
2␲i ⳵q
veals the time independence of H, and Eq. 共38兲 specifies how
Comparison with the equations of motion 共13兲 yields H itself determines the time dependence of all other dynami-
2␲i cal quantities.
q̇ = 共Hq − qH兲, 共33兲 Why should ␯共nm兲, H共nn兲, and H共mm兲 be related? These
h quantities are completely different structural elements of dif-
ferent matrices. The parameter ␯共nm兲 is a transition quantity
2␲i that characterizes the off-diagonal, time-dependent part of q
ṗ = 共Hp − pH兲. 共34兲
h and p. In contrast, H共nn兲 is a state quantity that characterizes
the diagonal, time-independent part of H共pq兲. It is a non-
Denoting the matrix Hg − gH by 兩 Hg 兩 for brevity, one has

冏 冏冏冏 冏冏
trivial claim to say that these mechanical elements are re-
H H H lated.
= b+a , 共35兲 It is important to distinguish between the Bohr meaning of
ab a b
En − Em = h␯ and the Born–Jordan meaning of H共nn兲
from which generally for g = g共pq兲 one may conclude that − H共mm兲 = h␯共nm兲. For Bohr, En denotes the mechanical en-

ġ =
2␲i H
h g
冏冏
=
2␲i
h
共Hg − gH兲 . ” 共36兲
ergy of the electron and ␯ denotes the spectral frequency of
the radiation. In the old quantum theory there exists ad hoc,
semiclassical rules to calculate En. There did not exist any
The derivation of Eq. 共36兲 clearly displays Born and Jordan’s mechanical rules to calculate ␯, independent of En and Em.
expertise in commutator algebra. The essential step to go The relation between En − Em and ␯ was postulated. Born and
from Eq. 共27兲 to Eq. 共31兲 is to note that Eq. 共27兲 can be Jordan did not postulate any connection between H共nn兲,
rewritten as a commutator-derivative relation, pnq − qpn H共mm兲, and ␯共nm兲. The basic mechanical laws 共law of mo-
= 共h / 2␲i兲dpn / dp, which is equivalent to the nth term of the tion and law of commutation兲 allow them to calculate the
series representation of Eq. 共31兲. The generalized commuta- frequencies ␯共nm兲 which paramaterize q and the energies
tion rules in Eqs. 共27兲 and 共28兲, and the relation between H共nn兲 stored in H. The theorem in Eq. 共38兲 states that the

134 Am. J. Phys., Vol. 77, No. 2, February 2009 William A. Fedak and Jeffrey J. Prentis 134

Downloaded 02 Oct 2012 to 136.159.235.223. Redistribution subject to AAPT license or copyright; see http://ajp.aapt.org/authors/copyright_permission
calculated values of the mechanical parameters H共nn兲, condition兴, one can prove the general validity of the law of
H共mm兲, and ␯共nm兲 will always satisfy the relation H共nn兲 conservation of energy and the Bohr frequency relation in the
− H共mm兲 = h␯共nm兲. sense conjectured by Heisenberg: this proof could not be
The equation of motion 共36兲 is the key to proving the carried through in its entirety by him even for the simple
energy theorems. Born and Jordan wrote “In particular, if in examples which he considered.”71 Because p and q do not
Eq. 共36兲 we set g = H, we obtain commute, the mechanism responsible for energy conserva-
tion in quantum mechanics is significantly different than the
Ḣ = 0. 共39兲 classical mechanism. Born and Jordan emphasize this differ-
ence by writing “Whereas in classical mechanics energy con-
Now that we have verified the energy-conservation law and
servation 共Ḣ = 0兲 is directly apparent from the canonical
recognized the matrix H to be diagonal 关by the diagonality
equations, the same law of energy conservation in quantum
theorem, Ḣ = 0 ⇒ H is diagonal兴, Eqs. 共33兲 and 共34兲 can be
put into the form mechanics, Ḣ = 0 lies, as one can see, more deeply hidden
beneath the surface. That its demonstrability from the as-
h␯共nm兲q共nm兲 = 共H共nn兲 − H共mm兲兲q共nm兲, 共40兲 sumed postulates is far from being trivial will be appreciated
if, following more closely the classical method of proof, one
h␯共nm兲p共nm兲 = 共H共nn兲 − H共mm兲兲p共nm兲, 共41兲 sets out to prove H to be constant simply by evaluating Ḣ.”72
We carry out Born and Jordan’s suggestion “to prove H to
from which the frequency condition follows.”67 Given the
importance of this result, it is worthwhile to elaborate on the be constant simply by evaluating Ḣ” for the special Hamil-
proof. Because the nm component of any matrix g is tonian
g共nm兲e2␲i␯共nm兲t, the nm component of the matrix relation in H = p2 + q3 . 共45兲
Eq. 共33兲 is
In order to focus on the energy calculus of the p and q
2␲i␯共nm兲q共nm兲e2␲i␯共nm兲t matrices, we have omitted the scalar coefficients in Eq. 共45兲.
2␲i If we write Eq. 共45兲 as H = pp + qqq, calculate Ḣ, and use the
=
h k
兺 共H共nk兲q共km兲 equations of motion q̇ = 2p, ṗ = −3q2, we find73

