Fe3O4 + CO = 3 FeO + CO2

(T) (T) (T) (T)

_____ _ ___ _ ______ _ ___

T(K) Delta_H�(J) Delta_G�(J) Delta_Vol(litre) Delta_S�(J/K) Delta_Cp(J/K)

Keq T
_____________ ____________ ___________ ________________ _____________ _____________
__________ _

------ Fe3O4(s1) CO(g) FeO(s) CO2(g) ------

373.00 37151.5 18739.0 0.0000E+00 49.363 6.4762E-01

2.3762E-03
473.00 36740.7 13831.0 0.0000E+00 48.435 -9.4073E+00
2.9692E-02
573.00 35147.7 9121.1 0.0000E+00 45.422 -2.3221E+01
1.4742E-01
673.00 31901.4 4818.6 0.0000E+00 40.242 -4.2899E+01
4.2269E-01
773.00 26284.7 1157.7 0.0000E+00 32.506 -7.1069E+01
8.3516E-01
848.12 19925.0 -1001.8 0.0000E+00 24.674 -9.9394E+01
1.1526E+00
------ Fe3O4(s2) CO(g) FeO(s) CO2(g) ------

Fe3O4(1 mol): DH� = 1568.4 DG� = 0 ------ DS� = 1.849

848.12 18356.6 -1001.8 0.0000E+00 22.825 -1.1108E+01

1.1526E+00
873.00 18085.0 -1565.8 0.0000E+00 22.509 -1.0711E+01
1.2407E+00
973.00 17118.1 -3761.2 0.0000E+00 21.459 -8.4613E+00
1.5919E+00
1073.00 16422.3 -5869.8 0.0000E+00 20.775 -5.3219E+00
1.9308E+00
1173.00 16077.7 -7928.7 0.0000E+00 20.466 -1.4617E+00
2.2546E+00
1273.00 16149.7 -9975.1 0.0000E+00 20.522 2.9908E+00
2.5662E+00
1373.00 16692.3 -12044.9 0.0000E+00 20.930 7.9363E+00
2.8723E+00
_____________ ____________ ___________ ________________ _____________ _____________
__________ _