Safety Data Sheet

A00331 COLLREPAIR DG
Revision date : 2016/11/28 Page: 1/10
Version: 1.1 (30598483/SDS_COS_MX/EN)

1. Identification

Product identifier used on the label

A00331 COLLREPAIR DG
Recommended use of the chemical and restriction on use
Recommended use*: cosmetics

* The “Recommended use” identified for this product is provided solely to comply with a Federal requirement and is not part of
the seller's published specification. The terms of this Safety Data Sheet (SDS) do not create or infer any warranty, express or
implied, including by incorporation into or reference in the seller's sales agreement.

Details of the supplier of the safety data sheet

Company:
BASF Mexicana S.A. de C.V.
Av. Insurgentes Sur 975
Col. CD. De Los Deportes, C.P. 03710,
MEXICO

Telephone: +52 55 5325 2600

Emergency telephone number

Tel.: +1-800-849-5204 or +1-833-229-1000

CHEMTREC Int.: +1-703-527-3887

Other means of identification

Chemical family: aqueous solution

2. Hazards Identification
According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200

Classification of the product

No need for classification according to GHS criteria for this product.

Label elements

The product does not require a hazard warning label in accordance with GHS criteria.
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Version: 1.1 (30598483/SDS_COS_MX/EN)
Hazards not otherwise classified

No specific dangers known, if the regulations/notes for storage and handling are considered.

Labeling of special preparations (GHS):

The following percentage of the mixture consists of components(s) with unknown hazards regarding
the acute toxicity: 1 - 3 % dermal
The following percentage of the mixture consists of components(s) with unknown hazards regarding
the acute toxicity: 0.5 - 1.5 % oral
The following percentage of the mixture consists of components(s) with unknown hazards regarding
the acute toxicity: 1 - 5 % Inhalation - vapour
The following percentage of the mixture consists of components(s) with unknown hazards regarding
the acute toxicity: 1 - 5 % Inhalation - mist

According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200

Emergency overview

CAUTION:
SKIN OR EYE CONTACT MAY CAUSE IRRITATION.

3. Composition / Information on Ingredients

According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200

CAS Number Weight % Chemical name

59-67-6 1.0 - 3.0% nicotinic acid
107-41-5 1.0 - 3.0% 2-methylpentane-2,4-diol

4. First-Aid Measures

Description of first aid measures

General advice:
Remove contaminated clothing. If adverse health effects develop seek medical attention.

If inhaled:
Keep patient calm, remove to fresh air.

If on skin:
Wash thoroughly with soap and water. If irritation develops, seek medical attention.

If in eyes:
Wash affected eyes for at least 15 minutes under running water with eyelids held open.

If irritation develops, seek medical attention.

If swallowed:
Rinse mouth and then drink plenty of water.

Do not induce vomiting. Seek medical attention.

Most important symptoms and effects, both acute and delayed

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Version: 1.1 (30598483/SDS_COS_MX/EN)
Symptoms: The most important known symptoms and effects are described in the labelling (see
section 2) and/or in section 11., Further important symptoms and effects are so far not known.
Hazards: No hazard is expected under intended use and appropriate handling.

Indication of any immediate medical attention and special treatment needed

Note to physician
Treatment: Symptomatic treatment (decontamination, vital functions).

5. Fire-Fighting Measures

Extinguishing media

Suitable extinguishing media:

water spray, foam, dry powder, carbon dioxide

Special hazards arising from the substance or mixture

Hazards during fire-fighting:
Product is not combustible or explosive.

Advice for fire-fighters

Protective equipment for fire-fighting:
Firefighters should be equipped with self-contained breathing apparatus and turn-out gear.

Further information:
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.

6. Accidental release measures

Personal precautions, protective equipment and emergency procedures

Information regarding personal protective measures see, section 8.

Environmental precautions
Do not discharge into drains/surface waters/groundwater. Discharge into the environment must be
avoided.

Methods and material for containment and cleaning up

For small amounts: Pick up with suitable absorbent material. Dispose of absorbed material in
accordance with regulations.
For large amounts: Dike spillage. Pick up with suitable appliance and dispose of.

7. Handling and Storage

Precautions for safe handling

Handle in accordance with good industrial hygiene and safety practice.

Protection against fire and explosion:

No special precautions necessary.

Conditions for safe storage, including any incompatibilities

Suitable materials for containers: High density polyethylene (HDPE), glass

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Version: 1.1 (30598483/SDS_COS_MX/EN)

Further information on storage conditions: Keep container tightly closed and dry; store in a cool
place. To be mixed before using. Close containers after use. Protect against heat.

Storage stability:
Storage temperature: 10 - 30 °C
Avoid freezing.