− q共nk兲H共km兲兲e2␲i关␯共nk兲+␯共km兲兴t . 共42兲 Ḣ = q共pq − qp兲 + 共qp − pq兲q. 共46兲

Given the diagonality of H, H共nk兲 = H共nn兲␦nk and H共km兲 Equation 共46兲 reveals how the value of pq − qp uniquely
= H共mm兲␦km, and the Ritz rule, ␯共nk兲 + ␯共km兲 = ␯共nm兲, Eq. determines the value of Ḣ. The quantum condition, pq − qp
共42兲 reduces to = 共h / 2␲i兲1, reduces Eq. 共46兲 to Ḣ = 0. In classical mechanics
1 the classical condition, pq − qp = 0, is taken for granted in
␯共nm兲 = 共H共nn兲 − H共mm兲兲. 共43兲 proving energy conservation. In quantum mechanics the con-
h dition that specifies the nonzero value of pq − qp plays a
In this way Born and Jordan demonstrated how Bohr’s fre- nontrivial role in establishing energy conservation. This non-
quency condition, h␯共nm兲 = H共nn兲 − H共mm兲, is simply a sca- triviality is what Born and Jordan meant when they wrote
that energy conservation in quantum mechanics “lies more
lar component of the matrix equation, hq̇ = 2␲i共Hq − qH兲. In
deeply hidden beneath the surface.”
any presentation of quantum mechanics it is important to Proving the law of energy conservation and the Bohr fre-
explain how and where Bohr’s frequency condition logically quency condition was the decisive test of the theory—the
fits into the formal structure.68 final validation of the new quantum mechanics. All of the
According to Postulate 4, the nth diagonal element H共nn兲 pieces of the “quantum puzzle” now fit together. After prov-
of H is equal to the energy of the nth stationary state. Logi- ing the energy theorems, Born and Jordan wrote that “The
cally, this postulate is needed to interpret Eq. 共38兲 as the fact that energy-conservation and frequency laws could be
original frequency condition conjectured by Bohr. Born and proved in so general a context would seem to us to furnish
Jordan note that Eqs. 共8兲 and 共38兲 imply that the mechanical strong grounds to hope that this theory embraces truly deep-
energy H共nn兲 is related to the spectral term Wn as follows: seated physical laws.”74
Wn = H共nn兲 + constant.69
This mechanical proof of the Bohr frequency condition
established an explicit connection between time evolution VII. CONCLUSION
and energy. In the matrix scheme all mechanical quantities To put the discovery of quantum mechanics in matrix form
共p, q, and g共pq兲兲 evolve in time via the set of factors into perspective, we summarize the contributions of Heisen-
e2␲i␯共nm兲t, where ␯共nm兲 = 共H共nn兲 − H共mm兲兲 / h. Thus, all berg and Born–Jordan. Heisenberg’s breakthrough consists
g-functions have the form70 of four quantum-theoretical reinterpretations 共see the Appen-
dix兲:
g = 共g共nm兲e2␲i共H共nn兲−H共mm兲兲t/h兲. 共44兲
1. Replace the position coordinate x共t兲 by the set of transi-
Equation 共44兲 exhibits how the difference in energy between
tion components a共n , n − ␣兲ei␻共n,n−␣兲t.
state n and state m is the “driving force” behind the time
evolution 共quantum oscillations兲 associated with the change 2. Replace x2共t兲 with the set 兺␣a共n , n − ␣兲ei␻共n,n−␣兲ta共n
of state n → m. − ␣ , n − ␤兲ei␻共n−␣,n−␤兲t.
In the introduction of their paper, Born and Jordan write 3. Keep Newton’s second law, ẍ + f共x兲 = 0, but replace x as
“With the aid of 关the equations of motion and the quantum before.

