ganic and Physical Chemistry Test 2 2019 “SDUT ne cureay MOTUS as INSTRUCTIONAL OFFERING: OGANIC AND PHYSICAL CHEMISTRY SUBJECT CODE: OPCH101 DATE: 4 OCTOBER 2019 DURATION: 4 HOUR TIME: 14HO00 to 15HOO TOTAL MARKS: 50 SECTION B: 25 EXAMINER: PROF N. DEENADAYALU INSTRUCTIONS/REQUIREMENTS:- [1] WRITE YOUR SURNAME, INITIALS AND STUDENT NUMBER ON THE TOP LEFT HAND SIDE OF THE FOOLSCAP PAPER PROVIDED. [2] ANSWER ALL QUESTIONS. [3] SCIENTIFIC CALCULATORS MAY BE USED. CHEMICAL EQUILIBRIUM 113] QUESTION 1 iO 14 Give a suitable explanation/reason for the following statements: 1.1.1 the concentration of solid or liquid is not included in the equilibrium constant expression, (1) Reason: The cone. of the liquid stays the same and if a solid is used both the amount and volume changes keeping its conc the same. 4.1.2. For the reaction below S02 (g) + energy ——* S (s) + O29) an increase in temperature causes the concentration of SOz (9) to decrease. a Reason: An increase in temp for an endothermic reaction causes the reaction to shift to the right. ‘Therefore more SOz (g) is used and its concentration decreases. 1.1.3. A catalyst has no effect on the equilibrium position. ay Reason: A catalyst effects both the rates of the forward and reverse reaction and will not affect the equilibrium position 4.1.4 Anincrease in pressure changes the direction of the reaction to fewer number of gaseous molecules in a reaction at equilibrium. (ay Reason: When pressure increases, volume decreases, the concentration increases, affecting the Q. value. The side that has greater gaseous moles increases more to offset this the reaction moves to the side with fewer gaseous molesCaCOs (s) —-> €a0 (s) + CO2(g) Calculate Ke for the reaction. Kp = Poe = 0.105 Ke (0.0821 x T} 0.105 (0.0821 x 623)(1-) = 205x103 1.3 The solubility of a compound MXz of molar mass 346 g/mol is 4.63 x 10° g/L. Calculate the solubility product, Kep, for the compound MX. MX (s) | ——> MP" (aq) + 2X"- (aq) SY s s 2s Molar solubility (s) of MX2 4.63 x 10° g/L 346 wey 1.34 10 mol/L mye if [IM] pny VW (1.34 x 10%) (2 x 1.34 x 105)2 = (1.34104) (268x105 = 962x104 Jganic and Physical Chemists Test2 QUESTION 2 COLLIGATIVE PROPERTIES 241 Define osmosis. (1) Selective passage of solvent molecules ~ semi permeable membrane — from dilute to cone. Soin. Explain how the colligative property freezing point depression is applied in cold countries. (2) Use of salt on roads to lower Tf so ice isn’t formed Use of ethylene glycol in radiators to prevent water from freezing A solution of 6.85 g of a carbohydrate in 100 g of water has a density of 1.024 g Jom? and an osmotic pressure of 4.61 atm at T= 20.0 °C. Calculate the molar mass of the carbohydrate. © T MRT WRT 4.61 atm! {(0.0821 L atm /K mol) x 293)} 0.192 mol/L. a “\- Mass of soln, (6.85 g + 1009) _ 10899 Vol of soln mass/density M 108.9 g /1.024 g /em3 0.1044 L a mol/vol in L Moles CH (0.1044 L x 0.192 mol/L) 0.0200 mol mass/Molar mass Molar mass mass/moles 6.85 g CH/0.0200 mol 343 g/mol aOrganic and Physical Chemist Test2 2019 2.4 An aqueous solution containing an amino acid freezes at -2.5 °C. The molal freezing point of water, Ki, is 1.86 °C/m. Calculate the molality of the solution, (3) ATs ATeovex = ATeoin os [0-¢-2.5)]°C 2.5°C Kixm AT Ke a 2511.86 1.34 " END OF QUESTION PAPER DATA SHEET CONSTANTS: tat 101.325 kPa 4 atm 760mmHg = — 760torr 1 Faraday ( 96 500 C mot . Universal Gas Constant(R) = ~—_0.082087 L atm mol* K 314 J Kt molt FORMULAE ah mK AP XsoluteP solvent Ko Ke (Rx T)2" 7 MRT