8. Exposure Controls/Personal Protection

Components with occupational exposure limits
2-methylpentane-2,4-diol Exposure CLV 25 ppm 125 mg/m3 ;
limits
NIOSH Ceil_Time 25 ppm 125 mg/m3 ;
Pocket Guide
to Chemical
Hazards (US)

Personal protective equipment

Respiratory protection:
Not applicable with adequate ventilation.

Hand protection:
Chemical resistant protective gloves

Eye protection:
Safety glasses with side-shields.

Body protection:
Body protection must be chosen based on level of activity and exposure.

General safety and hygiene measures:

Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink
and animal feeding stuffs.

9. Physical and Chemical Properties

Form: liquid
Odour: product specific
Odour threshold: not applicable
Colour: yellow to amber
pH value: 3.0 - 6.0 (internal method)
( 20 °C)
Boiling range: 90 - 110 °C
( 1,013 hPa)
Flash point: > 101 °C
Aqueous preparation The product has
not been tested.
Flammability: not flammable
Flammability of Aerosol not applicable, the product does not
Products: form flammable aerosoles
Lower explosion limit: For liquids not relevant for
classification and labelling.
Upper explosion limit: For liquids not relevant for
classification and labelling.
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Autoignition: not determined
Vapour pressure: not determined
Density: approx. 1 g/cm3 (internal method)
( 20 °C)
Vapour density: not applicable
Partitioning coefficient n- not determined
octanol/water (log Pow):
Self-ignition not self-igniting
temperature:
Thermal decomposition: No decomposition if stored and handled as
prescribed/indicated.
Viscosity, dynamic: not determined
Viscosity, kinematic: not determined
Solubility in water: ( 20 °C)
soluble
Evaporation rate: Value can be approximated from
Henry's Law Constant or vapor
pressure.
Other Information: If necessary, information on other physical and chemical
parameters is indicated in this section., No further information
available.

10. Stability and Reactivity

Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.

Chemical stability
The product is chemically stable.

Possibility of hazardous reactions

No hazardous reactions if stored and handled as prescribed/indicated.

Conditions to avoid
No special precautions other than good housekeeping of chemicals.

Incompatible materials
metal alloys

Hazardous decomposition products

Decomposition products:
Hazardous decomposition products: No hazardous decomposition products if stored and handled as
prescribed/indicated.

Thermal decomposition:
No decomposition if stored and handled as prescribed/indicated.

11. Toxicological information

Primary routes of exposure

Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin
contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route
of entry for liquefied gases.
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Acute Toxicity/Effects

Acute toxicity
Assessment of acute toxicity: Virtually nontoxic after a single ingestion. The product has not been
tested. The statement has been derived from the properties of the individual components.

Oral
Type of value: ATE
Value: > 5,000 mg/kg

Information on: nicotinic acid

Type of value: LD50
Species: rat
Value: > 5,000 mg/kg (OECD Guideline 401)
Literature data.

Information on: 2-methylpentane-2,4-diol

Type of value: LD50
Species: rat
Value: > 2,000 mg/kg (Guideline 92/69/EEC, B.1)
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Inhalation
Type of value: ATE
Value: > 20.0000 mg/l
Determined for vapor

Type of value: ATE

Value: > 5.0000 mg/l
Determined for mist

Dermal
Type of value: ATE
Value: > 5,000 mg/kg

Irritation / corrosion
Assessment of irritating effects: Not irritating to eyes and skin. The product has not been tested. The
statement has been derived from the properties of the individual components.

Skin

Information on: nicotinic acid

Species: rabbit
Result: non-irritant
Literature data.

Information on: 2-methylpentane-2,4-diol

The European Union (EU) has classified this substance with 'Irritating to skin' (R38).
----------------------------------

Eye

Information on: nicotinic acid

Species: rabbit
Result: Irritant.
Method: OECD Guideline 405
Literature data.
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Version: 1.1 (30598483/SDS_COS_MX/EN)
Information on: 2-methylpentane-2,4-diol
The European Union (EU) has classified this substance with 'Irritating to eyes'.(R36).
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Sensitization
Assessment of sensitization: Skin sensitizing effects were not observed in animal studies. The
product has not been tested. The statement has been derived from substances/products of a similar
structure or composition.

Species: In vitro assay

Result: Non-sensitizing.
Method: In vitro skin sensitization test battery

Chronic Toxicity/Effects

Repeated dose toxicity

Assessment of repeated dose toxicity: None known

Genetic toxicity
Assessment of mutagenicity: Mutagenicity tests revealed no genotoxic potential. The product has not
been tested. The statement has been derived from substances/products of a similar structure or
composition.
Genetic toxicity in vitro: OECD Guideline 471 Bacterial reverse mutation assay Salmonella
typhimurium:negative
Data of a comparable product

Carcinogenicity
Assessment of carcinogenicity: Based on the ingredients there is no suspicion of a carcinogenic
effect in humans.

Reproductive toxicity
Assessment of reproduction toxicity: The chemical structure does not suggest a specific alert for
such an effect.