135 Am. J. Phys., Vol. 77, No. 2, February 2009 William A. Fedak and Jeffrey J. Prentis 135

Downloaded 02 Oct 2012 to 136.159.235.223. Redistribution subject to AAPT license or copyright; see http://ajp.aapt.org/authors/copyright_permission
4. Replace the old quantum condition, nh = 养 mẋ2dt, with h reinterpreting x共t兲 as a sum over transition components, he
= 4␲m兺␣兵兩a共n + ␣ , n兲兩2␻共n + ␣ , n兲 − 兩a共n , n − ␣兲兩2␻共n , n represented the position by the set of transition components.
− ␣兲其. We symbolically denote Heisenberg’s reinterpretation as
x → 兵a共n,n − ␣兲ei␻共n,n−␣兲t其. 共A2兲
The quantum mechanics of Born and Jordan consists of
five postulates: Equation 共A2兲 is the first breakthrough relation.
1. q = 共q共nm兲e2␲i␯共nm兲t兲, p = 共p共nm兲e2␲i␯共nm兲t兲, Reinterpretation 2: Multiplication. To calculate the energy
of a harmonic oscillator, Heisenberg needed to know the
2. ␯共jk兲 + ␯共kl兲 + ␯共lj兲 = 0,
quantity x2. How do you square a set of transition compo-
3. q̇ = ⳵H / ⳵p, ṗ = −⳵H / ⳵q, nents? Heisenberg posed this fundamental question twice in
4. En = H共nn兲, and his paper.80 His answer gave birth to the algebraic structure
5. 共pq − qp兲diagonal = h / 2␲i, of quantum mechanics. We restate Heisenberg’s question as
“If x is represented by 兵a共n , n − ␣兲ei␻共n,n−␣兲t其 and x2 is repre-
and four theorems sented by 兵b共n , n − ␤兲ei␻共n,n−␤兲t其, how is b共n , n − ␤兲 related to
1. 共pq − qp兲nondiagonal = 0, a共n , n − ␣兲?”
2. ġ = 共2␲i / h兲共Hg − gH兲, Heisenberg answered this question by reinterpreting the
square of a Fourier series with the help of the Ritz principle.
3. Ḣ = 0, and
He evidently was convinced that quantum multiplication,
4. h␯共nm兲 = H共nn兲 − H共mm兲.
whatever it looked like, must reduce to Fourier-series multi-
plication in the classical limit. The square of Eq. 共A1兲 gives
Quantum mechanics evolved at a rapid pace after the pa-
pers of Heisenberg and Born–Jordan. Dirac’s paper was re- x2共n,t兲 = 兺 b␤共n兲ei␤␻共n兲t , 共A3兲
ceived on 7 November 1925.6 Born, Heisenberg, and Jor- ␤
dan’s paper was received on 16 November 1925.5 The first
“textbook” on quantum mechanics appeared in 1926.75 In a where the ␤th Fourier amplitude is
series of papers during the spring of 1926, Schrödinger set
forth the theory of wave mechanics.76 In a paper received b␤共n兲 = 兺 a␣共n兲a␤−␣共n兲. 共A4兲

June 25, 1926 Born introduced the statistical interpretation of
the wave function.77 The Nobel Prize was awarded to In the new quantum theory Heisenberg replaceed Eqs. 共A3兲
Heisenberg in 1932 共delayed until 1933兲 to Schrödinger and and 共A4兲 with
Dirac in 1933, and to Born in 1954.
x2 → 兵b共n,n − ␤兲ei␻共n,n−␤兲t其, 共A5兲
APPENDIX: HEISENBERG’S FOUR where the n → n − ␤ transition amplitude is
BREAKTHROUGH IDEAS
b共n,n − ␤兲 = 兺 a共n,n − ␣兲a共n − ␣,n − ␤兲. 共A6兲
We divide Heisenberg’s paper2 into four major reinterpre- ␣
tations. For the most part we will preserve Heisenberg’s In constructing Eq. 共A6兲 Heisenberg uncovered the symbolic
original notation and arguments. algebra of atomic processes.
Reinterpretation 1: Position. Heisenberg considered one- The logic behind the quantum rule of multiplication can be
dimensional periodic systems. The classical motion of the summarized as follows. Ritz’s sum rule for atomic frequen-
system 共in a stationary state labeled n兲 is described by the cies, ␻共n , n − ␤兲 = ␻共n , n − ␣兲 + ␻共n − ␣ , n − ␤兲, implies the
time-dependent position x共n , t兲.78 Heisenberg represents this
product rule for Heisenberg’s kinematic elements, ei␻共n,n−␤兲t
periodic function by the Fourier series
= ei␻共n,n−␣兲tei␻共n−␣,n−␤兲t, which is the backbone of the multipli-
x共n,t兲 = 兺 a␣共n兲ei␣␻共n兲t . 共A1兲 cation rule in Eq. 共A6兲. Equation 共A6兲 allowed Heisenberg to
␣ algebraically manipulate the transition components.
Reinterpretation 3: Motion. Equations 共A2兲, 共A5兲, and
Unless otherwise noted, sums over integers go from −⬁ to ⬁. 共A6兲 represent the new “kinematics” of quantum theory—the
The ␣th Fourier component related to the nth stationary state new meaning of the position x. Heisenberg next turned his
has amplitude a␣共n兲 and frequency ␣␻共n兲. According to the attention to the new “mechanics.” The goal of Heisenberg’s
correspondence principle, the ␣th Fourier component of the mechanics is to determine the amplitudes, frequencies, and
classical motion in the state n corresponds to the quantum energies from the given forces. Heisenberg noted that in the
jump from state n to state n − ␣.8,26 Motivated by this prin- old quantum theory a␣共n兲 and ␻共n兲 are determined by solv-
ciple, Heisenberg replaced the classical component ing the classical equation of motion
a␣共n兲ei␣␻共n兲t by the transition component a共n , n
− ␣兲ei␻共n,n−␣兲t.79 We could say that the Fourier harmonic is ẍ + f共x兲 = 0, 共A7兲
replaced by a “Heisenberg harmonic.” Unlike the sum over and quantizing the classical solution—making it depend on
the classical components in Eq. 共A1兲, Heisenberg realized n—via the quantum condition
that a similar sum over the transition components is mean-
ingless. Such a quantum Fourier series could not describe the
electron motion in one stationary state 共n兲 because each term 冖 mẋdx = nh. 共A8兲
in the sum describes a transition process associated with two
states 共n and n − ␣兲. In Eqs. 共A7兲 and 共A8兲 f共x兲 is the force 共per mass兲 function
Heisenberg’s next step was bold and ingenious. Instead of and m is the mass.

