Explain [Co(NH ) ] is an inner orbital complex whereas [Ni(NH ) ] is an outer orbital complex.

Oxidation state of cobalt = +3 Oxidation state of Ni = +2

Electronic configuration of cobalt = d Electronic configuration of nickel = d
NH being a strong field ligand causes the pairing. Therefore, Ni can undergo d sp hybridization.
Hence, it is an inner orbital complex.
If NH causes the pairing, then only one 3 d orbital is empty. Thus, it cannot undergo d sp
hybridization. Therefore, it undergoes sp d hybridization.
Hence, it forms an outer orbital complex.
67% users found this answer helpful.
More Questions from Coordination Compounds
[NiCl ] is paramagnetic while [Ni(CO) ] is diamagnetic though both are tetrahedral. Why?
find oxidation no of Fe in Fe4[Fe(CN)6]3
What is the seris of IRVING WILLIAM STABILITY ORDER........
Explain on the basis of valence bond theory that...
3 6 3+
3 6 2+
2 Follow 0
68
3233
23
32
4 2− 4
2 Answers 1
1 Answers 1
1 Answers 4
3 Answers 1
View All Questions