Teratogenicity
Assessment of teratogenicity: The chemical structure does not suggest a specific alert for such an
effect.

Symptoms of Exposure

The most important known symptoms and effects are described in the labelling (see section 2)
and/or in section 11., Further important symptoms and effects are so far not known.

12. Ecological Information

Toxicity

Aquatic toxicity
Assessment of aquatic toxicity:
At the present state of knowledge, no negative ecological effects are expected. The product has not
been tested. The statement has been derived from the properties of the individual components.

Toxicity to fish

Information on: nicotinic acid

LC50 (96 h) 520 mg/l, Salmo trutta fario (L) (OECD Guideline 203, static)
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Version: 1.1 (30598483/SDS_COS_MX/EN)
The details of the toxic effect relate to the nominal concentration. The product will cause changes in
the pH value of the test system. The result refers to an unneutralized sample.

Information on: 2-methylpentane-2,4-diol

LC50 (96 h) 8,690 mg/l, Pimephales promelas (Flow through.)
The details of the toxic effect relate to the nominal concentration. Literature data.
----------------------------------

Aquatic invertebrates

Information on: nicotinic acid

EC50 (48 h) 77 mg/l, Daphnia magna (DIN 38412 Part 11, static)
The details of the toxic effect relate to the nominal concentration. The product will cause changes in
the pH value of the test system. The result refers to an unneutralized sample. After neutralization, it
is no longer toxic.

Information on: 2-methylpentane-2,4-diol

EC50 (48 h) 3,200 mg/l, Daphnia magna (OECD Guideline 202, part 1, static)
The details of the toxic effect relate to the nominal concentration. Literature data.
----------------------------------

Aquatic plants

Information on: nicotinic acid

EC50 (72 h) 105.67 mg/l (biomass), Scenedesmus subspicatus (DIN 38412 Part 9, static)
The details of the toxic effect relate to the nominal concentration. The product will cause changes in
the pH value of the test system. The result refers to an unneutralized sample. After neutralization a
reduction in harmful effect can be observed.

Information on: 2-methylpentane-2,4-diol

EC50 (72 h) > 430 mg/l (growth rate), Selenastrum capricornutum (OECD Guideline 201, static)
Nominal concentration.
----------------------------------

Persistence and degradability

Assessment biodegradation and elimination (H2O)

The product is biodegradable. The product has not been tested. The statement has been derived
from the properties of the individual components.

Elimination information

Information on: nicotinic acid

100 % DOC reduction (14 d) (OECD 301E/92/69/EEC, C.4-B) (aerobic, activated sludge)

Information on: 2-methylpentane-2,4-diol

60 - 70 % DOC reduction (28 d) (OECD 301E; 84/449/EEC, C.3) (aerobic, municipal sewage
treatment plant effluent)
Literature data.
90 - 100 % DOC reduction (28 d) (OECD Guideline 302 B) (aerobic, activated sludge)
Literature data.
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Bioaccumulative potential

Assessment bioaccumulation potential

Study not necessary due to exposure considerations.
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Version: 1.1 (30598483/SDS_COS_MX/EN)
Mobility in soil

Assessment transport between environmental compartments

Study not necessary due to exposure considerations.

Additional information

Other ecotoxicological advice:

The product has not been tested.

13. Disposal considerations

Waste disposal of substance:
Observe national and local legal requirements.

14. Transport Information

Land transport
TDG
Not classified as a dangerous good under transport regulations

Sea transport
IMDG
Not classified as a dangerous good under transport regulations

Air transport
IATA/ICAO
Not classified as a dangerous good under transport regulations

15. Regulatory Information

Federal Regulations

Not applicable

NFPA Hazard codes:

Health : 1 Fire: 1 Reactivity: 0 Special:

HMIS III rating

Health: 1 Flammability: 1 Physical hazard: (Essentially no hazard )

16. Other Information

SDS Prepared by:
BASF NA Product Regulations
SDS Prepared on: 2016/11/28
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Revision date : 2016/11/28 Page: 10/10
Version: 1.1 (30598483/SDS_COS_MX/EN)
We support worldwide Responsible Care® initiatives. We value the health and safety of our
employees, customers, suppliers and neighbors, and the protection of the environment. Our
commitment to Responsible Care is integral to conducting our business and operating our facilities in
a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring
the safe and environmentally sound handling of our products, and minimizing the impact of our
operations on society and the environment during production, storage, transport, use and disposal of
our products.

IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED

HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE , IT IS
PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT
PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU MAKE TESTS TO
DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR
TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING
WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE
MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET
FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED
WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE
SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED
A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY
UNDERSTAND AND AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION
FURNISHED BY OUR COMPANY HEREUNDER ARE GIVEN GRATIS AND WE ASSUME NO
OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION
GIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK.
END OF DATA SHEET