136 Am. J. Phys., Vol. 77, No. 2, February 2009 William A. Fedak and Jeffrey J. Prentis 136

Downloaded 02 Oct 2012 to 136.159.235.223. Redistribution subject to AAPT license or copyright; see http://ajp.aapt.org/authors/copyright_permission
Heisenberg assumed that Newton’s second law in Eq. 共A7兲 Phys. 35, 557–615 共1926兲, English translation in Ref. 3, paper 15.
6
is valid in the new quantum theory provided that the classical P. A. M. Dirac, “The fundamental equations of quantum mechanics,”
Proc. R. Soc. London, Ser. A 109, 642–653 共1925兲, reprinted in Ref. 3,
quantity x is replaced by the set of quantities in Eq. 共A2兲, and paper 14.
f共x兲 is calculated according to the new rules of amplitude 7
The name “matrix mechanics” did not appear in the original papers of
algebra. Keeping the same form of Newton’s law of dynam- 1925 and 1926. The new mechanics was most often called “quantum
ics, but adopting the new kinematic meaning of x is the third mechanics.” At Göttingen, some began to call it “matrix physics.”
Heisenberg breakthrough. Heisenberg disliked this terminology and tried to eliminate the math-
Reinterpretation 4: Quantization. How did Heisenberg re- ematical term “matrix” from the subject in favor of the physical expres-
sion “quantum-theoretical magnitude.” 关Ref. 17, p. 362兴. In his Nobel
interpret the old quantization condition in Eq. 共A8兲? Given Lecture delivered 11 December 1933, Heisenberg referred to the two
the Fourier series in Eq. 共A1兲, the quantization condition, versions of the new mechanics as “quantum mechanics” and “wave me-
nh = 养 mẋ2dt, can be expressed in terms of the Fourier param- chanics.” See Nobel Lectures in Physics 1922–1941 共Elsevier, Amster-
eters a␣共n兲 and ␻共n兲 as dam, 1965兲兴.
8
W. A. Fedak and J. J. Prentis, “Quantum jumps and classical harmonics,”
nh = 2␲m 兺 兩a␣共n兲兩2␣2␻共n兲. 共A9兲 9
Am. J. Phys. 70, 332–344 共2002兲.
␣ I. J. R. Aitchison, D. A. MacManus, and T. M. Snyder, “Understanding
Heisenberg’s ‘magical’ paper of July 1925: A new look at the calcula-
For Heisenberg, setting 养pdx equal to an integer multiple of tional details,” Am. J. Phys. 72 1370–1379 共2004兲.
10
h was an arbitrary rule that did not fit naturally into the J. Bernstein, “Max Born and the quantum theory,” Am. J. Phys. 73,
dynamical scheme. Because his theory focuses exclusively 999–1008 共2005兲.
11
S. Tomonaga, Quantum Mechanics 共North-Holland, Amsterdam, 1962兲,
on transition quantities, Heisenberg needed to translate the
Vol. 1.
old quantum condition that fixes the properties of the states 12
M. Jammer, The Conceptual Development of Quantum Mechanics
to a new condition that fixes the properties of the transitions 共McGraw-Hill, New York, 1966兲.
between states. Heisenberg believed14 that what matters is 13
J. Mehra and H. Rechenberg, The Historical Development of Quantum
the difference between 养pdx evaluated for neighboring Theory 共Springer, New York, 1982兲, Vol. 3.
14
states: 关养pdx兴n − 关养pdx兴n−1. He therefore took the derivative Duncan, A. and Janssen, M., “On the verge of Umdeutung in Minnesota:
Van Vleck and the correspondence principle,” Arch. Hist. Exact Sci. 61,
of Eq. 共A9兲 with respect to n to eliminate the forced n de- 553–624 共2007兲.
pendence and to produce a differential relation that can be 15
E. MacKinnon, “Heisenberg, models and the rise of matrix mechanics,”
reinterpreted as a difference relation between transition Hist. Stud. Phys. Sci. 8, 137–188 共1977兲.
16
quantities. In short, Heisenberg converted G. Birtwistle, The New Quantum Mechanics 共Cambridge U.P., London,
1928兲.
d
h = 2␲m 兺 ␣
17
C. Jungnickel and R. McCormmach, Intellectual Mastery of Nature 共Uni-
共兩a␣共n兲兩2␣␻共n兲兲 共A10兲 versity of Chicago Press, Chicago, 1986兲, Vol. 2.
␣ dn 18
W. Heisenberg, “Development of concepts in the history of quantum
theory,” Am. J. Phys. 43, 389–394 共1975兲.
to 19
M. Bowen and J. Coster, “Born’s discovery of the quantum-mechanical
⬁ matrix calculus,” Am. J. Phys. 48, 491–492 共1980兲.
h = 4␲m 兺 兵兩a共n + ␣,n兲兩2␻共n + ␣,n兲
20
M. Born, My Life: Recollections of a Nobel Laureate 共Taylor & Francis,
␣=0 New York, 1978兲. Born wrote that 共pp. 218–219兲 “This paper by Jordan
and myself contains the formulation of matrix mechanics, the first printed
− 兩a共n,n − ␣兲兩2␻共n,n − ␣兲其. 共A11兲 statement of the commutation law, some simple applications to the har-
monic and anharmonic oscillator, and another fundamenal idea: the quan-
In a sense Heisenberg’s “amplitude condition” in Eq. 共A11兲 tization of the electromagnetic field 共by regarding the components as
is the counterpart to Bohr’s frequency condition 共Ritz’s fre- matrices兲. Nowadays, textbooks speak without exception of Heisenberg’s
quency combination rule兲. Heisenberg’s condition relates the matrices, Heisenberg’s commutation law and Dirac’s field quantization.”
21
In 1928 Einstein nominated Heisenberg, Born, and Jordan for the Nobel
amplitudes of different lines within an atomic spectrum and Prize 关See A. Pais, Subtle Is the Lord: The Science and the Life of Albert
Bohr’s condition relates the frequencies. Equation 共A11兲 is Einstein 共Oxford U.P., New York, 1982兲, p. 515兴. Possible explanations of
the fourth Heisenberg breakthrough.81 why Born and Jordan did not receive the Nobel Prize are given in Ref. 10
Equations 共A7兲 and 共A11兲 constitute Heisenberg’s new and Ref. 22, pp. 191–193.
22
mechanics. In principle, these two equations can be solved to N. Greenspan, The End of the Certain World: The Life and Science of
find a共n , n − ␣兲 and ␻共n , n − ␣兲. No one before Heisenberg Max Born 共Basic Books, New York, 2005兲.
23
See Ref. 20, p. 220.
knew how to calculate the amplitude of a quantum jump. 24
E. Merzbacher, Quantum Mechanics 共Wiley, New York, 1998兲, pp. 320–
Equations 共A2兲, 共A6兲, 共A7兲, and 共A11兲 define Heisenberg’s 323.
program for constructing the line spectrum of an atom from 25
Reference 11, p. 205.
26
the given force on the electron. N. Bohr, “On the quantum theory of line-spectra,” reprinted in Ref. 3,
paper 3.
27
Reference 3 p. 276 paper 12.
a兲 28
Electronic mail: bfedak@umd.umich.edu Reference 20, pp. 217–218.
b兲 29
Electronic mail: jprentis@umd.umich.edu Reference 20, p. 218.
1 30
The name “quantum mechanics” appeared for the first time in the litera- Reference 3, pp. 277, paper 13.
ture in M. Born, “Über Quantenmechanik,” Z. Phys. 26, 379–395 共1924兲. 31
Reference 3, pp. 277–278, paper 13.
2 32
W. Heisenberg, “Über quantentheoretische Umdeutung kinematischer R. L. Liboff, Introductory Quantum Mechanics 共Addison-Wesley, San
und mechanischer Beziehungen,” Z. Phys. 33, 879–893 共1925兲, trans- Francisco, 2003兲, Chap. 3; R. Shankar, Principles of Quantum Mechanics
lated in Ref. 3, paper 12. 共Plenum, New York, 1994兲, Chap. 4; C. Cohen-Tannoudji, B. Diu, and F.
3
Sources of Quantum Mechanics, edited by B. L. van der Waerden 共Dover, Laloë, Quantum Mechanics 共Wiley, New York, 1977兲, Chap. III.
33
New York, 1968兲. Reference 3, p. 287, paper 13.
4 34
M. Born and P. Jordan, “Zur Quantenmechanik,” Z. Phys. 34, 858–888 Reference 12, pp. 217–218.
共1925兲; English translation in Ref. 3, paper 13. 35
Reference 3, p. 280, paper 13.
5 36
M. Born, W. Heisenberg, and P. Jordan, “Zur Quantenmechanik II,” Z. A. Cayley, “Sept différents mémoires d’analyse,” Mathematika 50, 272–

137 Am. J. Phys., Vol. 77, No. 2, February 2009 William A. Fedak and Jeffrey J. Prentis 137

Downloaded 02 Oct 2012 to 136.159.235.223. Redistribution subject to AAPT license or copyright; see http://ajp.aapt.org/authors/copyright_permission
317 共1855兲; A. Cayley, “A memoir on the theory of matrices,” Philos. 50
See the chapter “The transition to quantum mechanics” in Ref. 12, pp.
Trans. R. Soc. London, Ser. A 148, 17–37 共1858兲. 181–198 for applications of “Born’s correspondence rule.” The most im-
37
The last chapter 共Bemerkungen zur Elektrodynamik兲 is not translated in portant application was deriving Kramer’s dispersion formula. See Ref. 3,
Ref. 3. See Ref. 13, pp. 87–90 for a discussion of the contents of this papers 6–10 and Ref. 14.
51
section. Reference 11, pp. 144–145.
38
In Heisenberg’s paper 共see Ref. 2兲 the connection between 兩q共nm兲兩2 and 52
The exact relation between the orbital frequency and the optical fre-
transition probability is implied but not discussed. See Ref. 3, pp. 30–32, quency is derived as follows. Consider the transition from state n of
for a discussion of Heisenberg’s assertion that the transition amplitudes energy E共n兲 to state n − ␶ of energy E共n − ␶兲. In the limit n Ⰷ ␶, that is,
determine the transition probabilibities. The relation between a squared large “orbit” and small “jump,” the difference E共n兲 − E共n − ␶兲 is equal to
amplitude and a transition probability originated with Bohr who conjec- the derivative ␶dE / dn. Given the old quantum condition J = nh, it follows
tured that the squared Fourier amplitude of the classical electron motion that dE / dn = hdE / dJ. Thus for n Ⰷ ␶ and J = nh, we have the relation
provides a measure of the transition probability 共see Refs. 8 and 26兲. The 关E共n兲 − E共n − ␶兲兴 / h = ␶dE / dJ, or equivalently, ␯共n , n − ␶兲 = ␶␯共n兲. This rela-
correspondence between classical intensities and quantum probabilities tion proves an important correspondence theorem: In the limit n Ⰷ ␶, the
was studied by several physicists including H. Kramers, Intensities of frequency ␯共n , n − ␶兲 associated with the quantum jump n → n − ␶ is equal
Spectral Lines 共A. F. Host and Sons, Kobenhaven, 1919兲; R. Ladenburg to the frequency ␶␯共n兲 associated with the ␶th harmonic of the classical
in Ref. 3, paper 4, and J. H. Van Vleck, “Quantum principles and line motion in the state n. See Refs. 8 and 26.
53
spectra,” Bulletin of the National Research Council, Washington, DC, Reference 3, p. 191, paper 7.
54
1926, pp. 118–153. Suppose that the number of states is finite and equal to the integer N.
39
Reference 3, p. 287, paper 13. Then, according to Eq. 共20兲, the diagonal sum 共trace兲 of pq − qp would be
40
W. Ritz, “Über ein neues Gesetz der Serienspektren,” Phys. Z. 9, 521– D共pq − qp兲 = Nh / 2␲i. This nonzero value of the trace contradicts the
529 共1908兲; W. Ritz, “On a new law of series spectra,” Astrophys. J. 28, purely mathematical relation D共pq − qp兲 = 0, which must be obeyed by all
237–243 共1908兲. The Ritz combination principle was crucial in making finite matrices.
55
sense of the regularities in the line spectra of atoms. It was a key principle Heisenberg interview quoted in Ref. 12, p. 281, footnote 45.
56
that guided Bohr in constructing a quantum theory of line spectra. Ob- Reference 17, p. 361.
57
servations of spectral lines revealed that pairs of line frequencies combine Reference 3, p. 288, paper 13. The name “Diagonality theorem” is ours.
共add兲 to give the frequency of another line in the spectrum. The Ritz The condition ␯共nm兲 ⫽ 0 when n ⫽ m implies that the system is nonde-
combination rule is ␯共nk兲 + ␯共km兲 = ␯共nm兲, which follows from Eqs. 共4兲 generate.
and 共7兲. As a universal, exact law of spectroscopy, the Ritz rule provided 58
In contemporary language a conserved quantity is an operator that com-
a powerful tool to analyze spectra and to discover new lines. Given the mutes with the Hamiltonian operator H. For such commuting operators
measured frequencies ␯1 and ␯2 of two known lines in a spectrum, the there exists a common set of eigenvectors. In the energy eigenbasis that
Ritz rule told spectroscopists to look for new lines at the frequencies ␯1 underlies the Born–Jordan formulation, the matrices representing H and
+ ␯2 or ␯1 − ␯2. all conserved quantities are automatically diagonal.
41 59
In the letter dated 18 September 1925 Heisenberg explained to Pauli that Born and Jordan’s proof that Eq. 共24兲 vanishes is based on a purely
the frequencies ␯ik in the Born–Jordan theory obey the “combination mathematical property of “symbolic differentiation” discussed in Sec. II
relation ␯ik + ␯kl = ␯il or ␯ik = 共Wi − Wk兲 / h but naturally it is not to be as- of their paper 共See Ref. 4兲. For a separable Hamiltonian of the form H
sumed that W is the energy.” See Ref. 3, p. 45. = p2 / 2m + U共q兲, the proof is simpler. For this case Eq. 共24兲 becomes ḋ
42
Reference 3, p. 287, paper 13. = q共⳵U / ⳵q兲 − 共⳵U / ⳵q兲q + p共p / m兲 − 共p / m兲p. Because p and q are sepa-
43
Reference 3, p. 289, paper 13.
44 rated in this expression, we do not have to consider the inequality pq
Born and Jordan devote a large portion of Chap. 1 to developing a matrix
calculus to give meaning to matrix derivatives such as dq / dt and ⳵H / ⳵p. ⫽ qp. The expression reduces to ḋ = 0.
60
They introduce the process of “symbolic differentiation” for constructing Reference 3, p. 292, paper 13. In Ref. 4, Born and Jordan refer to pq
the derivative of a matrix with respect to another matrix. For a discussion − qp = 共h / 2␲i兲1 as the “vershärfte Quantenbedingung,” which has been
of Born and Jordan’s matrix calculus, see Ref. 13, pp. 68–71. To deal translated as “sharpened quantum condition” 共Ref. 13, p. 77兲, “stronger
with arbitrary Hamiltonian functions, Born and Jordan formulated a more quantum condition” 共Ref. 3, p. 292兲, and “exact quantum condition” 共Ref.
general dynamical law by converting the classical action principal, 12, p. 220兲.
61
兰Ldt = extremum, into a quantal action principal, D共pq̇ − H共pq兲兲 J. J. Sakurai, Modern Quantum Mechanics 共Addison-Wesley, San Fran-
= extremum, where D denotes the trace 共diagonal sum兲 of the Lagrangian cisco, 1994兲, pp. 83–84; A. Messiah, Quantum Mechanics 共J Wiley, New
matrix, pq̇ − H. See Ref. 3, pp. 289–290. York, 1958兲, Vol. I, p. 316.
62
45
Reference 3, p. 292. This statement by Born and Jordan appears in Sec. Reference 3, p. 293, paper 13.
63
IV of their paper following the section on the basic laws. We have in- Proving the frequency condition—the second general principle of Bohr—
cluded it with the postulates because it is a deep assumption with far- was especially important because this purely quantal condition was gen-
reaching consequences. erally regarded as a safely established part of physics. Prior to Born and
46
In contemporary language the states labeled n = 0 , 1 , 2 , 3 , . . . in Heisen- Jordan’s mechanical proof of the frequency condition, there existed a
berg’s paper and the Born–Jordan paper are exact stationary states 共eigen- “thermal proof” given by Einstein in his historic paper, “On the quantum
states of H兲. The Hamiltonian matrix is automatically a diagonal matrix theory of radiation,” Phys. Z. 18, 121 共1917兲, translated in Ref. 3, pp,
with respect to this basis. 63–77. In this paper Einstein provides a completely new derivation of
47 Planck’s thermal radiation law by introducing the notion of transition
Although Heisenberg, Born, and Jordan made the “energy of the state”
and the “transition between states” rigorous concepts, it was Schrödinger probabilities 共A and B coefficients兲. Bohr’s frequency condition emerges
who formalized the concept of the “state” itself. It is interesting to note as the condition necessary to reduce the Boltzmann factor exp关共En
that “On quantum mechanics II” by Born, Heisenberg, and Jordan was − Em兲 / kT兴 in Einstein’s formula to the “Wien factor” exp共h␯ / kT兲 in
published before Schrödinger and implicitly contains the first mathemati- Planck’s formula.
64
cal notion of a quantum state. In this paper 共Ref. 3, pp. 348–353兲, each Reference 3, p. 291, paper 13.
65
Hermitian matrix a is associated with a “bilinear form” 兺nma共nm兲xnxm* . Reference 3, pp. 291–292, paper 13. Born and Jordan do not refer to the
Furthermore, they identified the “energy spectrum” of a system with the consequences in Eqs. 共37兲 and 共38兲 as theorems. The label “Energy theo-
set of “eigenvalues” W in the equation Wxk − 兺lH共kl兲xl = 0. In present-day rems” is ours.
66
symbolic language the bilinear form and eigenvalue problem are 具⌿兩a兩⌿典 Instead of postulating the equations of motion and deriving the energy
and H兩⌿典 = W兩⌿典, respectively, where the variables xn are the expansion theorems, we could invert the proof and postulate the energy theorems
coefficients of the quantum state 兩⌿典. At the time, they did not realize the and derive the equations of motion. This alternate logic is mentioned in
physical significance of their eigenvector 共x1 , x2 , . . . 兲 as representing a Ref. 3, p. 296 and formalized in Ref. 5 共Ref. 3, p. 329兲. Also see J. H. Van
stationary state. Vleck, “Note on the postulates of the matrix quantum dynamics,” Proc.
48
Reference 3, pp. 290–291, paper 13. Natl. Acad. Sci. U.S.A. 12, 385–388 共1926兲.
49 67
This is the sentence from Born’s 1924 paper 共See Ref. 1兲 where the name Reference 3, pp. 293–294, paper 13. The proof of the energy theorems
“quantum mechanics” appears for the first time in the physics literature was based on separable Hamiltonians defined in Eq. 共29兲. To generalize
关Ref. 3, p. 182兴. the proof Born and Jordan consider more general Hamiltonian functions

138 Am. J. Phys., Vol. 77, No. 2, February 2009 William A. Fedak and Jeffrey J. Prentis 138

Downloaded 02 Oct 2012 to 136.159.235.223. Redistribution subject to AAPT license or copyright; see http://ajp.aapt.org/authors/copyright_permission
76
H共pq兲 and discover the need to symmetrize the functions. For example, E. Schrödinger, Collected Papers on Wave Mechanics 共Chelsea, New
for H* = p2q, it does not follow that Ḣ* = 0. However, they note that H York, 1978兲.
77
= 共p2q + qp2兲 / 2 yields the same equations of motion as H* and also con- M. Born, “Zur Quantenmechanik der Stoßvorgänge,” Z. Phys. 37, 863–
serves energy, Ḣ = 0. The symmetrization rule reflects the noncommuta- 867 共1926兲.
78
tivity of p and q. Heisenberg’s “classical” quantity x共n , t兲 is the classical solution x共t兲 of
68 Newton’s equation of motion subject to the old quantum condition
In the Heisenberg, Born–Jordan approach the transition components of
the “matter variables” q and p are simply assumed to oscillate in time 养mẋdx = nh. For example, given the purely classical position function
with the radiation frequencies. In contemporary texts a rigorous proof of x共t兲 = a cos ␻t of a harmonic oscillator, the condition 养mẋ2dt = nh quan-
Bohr’s frequency condition involves an analysis of the interaction be- tizes the amplitude, making a depend on n as follows: a共n兲 = 冑nh / ␲m␻.
tween matter and radiation 共radiative transitions兲 using time-dependent Thus, the motion of the harmonic oscillator in the stationary state n is
69
perturbation theory. See Ref. 24, Chap. 19. described by x共n , t兲 = 冑nh / ␲m␻ cos ␻t.
70
Reference 3, p. 292, paper 13. 79
The introduction of transition components a共n , n − ␶兲ei␻共n,n−␣兲t into the
Using the language of state vectors and bra-kets, the matrix element of an formalism was a milestone in the development of quantum theory. The
operator g is gnm共t兲 = 具⌿n共t兲兩g兩⌿m共t兲典, where the energy eigenstate is one-line abstract of Heisenberg’s paper reads “The present paper seeks to
兩⌿n共t兲典 = exp共−2␲iEnt / h兲兩⌿n共0兲典. This Schrödinger element is equivalent establish a basis for theoretical quantum mechanics founded exclusively
to the Born–Jordan element in Eq. 共44兲. upon relationships between quantities which in principle are observable”
71
Reference 3, p. 279, paper 13. Heisenberg was able to demonstrate en-
共Ref. 3, p. 261兲. For Heisenberg, the observable quantities were a共n , n
ergy conservation and Bohr’s frequency condition for two systems 共an-
− ␶兲 and ␻共n , n − ␶兲, that is, the amplitudes and the frequencies of the
harmonic oscillator and rotator兲. The anharmonic oscillator analysis was
spectral lines. Prior to 1925, little was known about transition amplitudes.
limited to second-order perturbation theory.
72 There was a sense that Einstein’s transition probabilities were related to
Reference 3. Born and Jordan do not pursue this direct method of proof
noting that for the most general Hamiltonians the calculation “becomes the squares of the transition amplitudes. Heisenberg made the transition
so exceedingly involved that it seems hardly feasible.” 共Ref. 3, p. 296兲. amplitudes 共and frequencies兲 the central quantities of his theory. He dis-
In a footnote on p. 296, they note that for the special case covered how to manipulate them, relate them, and calculate their values.
80
H = p2 / 2m + U共q兲, the proof can be carried out immediately. The details Reference 3, pp. 263–264, paper 12.
81
of this proof can be found in Ref. 73. Heisenberg notes 共Ref. 3, p. 268, paper 12兲 that Eq. 共A11兲 is equivalent to
73
J. J. Prentis and W. A. Fedak, “Energy conservation in quantum mechan- the sum rule of Kuhn and Thomas 共Ref. 3, paper 11兲. For a discussion of
ics,” Am. J. Phys. 72, 580–590 共2004兲. Heisenberg’s development of the quantum condition, see Mehra and H.
74
Reference 3, p. 296, paper 13. Rechenberg, The Historical Development of Quantum Theory 共Springer,
75
M. Born, Problems of Atomic Dynamics 共MIT Press, Cambridge, 1970兲. New York, 1982兲, Vol. 2, pp. 243–245, and Ref. 14.

SCIENTIFIC APTITUDE AND AUTISM


There’s even some evidence that scientific abilities are associated with traits characteristic of
autism, the psychological disorder whose symptoms include difficulties in social relationships and
communication, or its milder version, Asperger syndrome. One recent study, for instance, exam-
ined different groups according to the Autism-Spectrum Quotient test, which measures autistic
traits. Scientists scored higher than nonscientists on this test, and within the sciences, mathema-
ticians, physical scientists, and engineers scored higher than biomedical scientists.

Sidney Perkowitz, Hollywood Science: Movies, Science, and the End of the World 共Columbia University Press, 2007兲,
p. 170.

139 Am. J. Phys., Vol. 77, No. 2, February 2009 William A. Fedak and Jeffrey J. Prentis 139

Downloaded 02 Oct 2012 to 136.159.235.223. Redistribution subject to AAPT license or copyright; see http://ajp.aapt.org/authors/copyright_permission

You might also like